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21.
I.TheProcessofAdministrativeDivisionSystemChanges(ADSC)Therelationshipbetweenthechangesinadministrativedivisionsystemandurbanizationprocessmain1ydisplaysinthemutualtransferringbetweenurbanandruralareas.Thiskindoftransferringisduetotheadjustmentoftheadm… 相似文献
22.
Mobility of Al, Co, Cr, Cu, Fe, Mn, Ni and V in sulphide-bearing fine-grained sediments exposed to atmospheric O2: an experimental study 总被引:1,自引:0,他引:1
Mats Åström 《Environmental Geology》1998,36(3-4):219-226
The major aim was to increase our knowledge on the behaviour of Al, Co, Cr, Cu, Fe, Mn, Ni and V in sulphide-bearing fine-grained
sediments exposed to atmospheric oxygen. Samples of this type of sediment collected in a previous investigation at eight sites
in western Finland were digested in HClO4-HNO3-HCl-HF at 200 °C and in HCl:HNO3:H2O at 95 °C (aqua regia), and subjected to extractions with ammonium acetate and hydrogen peroxide. Metals and S in the leachates
were determined with ICP-AES. The results of the chemical analyses are compared with previously reported experimental data.
The concentrations of Al and Fe in the sulphide-bearing fine-grained sediments are about 7% and 5%, respectively. Of the trace
metals studied, Mn is most abundant followed in decreasing order by V>Cr>Ni>Cu>Co. On oxidation of the sediments, high proportions
of Co, Mn and Ni, intermediate proportions of Cu but low proportions of Fe, Al, Cr and V are released. The extent of the release
of a metal on oxidation is controlled either by (1) the level to which the pH of the sediments drops on oxidation (Al, Cu,
Cr, V), (2) the amount of the metal associated with easily reduced phases (metal sulphides) in the sediments (Ni, Co) or (3)
the sum of the amount associated with reduced phases and adsorbed on soil compounds (Mn). No control of the release of Fe
on oxidation of the sediments was identified. Based on the results of the study it is argued that artificial drainage and
the subsequent oxidation of sulphide-bearing sediments will result in extensive leaching of Co, Mn and Ni, moderate leaching
of Cu and limited leaching of Cr and V into drainages. The major elements, Fe and Al, have the potential to be mobilised and
leached in large amounts, though the proportions mobilised/leached will remain low. It is suggested that the identification
of sulphide-bearing sediments with a high potential of metal release should be based on determination of metals in easily
mobilised reduced compounds (dissolved e.g. in H2O2) and of the level to which the pH of the sediments drops on oxidation.
Received: 16 October 1997 · Accepted: 9 March 1998 相似文献
23.
Linda J. Alakangas Frédéric A. Mathurin Mikko Faarinen Bill Wallin Mats E. Åström 《Aquatic Geochemistry》2014,20(4):405-418
Several countries are preparing to dispose of radioactive nuclear waste deep underground in crystalline rock. This type of bedrock is commonly extensively fractured and consequently carries groundwater that serves as a medium for transporting metals and radionuclides. A group of metals of particular interest in this context is the rare earth elements (REEs), because they are analogues of actinides contained within radioactive waste and are tracers of hydrological pathways and geochemical processes. Concentrations of REEs are commonly low in these groundwaters, leading to values below detection limits of standard monitoring methods, particularly for the heavy REEs. We present a new technical set-up for monitoring REEs (and other trace metals) in groundwater in fractured crystalline rock. The technique consists of passing the fracture groundwater, commonly under high pressure and containing reduced chemical species, through a device that maintains the physicochemical character of the groundwater. Within the device, diffusive gradient in thin-film (DGT) discs are installed in triplicate. With this set-up, we studied REEs in groundwater in fractures at depths of approximately ?144, ?280, and ?450 m in granitoids in the Äspö Hard Rock Laboratory in southern Sweden. The entire REE suite was detected (concentrations down to 0.1 ng L?1) and was differently fractionated among the groundwaters. The shallowest groundwater, composed of dilute modern Baltic Sea water, was enriched in the heavy REEs, whereas the deeper groundwaters, dominated by old saline water, were depleted in the heavy REEs. Deployment periods varying from 1 to 4 weeks delivered similar REE concentrations, indicating stability and reproducibility of the experimental set-up. The study finds that 1 week of deployment may be enough. However, if the overall setting and construction allow for longer deployment times, 2–3 weeks will be optimal in terms of reaching reliable REE concentrations well above the detection limit while maintaining the performance of the DGT samplers. 相似文献
24.
