Petrogenesis of the Dullstroom Formation, Bushveld Magmatic Province, South Africa   总被引：2，自引：1，他引：1  

Paul C. Buchanan  Christian Koeberl  Wolf Uwe Reimold 《Contributions to Mineralogy and Petrology》1999,137(1-2):133-146

The Precambrian Dullstroom Formation of South Africa, which is predominantly composed of basaltic andesites interbedded with subordinate sedimentary and felsic volcanic strata, represents the first phase of an extended period of magmatism that was responsible for the Bushveld Magmatic Province, including the extrusive Rooiberg Group and the intrusive Bushveld Complex. New geochemical and isotopic data for the Dullstroom Formation are presented in an effort to elucidate the petrogenetic processes operative during the initiation of this magmatic episode. The volcanic units of the central portion of the Dullstroom Formation have been subdivided into at least three interbedded compositional groups: low Ti mafic to intermediate units, high-Ti mafic to intermediate units, and high Mg felsic units. High Ti and low Ti volcanic units are similar in some compositional characteristics to basalts of the nearby northern and southern provinces, respectively, of the Mesozoic Karoo continental flood basalts. Isotopic and compositional data for low Ti Dullstroom strata are consistent with bulk assimilation into a melt similar in composition to a southern Karoo basalt of 20% upper continental crust accompanied by 20% fractional crystallization of pyroxene and plagioclase. Isotopic and compositional data for high Ti Dullstroom strata are consistent with magma mixing of 30% northern Karoo K-rich basalt and 70% southern Karoo basalt followed by 20% assimilation of upper continental crust and 20% fractional crystallization of pyroxene and plagioclase. Compositions of high Mg felsic volcanic strata are consistent with 25% assimilation of a mixture of silica-rich sedimentary rock and upper continental crust into a melt similar in composition to low Ti volcanic units with 25% fractional crystallization of pyroxene and plagioclase. However, it has been suggested that compositions of these high Mg felsic strata may also be consistent with interaction of a crustal melt. Assimilation, fractional crystallization, and magma mixing that apparently affected these Dullstroom Formation volcanic strata may have occurred in a series of shallow magma chambers. These data are consistent with the suggestion that Dullstroom Formation volcanic rocks are the result of a mantle plume. Mantle plume origin also is suggested by the large volume of intrusive and extrusive strata associated with this magmatic episode. These data do not support the hypothesis that the Bushveld Complex and the Rooiberg Group formed by impacts of a cluster of comets or asteroids. Received: 14 October 1998 / Accepted: 17 May 1999  相似文献   

Plankton prognoses in the North Sea     

Greve  Wulf  Lange  Uwe 《Ocean Dynamics》1999,51(10):155-160

Ocean Dynamics - Our understanding of the marine ecosystem is expressed in our ability to predict ecological processes. Several approaches are compared to make such predictions on plankton...  相似文献   

Verhalten ausgewählter Arzneimittel bei der künstlichen Grundwasseranreicherung – Eliminierung und Effekte auf die mikrobielle Besiedlung     

Gudrun Preuß  Uwe Willme  Ninette Zullei‐Seibert 《洁净——土壤、空气、水》2001,29(5):269-277

Behaviour of Some Pharmaceuticals during Artificial Groundwater Recharge – Elimination and Effects on Microbiology The behaviour of bezafibrate, carbamazepine, clofibric acid, diclofenac, ibuprofen, and gemfibrozil during artificial groundwater recharge was investigated with different test systems simulating field conditions. The given concentrations of the pharmaceuticals were 100 μg/L in the influent of the systems. Concentrations in the influent as well as in the effluent were measured by GC‐MS. These column experiments indicated a significant elimination of bezafibrate, diclofenac, and ibuprofen (60 to 80%) during slow sand filtration. The results showed a moderate elimination of clofibric acid and gemfibrozil (40 to 60%) but a rather low elimination of carbamazepine (<40%). The adaptation times until the elimination processes started were about 5 days. Only the elimination of carbamazepine needed a lag phase up to 17 days. Additional column experiments with groundwater model systems indicated a high persistence of pharmaceuticals under aerobic and anaerobic groundwater conditions. The elimination was less than 20%. Only diclofenac was eliminated with rates between 60% and 80% in aerobic systems and between 40% and 60% in anaerobic systems. Analysis of eubacterial 16S‐rDNA by PCR and DGGE demonstrated changes in the microbial community structure in slow sand filters after application of pharmaceuticals. Adaptation processes may cause these changes, e.g. the appearance or disappearance of single species. Also differences between the populations of water and of the solid phase in slow sand filters could be demonstrated by DGGE pattern.  相似文献   

