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41.
Marina A. Yudovskaya Vadim V. Distler Ilya V. Chaplygin Andrew V. Mokhov Nikolai V. Trubkin Sonya A. Gorbacheva 《Mineralium Deposita》2006,40(8):828-848
The distribution of gold in high-temperature fumarole gases of the Kudryavy volcano (Kurile Islands) was measured for gas, gas condensate, natural fumarolic sublimates, and precipitates in silica tubes from vents with outlet temperatures ranging from 380 to 870°C. Gold abundance in condensates ranges from 0.3 to 2.4 ppb, which is significantly lower than the abundances of transition metals. Gold contents in zoned precipitates from silica tubes increase gradually with a decrease in temperature to a maximum of 8 ppm in the oxychloride zone at a temperature of approximately 300°C. Total Au content in moderate-temperature sulfide and oxychloride zones is mainly a result of Au inclusions in the abundant Fe–Cu and Zn sulfide minerals as determined by instrumental neutron activation analysis. Most Au occurs as a Cu–Au–Ag triple alloy. Single grains of native gold and binary Au–Ag alloys were also identified among sublimates, but aggregates and crystals of Cu–Au–Ag alloy were found in all fumarolic fields, both in silica tube precipitates and in natural fumarolic crusts. Although the Au triple alloy is homogeneous on the scale of microns and has a composition close to (Cu,Ni,Zn)3(Au,Ag)2, transmission electron microscopy (TEM) shows that these alloy solid solutions consist of monocrystal domains of Au–Ag, Au–Cu, and possibly Cu2O. Gold occurs in oxide assemblages due to the decomposition of its halogenide complexes under high-temperature conditions (650–870°C). In lower temperature zones (<650°C), Au behavior is related to sulfur compounds whose evolution is strongly controlled by redox state. Other minerals that formed from gas transport and precipitation at Kudryavy volcano include garnet, aegirine, diopside, magnetite, anhydrite, molybdenite, multivalent molybdenum oxides (molybdite, tugarinovite, and ilsemannite), powellite, scheelite, wolframite, Na–K chlorides, pyrrhotite, wurtzite, greenockite, pyrite, galena, cubanite, rare native metals (including Fe, Cr, Mo, Sn, Ag, and Al), Cu–Zn–Fe–In sulfides, In-bearing Pb–Bi sulfosalts, cannizzarite, rheniite, cadmoindite, and kudriavite. Although most of these minerals are fine-grained, they are strongly idiomorphic with textures such as gas channels and lamellar, banded, skeletal, and dendrite-like crystals, characteristic of precipitation from a gas phase. The identified textures and mineral assemblages at Kudryavy volcano can be used to interpret geochemical origins of both ancient and modern ore deposits, particularly gold-rich porphyry and related epithermal systems. 相似文献
42.
Innokenty Kantor Leonid Dubrovinsky Catherine McCammon Anastasia Kantor Sakura Pascarelli Giuliana Aquilanti Wilson Crichton Maurizio Mattesini Rajeev Ahuja Jailton Almeida Vadim Urusov 《Physics and Chemistry of Minerals》2006,33(1):35-44
Combined X-ray powder diffraction, Mössbauer, and XANES spectroscopy in situ experiments revealed the transformation of cubic (Mg0.8Fe0.2)O ferropericlase to a rhombohedrally distorted phase at 35(1) GPa and room temperature. The Mössbauer spectroscopy results show that the rhombohedral distortion does not involve magnetic ordering. Combined with data from the literature, our results imply that the cubic to rhombodedral transition occurs in (Mg,Fe)O under conditions of non-hydrostatic stress over a wide range of composition (0.2≤x Fe≤1). 相似文献
43.
44.
Gerhard P. Brey Vadim Bulatov Andrei Girnis Jeff W. Harris Thomas Stachel 《Lithos》2004,77(1-4):655-663
Experiments on compositions along the join MgO–NaA3+Si2O6 (A=Al, Cr, Fe3+) show that sodium can be incorporated into ferropericlase at upper mantle pressures in amounts commonly found in natural diamond inclusions. These results, combined with the observed mineral parageneses of several diamond inclusion suites, establish firmly that ferropericlase exists in the upper mantle in regions with low silica activity. Such regions may be carbonated dunite or stalled and degassed carbonatitic melts. Ferropericlase as an inclusion in diamond on its own is not indicative of a lower mantle origin or of a deep mantle plume. Coexisting phases have to be taken into consideration to decide on the depth of origin. The composition of olivine will indicate an origin from the upper mantle or border of the transition zone to the lower mantle and whether it coexisted with ferropericlase in the upper mantle or as ringwoodite. The narrow and flat three phase loop at the border transition zone—lower mantle together with hybrid peridotite plus eclogite/sediments provides an explanation for the varying and Fe-rich nature of the diamond inclusion suite from Sao Luiz, Brazil. 相似文献
45.
