Some Observations on the Determination of Gold and the Platinum-Group Elements in Black Shales   总被引：2，自引：0，他引：2  

Valentin N. Mitkin  Alexander A. Galizky  Tamara M. Korda 《Geostandards and Geoanalytical Research》2000,24(2):227-240

This research compares various ways of applying oxidative chemical decomposition to the analysis of gold-bearing black shale ores from the Russian Natalka and Sukhoj Log deposits. This study was conducted as part of the certification program for the Russian candidate black shale reference materials SLG-1 and SCHS-1 and also because of the paucity of data available on the determination of the platinum group elements (PGE) in analogous sample types. We report direct evidence of PGE volatilisation from black shale materials when processed in the presence of oxygen. We also developed a comprehensive analytical scheme for the quantitative determination of PGE in all phases (gaseous and ash) produced during slow combustion of carbonaceous materials in oxygen.
This study has shown that during combustion in oxygen at 600 °C, PGE contained in the Natalka black shale ores are lost as gaseous reaction products. Thus, the volatilized PGE (recovered in traps) account for up to 14% Pt, 40% Pd, 40% Ru and 10 % Ir relative to their total concentrations in a carbonaceous concentrate. It was also established that in the process of combustion, Au quantitatively remains in the ash cake.
In order to avoid the deleterious effects of oxygen on the volatility of the PGE, we propose a new comprehensive sample decomposition method based on the application of fluoroxidants such as BrF₃ and KBrF₄. This method was validated using samples of black shale ores and their processing products by comparing our results with those obtained independently using sealed autoclave processing of the same materials. It was shown that PGE in black shale ores and their processing products not only exist in commercially exploitable quantities but that a small proportion of PGE compounds are soluble in alcohol. We propose that in gold-bearing black shale ores, PGE are present as organometallic compounds.  相似文献   

Detection of point scatterers using diffraction imaging and deep learning     

Valentin Tschannen  Norman Ettrich  Matthias Delescluse  Janis Keuper 《Geophysical Prospecting》2020,68(3):830-844

Diffracted waves carry high-resolution information that can help interpreting fine structural details at a scale smaller than the seismic wavelength. However, the diffraction energy tends to be weak compared to the reflected energy and is also sensitive to inaccuracies in the migration velocity, making the identification of its signal challenging. In this work, we present an innovative workflow to automatically detect scattering points in the migration dip angle domain using deep learning. By taking advantage of the different kinematic properties of reflected and diffracted waves, we separate the two types of signals by migrating the seismic amplitudes to dip angle gathers using prestack depth imaging in the local angle domain. Convolutional neural networks are a class of deep learning algorithms able to learn to extract spatial information about the data in order to identify its characteristics. They have now become the method of choice to solve supervised pattern recognition problems. In this work, we use wave equation modelling to create a large and diversified dataset of synthetic examples to train a network into identifying the probable position of scattering objects in the subsurface. After giving an intuitive introduction to diffraction imaging and deep learning and discussing some of the pitfalls of the methods, we evaluate the trained network on field data and demonstrate the validity and good generalization performance of our algorithm. We successfully identify with a high-accuracy and high-resolution diffraction points, including those which have a low signal to noise and reflection ratio. We also show how our method allows us to quickly scan through high dimensional data consisting of several versions of a dataset migrated with a range of velocities to overcome the strong effect of incorrect migration velocity on the diffraction signal.  相似文献   

Treatment of Crystal Violet from Synthetic Solution Using Membranes Doped with Natural Fruit Extract          下载免费PDF全文

Simona Caprarescu  Alexandra R. Miron  Violeta Purcar  Anita‐Laura Radu  Andrei Sarbu  Cristian Andi Nicolae  Mihaela Pascu  Daniela Ion‐Ebrasu  Valentin Raditoiu 《洁净——土壤、空气、水》2018,46(7)

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Determination of the equilibrium fO2 in bulk samples of H,L, and LL ordinary chondrites by solid‐state electrochemistry          下载免费PDF全文

Valentin O. Osadchii  Mark V. Fedkin  Evgeniy G. Osadchii 《Meteoritics & planetary science》2017,52(10):2275-2283

High‐temperature solid‐state electrochemistry techniques (EMF method) were used to measure the oxygen fugacity (fO₂) of the ordinary chondrites Ochansk (H4), Savtschenskoje (LL4), Elenovka (L5), Vengerovo (H5), and Kharkov (L6). The fO₂ results are presented in the form of the following equations: It was found that fO₂ regularly increases from H chondrites to LL chondrites. Measured fO₂ are ~1.5 higher than those previously calculated from mineral assemblages. Kharkov (L6) is a little more oxidized than Elenovka (L5) in agreement with the progressive oxidation model. At the same time, Ochansk (H4) is more oxidized than Vengerovo (H5) and exhibits a slightly different slope compared to other chondrites and at T > 1200 K, becomes more reduced than Kharkov (L6) or Elenovka (L5). Measured oxygen fugacity values of meteorites fall within (0.1–1.0)·log fO₂ of one another. The possible explanation of discrepancies between measured and calculated values is discussed.  相似文献   

