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991.
Lead isotope ratios of galena from the carbonate-hosted massive sulphide deposits of Kabwe (Pb-Zn) and Tsumeb (Pb-Zn-Cu) in Zambia and Namibia, respectively, have been measured and found to be homogeneous and characteristic of upper crustal source rocks. Kabwe galena has average isotope ratios of 206/204Pb = 17.997 ± 0.007, 207/204Pb = 15.713 ± 0.010 and 208/204Pb = 38.410 ± 0.033. Tsumeb galena has slightly higher 206/204Pb (18.112 ± 0.035) and slightly lower 207/204Pb (15.674 ± 0.016) and 208/204Pb (38.276 ± 0.073) ratios than Kabwe galena. The isotopic differences are attributed to local differences in the age and composition of the respective source rocks for Kabwe and Tsumeb. The homogeneity of the ore lead in the two epigenetic deposits suggests lead sources of uniform isotopic composition or, alternatively, thorough mixing of lead derived from sources with relatively similar isotopic compositions. Both deposits have relatively high 238U/204Pb ratios of 10.31 and 10.09 for Kabwe and Tsumeb galenas, respectively. These isotope ratios are considered to be typical of the upper continental crust in the Damaran-Lufilian orogenic belt, as also indicated by basement rocks and Cu-Co sulphides in stratiform Katangan metasediments which have a mean μ-value of 10.25 ± 0.12 in the Copperbelt region of Zambia and the Democratic Republic of Congo (formerly Zaire). The 232Th/204Pb isotope ratios of 43.08 and 40.42 for Kabwe and Tsumeb suggest Th-enriched source regions with 232Th/235U (κ-values) of 4.18 and 4.01, respectively. Model isotopic ages determined for the Kabwe (680 Ma) and Tsumeb (530 Ma) deposits indicate that the timing of the mineralisation was probably related to phases of orogenic activity associated with the Pan-African Lufilian and Damaran orogenies, respectively. Galena from the carbonate-hosted Kipushi Cu-Pb-Zn massive sulphide deposit in the Congo also has homogeneous lead isotope ratios, but its isotopic composition is comparable to that of the average global lead evolution curve for conformable massive sulphide deposits. The μ (9.84) and κ (3.69) values indicate a significant mantle component, and the isotopic age of the Kipushi deposit (456 Ma) suggests that the emplacement of the mineralisation was related to a post-tectonic phase of igneous activity in the Lufilian belt. The isotope ratios (206/204Pb, 207/204Pb, 208/204Pb) of the three deposits are markedly different from the heterogeneous lead ratios of the Katangan Cu-Co stratiform mineralisation of the Copperbelt as well as those of the volcanogenic Nampundwe massive pyrite deposit in the Zambezi belt which typically define radiogenic linear trends on lead-lead plots. The host-rock dolomite of the Kabwe deposit also has homogeneous lead isotope ratios identical to the ore galena. This observation indicates contamination of the Kabwe Dolomite Formation with ore lead during mineralisation. Received: 8 September 1997 / Accepted: 21 August 1998  相似文献   
992.
The Almadén district is the largest mercury concentration in the world, with a total content of about 250 000 t of mercury, nearly one third of the known total mercury resources of the Earth. Mercury has been exploited since the Celtic and Roman times, with peak production during the Renaissance and between 1939–1945. The district is hosted by a Paleozoic synclinorium overlying Precambrian rocks. The Paleozoic sequence comprises epicontinental quartz arenite rocks, including black shales and quartzites. Diatremes, alkaline lavas of different composition, and late tholeiitic diabases account for the Ordovician to Devonian magmatism. The tectonic setting of this complex suite corresponds to the intraplate type. The mercury deposits of Almadén can be classified into two main types: type 1, early stratiform type ores characterized by cinnabar deposition on the lower Silurian quartzites (Criadero quartzite; e.g. the Almadén and El Entredicho deposits), and type 2, late discordant orebodies (e.g. Las Cuevas), largely hosted or related to diatremes (the `frailesca rocks') of alkaline basaltic composition. In type 1 cinnabar was deposited during diagenesis, in relation to hydrothermal circulation driven by magmatic activity. Type 2 include a variety of deposits having in common the discordant character of the orebodies (e.g. veins, stockworks, massive replacements), and their wide dispersion along the stratigraphic column, i.e. from Lower Silurian (e.g. Nueva Concepción) to Upper Devonian (e.g. Corchuelo). Received: 23 October 1998 / Accepted: 4 January 1999  相似文献   
993.
