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11.
Lars A. Olsen Tonci Balic-Zunic Emil Makovicky Angela Ullrich Ronald Miletich 《Physics and Chemistry of Minerals》2007,34(7):467-475
A single-crystal sample of galenobismutite was subjected to hydrostatic pressures in the range of 0.0001 and 9 GPa at room temperature using the diamond-anvil cell technique. A series of X-ray diffraction intensities were collected at ten distinct pressures using a CCD equipped 4-circle diffractometer. The crystal structure was refined to R1(|F0| > 4σ) values of approximately 0.05 at all pressures. By fitting a third-order Birch-Murnaghan equation of state to the unit-cell volumes V 0 = 700.6(2) Å3, K 0 = 43.9(7) GPa and dK/dP = 6.9(3) could be determined for the lattice compression. Both types of cations in galenobismutite have stereochemically active lone electron pairs, which distort the cation polyhedra at room pressure. The cation eccentricities decrease at higher pressure but are still pronounced at 9 GPa. Galenobismutite is isotypic with CaFe2O4 (CF) but moves away from the idealised CF-type structure during compression. Instead of the two octahedral cation sites and one bi-capped trigonal-prismatic site, PbBi2S4 attains a new high-pressure structure characterised by one octahedral site and two mono-capped trigonal-prismatic sites. Analyses of the crystal structure at high pressure confirm the preference of Bi for the octahedral site and the smaller one of the two trigonal-prismatic sites. 相似文献
12.
J. Escuder Viruete M. Joubert P. Urien R. Friedman D. Weis T. Ullrich A. Prez-Estaún 《Lithos》2008,104(1-4):378-404
We present new regional petrologic, geochemical, Sr–Nd isotopic, and U–Pb geochronological data on the Turonian–Campanian mafic igneous rocks of Central Hispaniola that provide important clues on the development of the Caribbean island-arc. Central Hispaniola is made up of three main tectonic blocks—Jicomé, Jarabacoa and Bonao—that include four broad geochemical groups of Late Cretaceous mafic igneous rocks: group I, tholeiitic to calc-alkaline basalts and andesites; group II, low-Ti high-Mg andesites and basalts; group III, tholeiitic basalts and gabbros/dolerites; and group IV, tholeiitic to transitional and alkalic basalts. These igneous rocks show significant differences in time and space, from arc-like to non-arc-like characteristics, suggesting that they were derived from different mantle sources. We interpret these groups as the record of Caribbean arc-rifting and back-arc basin development in the Late Cretaceous. The> 90 Ma group I volcanic rocks and associated cumulate complexes preserved in the Jicomé and Jarabacoa blocks represent the Albian to Cenomanian Caribbean island-arc material. The arc rift stage magmatism in these blocks took place during the deposition of the Restauración Formation from the Turonian–Coniacian transition (~ 90 Ma) to Santonian/Lower Campanian, particularly in its lower part with extrusion at 90–88 Ma of group II low-Ti, high-Mg andesites/basalts. During this time or slightly afterwards adakitic rhyolites erupted in the Jarabacoa block. Group III tholeiitic lavas represent the initiation of Coniacian–Lower Campanian back-arc spreading. In the Bonao block, this stage is represented by back-arc basin-like basalts, gabbros and dolerite/diorite dykes intruded into the Loma Caribe peridotite, as well as the Peralvillo Sur Formation basalts, capped by tuffs, shales and Campanian cherts. This dismembered ophiolitic stratigraphy indicates that the Bonao block is a fragment of an ensimatic back-arc basin. In the Jicomé and Jarabacoa blocks, the mainly Campanian group IV basalts of the Peña Blanca, Siete Cabezas and Pelona–Pico Duarte Formation, represent the subsequent stage of back-arc spreading and off-axis non-arc-like magmatism, caused by migration of the arc toward the northeast. These basalts have geochemical affinities with the mantle domain influenced by the Caribbean plume, suggesting that mantle was flowing toward the NE, beneath the extended Caribbean island-arc, in response to rollback of the subducting proto-Caribbean slab. 相似文献
13.