Sacred ground; the Maipés necropolis of north‐west Gran Canaria     

Valentin R. Troll  Alejandro Rodriguez‐Gonzalez  Frances M. Deegan  Francisco Jos Perez‐Torrado  Juan Carlos Carracedo  Konstantinos Thomaidis  Harri Geiger  Fiona C. Meade 《Geology Today》2019,35(2):55-62

Gran Canaria, like most of the Canary Islands, shows evidence for young basaltic volcanism in the form of cinder cones and valley‐hugging lava flows. These landforms were of no particular use to the aboriginal population, nor to the subsequent Spanish settlers, and young lava flows and lava fields are still referred to as ‘malpaís’ (badlands) in the Canary Islands. In north‐west Gran Canaria, one such lava flow fills the bottom of a steep‐sided valley, which reaches the sea at the present day village of Agaete. The lava flow erupted c. 3030 ± 90 yr bp and displays a total length of ～ 11 km. At its distal end, just outside Agaete, it hosts one of Europe’s largest and most important pre‐historic burial sites constructed of volcanic rock: the Maipés necropolis. Over 700 pre‐historic tombs (or tumuli) constructed from the aa‐type clinker materials have been identified on top of the valley‐filling lava flow. The up to soccer‐ball sized vesicular clinker fragments are sufficiently low in density to provide abundant, workable basalt blocks for the construction of the tumuli, allowing the pre‐hispanic aboriginal population to create a large and magnificent ‘sacred ground’ in an otherwise barren landscape.  相似文献   

Case study: a 3D resistivity and induced polarization imaging from downstream a waste disposal site in Brazil   总被引：2，自引：2，他引：0  

Andréa Teixeira Ustra  Vagner Roberto Elis  Giulliana Mondelli  Lázaro Valentin Zuquette  Heraldo Luiz Giacheti 《Environmental Earth Sciences》2012,66(3):763-772

A contaminated site from a downstream municipal solid waste disposal site in Brazil was investigated by using a 3D resistivity and induced polarization (IP) imaging technique. This investigation purpose was to detect and delineate contamination plume produced by wastes. The area was selected based on previous geophysical investigations, and chemical analyses carried out in the site, indicating the presence of a contamination plume in the area. Resistivity model has successfully imaged waste presence (ρ < 20 Ωm), water table depth, and groundwater flow direction. A conductive anomaly (ρ < 20 Ωm) outside wastes placement was interpreted as a contamination plume. Chargeability model was also able to imaging waste presence (m > 31 mV/V), water table depth, and groundwater flow direction. A higher chargeability zone (m > 31 mV/V) outside wastes placement and following conductive anomaly was interpreted as a contamination plume. Normalized chargeability (MN = m/ρ) confirmed polarizable zone, which could be an effect of a salinity increase (contamination plume), and the clay presence in the environment.  相似文献   

Influence of agricultural development and climate changes on the drainage valley density of the southern half of the Russian Plain   总被引：1，自引：1，他引：0  

Valentin Golosov  Nadezhda Ivanov  Saniya Kurbanova 《国际泥沙研究》2017,32(1)

The southern half of the Russian Plain is characterized by a relatively short history of intensively ploughed lands.The duration varies from approximately three centuries in the southern part of the forest zone to less than one century in some parts of the steppe zone.It was found that after cultivation,on more than 40％ of lands in river basins the drainage valley density (Ddv) decreased by 15-58％ in all landscape zones.In the first stage,the Ddv decrease was mostly associated with increasing surface runoff coefficient after cultivation of virgin lands with proportional decreases in groundwater runoff.In the second stage,usually after reaching areas of arable lands in river basins ＞ 60％,the volume of eroded sediments entering small fiver channels exceeded the transport capacities of the permanent water-courses.As a result,the river channels completely silted.In later stages,the sediment redistribution cascade within the small river basins of the Russian Plain stabilized because of the increasing proportion of sediment eroded from the basin areas and re-deposited before entering the river channels because of the increasing area of sediment sinks due to the increase in dry valley lengths and total areas.The morphological parameters of small valleys and groundwater discharges are the key parameters that affect the intensity of small river aggradation on the regional scale.  相似文献   

Volcanic and structural evolution of Pico do Fogo,Cape Verde          下载免费PDF全文

Juan‐Carlos Carracedo  Francisco J. Perez‐Torrado  Alejandro Rodriguez‐Gonzalez  Raphaël Paris  Valentin R. Troll  Abigail K. Barker 《Geology Today》2015,31(4):146-152

