Shock‐metamorphic microfeatures in chert from the Jebel Waqf as Suwwan impact structure,Jordan     

Martin SCHMIEDER  Wolf Uwe REIMOLD  Elmar BUCHNER  Maria KHIRFAN  Elias SALAMEH  Hani KHOURY 《Meteoritics & planetary science》2011,46(4):574-586

Abstract– The petrographic investigation of a shocked, chalcedony‐, quartzine‐, and quartz‐bearing allochthonous chert nodule (probably Upper Cretaceous) recovered from surficial wadi gravels in the inner parts of the central uplift of the approximately 6 km in diameter Jebel Waqf as Suwwan impact structure, Jordan, reveals new potential shock indicators in microfibrous–spherulitic silica, in addition to well‐established shock‐metamorphic effects in coarser crystalline quartz. The microcrystalline chert groundmass exhibits a macroscopic dendritic and suborthogonal fracture pattern commonly associated with thin “recrystallization bands” that intersect the pre‐existing diagenetic chert fabric. Fibrous aggregates of quartzine spherulites in chalcedony‐quartzine‐quartz veinlets locally have a shattered appearance and show conspicuous “curved fractures” perpendicular to the quartzine fiber direction (and parallel to [0001]) that commonly trend subparallel to planar fractures (PFs) in neighboring shocked quartz. Quartz exhibits PFs, feather features (FFs), and mainly single sets of planar deformation features (PDFs) parallel to the basal plane (0001) (Brazil twins) and, rarely, additional PDFs parallel to {101¯3}. Shock petrography indicates shock pressures of ≥10 GPa and high shock‐induced differential stresses that affected the chert nodule. The internal crosscutting relationships of primary diagenetic and impact‐related deformational features together with shockpressure estimates suggest that the curved fractures across quartzine spherulites might represent specific (low‐ to medium‐pressure) shock‐metamorphic features, possibly in structural analogy to basal plane PFs in quartz. The dendritic–suborthogonal fractures in the microcrystalline chert groundmass and recrystallization bands are likely related to impact‐induced shear deformation and recrystallization, respectively, and cannot be considered as definite shock indicators.  相似文献   

The reflectivity spectrum and opposition effect of Titan's surface observed by Huygens' DISR spectrometers     

Erich Karkoschka  Stefan E. Schröder  Martin G. Tomasko  Horst Uwe Keller 《Planetary and Space Science》2012,60(1):342-355

We determined Titan's reflectivity spectrum near the Huygens' landing site from observations taken with the Descent Imager/Spectral Radiometer below 500 m altitude, in particular the downward-looking photometer and spectrometers. We distinguish signal coming from illumination by sunlight and the lamp onboard Huygens based on their different spectral signatures. For the sunlight data before landing, we find that spatial variations of Titan's reflectivity were only ～0.8%, aside from the phase angle dependence, indicating that the probed area within ～100 m of the landing site was very homogeneous. Only the very last spectrum taken before landing gave a 3% brighter reflectivity, which probably was caused by one bright cobble inside its footprint. The contrast of the cobble was higher at 900 nm wavelength than at 600 nm.For the data from lamp illumination, we confirm that the phase function of Titan's surface displays a strong opposition effect as found by Schröder and Keller (2009. Planetary and Space Science 57, 1963–1974). We extend the phase function to even smaller phase angles (0.02°), which are among the smallest phase angles observed in the solar system. We also confirm the reflectivity spectrum of the dark terrain near the Huygens' landing site between 900 and 1600 nm wavelength by Schröder and Keller (2008. Planetary and Space Science 56, 753–769), but extend the spectrum down to 435 nm wavelength. The reflectivity at zero phase angle peaks at 0.45±0.06 around 750 nm wavelength and drops down to roughly 0.2 at both spectral ends. Our reflectivity of 0.45 is much higher than all previously reported values because our observations probe lower phase angles than others. The spectrum is very smooth except for a known absorption feature longward of 1350 nm. We did not detect any significant variation of the spectral shape along the slit for exposures after landing, probing a 25×4 cm² area. However, the recorded spectral shape was slightly different for exposures before and after landing. This difference is similar to the spectral differences seen on scales of kilometers (Keller et al., 2008. Planetary and Space Science 56, 728–752), indicating that most observations may probe spatially variable contributions from two basic materials, such as a dark soil partially covered by bright cobbles.We used the methane absorption features to constrain the methane mixing ratio near the surface to 5.0±0.3%, in agreement with the 4.92±0.24% value measured in situ by Niemann et al. (2005. Nature 438, 779–784), but smaller than their revised value of 5.65±0.18% (Niemann et al., 2010. Journal of Geophysical Research 115, E12006). Our results were made possible by an in depth review of the calibration of the spectroscopic and photometric data.  相似文献   