Bio-physical glider measurements from a unique process-oriented experiment in the Eastern Alboran Sea (AlborEx) allowed us to observe the distribution of the deep chlorophyll maximum (DCM) across an intense density front, with a resolution (~ 400 m) suitable for investigating sub-mesoscale dynamics. This front, at the interface between Atlantic and Mediterranean waters, had a sharp density gradient (Δρ ~ 1 kg/m3 in ~ 10 km) and showed imprints of (sub-)mesoscale phenomena on tracer distributions. Specifically, the chlorophyll-a concentration within the DCM showed a disrupted pattern along isopycnal surfaces, with patches bearing a relationship to the stratification (buoyancy frequency) at depths between 30 and 60 m. In order to estimate the primary production (PP) rate within the chlorophyll patches observed at the sub-surface, we applied the Morel and Andrè (J Geophys Res 96:685–698 1991) bio-optical model using the photosynthetic active radiation (PAR) from Argo profiles collected simultaneously with glider data. The highest production was located concurrently with domed isopycnals on the fresh side of the front, suggestive that (sub-)mesoscale upwelling is carrying phytoplankton patches from less to more illuminated levels, with a contemporaneous delivering of nutrients. Integrated estimations of PP (1.3 g C m?2d?1) along the glider path are two to four times larger than the estimations obtained from satellite-based algorithms, i.e., derived from the 8-day composite fields extracted over the glider trip path. Despite the differences in spatial and temporal sampling between instruments, the differences in PP estimations are mainly due to the inability of the satellite to measure DCM patches responsible for the high production. The deepest (depth > 60 m) chlorophyll patches are almost unproductive and probably transported passively (subducted) from upper productive layers. Finally, the relationship between primary production and oxygen is also investigated. The logarithm of the primary production in the DCM interior (chlorophyll (Chl) > 0.5 mg/m3) shows a linear negative relationship with the apparent oxygen utilization, confirming that high chlorophyll patches are productive. The slope of this relationship is different for Atlantic, mixed interface waters and Mediterranean waters, suggesting the presence of differences in planktonic communities (whether physiological, population, or community level should be object of further investigation) on the different sides of the front. In addition, the ratio of optical backscatter to Chl is high within the intermediate (mixed) waters, which is suggestive of large phytoplankton cells, and lower within the core of the Atlantic and Mediterranean waters. These observations highlight the relevance of fronts in triggering primary production at DCM level and shaping the characteristic patchiness of the pelagic domain. This gains further relevance considering the inadequacy of optical satellite sensors to observe DCM concentrations at such fine scales.  相似文献   
994.
The main objective of the LAgrangian Transport EXperiment (LATEX) project was to study the influence of coastal mesoscale and submesoscale physical processes on circulation dynamics, cross-shelf exchanges, and biogeochemistry in the western continental shelf of the Gulf of Lion, Northwestern Mediterranean Sea. LATEX was a five-year multidisciplinary project based on the combined analysis of numerical model simulations and multi-platform field experiments. The model component included a ten-year realistic 3D numerical simulation, with a 1 km horizontal resolution over the gulf, nested in a coarser 3 km resolution model. The in situ component involved four cruises, including a large-scale multidisciplinary campaign with two research vessels in 2010. This review concentrates on the physics results of LATEX, addressing three main subjects: (1) the investigation of the mesoscale to submesoscale processes. The eddies are elliptic, baroclinic, and anticyclonic; the strong thermal and saline front is density compensated. Their generation processes are studied; (2) the development of sampling strategies for their direct observations. LATEX has implemented an adaptive strategy Lagrangian tool, with a reference software available on the web, to perform offshore campaigns in a Lagrangian framework; (3) the quantification of horizontal mixing and cross-shelf exchanges. Lateral diffusivity coefficients, calculated in various ways including a novel technique, are in the range classically encountered for their associated scales. Cross-shelf fluxes have been calculated, after retrieving the near-inertial oscillation contribution. Further perspectives are discussed, especially for the ongoing challenge of studying submesoscale features remotely and from in situ data.  相似文献   
995.
The coast of Mozambique is often affected by storms, particularly tropical cyclones during summer or sometimes midlatitude systems in the southern part. Storm surges combined with high freshwater discharge can drive huge coastal floods, affecting both urban and rural areas. To improve the knowledge about the impact of storm surges in the coast of Mozambique, this study presents the first attempt to model this phenomenon through the implementation of the Princeton Ocean Model (POM) in the Southwestern Indian Ocean domain (SWIO; 2–32°S, 28–85°E) using a regular grid with 1/6° of spatial resolution and 36 sigma levels. The simulation was performed for the period 1979–2010, and the most interesting events of surges were related to tropical cyclones Bonita (1996) and Lisette (1997) that occurred in the Mozambique Channel. The results showed that the model represented well the amplitude and phase of principal lunar and solar tidal constituents, as well as it captured the spatial pattern and magnitudes of SST with slight positive bias in summer and negative bias in winter months. In terms of SSH, the model underestimated the presence of mesoscale eddies, mainly in the Mozambique Channel. Our results also showed that the atmospheric sea level pressure had a significant contribution to storm heights during the landfall of the tropical cyclones Bonita (1996) and Lisette (1997) in the coast of Mozambique contributing with about 20 and 16% of the total surge height for each case, respectively, surpassing the contribution of the tide-surge nonlinear interactions by a factor of 2.  相似文献   
996.
