Influence of the Mississippi River on <Emphasis Type="Italic">Pseudo-nitzschia</Emphasis> spp. Abundance and Toxicity in Louisiana Coastal Waters     

Sibel Bargu  Melissa M. Baustian  Nancy N. Rabalais  Ross Del Rio  Benjamin Von Korff  R. Eugene Turner 《Estuaries and Coasts》2016,39(5):1345-1356

The presence of domoic acid (DA) toxin from multiple species of Pseudo-nitzschia is a concern in the highly productive food webs of the northern Gulf of Mexico. We documented the Pseudo-nitzschia presence, abundance, blooms, and toxicity over three years along a transect ～100 km west of the Mississippi River Delta on the continental shelf. Pseudo-nitzschia were present throughout the year and occurred in high abundances (>10⁴ cells l^?1) in the early spring months during high Mississippi River (MSR) flow (～20,000 m³ s^?1) but were most abundant (>10⁶ cells l^?1) when MSR discharge was relatively lower among the spring months. A high particulate toxin production (maximum reaching 13 μg DA l^?1) was associated with the high cell abundances and exceeded, by an order of magnitude, prior reports of particulate DA concentrations in Louisiana coastal waters. Differences in Pseudo-nitzschia peak times and its toxicity were correlated mainly with the timing and magnitude of MSR discharge and changes in associated parameters such as nutrient stoichiometry and salinity. A negative relationship between high MSR discharge and Pseudo-nitzschia and particulate DA concentrations was documented. These riverine dynamics have the potential to influence DA contamination in pelagic and benthic food webs in the coastal waters of the northern Gulf of Mexico.  相似文献   

Metal enrichment and contamination in a karst cave associated with anthropogenic activities in the Witwatersrand Basin,South Africa     

Gerhard du Preez  Victor Wepener  Ingrid Dennis 《Environmental Earth Sciences》2016,75(8):653

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Kampelite,Ba3Mg1.5Sc4(PO4)6(OH)3·4H2O,a new very complex Ba-Sc phosphate mineral from the Kovdor phoscorite-carbonatite complex (Kola Peninsula,Russia)     

Yakovenchuk  Victor N.  Ivanyuk  Gregory Yu.  Pakhomovsky  Yakov A.  Panikorovskii  Taras L.  Britvin  Sergei N.  Krivovichev  Sergey V.  Shilovskikh  Vladimir V.  Bocharov  Vladimir N. 《Mineralogy and Petrology》2018,112(1):111-121

Mineralogy and Petrology - Kampelite, Ba3Mg1.5Sc4(PO4)6(OH)3·4H2O, is a new Ba-Sc phosphate from the Kovdor phoscorite-carbonatite complex (Kola Peninsula, Russia). It is orthorhombic, Pnma,...  相似文献   

Development,urban planning and political decisions. A triad that built territories at risk     

Lara  Alejandro  Bucci  Felipe  Palma  Cristobal  Munizaga  Juan  Montre-Águila  Victor 《Natural Hazards》2021,109(2):1935-1957

Natural Hazards - Chilean geography exposes the country to high-level risks such as earthquakes and tsunamis. The disasters of 1930, 1960, 2010, and 2014 testify to the continuous link between...  相似文献   

Holocene cool‐water carbonate and terrigenous sediments from southern Spencer Gulf,South Australia     

M. K. Fuller  Y. Bone  V. A. Gostin  C. C. Von Der Borch 《Australian Journal of Earth Sciences》2013,60(4):353-363

Holocene sediments from southern Spencer Gulf are cool‐water carbonate‐rich gravels and sands, dominated by molluscs and Bryozoa. Five sedimentary fades are recognized: (i) molluscan gravel; (ii) branching coralline‐algal gravel, associated with shallow partially protected environments; (iii) molluscan‐biyozoan sand; (iv) mixed bioclastic sand, representative of the deeper central region of the lower gulf; and (v) bryozoan gravel, an isolated fades developed in a semi‐protected micro‐environment. The southern gulf is characterized by complex oceanographic conditions together with variations in water depth and substrate. The sediments share the characteristics of both the southern shelf and upper Spencer Gulf. Grain‐size distribution and sedimentary facies are controlled by a combination of all the above processes. Past sea level fluctuations are recognized from sea floor strand‐line deposits. The relic component of the palimpsest sediments has eroded from the Pleistocene aeolianite dunes. The sediments, therefore, reflect both the modern marine and past environments.  相似文献   

Mg---NH₄ exchange on humic acid: A radiotracer technique for conditional exchange constants in a seawater medium     

