Impact of ancient metal smelting on arsenic pollution in the Pecora River Valley,Southern Tuscany,Italy     

Pilario Costagliola  Marco Benvenuti  Laura Chiarantini  Sara Bianchi  Francesco Di Benedetto  Mario Paolieri  Luca Rossato 《Applied Geochemistry》2008

A significant As anomaly has been reported in the literature for stream sediments and unlithified Quaternary deposits of the Pecora River valley in Southern Tuscany, extending from the “Colline Metallifere” pyrite-base metals district to the Tyrrhenian Sea. The As anomaly spreads over several square kilometers around a core that exceeds 500 ppm. Several source contributions (from natural to anthropogenic) have been invoked to explain the observed As distribution in the Pecora Valley, including the metal-working industry which was active in this area, particularly in Etrusco-Roman times and in the Middle Ages. In order to evaluate the contribution of ancient mining and metallurgical activities in the Pecora Valley to elevated As concentrations in the environment, a detailed mineralogical and geochemical survey of metallurgical slags and smelted ore minerals was undertaken from six different sites through the Pecora Valley: Poggio Butelli (Etrusco-Roman iron slags); Sata Creek, Arialla, Marsiliana, Forra and Cascata sites (all Medieval base metals slags). The As content of Etrusco-Roman slags is relatively low (few tens of ppm), whereas Medieval slags show variable, but higher amounts of base metals (±Ag) (ranging from tens to tens of thousands ppm) and As (up to 267 ppm, with average contents of about 40 ppm). Arsenic is mostly partitioned in sulfides disseminated through the glassy groundmass rather than in solid solution with the glassy matrix. Remnants of the ore used for base metal and Ag smelting during the Middle Ages had the highest As contents (up to about 1000 ppm).  相似文献   

Magma sources and gold mineralisation in the Mount Leyshon and Tuckers Igneous Complexes, Queensland, Australia: U-Pb and Hf isotope evidence   总被引：2，自引：0，他引：2  

Valeria Murgulov  Suzanne Y. O''Reilly  William L. Griffin  Phillip L. Blevin   《Lithos》2008,101(3-4):281-307

In situ LAM-ICPMS U-Pb, Hf-isotope and trace-element analyses of zircon have been used to evaluate the relative contributions of juvenile mantle and crustal sources to the intrusive rocks of the mafic to intermediate, gold-poor Tuckers Igneous Complex (TIC), and the spatially and temporally related, felsic Mount Leyshon Igneous Complex (MLIC), which hosts a gold-rich porphyry system.

The TIC intrusions range in age from 304.2 ± 9.1 Ma to 288.5 ± 6.4 Ma, and the MLIC intrusions from 291.0 ± 4.8 Ma to 288 ± 6 Ma. Cross-cutting relationships define the intrusion sequence from oldest to youngest; Diorite, Monzodiorite, Mafic Granodiorite and Biotite Microgranite within the TIC; Early Dyke, Southern Porphyry and Late Dyke within the MLIC.

Zircons from the earliest rock type within each complex have a wide range in _Hf (5.2 to 14.8 for the TIC Diorite, 2.0 to 12.4 for the MLIC Early Dykes) suggesting the mixing of juvenile and crustal magmas. This interpretation is supported by trace-element data that show the presence of two distinct zircon populations in the MLIC Early Dyke. The later intrusive rocks have narrower ranges in _Hf (typically < 4 _Hf units) and trace-element patterns of zircon. This homogeneity suggests derivation from magmas produced by further mixing and fractional crystallisation of the TIC Diorite and the MLIC Early Dyke magmas respectively. A greater crustal contribution to the gold-rich MLIC is inferred from the range of median _Hf (3.2 to 4.5 for the MLIC, 5.4 to 8.7 for the TIC). We suggest that the MLIC was derived by melting of more felsic crustal rocks, and with less input from juvenile mantle, then the TIC; it was not derived by fractional crystallisation of an intermediate to mafic TIC-like magma. Modelling of Hf isotope data yields a mean model age of 1040 ± 10 Ma (at ¹⁷⁶Lu/¹⁷⁷Hf = 0.015) for the crustal component in both complexes.