The observation of extreme waves at FINO 1 during storm Britta on the 1st November 2006 has initiated a series of research studies regarding the mechanisms behind. The roles of stability and the presence of the open cell structures have been previously investigated but not conclusive. To improve our understanding of these processes, which are essential for a good forecast of similarly important events offshore, this study revisits the development of storm Britta using an atmospheric and wave coupled modeling system, wind and wave measurements from ten stations across the North Sea, cloud images and Synthetic Aperture Radar (SAR) data. It is found here that a standard state-of-the-art model is capable of capturing the important characteristics of a major storm like Britta, including the storm path, storm peak wind speed, the open cells, and peak significant wave height (H s ) for open sea. It was also demonstrated that the impact of the open cells has negligible contribution to the development of extreme H s observed at FINO 1. At the same time, stability alone is not sufficient in explaining the development of extreme H s . The controlling conditions for the development of Britta extreme H s observed at FINO 1 are the persistent strong winds and a long and undisturbed fetch over a long period.  相似文献   
997.
Low‐frequency passive integrated transponders (PIT tags), are commonly used for monitoring pebble mobility in gravel‐bed rivers. Although early studies reported high recovery rates for PIT tags used in small streams, recovery rates in larger systems remain low, substantially limiting the possibilities for their use in such rivers. These low recovery rates are potentially due to missed detections caused by tag signal collision, burial in the sediment layer deeper than the maximum detection range and insufficient (but still exhausting) field effort to cover the concerned areas. A potential solution for addressing these problems is to use active ultra‐high frequency (a‐UHF) transponders as these have a greater detection range and anti‐collision protocols. In order to assess the potential of such transponders for pebble tracking in rivers, we used 433.92 MHz COIN‐ID and COIN‐HC models (ELA Innovation Company, Montpellier, France). We completed several tests to (i) characterize transponder detection ranges in the water and in saturated sediment and (ii) develop field protocols for locating tags by combining global positioning systems (GPS) sites and transponder received signal strength indication (RSSI) levels. The results showed that (i) the maximum detection ranges are about 2.4 m in the water column and more than 2.6 m in a column of saturated gravelly‐sandy sediment, (ii) RSSI spatial interpolation can be used to determine transponder position with good accuracy (< 1 m), (iii) the desired minimal level of accuracy can be adjusted depending on in‐field effort and signal impulse interval, (iv) the RSSI maximal value observed cannot yet be used to determine transponder burial depth because of the multipath propagation of radio frequencies and the semi‐directional emission of the tag signal. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   
998.
West Africa experienced severe drought during the 1970s and 1980s, posing a threat to water resources. A wetter climate more recently suggests recovery from the drought. The Mann-Kendall trend and Theil-Sen’s slope estimator were applied to detect probable trends in weather elements in four sub-basins of the Niger River Basin between 1970 and 2010. The cross-entropy method was used to detect breakpoints in rainfall and runoff, Spearman’s rank test for correlation between the two, and cross-correlation analysis for possible lags. Results showed an overall increase in rainfall and runoff and a decrease in sunshine duration. Spearman’s coefficients suggest significant (5%) moderate to strong rainfall–runoff correlation for three sub-basins. A significant lower runoff was observed around 1979, with a rainfall break around 1992, indicating possible cessation of the drought. Temperatures increased significantly, at 0.02–0.05°C year-1, with a negative wind speed trend for most stations. Half of the stations exhibited an increase in potential evapotranspiration.
EDITOR M.C. Acreman

ASSOCIATE EDITOR Not assigned  相似文献   
999.
This paper discusses the analysis and modelling of the hydrological system of the basin of the Kara River, a transboundary river in Togo and Benin, as a necessary step towards sustainable water resources management. The methodological approach integrates the use of discharge parameters, flow duration curves and the lumped conceptual model IHACRES. A Sobol sensitivity analysis is performed and the model is calibrated by applying the shuffled complex evolution algorithm. Results show that discharge generation in three nested catchments of the basin is affected by landscape physical characteristics. The IHACRES model adequately simulates the rainfall–runoff dynamics in the basin with a mean modified Nash-Sutcliffe efficiency measure of 0.6. Modelling results indicate that parameters controlling rainfall transformation to effective rainfall are more sensitive than those routing the streamflow. This study provides insights into understanding the catchment’s hydrological system. Nevertheless, further investigations are required to better understand detailed runoff generation processes.
EDITOR M.C. Acreman; ASSOCIATE EDITOR N Verhoest  相似文献   
1000.
A stochastic flow representation is considered with the Eulerian velocity decomposed between a smooth large scale component and a rough small-scale turbulent component. The latter is specified as a random field uncorrelated in time. Subsequently, the material derivative is modified and leads to a stochastic version of the material derivative to include a drift correction, an inhomogeneous and anisotropic diffusion, and a multiplicative noise. As derived, this stochastic transport exhibits a remarkable energy conservation property for any realizations. As demonstrated, this pivotal operator further provides elegant means to derive stochastic formulations of classical representations of geophysical flow dynamics.  相似文献   
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