Investigating the redox sensitivity of para-toluenesulfonamide (p-TSA) in groundwater     

Raffaella Meffe  Gudrun Massmann  Claus Kohfahl  Thomas Taute  Doreen Richter  Uwe Dünnbier  Asaf Pekdeger 《Environmental Earth Sciences》2012,65(3):861-870

The groundwater downstream of a former sewage irrigation farm in Berlin is contaminated with ammonium (NH₄ ⁺) and para-toluenesulfonamide (p-TSA), besides other anthropogenic pollutants. In the field, in situ removal of NH₄ ⁺ by gaseous oxygen (O₂) and air injection is currently being tested. A laboratory column experiment using aquifer material and groundwater from the site was performed to determine whether this remediation technology is also feasible to reduce high p-TSA concentrations in the anoxic groundwater. First, the column was operated under anoxic conditions. Later, compressed air was introduced into the system to simulate oxic conditions. Samples were collected from the column outlet before and after the addition of compressed air. The experiment revealed that whereas p-TSA was not removed under anoxic conditions, it was almost fully eliminated under oxic conditions. Results were modelled using a transient one-dimensional solute transport model. The degradation rate constants for p-TSA increased from 2.8E−06 to 7.5E−05 s^–1 as a result of microbial adaption to the change of redox conditions. Results show that O₂ injection into an anoxic aquifer is a successful strategy for p-TSA remediation.  相似文献   

Thermo-hydro-mechanical modeling of carbon dioxide injection for enhanced gas-recovery (CO2-EGR): a benchmarking study for code comparison   总被引：2，自引：1，他引：1  

Zhengmeng Hou  Yang Gou  Joshua Taron  Uwe Jens Gorke  Olaf Kolditz 《Environmental Earth Sciences》2012,67(2):549-561

The objective of this paper was to investigate the THM-coupled responses of the storage formation and caprock, induced by gas production, CO₂-EGR (enhanced gas recovery), and CO₂-storage. A generic 3D planer model (20,000?×?3,000?×?100?m, consisting of 1,200?m overburden, 100?m caprock, 200?m gas reservoir, and 1,500?m base rock) is adopted for the simulation process using the integrated code TOUGH2/EOS7C-FLAC3D and the multi-purpose simulator OpenGeoSys. Both simulators agree that the CO₂-EGR phase under a balanced injection rate (31,500?tons/year) will cause almost no change in the reservoir pressure. The gas recovery rate increases 1.4?% in the 5-year CO₂-EGR phase, and a better EGR effect could be achieved by increasing the distance between injection and production wells (e.g., 5.83?% for 5?km distance, instead of 1.2?km in this study). Under the considered conditions there is no evidence of plastic deformation and both reservoir and caprock behave elastically at all operation stages. The stress path could be predicted analytically and the results show that the isotropic and extensional stress regime will switch to the compressional stress regime, when the pore pressure rises to a specific level. Both simulators agree regarding modification of the reservoir stress state. With further CO₂-injection tension failure in reservoir could occur, but shear failure will never happen under these conditions. Using TOUGH-FLAC, a scenario case is also analyzed with the assumption that the reservoir is naturally fractured. The specific analysis shows that the maximal storage pressure is 13.6?MPa which is determined by the penetration criterion of the caprock.  相似文献   

