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111.
The Rio do Peixe Basin is part of a series of aborted Cretaceous rifts formed within the Proterozoic Borborema Province, onshore NE Brazil in response to rifting between Africa and South America. The basin is remarkably well-imaged and comprises fault-bounded depocentres, the main ones being the NE-oriented Brejo das Freiras and the E–W-oriented Sousa half-grabens. These grabens and their bounding faults are influenced by Neoproterozoic basement shear zones and present a complex framework of secondary normal faults and folds. Recent workers also interpret large reverse faults and regional post-rift shortening driven by far-field stresses from the Andes. For those reasons, the basin represents an ideal setting to investigate the multiphase history of rift basins. We thus combine borehole-calibrated 2D and 3D seismic and magnetic data with section restoration and numerical modelling to investigate the architecture and evolution of this basin. We aim to understand: (i) the controls of the basement fabric in 3D fault architecture and kinematics and (ii) how syn-rift faults controlled the geometry and development of fault-related folds. By doing this, we also investigate the timing, kinematics, and magnitude of inversion in the basin to explore its multiphase history. We demonstrate that (i) the basement fabric controlled not only the strike of faults but also their geometry and polarity at depth, (ii) folds in the syn-rift sequence are attributed simply to syn-rift extension along stepped and/or curved faults, and (iii) inverted and/or reverse faults occur within the basin, but these are minor and appear to have formed during rifting. We explain this minor inversion by a change in plate kinematics related to the onset of the nearby transform margin to the north. These results have implications for understanding the 3D evolution of oblique grabens, the role of structural inheritance, and the recognition of inversion- versus extension-related folds in rift basins worldwide.  相似文献   
112.
A greenhouse pot experiment was conducted to investigate the effect of compost addition on the phytoremediation ability of Medicago sativa, Brassica napus, and Lolium perenne in soils contaminated with pyrene. Pyrene concentrations were evaluated after 90 days in contaminated uncultivated amended‐soil, cultivated amended‐soils, and shoots and roots of the three plant species. The addition of compost enhances significantly pyrene dissipation from 16 to 26% in uncultivated soil, whereas in cultivated soils it appears not to have any significant effect on pyrene dissipation, neither pyrene was detectable in shoots and roots of the three species examined. The high partition coefficient of pyrene to compost dissolved organic matter (DOM) and the molar absorptivity values at 280 nm (ε280) indicate a high affinity of pyrene to compost DOM molecules, likely due to their aromatic character. These results suggest that compost improves pyrene removal from soil, possibly by promoting its adsorption onto compost DOM. This property is very important in indicating that compost can be used, besides for its amendment capacity, also as a potential tool for remediation of contaminated soils.  相似文献   
113.
Perfluorinated compounds (PFCs), widely used for their hydro-oil repellent properties, are almost non-degradable in the environment; there is scientific evidence that indicate bioaccumulation. They represent a threat to many organisms, because they are toxic and are endocrine disruptors. Scientific studies have demonstrated the presence of PFCs in blood and liver samples of fish, turtles, birds and mammals of marine ecosystems in different geographical areas. The aim of this study was to determine the distribution of PFOS and PFOA in blood samples of the marine turtle Caretta caretta, using a minimally invasive sampling procedure. 49 blood samples of marine turtle, taken from several Italian marine turtle rescue centers, were analyzed. While PFOA was never detected, measurable concentrations of PFOS were found in 15 blood samples; the values show a range from 1.14 ng/g to 28.51 ng/g (wet wt.). No differences between groups of samples taken from different areas were found.  相似文献   
114.
Numerous socio-economic activities depend on the seasonal rainfall and groundwater recharge cycle across the Central American Isthmus. Population growth and unregulated land use changes resulted in extensive surface water pollution and a large dependency on groundwater resources. This work combines stable isotope variations in rainfall, surface water, and groundwater of Costa Rica, Nicaragua, El Salvador, and Honduras to develop a regionalized rainfall isoscape, isotopic lapse rates, spatial–temporal isotopic variations, and air mass back trajectories determining potential mean recharge elevations, moisture circulation patterns, and surface water–groundwater interactions. Intra-seasonal rainfall modes resulted in two isotopically depleted incursions (W-shaped isotopic pattern) during the wet season and two enriched pulses during the mid-summer drought and the months of the strongest trade winds. Notable isotopic sub-cloud fractionation and near-surface secondary evaporation were identified as common denominators within the Central American Dry Corridor. Groundwater and surface water isotope ratios depicted the strong orographic separation into the Caribbean and Pacific domains, mainly induced by the governing moisture transport from the Caribbean Sea, complex rainfall producing systems across the N-S mountain range, and the subsequent mixing with local evapotranspiration, and, to a lesser degree, the eastern Pacific Ocean fluxes. Groundwater recharge was characterized by (a) depleted recharge in highland areas (72.3%), (b) rapid recharge via preferential flow paths (13.1%), and enriched recharge due to near-surface secondary fractionation (14.6%). Median recharge elevation ranged from 1,104 to 1,979 m a.s.l. These results are intended to enhance forest conservation practices, inform water protection regulations, and facilitate water security and sustainability planning in the Central American Isthmus.  相似文献   
115.