Tectonic reconstructions based on the geodynamic analysis of geologic, paleomagnetic, structural and kinematic data of Cenozoic age from the western Bering Sea region are proposed in the present paper. The most active tectonic and magmatic processes took place in the Komandorsky segment of the Bering Sea, exemplified by the Late Cretaceous–Early Eocene Olutorsky Arc and Eocene–Oligocene Govena–Karaginsky Arc, which was built on the structures of the Olutorsky Arc. A model of the complex collision of these two arcs with the paleocontinental margin, which considers rotations of the geological blocks from the various structural zones of the western margin of the Bering Sea in the horizontal plane (paleomagnetic data), was proposed by the authors. According to this model the collision of the flanks of the Olutorsky and Govena–Karaginsky arcs took place in the Eocene, before the collision of the central parts in the Miocene. 相似文献
46.
Vadim A. Antonov Faziliddin T. Shamshiev 《Celestial Mechanics and Dynamical Astronomy》1993,56(3):451-469
This paper deals with the plane motion of a star in the gravitational field of a system which is in a steady state and rotates with a constant angular velocity. For these systems a class of potentials permitting a local integral, linear with respect to the velocity components, has been found. The concept of the local integral itself was introduced by one of the authors of the present paper (Antonov, 1981). A detailed model has been constructed. The corresponding domain of the particle motion and the form of the trajectory coils have been determined. The result is compared with the motion in a more realistic potential. 相似文献
47.
As is known, a variable parameter for partial ionicity is often involved in the techniques of modeling structure and properties of inorganic crystals by energy-minimization methods. In such a case, to make a calculated energy comparable to experimental estimate (atomization energy) there is a need to involve an intraatomic energy term, the so-called charge-transfer energy (Urusov and Eremin 1995). For this purpose a set of charge-transfer energies for valence states of many elements is compiled. The procedure based on aspiration of equalizing the electronic levels electronegativities is proposed to estimate the total contribution of the charge-transfer energy in the cohesive energy of a crystal. The other prescribed quantities are repulsive potential parameters which are related to the energetic propertis of valence shells of bonded atoms. The final potential function consists of an effective Coulomb attraction, repulsion and covalent Morse type term, properly weighted. The energy-minimization procedure is performed for various values of the ionicity degree parameter of the crystal under study. Thereafter the charge-transfer energy correction is introduced in order for the cohesive energy calculations to be made. The calculations of structure, energy and elastic properties were performed using the METAPOCS code with ionicity variation for halides (NaCl, CaF2), oxides (MgO, Al2O3, SiO2 quartz and SnO2), sulphide ZnS and silicate CaSnSiO5. The resulting cohesive energies usually agree with experiment much better than those calculated in pure ionic or covalent approximations. As to elastic properties of crystals under consideration, they are generally functions of the ionicity parameter too and in most instances the predicted properties at intermediate values of the ionicity degree are in a satisfactory accordance with experimental data. 相似文献
48.
49.
Vadim A. Kravchinsky Michael E. Evans John A. Peck Hideo Sakai Mikhail A. Krainov John W. King Mikhail I. Kuzmin 《Geophysical Journal International》2007,170(1):101-116
Magnetic remanence vectors for 1737 samples from two ∼100 m cores of Lake Baikal sediments are reported along with complete magnetic susceptibility profiles obtained from a pass-through system. Chronological control is established by means of two independent correlations; first, by matching susceptibility variations to the oceanic oxygen isotope record and second, by matching the relative palaeointensity variations to the SINT-800 global reference curve. These both imply an average deposition rate of 15 cm kyr–1 and a basal age of ∼640 ka. Spectral analysis reveals the presence of Milankovitch signals at ∼100 kyr (eccentricity), ∼41 kyr (obliquity) and ∼23 and ∼19 kyr (precession). Stable remanence vectors are almost all of normal polarity. The few exceptions comprise brief intervals of low and/or negative inclinations which probably represent geomagnetic excursions. However, these are far less numerous than the high sedimentation rate would lead one to expect. Furthermore, only four of them can be readily matched to the—still poorly understood—global pattern. These are the Laschamp, the Albuquerque, the Iceland Basin and perhaps the West Eifel excursions which occurred at ∼38 000, ∼146 000, at 180 000–190 000 and at 480 000–495 000 yr ago, respectively. 相似文献
50.