Angela Ullrich Wilfried Schranz Ronald Miletich 《Physics and Chemistry of Minerals》2009,36(10):545-555
The high-pressure behavior of the lattice elasticity of spodumene, LiAlSi2O6, was studied by static compression in a diamond-anvil cell up to 9.3 GPa. Investigations by means of single-crystal XRD and
Raman spectroscopy within the hydrostatic limits of the pressure medium focus on the pressure ranges around ~3.2 and ~7.7 GPa,
which have been reported previously to comprise two independent structural phase transitions. While our measurements confirm
the well-established first-order C2/c–P21/c transformation at 3.19 GPa (with 1.2% volume discontinuity and a hysteresis between 0.02 and 0.06 GPa), both unit-cell dimensions
and the spectral changes observed in high-pressure Raman spectra give no evidence for structural changes related to a second
phase transition. Monoclinic lattice parameters and unit-cell volumes at in total 59 different pressure points have been used
to re-calculate the lattice-related properties of spontaneous strain, volume strain, and the bulk moduli as a function of
pressure across the transition. A modified Landau free energy expansion in terms of a one component order parameter has been
developed and tested against these experimentally determined data. The Landau solution provides a much better reproduction
of the observed anomalies than any equation-of-state fit to data sets truncated below and above P
tr, thus giving Landau parameters of K
0 = 138.3(2) GPa, K′ = 7.46(5), λ
V
= 33.6(2) GPa, a = 0.486(3), b = −29.4(6) GPa and c = 551(11) GPa. 相似文献
14.
Clivia?HejnyEmail author Raffaela?Sagl Daniel?M.?T?bbens Ronald?Miletich Manfred?Wildner Lutz?Nasdala Angela?Ullrich Tonci?Balic-Zunic 《Physics and Chemistry of Minerals》2012,39(5):399-412
The structure of realgar, As4S4, and its evolution with pressure have been investigated employing in situ X-ray diffraction, optical absorption and vibrational spectroscopy on single-crystal samples in diamond-anvil cells. Compression under true hydrostatic conditions up to 5.40 GPa reveals equation-of-state parameters of V 0 = 799.4(2.4) Å3 and K 0 = 10.5(0.4) GPa with \(K_0^\prime\) = 8.7. The remarkably high compressibility can be attributed to a denser packing of the As4S4 molecules with shortening of the intermolecular bonds of up to 12 %, while the As4S4 molecules remain intact showing rigid-unit behaviour. From ambient pressure to 4.5 GPa, Raman spectra exhibit a strong blue shift of the Raman bands of the lattice-phonon regime of 24 cm–1, whereas frequencies from intramolecular As-S stretching modes show negligible or no shifts at all. On pressurisation, realgar shows a continuous and reversible colour change from bright orange over deep red to black. Optical absorption spectroscopy shows a shift of the absorption edge from 2.30 to 1.81 eV up to 4.5 GPa, and DFT calculations show a corresponding reduction in the band gap. Synchrotron-based measurements on polycrystalline samples up to 45.5 GPa are indexed according to the monoclinic structure of realgar. 相似文献
15.
The first laser-induced 40Ar-39Ar incremental-heating mineral age data for the Timok Massif of the Banatitic Magmatic and Metallogenetic Belt (BMMB) demonstrate that the main mineralization stage at the giant Majdanpek Cu–Au(–Mo) porphyry deposit took place at 83.6–84.0±0.6 Ma (2), coinciding with the later, 83±1–89.0±0.6 Ma, stages of the first cycle of andesitic volcanism. The earliest-Campanian age for hydrothermal activity precludes an association with the later history of the BMMB, and discounts the metallogenetic role of Laramide plutonism for the dated deposits.Editorial handling: A. Cheilletz 相似文献
16.
M. John S. Heuss-Aßbichler A. Ullrich 《International Journal of Environmental Science and Technology》2016,13(9):2127-2134
In this study, a facile precipitation process to treat wastewater from zinc plating industry is presented. Water purification rates of Zn range between 96.40 % and 99.99 % depending on the reaction conditions. Optimal results are gained at a low pH value of 9, low temperature of 40 °C and a fast alkalization using NaOH solution containing 16 % pure NaOH. Traces of Ni, Fe, Zn, Cu and Cr present in the wastewater were almost completely removed. The precipitates were analysed by X-ray diffraction, infrared and Raman spectroscopy, electron microscopy and magnetic measurements. They consist of doped ZnO as a main phase. Although ZnO exclusively crystallizes in nanoparticle size, the morphology is directly influenced by the experimental parameters. Additionally, very small amounts of ZnCO3 and Zn(OH)2 were detected. Magnetic investigations indicate the incorporation of Ni and Fe into the ZnO lattice. The measured saturation magnetization is ~0.01 emu/g and the Curie temperature is ~75 °C. 相似文献
17.
One‐dimensional expression to calculate specific yield for shallow groundwater systems with microrelief 
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下载免费PDF全文 Although the importance to account for microrelief in the calculation of specific yields for shallow groundwater systems is well recognized, the microrelief influence is often treated very simplified, which can cause considerable errors. We provide a general one‐dimensional expression that correctly represents the effect of a microrelief on the total specific yield that is composed of the soil and surface specific yield. The one‐dimensional expression can be applied for different soil hydraulic parameterizations and soil surface elevation frequency distributions. Applying different van Genuchten parameters and a simple linear microrelief model, we demonstrate that the specific yield is influenced by the microrelief not only when surface storage directly contributes to specific yield by (partial) inundation but also when water levels are lower than the minimum surface elevation. Compared with a simplified representation of the soil specific yield, in which a mean soil surface is assumed for the calculation of soil specific yield, the correct representation can lead to lower as well as higher soil specific yields depending on the specific interaction of the soil water retention characteristics and the microrelief. The new equation can be used to obtain more accurate evapotranspiration estimates from water level fluctuations and to account for the effect of microtopographic subgrid variability on simulated water levels of spatially distributed hydrological models. Copyright © 2015 The Authors Hydrological Processes Published by John Wiley & Sons Ltd 相似文献
18.
