Factors influencing the release of dissolved organic carbon and dissolved forms of nitrogen from a small upland headwater during autumn runoff events   总被引：1，自引：0，他引：1  

Richard Cooper  Vera Thoss  Helen Watson 《水文研究》2007,21(5):622-633

We identify and assess the relative importance of the principal factors influencing the release of dissolved organic carbon (DOC) and dissolved forms of nitrogen (N) from a small upland headwater dominated by podzolic soils during a sequence of autumn runoff events. We achieve this by subjecting high‐resolution hydrometeorological and hydrochemical data to an R‐mode principal component factor analysis and a stepwise multivariate regression analysis. We find that the release of DOC and N is influenced by four principal factors, namely event magnitude, soil water flow through the Bs horizon, the length of time since the soil profile was last flushed, and rewetting of the H horizon. The release of DOC and dissolved organic nitrogen (DON) is most strongly influenced by the combination of event magnitude and soil water flow through the Bs horizon, and to a lesser extent by the length of time since the soil profile was last flushed. Rewetting of the H horizon also influences the release of DOC, but this is not the case for DON. The release of nitrate (NO₃‐N) is most strongly influenced by the combination of the length of time since the soil profile was last flushed and rewetting of the H horizon, and to a lesser extent by event magnitude. Soil water flow through the Bs horizon does not influence the release of NO₃‐N. We argue that the mechanisms by which the above factors influence the release of DOC and N are probably strongly associated with moisture‐dependent biological activity, which governs the turnover of organic matter in the soil and limits the availability of NO₃‐N in the soil for leaching. We conclude that the release of DOC and N from upland headwaters dominated by podzolic soils is largely controlled by the variable interaction of hydrometeorological factors and moisture‐dependent biological processes, and that a shift in climate towards drier summers and wetter winters may result in the release of DOC and N becoming increasingly variable and more episodic in the future. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Application of LPW and SAI SAFNWC/MSG satellite products in pre-convective environments     

Miguel A. Martinez  Mercedes Velazquez  Marcelino Manso  Irene Mas 《Atmospheric Research》2007,83(2-4):366-379

The Spinning Enhanced Visible and Infrared Imagery (SEVIRI) instrument, on board the Meteosat Second Generation (MSG), is a radiometer with eight infrared (IR) spectral bands. Seven of these channels are used to retrieve Layer Precipitable Water (LPW) and Stability Analysis Imagery (SAI). Both products are the PGE07 and the PGE08 of SAFNWC (Satellite Application Facility on support to Nowcasting and Very Short-Range Forecasting). The authors at Instituto Nacional de Meteorología (INM) have developed the LPW and SAI algorithms, in the SAFNWC framework. Both products are retrieved using statistical retrieval based on neural networks. The main advantage of these algorithms versus physical retrieval algorithms is the independence from the Numerical Weather Prediction (NWP) models. The LPW provides information on the water vapor contained in a vertical column of unit cross-section area in three layers in the troposphere (low, middle and high) and in the total layer in cloud free areas. The SAI provides estimations of the atmospheric instability in cloud free areas, in particular the Lifted Index (LI).The stability and precipitable water obtained with both products are routinely generated every 15 min at a satellite horizontal resolution of 3 km in NADIR. A significant advantage of these MSG products, compared to traditional measurements such as radiosondes, is their ability to measure high resolution temporal and spatial variations of atmospheric stability and moisture in pre-convective environments. The main disadvantage is that they do not have the vertical resolution of radiosonde. The MSG moisture and stability time trend fields are especially useful during the period preceding the outbreak of convection due to the high resolution. Once the outbreak of convection occurs, the products calculated in the clear air pixels surrounding the convective system will allow to foresee the evolution of the convection.  相似文献   

Monitoring Changes of Ice Streams Using Time Series of Satellite-Altimetry-Based Digital Terrain Models     

Ute C. Herzfeld  Craig S. Lingle  Cecily Freeman  Chris A. Higginson  Michael P. Lambert  Li-Her Lee  Vera A. Voronina 《Mathematical Geology》1997,29(7):859-890

The Antarctic Ice Sheet plays a major role in the global system, and the large ice streams discharging into the circumpolar sea represent its gateways to the world's oceans. Satellite radar altimeter data provide an opportunity for mapping surface elevation at kilometer-resolution with meter-accuracy. Geostatistical methods have been developed for the analysis of these data. Applications to Seasat data and data from the Geosat Exact Repeat Mission indicate that the grounding line of Lambert Glacier/Amery Ice Shelf, the largest ice stream in East Antarctica, has advanced 10–12 km between 1978 and 1987–89. The objectives of this paper are to explore possibilities and limitations of satellite-altimetry-based mapping to capture changes for shorter time windows and for smaller areas, and to investigate some methodological aspects of the data analysis. We establish that one season of radar altimeter data is sufficient for constructing a map. This allows study of interannual variation and is the key for a time-series analysis approach to study changes in ice streams. Maps of the lower Lambert Glacier and the entire Amery Ice Shelf are presented for austral winters 1978, 1987, 1988, and 1989. As a first step toward understanding the dynamics of the ice-stream/ice-shelf system, elevation changes are calculated for grounded ice, the grounding zone, and floating ice. In the absence of (sufficient) surface gravity control for the Lambert Glacier/Amery Ice Shelf area, altimetry-based maps may facilitate improvement of geoid models as they provide constraints on the terrain correction in the inverse gravimetric problem.  相似文献   

