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61.
In the two previous papers of this series, we demonstrated how a novel approach to erosion modelling (Mahleran – Model for Assessing Hillslope‐Landscape Erosion, Runoff And Nutrients) provided distinct advantages in terms of process representation and explicit scaling characteristics when compared with existing models. A first evaluation furthermore demonstrated the ability of the model to reproduce spatial and temporal patterns of erosion and their particle‐size characteristics on a large rainfall‐simulation plot. In this paper, we carry out a more detailed evaluation of the model using monitored erosion events on plots of different size. The evaluation uses four plots of 21·01, 115·94, 56·84 and 302·19 m2, with lengths of 4·12, 14·48, 18·95 and 27·78 m, respectively, on similar soils to the rainfall‐simulation plot, for which runoff and erosion were monitored under natural rainfall. Although the model produces the correct ranking of the magnitude of erosion events, it performs less well in reproducing the absolute values and particle‐size distributions of the eroded sediment. The implications of these results are evaluated in terms of requirements for process understanding and data for parameterization of improved soil‐erosion models. We suggest that there are major weaknesses in the current understanding and data underpinning existing models. Consequently, a more holistic re‐evaluation is required that produces functional relationships for different processes that are mutually consistent, and that have appropriate parameterization data to support their use in a wide range of environmental conditions. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
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This study examined the hysteresis exhibited in concentration–discharge (C–Q) relationships in the runoff from four hydrologically separated fields (catchments) at an intensively managed grassland. The objectives were to examine C–Q relationships constructed from high-resolution time series of flow, temperature, pH, conductivity, nitrate and turbidity, and their implications for hydrological processes. High-resolution datasets from the quality assured records of the Rothamsted Research North Wyke Farm Platform in the UK were examined using a graphical method and cross-correlation statistics. The study found that storm events based C–Q hysteresis reflects the cross-correlation that is generally hidden in time series analysis of large datasets, and that although Q and water quality variables can be effectively influenced by catchment size, the C–Q relationship is less significantly influenced. The dominant C–Q relationships of the water variables in the study area reflect that saturated overland flow was prevalent during the study period in the catchments, while the CCF results indicate coupled transfer of sediments and solute in the area at lag ≥ 0.
EDITOR D. Koutsoyiannis

ASSOCIATE EDITOR M. D. Fidelibus  相似文献   
64.
The processes of hillslope runoff and erosion are typically represented at coarse spatial resolution in catchment‐scale models due to computational limitations. Such representation typically fails to incorporate the important effects of topographic heterogeneity on runoff generation, overland flow, and soil erosion. These limitations currently undermine the application of distributed catchment models to understand the importance of thresholds and connectivity on hillslope and catchment‐scale runoff and erosion, particularly in semi‐arid environments. This paper presents a method for incorporating high‐resolution topographic data to improve sub‐grid scale parameterization of hillslope overland flow and erosion models. Results derived from simulations conducted using a kinematic wave overland flow model at 0.5 m spatial resolution are used to parameterize the depth–discharge relationship in the overland flow model when applied at 16 m resolution. The high‐resolution simulations are also used to derive a more realistic parameterization of excess flow shear stress for use in the 16 m resolution erosion model. Incorporating the sub‐grid scale parameterization in the coarse‐resolution model (16 m) leads to improved predictions of overland flow and erosion when evaluated using results derived from high‐resolution (0.5 m) model simulations. The improvement in performance is observed for a range of event magnitudes and is most notable for erosion estimates due to the non‐linear dependency between the rates of erosion and overland flow. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
65.