Gold was precipitated in the MLIC Breccia during the emplacement of the Late Dykes. The isotopically homogenous nature of the Late Dykes suggests that no additional juvenile-mantle input was involved at the mineralisation stage. This supports a model in which gold and other metals were indigenous to the Late Dykes magma and were concentrated by magma differentiation and fluid-evolution processes.  相似文献   

New precipitation and temperature grids for northern Patagonia: Advances in relation to global climate grids          下载免费PDF全文

Emilio Bianchi  Ricardo Villalba  Maximiliano Viale  Fleur Couvreux  Rocio Marticorena 《Acta Meteorologica Sinica》2016,30(1):38-52

Climate data of mean monthly temperature and total monthly precipitation compiled from different sources in northern Patagonia were interpolated to 20-km resolution grids over the period 1997–2010. This northern Patagonian climate grid (NPCG) improves upon previous gridded products in terms of its spatial resolution and number of contributing stations, since it incorporates 218 and 114 precipitation and temperature records, respectively. A geostatistical method using surface elevation from a Digital Elevation Model (DEM) as the ancillary variable was used to interpolate station data into even spaced points. The maps provided by NPCG are consistent with the broad spatial and temporal patterns of the northern Patagonian climate, showing a comprehensive representation of the latitudinal and altitudinal gradients in temperature and precipitation, as well as their related patterns of seasonality and continentality. We compared the performance of NPCG and various other datasets available to the climate community for northern Patagonia. The grids used for the comparison included those of the Global Precipitation Climatology Project, ERAInterim, Climate Research Unit (University of East Anglia), and University of Delaware. Based on three statistics that quantitatively assess the spatial coherence of gridded data against available observations (bias, MAE, and RMSE), NPCG outperforms other global grids. NPCG represents a useful tool for understanding climate variability in northern Patagonia and a valuable input for regional models of hydrological and ecological processes. Its resolution is optimal for validating data from the general circulation models and working with raster data derived from remote sensing, such as vegetation indices.  相似文献   

Impact of fishing on size composition and diversity of demersal fish communities   总被引：16，自引：16，他引：16  

Bianchi  G.; Gislason  H.; Graham  K.; Hill  L.; Jin  X.; Koranteng  K.; Manickchand-Heileman  S.; Paya  I.; Sainsbury  K.; Sanchez  F.; Zwanenburg  K. 《ICES Journal of Marine Science》2000,57(3):558-571

  相似文献   

Ficopomatus'Reefs' in the Po River Delta (Northern Adriatic): Their Constructional Dynamics, Biology, and Influences on the Brackish-water Biota     

Carlo Nike  Bianchi Carla  Morri 《Marine Ecology》1996,17(1-3):51-66

Abstract. The serpulid polychaete Ficopomatus enigmaticus (F auvel , 1923) builds huge aggregates in the "Sacca del Canarin", a brackish inlet of the Po River Delta (Italy). Distribution, structure and development of these 'reefs'. together with their associated biota, were studied by field observations and settlement panels from 1977 to 1979. Some aspects of the serpulid biology (settlement periods, tube growth, life strategy) were also taken into account. Ficopomatus reefs influence in many ways the brackish-water ecosystem: they form the main hard substrate; are major sediment source; help in regulating the trophic status of the lagoon; and act as refuge for many invertebrate species.  相似文献   

The Distribution of Polychaetes Along Environmental Gradients: An Example from the Or betel I o Lagoon, Italy     

C. Lardicci    M. Abbiati    R. Crema    C. Morri    C. N. Bianchi  A. Castelli 《Marine Ecology》1993,14(1):35-52

  相似文献   

Size matters more than method: Visual quadrats vs photography in measuring human impact on Mediterranean rocky reef communities     

Valeriano Parravicini  Carla Morri  Giada Ciribilli  Monica Montefalcone  Giancarlo Albertelli  Carlo Nike Bianchi 《Estuarine, Coastal and Shelf Science》2009,81(3):359-367