Discrimination between different water bodies from a multilayered aquifer (Kaluvelly watershed,India): Trace element signature     

Nathalie Gassama  Haino Uwe Kasper  Aline Dia  Constantin Cocirta  Martine Bouhnik-LeCoz 《Applied Geochemistry》2012

In the multilayered aquifer of Kaluvelly (India), comprising various sedimentary layers overlying a charnockitic basement, concentrations of trace elements were measured in aquifer formations and in groundwaters to identify geochemical tracers for water bodies. The two main sandstones (Cuddalore and Vanur) originate from the charnockites and the Cuddalore sandstone has experienced lateritization. In the studied area, two charnockite end-members were identified: a dioritic and a granitic one. Mineralogical composition and whole-rock Ti concentrations confirmed the charnockite which displayed the granitic composition as the parent rock of the two sandstones. Titanium distribution indicates that the Cuddalore sandstone originates from a more intense weathering of the parent material than the Vanur sandstone. Despite extensive differences in trace element contents recorded in aquifer formations, only a few trace elements were suitable to distinguish the water bodies. Among soluble elements, Li (in the Vanur aquifer) and Ba (in the charnockite and carbonaceous aquifers) can be used as tracers. As the input of these elements in solution is mainly regulated by the available stock, for a given mineralogical origin there is a direct link between the aquifer formation composition and water signature. With the exception of As, concentrations of redox-sensitive elements were not preserved during pumping because of oxidation, preventing their use as tracers. Low-mobility elements such as La, Ce, Th, Zr, Nb, Hf, or Ta were too insoluble to be detected in waters and/or to record the aquifer formation signature. Their input in solution was not regulated by the available stock but by the dissolution rate of rock-forming minerals. Only Ti can be used to distinguish between two out of the three aquifers (charnockite and Vanur). The specific behavior of Ti recorded in these waters may be linked to rutile inclusions within plagioclases and to the influence of climate on Ti solubility.  相似文献   

The crystal structure of cualstibite-1M (formerly cyanophyllite), its revised chemical formula and its relation to cualstibite-1T     

Uwe Kolitsch  Gerald Giester  Thomas Pippinger 《Mineralogy and Petrology》2013,107(2):171-178

The crystal structure of the rare secondary mineral cualstibite-1M (formerly cyanophyllite), originally reported to have the chemical formula 10CuO·2Al₂O₃·3Sb₂O₃·25H₂O and orthorhombic symmetry, was solved from single-crystal intensity data (Mo-Kα X-radiation, CCD area detector, 293 K, 2θ_max?=?80) collected on a twinned crystal containing very minor Mg. The mineral is monoclinic, P2₁/c (no. 14), with a?=?9.938(1), b?=?8.890(1), c?=?5.493(1) Å, β?=?102.90(1)°, V?=?473.05(11) ų; R1(F)?=?0.0326. All crystals investigated turned out to be non-merohedric twins. The atomic arrangement has a distinctly layered character. Brucite-like sheets composed of two [4?+?2]-coordinated (Cu,Al,Mg) sites are linked by weak hydrogen-bonding (O···O?~?2.80 Å) to isolated regular Sb(OH)₆ octahedra (<Sb-O>?=?1.975 Å). The layered, pseudotrigonal character explains the perfect cleavage and the proneness to twinning. The Sb site is fully occupied and the two (Cu,Al,Mg) sites have occupancies of Cu_0.79Al_0.17Mg_0.04 and Cu_0.72Al_0.23Mg_0.05. The Cu-richer site shows a slightly stronger Jahn-Teller-distortion. The resulting empirical formula, which necessitates a H₂O-for-OH substitution to obtain charge balance, is (Cu_2.23Al_0.63Mg_0.14)(OH)_5.63(H₂O)_0.37[Sb⁵⁺(OH)₆]. The ideal chemical formula is (Cu,Al)₃(OH)₆[Sb⁵⁺(OH)₆], with Cu:Al = 2:1. The structure is closely related to those of trigonal cualstibite-1T [Cu₂AlSb(OH)₁₂, P-3, with ordered Cu-Al distribution in the brucite sheets], and its Zn analogue zincalstibite-1T [Zn₂AlSb(OH)₁₂]. Cualstibite-1M and cualstibite-1T are polytypes and, together with zincalstibite-1T, zincalstibite-9R and omsite, belong to the cualstibite group within the hydrotalcite supergroup, which comprises all natural members of the large family of layered double hydroxides (LDH).  相似文献   