Marta T. Von Breymann  C. Andr  Ungerer  Erwin Suess 《Chemical Geology》1988,70(4):349-357

A radiotracer technique, employing ²⁷Mg, is used to determine the Mg released by ammonium exchange on undis-solved humic acid in a seawater medium. This new method allows for the measurement of exchangeable Mg on the solid phase surface, which eliminates the problem caused by the high-Mg background in the seawater matrix. The precision calculated from the counting statistics is better than ±2%; the reproducibility among repeated counts ranged from ±1% to ±3%. The higher sensitivity of the method allows for monitoring the Mg---NH₄ exchange at concentrations as low as 30 mM NH₄. This is a major improvement relative to the data obtained with the analytical methods used so far, which allow detection of exchangeable Mg only at NH₄ concentrations higher than 1 M. The lower experimental concentrations are more in accordance with the natural ammonium levels found in anoxic marine sediments. For the undissolved humic acid used in this experiment, the amount of exchangeable Mg in apparent equilibrium with an ammonium-free seawater matrix was found to be 96.6 ± 0.4 meq/100g. The Mg---NH₄ exchange on humic acid in seawater comes to a steady-state value in < 18 min. The conditional equilibrium constant obtained for this reaction, K_cond = 0.039 ± 0.001 M⁻¹. The technique can be expanded to other geochemical solid phases in seawater and it can be modified to study the behavior of the major cations by using ²⁴Na, ⁴²K and ⁴⁹Ca.  相似文献   

Activity-composition relations in FeTiO3-MnTiO3 ilmenite solid solutions from EMF measurements at 1050–1300 K     

Hugh St. C. O'Neill  Mark I. Pownceby  Victor J. Wall 《Contributions to Mineralogy and Petrology》1989,103(2):216-222

The activity of FeTiO₃ in the binary ilmenitepyrophanite (FeTiO₃-MnTiO₃) solid solution has been determined for the temperature range 1050–1300 K by displacement of the reaction: 2 FeTiO₃=2 Fe+2 TiO₂+O₂ in T-O₂ space, using an electrochemical technique with calcia- and yttria-stabilized zirconia solid electrolytes. The activities show small positive deviations from ideality, which, although the data are unusually precise, may be perfectly described by the simple regular solution model, with an interaction parameter, W _Fe-Mn ^ilm , of 2.2±0.3 kJ g-atom^–1, which is independent of temperature. This value, together with the experimental data on the partitioning of Fe and Mn between ilmenite and garnet (Pownceby et al. 1987), gives W _Fe-Mn ^gt =1.2±0.5 kJ g-atom^–1 for the almandine-spessartine (Fe₃Al₂Si₃O₁₂-Mn₃Al₂Si₃O₁₂) solid solution.  相似文献   

Geography's Research Performance Based on Annals Manuscripts, 1987–1993*     

Stanley D. Brunn 《The Professional geographer》1995,47(2):204-215

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The compressibility of silicate liquids containing Fe2O3 and the effect of composition,temperature, oxygen fugacity and pressure on their redox states     

Victor C. Kress  Ian S. E. Carmichael 《Contributions to Mineralogy and Petrology》1991,108(1-2):82-92

Ultrasonic longitudinal acoustic velocities in oxidized silicate liquids indicate that the pressure derivative of the partial-molar volume of Fe₂O₃ is the same in iron-rich alkali-, alkaline earth- and natural silicate melt compositions at 1 bar. The dV/dP for multicomponent silicate liquids can be expressed as a linear combination of partial-molar constants plus a positive excess term for Na₂O−Al₂O₃ mixing. Partial-molar properties for FeO and Fe₂O₃ components allow extension of the empirical expression of Sack et al. (1980) to permit the calculation of Fe-redox equilibrium in a natural silicate liquid as a function of composition, temperature, fo₂ and pressure; a more formal thermodynamic expression is presented in the Appendix. The predicted equilibrium fo₂ of natural silicate melts, of fixed oxygen content, closely parallels that defined by the metastable assemblage fayalite+magnetite+β-quartz (FMQ), in pressure-temperature space. A silicate melt initially equilibrated at 3 GPa and FMQ, will remain within approximately 0.5 log₁₀ units of FMQ during its closed-system ascent. Thus, for magmas closed to oxygen, iron-redox equilibrium in crystal-poor pristine glassy lavas represents an excellent probe of the relative oxidation state of their source regions.  相似文献   

Book review     

Konrad Von Moltke 《Climatic change》1991,18(4):471-472

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