Non‐stationary hydrological model parameters: a framework based on SOM‐B          下载免费PDF全文

Markus Wallner  Uwe Haberlandt 《水文研究》2015,29(14):3145-3161

The application of stationary parameters in conceptual hydrological models, even under changing boundary conditions, is a common yet unproven practice. This study investigates the impact of non‐stationary model parameters on model performance for different flow indices and time scales. Therefore, a Self‐Organizing Map based optimization approach, which links non‐stationary model parameters with climate indices, is presented and tested on seven meso‐scale catchments in northern Germany. The algorithm automatically groups sub‐periods with similar climate characteristics and allocates them to similar model parameter sets. The climate indices used for the classification of sub‐periods are based on (a) yearly means and (b) a moving average over the previous 61 days. Classification b supports the estimation of continuous non‐stationary parameters. The results show that (i) non‐stationary model parameters can improve the performance of hydrological models with an acceptable growth in parameter uncertainty; (ii) some model parameters are highly correlated to some climate indices; (iii) the model performance improves more for monthly means than yearly means; and (iv) in general low to medium flows improve more than high flows. It was further shown how the gained knowledge can be used to identify insufficiencies in the model structure. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Vegetation impacts soil water content patterns by shaping canopy water fluxes and soil properties          下载免费PDF全文

Johanna Clara Metzger  Thomas Wutzler  Nicolas Dalla Valle  Janett Filipzik  Christoph Grauer  Robert Lehmann  Martin Roggenbuck  Danny Schelhorn  Josef Weckmüller  Kirsten Küsel  Kai Uwe Totsche  Susan Trumbore  Anke Hildebrandt 《水文研究》2017,31(22):3783-3795

Soil water content is a key variable for biogeochemical and atmospheric coupled processes. Its small‐scale heterogeneity impacts the partitioning of precipitation (e.g., deep percolation or transpiration) by triggering threshold processes and connecting flow paths. Forest hydrologists frequently hypothesized that throughfall and stemflow patterns induce soil water content heterogeneity, yet experimental validation is limited. Here, we pursued a pattern‐oriented approach to explore the relationship between net precipitation and soil water content. Both were measured in independent high‐resolution stratified random designs on a 1‐ha temperate mixed beech forest plot in Germany. We recorded throughfall (350 locations) and stemflow (65 trees) for 16 precipitation events in 2015. Soil water content was measured continuously in topsoil and subsoil (210 profiles). Soil wetting was only weakly related to net precipitation patterns. The precipitation‐induced pattern quickly dissipates and returns to a basic pattern, which is temporally stable. Instead, soil hydraulic properties (by the proxy of field capacity) were significantly correlated with this stable soil water content pattern, indicating that soil structure more than net precipitation drives soil water content heterogeneity. Also, both field capacity and soil water content were lower in the immediate vicinity of tree stems compared to further away at all times, including winter, despite stemflow occurrence. Thus, soil structure varies systematically according to vegetation in our site. We conclude that enhanced macroporosity increases gravity‐driven flow in stem proximal areas. Therefore, although soil water content patterns are little affected by net precipitation, the resulting soil water fluxes may strongly be affected. Specifically, this may further enhance the channelling of stemflow to greater depth and beyond the rooting zone.  相似文献   

Experimental observation of strong mixing due to internal wave focusing over sloping terrain     

Arno Swart  Astrid Manders  Uwe Harlander  Leo R.M. Maas 《Dynamics of Atmospheres and Oceans》2010

This paper reports on experimental observation of internal waves that are focused due to a sloping topography. A remarkable mixing of the density field was observed. This result is of importance for the deep ocean, where internal waves are believed to play a role in mixing. The experiments were performed on the rotating platform at the Coriolis Laboratory, Grenoble. The rotation, its modulation and density stratification were set to be in the internal wave regime. After applying various data processing techniques we observe internal wave rays, which converge to a limiting state: the wave attractor. At longer time scales we observe a remarkably efficient mixing of the density field, possibly responsible for driving observed sheared mean flows and topographic Rossby waves. We offer the hypothesis that focusing of internal waves to the wave attractor leads to the mixing.  相似文献   

Early Archean spherule layers from the Barberton Greenstone Belt,South Africa: Mineralogy and geochemistry of the spherule beds in the CT3 drill core          下载免费PDF全文