We report on simultaneous optical and X-ray observations of the Seyfert galaxy, NGC 3147. The XMM–Newton spectrum shows that the source is unabsorbed in the X-rays  ( N H < 5 × 1020 cm−2)  . On the other hand, no broad lines are present in the optical spectrum. The origin of this optical/X-rays misclassification (with respect to the Unification Model) cannot be attributed to variability, since the observations in the two bands are simultaneous. Moreover, a Compton-thick nature of the object can be rejected on the basis of the low-equivalent width of the iron Kα line (≃130 eV) and the large ratio between the 2–10 keV and the [O  iii ] fluxes. It seems therefore inescapable to conclude that NGC 3147 intrinsically lacks the Broad-Line Region, making it the first 'true' type 2 Seyfert galaxy.  相似文献   
116.
The paper presents the results of an experimental work carried out in a geotechnical centrifuge at the Schofield Centre of Cambridge University. Two reduced scale models of soft barriers in a sand layer underwent a series of ground shaking. In the first model a thin horizontal layer made of latex balloons filled with a cross-linked gel was created at about mid-height of the sand layer. In the second, the same balloons were deployed to form a V-shaped barrier aimed at isolating a relatively shallow volume of sand. The aim of the study was to get experimental evidence of the capability of such soft barriers to isolate a volume of soil thus reducing amplification of ground motion during severe seismic events. The experimental results were compared with FE numerical analyses of the same models, carried out also in free field to have a benchmark condition. By validating the FE modelling via the comparison with the experimental results, a robust model has been built, aimed at being used for carrying out a wider parametric numerical testing. The experimental results confirm the effectiveness of such soft barriers to reduce amplification in the isolated volumes during seismic events.  相似文献   
117.
The existence of linkages between ecological and geomorphological processes and the influence of human activities both on the biota and on geomorphology is well known for terrestrial environments, while it has been seldom reported for submerged ones. A survey in the Noli-Bergeggi area (NW Mediterranean Sea) has been carried out to test the hypothesis that the harvesting of Lithophaga lithophaga has an impact not only on the hammered rock, but also on the sediments at the cliff foot. Size and roundness of pebbles have been measured at different stations and statistical analyses have been used to test the differences between impact and control situations. Results show a dependence of the roundness of pebbles on the date mussel harvesting, indicating a decrease both of the roundness index and of its variability at the cliff foot in impacted sites. Conclusions stress the biogeomorphological nature of this activity, not limited to the present location.  相似文献   
118.
This study examines whether plankton of the Lagoon of Venice could be considered as a bio-indicator of areas subjected to various anthropogenic influences. This study was a two year hydrochemical and biological survey in five areas of the Lagoon of Venice, each with different environmental conditions due to pollution from urban, industrial, thermal and agricultural wastes. Phytoplankton associations did not show any promising species. In the different lagoonal areas, this community was differentiated into its major groups. In contrast, the copepod Acartia tonsa Dana could be considered as a target species in highly eutrophic areas.  相似文献   
119.
In April 2000, we collected box cores from five stations along a cross-shelf transect on the Louisiana (LA) continental shelf. Novel esters of carotenols and chlorins (carotenoid chlorin esters, CCEs), which are highly specific grazing markers, were identified in surface and deep sediments (>10 cm) from the LA shelf. Chlorophyll-a inventory indicated that CCEs are one of the major decay products of chlorophyll-a in shelf sediments. Abundances of total CCEs (9-18%) in surface sediments along the cross-shelf transect were comparable to the abundance of pheophytin-a, pyropheophytin-a, and total steryl chlorin esters (SCEs). Prior work has identified four CCEs which have dehydrated fucoxanthin/fucoxanthinol as a substitute alcohol of phytol. We report on four newly identified CCEs associated with nondehydrated fuxocanthin/fucoxanthinol esterified to (pyro)pheophorbide-a. These nondehydrated CCEs were generally present in lower concentrations than their dehydrated counterparts, but were detectable by atmospheric pressure chemical ionization (APCI) mass spectrometry coupled with high-performance liquid chromatography (HPLC). We attributed differences between this study and previous work to the time allowed for predepositional decay and grazing processes to occur. The rapid sedimentation of CCEs in the shallow water column (ca. 10 m) on the LA shelf allowed for effective burial of all CCEs compared to the deeper water column regions sampled by previous work. This speculation is supported by the fact that the concentrations of CCEs with nondehydrated fucoxanthin/fucoxanthinol were extremely low in sediments from the site on the outer LA shelf with a deeper (253 m) water column. We also tentatively identified an additional CCE and its isomer as fucoxanthinol didehydrate pyropheophorbide-a ester. We suggest that the formation and transformation of CCEs are primarily controlled by the following three biologically mediated reactions: demethoxycarbonylation, dehydration, and deacetylation. Our laboratory copepod grazing experiment also confirmed that CCEs can be excellent class-specific biomarkers of zooplankton grazing on phytoplankton.  相似文献   
120.
The effects of three hydrocarbon dispersant agents (Corexit 9527, Hydrogamosol LT and OSR LT 126) on the bacterial flora of the marine environment are analysed in 20-square-metre basins filled with lagoon seawater.Four months after the first treatment, oil slicks were no longer visible, whereas the appearance of the untreated reference slick had hardly changed. The treatment of 10-litre crude-oil slicks causes an appreciable and long lasting increase in the bacterial population.  相似文献   
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