Silicon-32 as a tool for dating the recent past   总被引：2，自引：2，他引：0  

L. Keith Fifield  Uwe Morgenstern 《Quaternary Geochronology》2009,4(5):400-405

Silicon-32, with a half-life of approximately 140 years, has the potential to fill the dating gap that lies between those chronologies based on the shorter-lived isotopes of ³H and ²¹⁰Pb, and those based on the longer-lived ¹⁴C. Silicon-32 is produced in the atmosphere by cosmic ray bombardment of argon, and falls out on the Earth's surface in precipitation. Silicon-32 methods may be used to date siliceous sediments and sponges, groundwater and glacier ice. Measurement of ³²Si concentrations in these archives is, however, not straightforward. Two methods are available: radioactive-decay counting of the activity of the daughter nucleus, ³²P, and accelerator mass spectrometry, but in both cases the detection of ³²Si pushes the boundaries of the technique. Even the half-life of ³²Si is not known to a precision of better than ±10%. In this paper, we review efforts to determine the isotope's half-life, survey the detection methods and discuss the applications of ³²Si chronology. We show that at least some of the chronometric potential of this radioisotope is close to being realised as a result of recent improvements in methods of measurement.  相似文献   

Assessing temporary carbon sequestration and storage projects through land use, land-use change and forestry: comparison of dynamic life cycle assessment with ton-year approaches     

Annie Levasseur  Pascal Lesage  Manuele Margni  Miguel Brand?o  Réjean Samson 《Climatic change》2012,115(3-4):759-776

In order to properly assess the climate impact of temporary carbon sequestration and storage projects through land-use, land-use change and forestry (LULUCF), it is important to consider their temporal aspect. Dynamic life cycle assessment (dynamic LCA) was developed to account for time while assessing the potential impact of life cycle greenhouse gases (GHG) emissions. In this paper, the dynamic LCA approach is applied to a temporary carbon sequestration project through afforestation, and the results are compared with those of the two principal ton-year approaches: the Moura-Costa and the Lashof methods. The dynamic LCA covers different scenarios, which are distinguished by the assumptions regarding what happens at the end of the sequestration period. In order to ascertain the degree of compensation of an emission through a LULUCF project, the ratio of the cumulative impact of the project to the cumulative impact of a baseline GHG emission is calculated over time. This ratio tends to 1 when assuming that, after the end of the sequestration project period, the forest is maintained indefinitely. Conversely, the ratio tends to much lower values in scenarios where part of the carbon is released back to the atmosphere due to e.g. fire or forest exploitation. The comparison of dynamic LCA with the ton-year approaches shows that it is a more flexible approach as it allows the consideration of every life cycle stage of the project and it gives decision makers the opportunity to test the sensitivity of the results to the choice of different time horizons.  相似文献   

Unusual Carbonatite Lavas from Active Volcano, Oldoinyo Lengai     

?ngelo R. Silva Neto  Mércia J. D. Bezerra  Maria Cláudia S. Farias  Ródio Luis Brand?o Camara 《Journal of the Geological Society of India》2009,74(1):145

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Unusual Carbonatite Lavas from Active Volcano, Oldoinyo Lengai  相似文献   

Geostandards and Geoanalytical Research Bibliographic Review 2016          下载免费PDF全文

Ulrike Weis  Beate Schwager  Brigitte Stoll  Uwe Nohl  Patricia Karlowski  Isabelle Leisgang  Florentine Zwillich  Klaus Peter Jochum 《Geostandards and Geoanalytical Research》2017,41(4):487-491

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