The behavior and dynamics of arsenic at Ilha do Mel, Guaraque?aba, and Paranaguá, located in the Paranaguá Estuarine Complex, Brazil, were investigated in this work. Samples were collected in March, September, and December of 2005. With respect to arsenic behavior, the total concentrations were higher for Paranaguá (22.5?±?2.5?μg?L?1) on average, followed by the samples of Guaraque?aba (14.4?±?3.2?μg?L?1) and Ilha do Mel (8.7?±?1.1?μg?L?1). The concentrations found in this work were consistently greater when compared to other estuaries. The results can be attributed to geological factors. Nevertheless, it was also possible to realize that higher concentrations were found in Paranaguá, the more impacted environment. These results represent a strong indication that human activities in the area contribute to the enrichment of the estuary with this metalloid. Arsenic was mainly present in the dissolved phase, which corresponded to more than 70% of the total concentration. This behavior can represent a greater residence time of this metalloid in the water column. The marine phytoplankton presence was decisive in dictating the distribution of As in the waters of Paranaguá estuary. Organic species, which are considered the less toxic, were found in higher concentrations in the eutrophic areas such as Guaraque?aba and Paranaguá. This was a typical behavior during the summer probably due to higher biological activity.  相似文献   
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On 22 January 2003, the M w?=?7.6 Tecomán earthquake struck offshore of the state of Colima, Mexico, near the diffuse triple junction between the Cocos, Rivera, and North American plates. Three-hundred and fifty aftershocks of the Tecomán earthquake with magnitudes between 2.6 and 5.8, each recorded by at least 7 stations, are relocated using the double difference method. Initial locations are determined using P and S readings from the Red Sismológica Telemétrica del Estado de Colima (RESCO) and a 1-D velocity model. Because only eight RESCO stations were operating immediately following the Tecomán earthquake, uncertainties in the initial locations and depths are fairly large, with average uncertainties of 8.0?km in depth and 1.4?km in the north?Csouth and east?Cwest directions. Events occurring between 24 January and 31 January were located using not only RESCO phase readings but also additional P and S readings from 11 temporary stations. Average uncertainties decrease to 0.8?km in depth, 0.3?km in the east?Cwest direction, and 0.7?km in the north?Csouth direction for events occurring while the temporary stations were deployed. While some preliminary studies of the early aftershocks suggested that they were dominated by shallow events above the plate interface, our results place the majority of aftershocks along the plate interface, for a slab dipping between approximately 20° and 30°. This is consistent with the slab positions inferred from geodetic studies. We do see some upper plate aftershocks that may correspond to forearc fault zones, and faults inland in the upper plate, particularly among events occurring more than 3?months after the mainshock.  相似文献   
68.
Sediment pathways and links to offshore processes are considered in the textural and magnetic characteristics of sediments of the intertidal flats and salt marshes of the north Sefton Coast, UK. In addition, sediment from a range of intertidal, marine and fluvial locations within the northwest region has similarly been characterised. Subsequently, the characteristics of these regional sediments, using a multivariate statistical approach of R- and Q-mode factor analyses, have been used to investigate the sediment transport pathways of the north Sefton Coast sediment. The benefits of fractionating sediment samples have been observed, and by using combinations of textural and isothermal remanent magnetic measurements, specific environments within the research have been successfully differentiated and characterised. Linkages between potential sediment source areas have also been established on a particle size-related basis.  相似文献   
69.
Our understanding of the effect of scale on runoff and sediment transfers within catchments is currently limited by a lack of available data. A multi‐scale dataset of 17 rainfall events collected simultaneously at four spatial scales within a small agricultural catchment in 2005–2006 is presented. Analysis using exploratory techniques and a two‐step, zero‐inflated lognormal mixed‐effects regression model, has demonstrated that event responses, and event response characteristics representing runoff and sediment peaks and area‐normalized yields, are scale dependent, and hence cannot be transferred directly between scales. Runoff and sediment yields increase as scale increases, and it is proposed that this effect, which differs from that observed in the few other studies of scale effects undertaken, is due to increasing connectivity within the catchment, and the dominance of preferential flow pathways including through macropores and field drains. The processes contributing to scale dependence in the data, and the possibility that certain processes dominate at particular scales, are discussed. The data presented here help to improve our spatial understanding of runoff and sediment transport in small agricultural catchments, and provide examples of the type of spatial dataset and the type of analysis that are essential if we are to develop models which are able to predict runoff and soil erosion accurately, and allow us to manage runoff and sediment transport effectively across scales. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
70.
The thermal behaviour of silica rocks upon heat treatment is dependent on the constituent minerals and petrographic texture types. These constituents can be shown to be mainly quartz in the form of two types of chalcedony (Length-fast (LF) chalcedony and Length-slow (LS) chalcedony, the latter also being termed quartzine) and moganite. Even though the thermal behaviour of LF-chalcedony is well understood, major uncertainties persist concerning the high-temperature behaviour of LS-chalcedony and moganite. We present here a comparative study of these three constituents of common silica rocks. Our results show that the chemical reaction is the same in all three, Si–OH + HO–Si → Si–O–Si + H2O, but that the reaction kinetics and activation temperatures are very different. LS-chalcedony begins to react from 200 °C upwards, that is at temperatures 50 °C below the ones observed in LF-chalcedony, and shows the fastest reaction kinetics of this ‘water’ loss. Chemically bound water (SiOH) in moganite is more stable at high temperatures and no specific activation temperature is necessary for triggering the temperature-induced ‘water’ loss. Moganite is also found to act as a stabilizer in silica rocks preventing them from temperature-induced fracturing. These findings have implications for the study of potential heat treatment temperatures of silica rocks (in industry and heritage studies), but they also shed light on the different structures of SiO2 minerals and the role of OH impurities therein.  相似文献   
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