Ali Elmas İsak Yılmaz Erdinç Yiğitbaş Thomas Ullrich 《International Journal of Earth Sciences》2011,100(6):1251-1263
In the eastern part of the Strandja Massif constituting the east end of the Rhodope Massif, the amphibolite facies basement
rocks intruded by Permian metagranites are juxtaposed against the greenschist facies cover metasediments of Triassic-Middle
Jurassic protolith age. The distinct metamorphic break between the basement and cover rocks requires a missing metamorphic
section. The boundary between the two groups of rocks is a ductile to brittle extensional shear zone with kinematic indicators
exhibiting a top to the E/NE shear sense. Footwall rocks are cut by weakly metamorphosed and foliated granite bodies which
are clearly distinguished from the Permian metagranites by their degree of deformation, cross-cutting relations and syn-tectonic/kinematic
character. Also, hangingwall rocks were intruded by unmetamorphosed and weakly foliated leucogranites. 40Ar/39Ar data indicate that the ductile deformation from 156.5 to 143.2 Ma (Middle Oxfordian-Earliest Berriasian) developed during
the syn-tectonic plutonism in the footwall. Deformation, and gradual/slower cooling-exhumation survived until to 123 Ma (Barremian).
The mylonitic and brittle deformation in the detachment zone developed during Oxfordian-Earliest Berriasian time (155.7–142.6 Ma)
and Early Valanginian-Aptian time (136–118.7 Ma), respectively. Our new field mapping and first 40Ar/39Ar ages demonstrate the existence of an extensional core complex of Late Jurassic-Early Cretaceous age not previously described
in the Rhodope/Strandja massifs. 相似文献
19.
Thomas Bissig Thomas D. Ullrich Richard M. Tosdal Richard Friedman Shane Ebert 《Journal of South American Earth Sciences》2008,26(1):16-35
Eocene to late Miocene magmatism in the central Peruvian high-plain (approx. between Cerro de Pasco and Huancayo; Lats. 10.2–12°S) and east of the Cordillera Occidental is represented by scattered shallow-level intrusions as well as subaerial domes and volcanic deposits. These igneous rocks are calc-alkalic and range from basalt to rhyolite in composition, and many of them are spatially, temporally and, by inference, genetically associated with varied styles of major polymetallic mineralization. Forty-four new 40Ar–39Ar and three U/Pb zircon dates are presented, many for previously undated intrusions. Our new time constraints together with data from the literature now cover most of the Cenozoic igneous rocks of this Andean segment and provide foundation for geodynamic and metallogenetic research.The oldest Cenozoic bodies are of Eocene age and include dacitic domes to the west of Cerro de Pasco with ages ranging from 38.5 to 33.5 Ma. South of the Domo de Yauli structural dome, Eocene igneous rocks occur some 15 km east of the Cordillera Occidental and include a 39.34 ± 0.28 Ma granodioritic intrusion and a 40.14 ± 0.61 Ma rhyolite sill, whereas several diorite stocks were emplaced between 36 and 33 Ma. Eocene mineralization is restricted to the Quicay high-sulfidation epithermal deposit some 10 km to the west of Cerro de Pasco.Igneous activity in the earliest Oligocene was concentrated up to 70 km east of the Cordillera Occidental and is represented by a number of granodioritic intrusions in the Milpo–Atacocha area. Relatively voluminous early Oligocene dacitic to andesitic volcanism gave rise to the Astabamba Formation to the southeast of Domo de Yauli. Some stocks at Milpo and Atacocha generated important Zn–Pb (–Ag) skarn mineralization. After about 29.3 Ma, magmatism ceased throughout the study region. Late Oligocene igneous activity was restricted to andesitic and dacitic volcanic deposits and intrusions around Uchucchacua (approx. 25 Ma) and felsic rocks west of Tarma (21–20 Ma). A relationship between the Oligocene intrusions and polymetallic mineralization at Uchucchacua is possible, but evidence remains inconclusive.Widespread magmatism resumed in the middle Miocene and includes large igneous complexes in the Cordillera Occidental to the south of Domo de Yauli, and smaller scattered intrusive centers to the north thereof. Ore deposits of modest size are widely associated with middle Miocene intrusions along the Cordillera Occidental, north of Domo de Yauli. However, small volcanic centers were also active up to 50 km east of the continental divide and include dacitic dikes and domes, spatially associated