The performances of two commonly used non-destructive sampling procedures for rocky benthic assemblages (i.e. photography and visually assessed quadrats) were compared. A damaging human activity, date mussel (Lithophaga lithophaga) harvesting (DMH), was chosen. Directly impacted sites were compared with reference conditions (controls). Both visual quadrats and photography were equally able to detect differences between impacted situations and controls. However, visual quadrats showed high variability among replicates and estimated higher species richness for controls, while photography did so for impacts. Pooling photos in a ‘sum photo quadrat’ showed that differences between the two methods are due to sampling unit size rather than sampling procedure itself. As a small sampling unit is unavoidable with photography, visual quadrats should be preferred in investigating shallow rocky reefs for their larger size; however, longer working time underwater with quadrats does not allow for numerous replicates. Pooling many photos to reach sampling sizes comparable with those of quadrats may be a valid alternative to reconcile image resolution and areal coverage.  相似文献   

Nest building in a Mediterranean wrasse (Symphodus ocellatus): are the algae used randomly chosen or actively selected?          下载免费PDF全文

Mauro Sinopoli  Carlo Cattano  Renato Chemello  Angela Timpanaro  Valeria Timpanaro  Michele Gristina 《Marine Ecology》2015,36(4):942-949

  相似文献   

Urban seagrass: status of Posidonia oceanica facing the Genoa city waterfront (Italy) and implications for management     

Montefalcone M  Albertelli G  Morri C  Bianchi CN 《Marine pollution bulletin》2007,54(2):206-213

A system of five adjacent Posidonia oceanica meadows facing the waterfront of Genoa city (Ligurian Sea, NW Mediterranean) was investigated over different spatial scales (meters-kilometers) using three environmental indices: conservation index (CI), substitution index (SI) and phase-shift index (PSI). CI revealed differences mostly at large spatial scale, distinguishing the poor condition of the meadows closest to Genoa centre and harbour from the comparatively healthy condition of the farthest meadows. SI showed differences mostly at small spatial scale (i.e., within meadows), suggesting the influence of local factors in the re-colonisation of regressed meadows by the seagrass Cymodocea nodosa and/or the invasive alga Caulerpa racemosa. Mapping of PSI showed that the meadows closest to Genoa centre and harbour have undergone a nearly total phase shift and have no real potential for recovery: attempts to re-establish P. oceanica there might be a waste of time and money. On the contrary, the meadows farthest from Genoa centre and harbour showed a comparatively low level of phase shift and could still fully recover given specific management actions.  相似文献   

Recent Trends Towards Oligotrophication of the Northern Adriatic: Evidence from Chlorophyll <Emphasis Type="Italic">a</Emphasis> Time Series     

Patricija Mozetič  Cosimo Solidoro  Gianpiero Cossarini  Giorgio Socal  Robert Precali  Janja Francé  Franco Bianchi  Cinzia De Vittor  Nenad Smodlaka  Serena Fonda Umani 《Estuaries and Coasts》2010,33(2):362-375

The results of the updated and quality-checked data base of field observations on chlorophyll a (Chl a) collected in the period 1970–2007 in the Northern Adriatic Sea are presented. From the last decade, SeaWiFS satellite information was also considered. Results demonstrate a global tendency towards Chl a reduction in the period of investigation, which is more marked in the eutrophic area under the influence of the Po River. In the rest of the basin, which presents meso- or oligotrophic characteristics, long-term changes are more difficult to detect. The long-term field dataset can be divided into two periods: the last decade characterized by the strong decrease observed in the whole northern Adriatic and the earlier period with no or slight increase. The recent substantial reduction of Chl a concentrations is confirmed all over the basin (−0.11 mg m⁻³ year⁻¹) from satellite-derived information. Results are consistent with recently evidenced decrease in concentrations of phosphate and ammonia and point to the existence of oligotrophication in the Northern Adriatic. Results indicate forcefully that the still common perception of the Adriatic Sea as a very eutrophic basin is no longer appropriate, at least for its northern part and in recent years.  相似文献