Copper oxidation state in chalcopyrite: Mixed Cu d and d characteristics     

C.I. Pearce  D.J. Vaughan  G. van der Laan 《Geochimica et cosmochimica acta》2006,70(18):4635-4642

The determination of the oxidation states of copper and iron in sulfides, and chalcopyrite (CuFeS₂) in particular, using 2p X-ray photoemission spectroscopy (XPS) and L_2,3-edge X-ray absorption spectroscopy (XAS) is revisited. Reassessment of the published spectra derived by these methods produces consistent results and reveals the ‘d count’ in the copper compounds to be intermediate between d⁹ and d¹⁰. Nevertheless, these covalent copper compounds can be divided into those nominally monovalent and those nominally divalent. The Fe L_2,3-edge XAS of chalcopyrite, along with Mössbauer data, confirm the presence of high-spin Fe³⁺. Chalcopyrite, despite recent published reports to the contrary, clearly belongs to the monovalent copper class.  相似文献   

Large Wind Farms and the Scalar Flux over an Heterogeneously Rough Land Surface   总被引：2，自引：2，他引：0  

Marc Calaf  Chad Higgins  Marc B. Parlange 《Boundary-Layer Meteorology》2014,153(3):471-495

The influence of surface heterogeneities extends vertically within the atmospheric surface layer to the so-called blending height, causing changes in the fluxes of momentum and scalars. Inside this region the turbulence structure cannot be treated as horizontally homogeneous; it is highly dependent on the local surface roughness, the buoyancy and the horizontal scale of heterogeneity. The present study analyzes the change in scalar flux induced by the presence of a large wind farm installed across a heterogeneously rough surface. The change in the internal atmospheric boundary-layer structure due to the large wind farm is decomposed and the change in the overall surface scalar flux is assessed. The equilibrium length scale characteristic of surface roughness transitions is found to be determined by the relative position of the smooth-to-rough transition and the wind turbines. It is shown that the change induced by large wind farms on the scalar flux is of the same order of magnitude as the adjustment they naturally undergo due to surface patchiness.  相似文献   

Prediction of piezometric surfaces and drain spacing for horizontal drain design     

Diana I. Cook  Paul M. Santi  Jerry D. Higgins 《Landslides》2012,9(4):547-556

Horizontal drains, used independently or as part of a more complex remediation scheme, are frequently installed to mitigate the effects of increased groundwater in slope stabilization projects. Due to a general trial and error approach to their design, the need for improved design practices has been recognized. The procedures established by Crenshaw and Santi in 2004 made some advances in this direction, but did not account for slopes with drains that were not horizontal or for sloping low-permeability layers underneath the slide mass. Furthermore, the method outlined by Crenshaw and Santi is time-consuming and requires some trial and error calculations to achieve convergence. Therefore, the method has been modified to account for nonhorizontal elements, and a horizontal drain spreadsheet has been developed to streamline the design for projects where horizontal drains will be installed. The horizontal drain spreadsheet may be used to: (1) predict a conservative piezometric profile in a drained slope for use in slope stability analyses, (2) predict piezometric heads in any single piezometer in a drainage field, and (3) predict drain spacing for design purposes. This document explains the revisions to Crenshaw and Santi’s procedures and provides instructions for applying the method. The instructions may be used for hand calculations, but are specifically intended for use with the horizontal drain spreadsheet. The spreadsheet may be used for slopes composed of silty or clayey sands, silts, and silty or sandy clays.  相似文献   

The Corossol structure: A possible impact crater on the seafloor of the northwestern Gulf of St. Lawrence,Eastern Canada     

Patrick Lajeunesse  Guillaume St‐Onge  Jacques Locat  Mathieu J. Duchesne  Michael D. Higgins  Richard Sanfaçon  Joseph Ortiz 《Meteoritics & planetary science》2013,48(12):2542-2558

We report on a 4.1 (±0.2) km diameter and 185 m deep circular submarine structure exposed on the seabed in >40 m water depths in the northwestern Gulf of St. Lawrence (Eastern Canada) from the analysis of high‐resolution multibeam bathymetric and seismic data. The presence of a circular form characterized by a central uplift and concentric rings resembles the morphology and geometry of complex meteorite impact structures. Also, other origins, such as kimberlites, intrusions, karsts, or diapirs, can be eliminated on geological criteria. A single 4 cm long breccia fragment recovered from the central uplift has numerous glassy droplets of fluorapatite composition, assumed to be impact melts, and a single quartz grain with planar intersection features thought to be shock‐induced planar deformation features (PDFs). The absolute age of this possible impact structure is unknown, but its geological setting indicates that it was formed long after the Mid‐Ordovician and before regional pre‐Quaternary sea‐level lowstands. Present results outline the need for further examination to confirm an impact origin and to precisely date the formation of the structure.  相似文献   

PDS 456: an extreme accretion rate quasar?     