with major base and precious metal mineralization at Cerro de Pasco and Colquijirca. Basaltic volcanism (14.54 ± 0.49 Ma) is locally observed in the back-arc domain south of Domo de Yauli approximately 30 km east of the Cordillera Occidental.After about 10 Ma intrusive activity decreased throughout Central Perú and ceased between 6 and 5 Ma. Late Miocene magmatism was locally related to important mineralization including San Cristobal (Domo de Yauli), Huarón and Yauricocha.Overall, there is no evidence for a systematic eastward migration of the magmatic arc through time. The arc broadened in the late Eocene to early Oligocene, and thereafter ceased over wide areas until the early Miocene, when magmatism resumed in a narrow arc. A renewed widening and subsequent cessation of the arc occurred in the late middle and late Miocene. The pattern of magmatism probably reflects two cycles of flattening of the subduction in the Oligocene and late Miocene. Contrasting crustal architecture between areas south and north of Domo de Yauli probably account for the differences in the temporal and aerial distribution of magmatism in these areas.Ore deposits are most abundant between Domo de Yauli and Cerro de Pasco and were generally emplaced in the middle and late Miocene during the transition to flat subduction and prior to cessation of the arc. Eocene to early Oligocene mineralization also occurred, but was restricted to a broad east–west corridor from Uchucchacua to Milpo–Atacocha, indicating a major upper-plate metallogenetic control. 相似文献
20.
Pascal Schouwink Ronald Miletich Angela Ullrich Ulrich A. Glasmacher Christina Trautmann Reinhard Neumann Barry P. Kohn 《Physics and Chemistry of Minerals》2010,37(6):371-387
Static elasticity measurements at high pressures were carried out on oriented fluorapatite single crystals, some of which
contained oriented amorphous ion tracks (ITs) implanted with relativistic Au ions (2.2 GeV) from the UNILAC linear accelerator
at GSI, Darmstadt. High-pressure experiments on irradiated and non-irradiated crystal sections were carried out in diamond-anvil
high-pressure cells under hydrostatic conditions. In situ single-crystal diffraction was performed to determine the high-precision
lattice parameters, simultaneously monitoring the widths of X-ray diffraction Bragg peaks. High-pressure Raman spectra were
analyzed with respect to the frequency shift and widths of bands, which correspond to the Raman-active vibrational modes of
the phosphate tetrahedra. Swift heavy ion irradiation was found to induce anisotropic lattice expansion and tensile strain
within the host lattice dependent on the ion-track orientation. The relatively low Grüneisen parameter for the ν
1b(A
g) mode, which has been assigned to originate from the volume fraction of the amorphous tracks, and the γ(ν
1a)/γ(ν
1b) ratio reveals compressive strain on the amorphous ITs. The comparative compressibilities for the host lattice reveal approximately
equivalent bulk moduli, but significantly different pressure derivatives (K
T = 88.4 ± 0.7 GPa, ∂K/∂P = 6.3 ± 0.3 for non-irradiated, K
T = 90.0 ± 1.7 GPa, ∂K/∂P = 3.8 ± 0.5 for irradiated samples). The axial compressibility moduli β
−1 reveal significant differences, which correlate with the ion-track orientation [ba - 1 \beta_{a}^{ - 1} = 240 ± 5 GPa, bc - 1 \beta_{c}^{ - 1} = 361 ± 14 GPa, ∂( ba - 1 ) \left( {\beta_{a}^{ - 1} } \right) /∂P = 11.3 ± 1.2, ∂( bc - 1 ) \left( {\beta_{c}^{ - 1} } \right) /∂P = 11.6 ± 3.4 for irradiation ⊥(100); 246 ± 9 GPa, 364 ± 57 GPa, 9.5 ± 2.9, 14.7 ± 14.1 for irradiation ⊥(001), 230.7 ± 3.6 GPa,
373.5 ± 5.1 GPa, 19.2 ± 1.4, 20.1 ± 1.8 for no irradiation]. Line widths of XRD Bragg peaks in irradiated apatites confirm
the strain of the host lattice, which appears to decrease with increasing pressure. By contrast, the bandwidths of Raman modes
increase with pressure, and this is attributed to increasing strain gradients on the length scale of the short-range order.
The investigations reveal considerable deviatoric stress on the [100]-oriented tracks due to the anisotropic elasticity, while
the compression is uniform for the directions perpendicular to the tracks, which are aligned parallel to the c-axis. This difference might be considered to control the diffusion properties related to the annealing kinetics and its observed
anisotropy, and hence to cause potential pressure effects on track-fading rates. 相似文献