In recent months the media have drawn attention to the Cape Verde archipelago, with particular focus on the island of Fogo, the only island presently active and with an eruption that began on 23 November 2014, finally ceasing on 7 February 2015. The Monte Amarelo conical shield forms most of the 476 km² almost circular island of Fogo. After attaining a critical elevation of about 3500 m, the Monte Amarelo shield volcano was decapitated by a giant landslide that formed a caldera‐like depression (Cha das Caldeiras), which was subsequently partially filled by basaltic nested volcanism. This younger eruptive activity culminated in the construction of the 2829 m‐high Pico do Fogo stratocone, apparently entirely made of layers of basaltic lapilli. Continued growth of the Pico do Fogo summit eruptions was interrupted in 1750, most likely after the stratocone reached a critical height. Since then, at least eight eruptions have taken place inside the landslide depression at the periphery of the Pico do Fogo cone, including the 2014–2015 eruptive event. Strong geological similarities with the Canary Islands, 1400 km to the north, have been frequently noted, probably as a consequence of a common process of origin and evolution associated with a mantle hot‐spot. These similarities are particularly evident when comparing Fogo with the Teide Volcanic Complex on Tenerife, where a lateral collapse of the Las Cañadas stratovolcano also formed a large depression (the Caldera de Las Cañadas), now partially filled with the 3718 m‐high Teide stratocone. However, important geological differences also exist and probably relate to the contrasting evolutionary stages of both islands. The Las Cañadas volcano on Tenerife formed at a late post‐erosional stage, with predominantly evolved (trachyte and phonolite) magmas, while at Fogo basaltic volcanism is still dominant.  相似文献   

Isotopic fingerprints of Milankovitch cycles in Pennsylvanian carbonate platform‐top deposits: the Valdorria record,Northern Spain          下载免费PDF全文

Valentin Chesnel  Óscar Merino‐Tomé  Luis Pedro Fernández  Elisa Villa  Elias Samankassou 《地学学报》2016,28(5):364-373

Sedimentary cyclic sequences deposited during the Late Palaeozoic Ice Age are widespread. Glacio‐eustatic control of the cyclic patterns is commonly accepted, and the durations of the cyclothems generally match the short‐ and long‐eccentricity Milankovitch orbital parameters. Nevertheless, geochemical fingerprints of orbital parameters are poorly documented in deep‐time sedimentary records. Here, we report on well‐exposed Bashkirian cyclothems of c. 123 ka and c. 400 ka durations from the Valdorria platform. The shorter‐term cyclothems can be grouped into longer‐term composite sequences that are consistent with generally accepted durations of c. 125 ka and c. 400 ka for Milankovitch eccentricity cycles. The stratigraphic pattern is mirrored by the isotope geochemical signals, which show distinct recurring trends. These trends are confirmed by statistical tests. Whereas intrinsic factors and/or subaerial exposure related to sea‐level lowstands might have truncated cycle patterns in tectonically stable basins, rapid subsidence of the Valdorria platform's foreland basin appears to have contributed to a faithful recording of cyclothems of different orders. The patterns and biostratigraphic constraint revealed in this study demonstrate the power of orbital forcing in imprinting sedimentary and geochemical signals in the rock record.  相似文献   

Thermal tracer testing in a sedimentary aquifer: field experiment (Lauswiesen,Germany) and numerical simulation   总被引：1，自引：0，他引：1  

Valentin Wagner  Tao Li  Peter Bayer  Carsten Leven  Peter Dietrich  Philipp Blum 《Hydrogeology Journal》2014,22(1):175-187

An active and short-duration thermal tracer test (TTT) was conducted in a shallow sedimentary aquifer at the Lauswiesen test site, near Tübingen, Germany. By injecting 16  m³ of warm water at 22°C, a thermal anomaly was created, which propagated along the local groundwater flow direction. This was comprehensively monitored in five observation wells at a few meters distance. The purpose of this well-controlled experiment was to determine the practicability of such a TTT and its suitability to examine hydraulic characteristics of heterogeneous aquifers. The results showed that the thermal peak arrival times in the observation wells were consistent with previous observations from alternative field testing such as direct-push injection logging (DPIL). Combined analysis of depth-dependent temperatures and peak arrival times, and comparison with a numerical heat transport model, offers valuable insights into the natural flow field and spatial distribution of hydraulic conductivities. The study was able to identify vertical flow focusing and bypassing, which are attributed to preferential flow paths common in such sedimentary sand and gravel aquifers. These findings are fundamental for further development of experimental designs of active and short-duration TTTs and provide a basis for a more quantitative analysis of advective and conductive transport processes.  相似文献