Seda Ozdemir  Toni Schulz  Christian Koeberl  Wolf Uwe Reimold  Tanja Mohr‐Westheide  Desiree Hoehnel  Ralf Thomas Schmitt 《Meteoritics & planetary science》2017,52(12):2586-2631

Little is known about the Hadean and the Archean impact record on Earth. In the CT3 drill core from the Fig Tree Group of the northern Barberton Greenstone Belt, 17 spherule layer intersections occur, which, provide an outstanding new opportunity to gain insights into meteorite bombardment of the early Earth. CT3 spherules, as primary features, mostly exhibit textural patterns similar to those of the other Barberton spherule layers, but locally mineralogical and chemical compositional differences are observed, likely as a result of various degrees of alteration. The observed mineralogy of the spherule layers is of secondary origin and comprises K‐feldspar, phyllosilicates, carbonates, sulfides, and oxides, with the exception of secondary Ni‐Cr spinel that is of primary origin. Our petrographic investigations suggest alteration by K‐metasomatism, sericitization, silicification, and carbonatization. Siderophile element contents of bulk samples show significant enrichments in Ni (up to 2 wt%) and Ir (up to ~3 ppm), similar to previously studied Archean spherule layers. These values are indicative of the presence of a meteoritic component. On the other hand, lithophile and chalcophile element abundances indicate hydrothermal overprint on the CT3 samples; this may also have influenced the redistribution of the meteoritic component(s). Last, we group the CT3 spherule layers, which occur in three intervals (A, B, and C), according to their petrographic and geochemical features, which indicate evidence for at least three distinct impact events before tectonic overprint that affected the original deposits.  相似文献   

From streambed temperature measurements to spatial‐temporal flux quantification: using the LPML method to study groundwater–surface water interaction          下载免费PDF全文

Christian Anibas  Uwe Schneidewind  Gerd Vandersteen  Ingeborg Joris  Piet Seuntjens  Okke Batelaan 《水文研究》2016,30(2):203-216

Knowledge on groundwater–surface water interaction and especially on exchange fluxes between streams and aquifers is an important prerequisite for the study of transport and fate of contaminants and nutrients in the hyporheic zone. One possibility to quantify groundwater–surface water exchange fluxes is by using heat as an environmlental tracer. Modern field equipment including multilevel temperature sticks and the novel open‐source analysis tool LPML make this technique ever more attractive. The recently developed LPML method solves the one‐dimensional fluid flow and heat transport equation by combining a local polynomial method with a maximum likelihood estimator. In this study, we apply the LPML method on field data to quantify the spatial and temporal variability of vertical fluxes and their uncertainties from temperature–time series measured in a Belgian lowland stream. Over several months, temperature data were collected with multilevel temperature sticks at the streambed top and at six depths for a small stream section. Long‐term estimates show a range from gaining fluxes of ?291 mm day^?1 to loosing fluxes of 12 mm day^?1; average seasonal fluxes ranged from ?138 mm day^?1 in winter to ?16 mm day^?1 in summer. With our analyses, we could determine a high spatial and temporal variability of vertical exchange fluxes for the investigated stream section. Such spatial and temporal variability should be taken into account in biogeochemical cycling of carbon, nutrients and metals and in fate analysis of contaminant plumes. In general, the stream section was gaining during most of the observation period. Two short‐term high stream stage events, seemingly caused by blockage of the stream outlet, led to a change in flow direction from gaining to losing conditions. We also found more discharge occurring at the outer stream bank than at the inner one indicating a local flow‐through system. With the conducted analyses, we were able to advance our understanding of the regional groundwater flow system. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Conference report: Large Meteorite Impacts and Planetary Evolution VI     

Roger Gibson  Wolf Uwe Reimold  Natalia Hauser  Elder Yokoyama 《Meteoritics & planetary science》2020,55(1):245-250

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US agricultural sector analysis on pesticide externalities – the impact of climate change and a Pigovian tax     

Nikolinka G. Shakhramanyan  Uwe A. Schneider  Bruce A. McCarl 《Climatic change》2013,117(4):711-723

Residuals from agricultural pesticides threaten the environment and human health. Climate change alters these externalities because it affects pest pressure and pesticide application rates. This study examines damages from pesticide externalities in US agriculture under different climate projections and the effects of alternative regulations. We find divergent impacts of externality regulation and climate change on agricultural production in the US. A Pigovian tax on pesticide externalities generally increases crop production cost, but farm revenue improves because of increased commodity prices. Climate change generally decreases US farm revenue because production increases and prices fall. Results also show a heterogeneous effect of climate change on pest management intensities across major crops.  相似文献