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171.
Massimo Chiaradia Dave Banks Robert Cliff Robert Marschik Antoine de Haller 《Mineralium Deposita》2006,41(6):565-573
The origin of the hypersaline fluids (magmatic or basinal brine?), associated with iron oxide (Cu–U–Au–REE) deposits, is controversial. We report the first chlorine and strontium isotope data combined with Cl/Br ratios of fluid inclusions from selected iron oxide–copper–gold (IOCG) deposits (Candelaria, Raúl–Condestable, Sossego), a deposit considered to represent a magmatic end member of the IOCG class of deposit (Gameleira), and a magnetite–apatite deposit (El Romeral) from South America. Our data indicate mixing of a high δ 37Cl magmatic fluid with near 0‰ δ 37Cl basinal brines in the Candelaria, Raúl–Condestable, and Sossego IOCG deposits and leaching of a few weight percent of evaporites by magmatic-hydrothermal (?) fluids at Gameleira and El Romeral. The Sr isotopic composition of the inclusion fluids of Candelaria, Raúl–Condestable, and El Romeral confirms the presence of a non-magmatic fluid component in these deposits. The heavy chlorine isotope signatures of fluids from the IOCG deposits (Candelaria, Raúl–Condestable, Sossego), reflecting the magmatic-hydrothermal component of these fluids, contrast with the near 0‰ δ 37Cl values of porphyry copper fluids known from the literature. The heavy chlorine isotope compositions of fluids of the investigated IOCG deposits may indicate a prevailing mantle Cl component in contrast to porphyry copper fluids, an argument also supported by Os isotopes, or could result from differential Cl isotope fractionation processes (e.g. phase separation) in fluids of IOCG and porphyry Cu deposits. 相似文献
172.
Planning for source water protection in Ontario 总被引:2,自引:0,他引:2
Ontario began developing a drinking water source protection planning process in 2000, after a rural community's water supply was contaminated by pathogens from agricultural runoff. An expert committee report has recommended legislating a new source protection “sphere of jurisdiction” for municipalities; however, no specific new municipal tools or authorities have been proposed as yet. This paper reports findings from an evaluation of the extent to which existing institutional arrangements for land use planning and water management facilitate or constrain source protection by municipalities. A case study of the Regional Municipality of Waterloo suggests there is the potential to link land use planning more strongly to water management through creative use of existing tools, forgoing the need for major institutional changes. 相似文献
173.
Variable vegetation cover and episodic sand movement on longitudinal desert sand dunes 总被引:6,自引:0,他引:6
Longitudinal (linear) sand dunes of the Simpson and Strzelecki dunefields in eastern central Australia present a paradox. Low levels of activity today stand in contrast to luminescence dating which has repeatedly shown deep deposits of sand on dune crests dating to within the late Holocene. In order to investigate the nature of dune activity in the Simpson–Strzelecki dunefield, vegetation and sand mobility were investigated by detailed vegetation survey and measurement of rippled area and loose sand depth of dunes at three sites along a climatic gradient. The response of both vegetation and sand movement to inter-annual climate variability was examined by repeat surveys of two sites in drought and non-drought conditions. Projected plant cover and plant + crust cover were found to have inverse linear relationships with rippled area and the area of deep loose sand. No relationship was found between these measures of sand movement and the plant frontal area index. A negative exponential relationship between equivalent mobile sand depth on dune surfaces and both vascular plant cover and vascular + crust cover was also found. There is no simple threshold of vegetation cover below which sand transport begins. Dunes with low perennial plant cover may form small dunes with slip faces leading to a positive feedback inhibiting ephemeral plant growth in wet years and accelerating sand transport rates. The linear dunefields are largely within the zone in which plant cover is sufficient to enforce low sand transport rates, and in which there is a strong response of vegetation and sand transport to inter-annual variation in rainfall. Both ephemeral plants (mostly forbs) and crust were found to respond rapidly to large (> 20 mm/month) rainfall events. On millennial time-scales, the level of dune activity is controlled by vegetation cover and probably not by fluctuations of wind strength. Land use or extreme, decadal time-scale, drought may destabilise dunes by removing perennial plant cover, accelerating wind erosion. 相似文献
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176.