Nils Perttu Kamhaeng Wattanasen Khamphouth Phommasone Sten-Åke Elming 《Journal of Applied Geophysics》2011,73(3):207-220
The aim of this study is to define and characterize water bearing geological formation and to test the possibility of using geophysical techniques to determine the hydrogeological parameters in three areas in the Vientiane basin, Laos. The investigated areas are part of the Khorat Plateau where halite is naturally occurring at depths as shallow as 50 m in the Thangon Formation. Magnetic Resonance Sounding (MRS) has been used in combination with Vertical Electrical Sounding (VES) in different geological environments. In total, 46 sites have been investigated and the MRS and VES recognized the stratigraphic unit N2Q1–3, consisting of alluvial unconsolidated sediments, as the main water bearing unit. The aquifer thickness varies usually between 10 and 40 m and the depth to the main aquifer range from 5 to 15 m. The free water content is here up to 30%, and the decay times vary between 100 and 400 ms, suggesting a mean pore size equivalent to fine sand to gravel. The resistivity is highly variable, but usually around 10–1500 Ω-m, except for some sites in areas 1 and 2, where the aquifer is of low resistivity, probably related to salt water. Hydraulic and storage-related parameters such as transmissivity, hydraulic column, have been estimated from the MRS. The MRS together with VES has been shown to be a useful and important tool for identifying and distinguishing freshwater from possible salt-affected water as well as the salt-related clay layer of the Thangon Formation. This clay layer is characterized by very low free water content and a resistivity lower than 5 Ω-m and can be found in all 3 areas at depths from 15 to 50 m. 相似文献
25.
If we are to limit global warming to 2 °C, all sectors in all countries must reduce their emissions of GHGs to zero not later than 2060–2080. Zero-emission options have been less explored and are less developed in the energy-intensive basic materials industries than in other sectors. Current climate policies have not yet motivated major efforts to decarbonize this sector, and it has been largely protected from climate policy due to the perceived risks of carbon leakage and a focus on short-term reduction targets to 2020. We argue that the future global climate policy regime must develop along three interlinked and strategic lines to facilitate a deep decarbonization of energy-intensive industries. First, the principle of common but differentiated responsibility must be reinterpreted to allow for a dialogue on fairness and the right to development in relation to industry. Second, a greater focus on the development, deployment and transfer of technology in this sector is called for. Third, the potential conflicts between current free trade regimes and motivated industrial policies for deep decarbonization must be resolved. One way forward is to revisit the idea of sectoral approaches with a broader scope, including not only emission reductions, but recognizing the full complexity of low-carbon transitions in energy-intensive industries. A new approach could engage industrial stakeholders, support technology research, development and demonstration and facilitate deployment through reducing the risk for investors. The Paris Agreement allows the idea of sectoral approaches to be revisited in the interests of reaching our common climate goals.Policy relevanceDeep decarbonization of energy-intensive industries will be necessary to meet the 2 °C target. This requires major innovation efforts over a long period. Energy-intensive industries face unique challenges from both innovation and technical perspectives due to the large scale of facilities, the character of their global markets and the potentially high mitigation costs. This article addresses these challenges and discusses ways in which the global climate policy framework should be developed after the Paris Agreement to better support transformative change in the energy-intensive industries. 相似文献
26.
27.
Claudio Arias Giulio Bigazzi Francescopaolo Bonadonna Karl Brunnacker Brigitte Urban 《Quaternary Science Reviews》1984,3(1):73-89
Biostratigraphic and palaeomagnetic research has been carried out on selected profiles in North-Western Germany and Central Italy in order to correlate Plio-Pleistocene sections.Around the Réunion subchronozone, vegetation in the Valle Ricca was dominated by a mountain forest type pointing to cool climatic conditions. In the Lower Rhine Basin vegetation had a slightly warmer character, but was also dominated strongly by a mountain type of forest vegetation, characteristic of cooler summers and higher precipitation than at present.Two warmer periods have been determined in the Central Italian profiles; the youngest around the Olduvai reversal, should correspond to the youngest Tiglian beds of the Lower Rhine Basin.Deposits older than the Réunion subzone have not been found in the Valle Ricca. In the Lower Rhine Basin, on the other hand, the Gauss-Matuyama boundary is located between the uppermost Pliocene, the Reuverian C and the Praetiglian. 相似文献
28.