Post-collisional extension of the East Greenland Caledonides: a geophysical perspective     

Vera Schlindwein  & Wilfried Jokat 《Geophysical Journal International》2000,140(3):559-567

Crustal extension during and following continental collision is well documented in the Arctic Caledonian fold belt. However, models for the post-collisional extension of the Caledonides are mainly based on geoscientific data from Scandinavia. For a more complete understanding of the evolution of the Caledonides, knowledge of the crustal structure of East Greenland is vital. Seismic and gravity studies have revealed a pronounced Moho topography and a west-dipping lower crustal reflector beneath the fjord region of East Greenland. These deep crustal structures are related to Late Caledonian extensional structures at the surface. The observations can be satisfactorily explained by applying simple shear or eduction models proposed for upper crustal extension in Scandinavia to the complementing lower crustal structures in East Greenland. However, exhumation of the Caledonian Northeast Greenland eclogite province cannot be accomplished by these models. Instead, a synthesis of geoscientific data has shown marked differences in the crustal structure of East Greenland north and south of about 76°N, indicating a different crustal evolution of the northern and southern parts of the East Greenland Caledonides.  相似文献   

Low‐frequency modulation and trend of the relationship between ENSO and precipitation along the northern to centre Peruvian Pacific coast          下载免费PDF全文

Luc Bourrel  Pedro Rau  Boris Dewitte  David Labat  Waldo Lavado  Aude Coutaud  Andrea Vera  Abigail Alvarado  Julio Ordoñez 《水文研究》2015,29(6):1252-1266

The relationship between El Niño Southern Oscillation (ENSO) and precipitation along the Peruvian Pacific coast is investigated over 1964–2011 on the basis of a variety of indices accounting for the different types of El Niño events and atmospheric and oceanographic manifestations of the interannual variability in the tropical Pacific. We show the existence of fluctuations in the ENSO/precipitation relationship at decadal timescales that are associated with the ENSO property changes over the recent decades. Several indices are considered in order to discriminate the influence of the two types of El Niño, namely, the eastern Pacific El Niño and the central Pacific El Niño, as well as the influence of large‐scale atmospheric variability associated to the Madden and Julian Oscillation, and of regional oceanic conditions. Three main periods are identified that correspond to the interleave periods between the main climatic transitions over 1964–2011, i.e. the shifts of the 1970s and the 2000s, over which ENSO experiences significant changes in its characteristics. We show that the relationship between ENSO and precipitation along the western coast of Peru has experienced significant decadal change. Whereas El Niño events before 2000 lead to increased precipitation, in the 2000s, ENSO is associated to drier conditions. This is due to the change in the main ENSO pattern after 2000 that is associated to cooler oceanic conditions off Peru during warm events (i.e. central Pacific El Niño). Our analysis also indicates that the two extreme El Niño events of 1982/1983 and 1997/1998 have overshadowed actual trends in the relationship between interannual variability in the tropical Pacific and precipitation along the coast of Peru. Overall, our study stresses on the complexity of the hydrological cycle on the western side of the Andes with regard to its relationship with the interannual to decadal variability in the tropical Pacific. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Spatio-temporal regression kriging for modelling urban NO2 concentrations     

Vera van Zoest  Frank B. Osei  Gerard Hoek  Alfred Stein 《International journal of geographical information science》2020,34(5):851-865

ABSTRACT

Recently developed urban air quality sensor networks are used to monitor air pollutant concentrations at a fine spatial and temporal resolution. The measurements are however limited to point support. To obtain areal coverage in space and time, interpolation is required. A spatio-temporal regression kriging approach was applied to predict nitrogen dioxide (NO₂) concentrations at unobserved space-time locations in the city of Eindhoven, the Netherlands. Prediction maps were created at 25 m spatial resolution and hourly temporal resolution. In regression kriging, the trend is separately modelled from autocorrelation in the residuals. The trend part of the model, consisting of a set of spatial and temporal covariates, was able to explain 49.2% of the spatio-temporal variability in NO₂ concentrations in Eindhoven in November 2016. Spatio-temporal autocorrelation in the residuals was modelled by fitting a sum-metric spatio-temporal variogram model, adding smoothness to the prediction maps. The accuracy of the predictions was assessed using leave-one-out cross-validation, resulting in a Root Mean Square Error of 9.91 μg m^?3, a Mean Error of ?0.03 μg m^?3 and a Mean Absolute Error of 7.29 μg m^?3. The method allows for easy prediction and visualization of air pollutant concentrations and can be extended to a near real-time procedure.  相似文献   