Paul Augustinus Michael Reid Sofia Andersson Yanbin Deng Mark Horrocks 《Journal of Paleolimnology》2006,35(4):789-805
Frozen sediment cores from Lake Pupuke in Auckland City, New Zealand, contain a high resolution decadal to annual scale record
of changing lake paleoenvironments and geochemistry that reflects changing landuse and hydrology in the catchment over the
past c. 190 years. A reliable chronology is available from AMS 14C and 210Pb dating of the sediments, with the timing of the older part of the record supported by the first appearance of pollen of
introduced Pinus and Plantago lanceolata associated with European settlement of Auckland in the early 1840s. Diatom stratigraphy, sediment elemental and carbon isotope
geochemistry reflect changes in sediment sources and lake conditions commensurate with European development of the Lake Pupuke
catchment, in particular enhanced algal productivity controlled by the influx of nutrients after c. 1920 AD. Attempts to prevent
nuisance algal blooms in 1933, 1934 and 1939 using CuSO4 addition produced Cu spikes in the sediment that allowed confirmation of the accuracy of the 210Pb chronology. Hence, the elemental and isotopic composition of the Lake Pupuke sediments reflect the timing of significant
anthropogenic activities, rather than climatic variations, that have occurred within the watershed over the past c. 190 years.
The comparison of records of land use change in the catchment with the multi-proxy record of changes in the sediments usually
allowed unambiguous identification of the signatures of change and their causes. 相似文献
177.
Lionel F. Villarroel Jerry R. Miller Paul J. Lechler Dru Germanoski 《Environmental Geology》2006,51(2):283-299
An intense, but localized rainfall event in February 2003, led to the severe erosion and failure of a tailings disposal impoundment at the Abarόa Antimony Mine in southern Bolivia. The failure released approximately 5,500 m3 of contaminated tailings into the Rio Chilco-Rio Tupiza drainage system. The impacts of the event on sediment quality are examined and compared to contamination resulting from historic mining operations in the headwaters of the basin. Of primary concern are contaminated floodplain soils located along downstream reaches of the Rio Tupiza which were found to contain lead (Pb), zinc (Zn), and antimony (Sb) concentrations that locally exceed Canadian, German, and Dutch guidelines for agricultural use. Spatial patterns in sediment-borne trace metal concentrations, combined with Pb isotopic data, indicate that Pb, Zn, and Sb are derived from three tributary basins draining the Abarόa, Chilcobija, and Tatasi-Portugalete mining districts. Downstream of each tributary, geographical patterns in trace metal concentrations reflect local geomorphic changes throughout the drainage system. Trace metal concentrations within the Rio Chilco decrease rapidly downstream as a result of dilution by uncontaminated sediments and storage of metal enriched particles (e.g., sulfide minerals) in the channel bed as a result of ongoing aggradation. Storage in the floodplains is limited. These processes significantly reduced the dispersal and, thus, the relative environmental affects of tailings eroded from the Abarόa Mine during the 2003 flood. In contrast, storage of Pb, Zn, and Sb in floodplains along the Rio Tupiza is significant, the majority of which is derived from historic mining operations, particularly mining within the Tatasi-Portugalete district. 相似文献
178.
Geraldo Magela da Costa Gabriel de Oliveira Polli Márcio A. Kahwage Eddy de Grave Antônio Claret Soares Sabioni Júlio Cesar Mendes 《Physics and Chemistry of Minerals》2006,33(3):161-166
Mössbauer spectra (MS) of blue, green and yellow beryl (ideally Be3Al2Si6O18) containing approximately 1% of iron were obtained at 295 and 500 K. Room temperature (RT) spectra of both blue and green samples showed the presence of an asymmetric Fe2+ doublet (ΔE
Q~2.7 mm/s, δ~1.1 mm/s), with a very broad low-velocity peak. There is no clear evidence for the presence of a ferric component. The MS of the yellow sample at RT consists of an intense central absorption with parameters typical for Fe3+ (ΔE
Q~0.4 mm/s, δ~0.29 mm/s), plus an apparently symmetrical Fe2+ doublet. This sample acquires a light-blue shade upon heating in air at about 620 K. Thermal treatments at high temperatures caused no significant changes in the MS, but the green and yellow beryl acquire a blue colour. All these results are interpreted in relation to the existence of channel water and the distribution of iron among the available crystallographic sites. 相似文献
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