A. Urban 《Astrophysics and Space Science》1982,83(1-2):3-14
Criteria for selecting continuous channel electron multipliers were applied to fifteen Mullard units without significantly affecting their overall lifetime. The gain fatigue vs accumulated counts, the change of the pulse height distribution during lifetime, the gain degradation vs count rates as well as the gain vs operating voltage and the resolution vs operating voltage have been investigated using a tritium source. The results provide several criteria to determine good, marginal and poor multipliers. From all tested devices 25% had a very low gain and did not operate satisfactory at the end of their lifetime investigations (4×109 accumulated counts). 40% of all devices could be classified as good multipliers. Their main characteristic was a gain recovery phenomenon after 3×109 accumulated counts with a progressive gain stabilizing. Multipliers classified as marginal exhibited some unexpected behaviour during the lifetime but a gain recovery phase and gain plateau region could be identified. Furthermore, the relative efficiency of the multipliers vs electron energy as a function of the operating voltage has been measured by using a near monoenergetic electron beam.Originally submitted to the journalSpace Science Instrumentation. 相似文献
29.
Transboundary impacts on regional ground water modeling in Texas 总被引:1,自引:0,他引:1
Recent legislation required regional grassroots water resources planning across the entire state of Texas. The Texas Water Development Board (TWDB), the state's primary water resource planning agency, divided the state into 16 planning regions. Each planning group developed plans to manage both ground water and surface water sources and to meet future demands of various combinations of domestic, agricultural, municipal, and industrial water consumers. This presentation describes the challenges in developing a ground water model for the Llano Estacado Regional Water Planning Group (LERWPG), whose region includes 21 counties in the Southern High Plains of Texas. While surface water is supplied to several cities in this region, the vast majority of the regional water use comes from the High Plains aquifer system, often locally referred to as the Ogallala Aquifer. Over 95% of the ground water demand is for irrigated agriculture. The LERWPG had to predict the impact of future TWDB-projected water demands, as provided by the TWDB, on the aquifer for the period 2000 to 2050. If detrimental impacts were noted, alternative management strategies must be proposed. While much effort was spent on evaluating the current status of the ground water reserves, an appropriate numerical model of the aquifer system was necessary to demonstrate future impacts of the predicted withdrawals as well as the effects of the alternative strategies. The modeling effort was completed in the summer of 2000. This presentation concentrates on the political, scientific, and nontechnical issues in this planning process that complicated the modeling effort. Uncertainties in data, most significantly in distribution and intensity of recharge and withdrawals, significantly impacted the calibration and predictive modeling efforts. Four predictive scenarios, including baseline projections, recurrence of the drought of record, precipitation enhancement, and reduced irrigation demand, were simulated to identify counties at risk of low final ground water storage volume or low levels of satisfied demand by 2050. 相似文献
30.
Deep massive sulphide exploration using 2D and 3D geoelectrical and induced polarization data in Skellefte mining district,northern Sweden
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Saman Tavakoli Tobias E. Bauer Thorkild M. Rasmussen Pär Weihed Sten‐Åke Elming 《Geophysical Prospecting》2016,64(6):1602-1619
Geoelectrical and induced polarization data from measurements along three profiles and from one 3D survey are acquired and processed in the central Skellefte District, northern Sweden. The data were collected during two field campaigns in 2009 and 2010 in order to delineate the structures related to volcanogenic massive sulphide deposits and to model lithological contacts down to a maximum depth of 1.5 km. The 2009 data were inverted previously, and their joint interpretation with potential field data indicated several anomalous zones. The 2010 data not only provide additional information from greater depths compared with the 2009 data but also cover a larger surface area. Several high‐chargeability low‐resistivity zones, interpreted as possible massive sulphide mineralization and associated hydrothermal alteration, are revealed. The 3D survey data provide a detailed high‐resolution image of the top ~450 m of the upper crust around the Maurliden East, North, and Central deposits. Several anomalies are interpreted as new potential prospects in the Maurliden area, which are mainly concentrated in the central conductive zone. In addition, the contact relationship between the major geological units, e.g., the contact between the Skellefte Group and the Jörn Intrusive Complex, is better understood with the help of 2010 deep‐resistivity/chargeability data. The bottommost part of the Vargfors basin is imaged using the 2010 geoelectrical and induced polarization data down to ~1‐km depth. 相似文献