Trends of persistent organic pollutants in the suspended matter of the River Rhine     

Thorsten Pohlert  Gudrun Hillebrand  Vera Breitung 《水文研究》2011,25(24):3803-3817

Recently amended European (EU) water policies call for an adequate monitoring of the chemical status of sediments and suspended matter (SM) in rivers. In this study, we focus on long‐term time series of particle‐bound hexachlorobenzene (HCB) and selected polychlorinated biphenyls (PCB‐138 and PCB‐153) that were monitored biweekly to monthly at eight stations in the River Rhine catchment. Our aims are (1) to detect trends in the concentration series HCB, PCB‐138 and PCB‐153, (2) to estimate the uncertainty of loads caused by SM collection techniques and load calculation procedures and (3) to detect trends in the subsequently calculated annual load series. HCB concentration in the SM for the period 1995–2008 significantly (p < 0·01) decreased at six of the eight monitoring stations. Decreasing PCB‐138 and PCB‐153 concentrations are significant at six of the eight and seven of the eight monitoring stations, respectively. A two‐way analysis of variance (ANOVA) that tested the effect of two collection techniques and four load calculation procedures on annual loads indicates homogeneity of the methods at four of the five monitoring stations. At Weil, only the loads of HCB, PCB‐138 and PCB‐153 are significantly affected by the collection technique. The trend analysis of an extended series (1985–2007) of annual HCB loads at Koblenz showed a significant decrease from about 110 kg year^?1 to about 15–23 kg year^?1; however, in the shorter period (1995–2007) only at two of the eight monitoring stations decreasing trends of annual contaminant load could be detected. We conclude that any of the tested load calculation procedures can be applied, as loads do no differ systematically. Although a high uncertainty in load estimation exists (e.g. maximum percentage error of E = [18·1, 122·5]% for HCB), the monitoring programme at the Rhine is adequate for analysing the long‐term chemical status of SM. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Lead Bioavailability to Freshwater Microalgae in the Presence of Dissolved Organic Matter: Contrasting Effect of Model Humic Substances and Marsh Water Fractions Obtained by Ultrafiltration     

Isabelle A. M. Worms  Vera I. Slaveykova  Kevin J. Wilkinson 《Aquatic Geochemistry》2015,21(2-4):217-230

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Tephra from andesitic Shiveluch volcano,Kamchatka, NW Pacific: chronology of explosive eruptions and geochemical fingerprinting of volcanic glass     

Vera Ponomareva  Maxim Portnyagin  Maria Pevzner  Maarten Blaauw  Philip Kyle  Alexander Derkachev 《International Journal of Earth Sciences》2015,104(5):1459-1482

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Observed spatiotemporal characteristics of drought on various time scales over the Czech Republic   总被引：4，自引：2，他引：2  

Vera Potop  Constanţa Boroneanţ  Martin Možný  Petr Štěpánek  Petr Skalák 《Theoretical and Applied Climatology》2014,115(3-4):563-581

This paper analyses the observed spatiotemporal characteristics of drought in the Czech Republic during the growing season (April to September) as quantified using the Standardised Precipitation Evapotranspiration Index (SPEI) on various time scales. The SPEI was calculated for various lags (1, 3, 6, 12, and 24 months) from monthly records of mean temperature and precipitation totals using a dense network of 184 climatological stations for the period 1961–2010. The characteristics of drought were analysed in terms of the temporal evolution of the SPEI, the frequency distribution and duration of drought at the country level, and for three regions delimited by station altitude. The driest and the wettest years during the growing season were identified. The frequency distribution of the SPEI values for seven drought category classes (in per cent) indicates that normal moisture conditions represent approximately 65 % of the total SPEI values for all time scales in all three regions, whereas moderate drought and moderate wet conditions are almost equally distributed around 10.5 %. Differences in extremely dry conditions (5 %) compared with extremely wet conditions (1.5 %) were observed with increasing SPEI time scales. The results of the non-parametric Mann–Kendall trend test applied to the SPEI series indicate prevailing negative trends (drought) at the majority of the stations. The percentage of stations displaying a significant negative trend for the 90, 95, 99, and 99.9 % confidence levels is approximately 40 %. An Empirical Orthogonal Functions (EOF) analysis was used to identify the principal patterns of variability of the SPEI during the growing season that accounted for the highest amount of statistical variance. The variance explained by the leading EOF range 66 to 56 %, whereas for EOF2 and EOF3, the value is between 7 and 11 % and between 4 and 7 %, respectively, for the SPEI is calculated for 1- to 24-month lags.  相似文献