J. N. Reeves  P. T. O'Brien  S. Vaughan  D. Law-Green  M. Ward  C. Simpson  K. A. Pounds  R. Edelson 《Monthly notices of the Royal Astronomical Society》2000,312(2):L17-L21

We present quasi-simultaneous ASCA and RXTE observations of the most luminous known active galactic nucleus in the local ( z <0.3) Universe, the recently discovered quasar PDS 456. Multiwavelength observations have been conducted that show that PDS 456 has a bolometric luminosity of ∼10⁴⁷ erg s⁻¹ peaking in the ultraviolet part of the spectrum. In the X-ray band the 2–10 keV (rest-frame) luminosity is 10⁴⁵ erg s⁻¹. The broad-band X-ray spectrum obtained with ASCA and RXTE contains considerable complexity. The most striking feature observed is a very deep, ionized iron K edge, observed at 8.7 keV in the quasar rest-frame. We find that these features are consistent with reprocessing from highly ionized matter, probably the inner accretion disc. PDS 456 appeared to show a strong (factor of ∼2.1) outburst in just ∼17 ks, although non-intrinsic sources cannot be completely ruled out. If confirmed, this would be an unusual event for such a high-luminosity source, with a light-crossing-time corresponding to ∼2 R _S . The implication would be that flaring occurs within the very central regions, or else that PDS 456 is a 'super-Eddington' or relativistically beamed system. Overall we conclude on the basis of the extreme blue/UV luminosity, the rapid X-ray variability and from the imprint of highly ionized material on the X-ray spectrum, that PDS 456 is a quasar with an unusually high accretion rate.  相似文献   

Geochronology of Bonney Drift, Taylor Valley, Antarctica: Evidence for Interglacial Expansions of Taylor Glacier   总被引：1，自引：0，他引：1  

Sean M. Higgins  Chris H. Hendy  & George H. Denton 《Geografiska Annaler: Series A, Physical Geography》2000,82(2-3):391-409

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The structure of force-free magnetic fields     

Evangelidis  E.A.  Vaughan  L.L.  Botha  G.J.J. 《Solar physics》2000,193(1-2):17-32

Incontrovertible evidence is presented that the force-free magnetic fields exhibit strong stochastic behavior. Arnold's solution is given with the associated first integral of energy. A subset of the solution is shown to be non-ergodic whereas the full solution is shown to be ergodic. The first integral of energy is applied to the study of these fields to prove that the equilibrium points of such magnetic configurations are saddle points. Finally, the potential function of the first integral of energy is shown to be a member of the Helmholtz family of solutions. Numerical results corroborate the theoretical conclusions and demonstrate the robustness of the energy integral, which remains constant for arbitrarily long computing times.  相似文献   

Dietary niche separation of three Late Pleistocene bear species from Vancouver Island,on the Pacific Northwest Coast of North America     

Cara Kubiak  Vaughan Grimes  Geert Van Biesen  Grant Keddie  Mike Buckley  Reba Macdonald  M. P. Richards 《第四纪科学杂志》2023,38(1):8-20

Competition between taxa related to climate changes has been proposed as a possible factor in Pleistocene megafaunal extinctions, and here we present isotope evidence of the diets of three co-existing bear species [black bear (Ursus americanus), brown bear (Ursus arctos), and the now extinct short-faced bear (Arctodus simus)] from a locale in western North America dating to the Late (Terminal) Pleistocene (~14.5–11.7 ka). The three bear species were found at several sites on Vancouver Island, on the western coast of Canada. To examine the chronological overlap and niche partitioning between these species of bear, we used direct radiocarbon dating, stable isotope analysis and ZooMS proteomic identification methods. Here we present new radiocarbon evidence from Terminal Pleistocene U. americanus, U. arctos and A. simus from several sites on the island, along with both bulk collagen and compound-specific isotope data for these species. Radiocarbon dates confirm the chronological overlap of Arctodus and both Ursus species in the montane regions of the island at the end of the Pleistocene. Stable isotope data reveal niche differentiation between these species, with U. americanus occupying a distinctly lower trophic position than the other two taxa.  相似文献   

The colours of opaque minerals by A. Peckett. Wiley, 1991. No. of pages: 471. Price: £95.00 (hardback). ISBN: 0471933473     

David J. Vaughan 《Geological Journal》1993,28(2):215-215

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