The Pozzo del Sale Groundwaters (Irpinia, Southern Apennines, Italy): Origin and Mechanisms of Salinization     

Tiziano Boschetti  Vincenzo De Felice  Fulvio Celico 《Aquatic Geochemistry》2013,19(4):303-322

Chemical and water isotope ratios data for groundwaters from the Pozzo del Sale area in the Irpinia sector of the Southern Apennines are presented. The water chemistry of the aquifer system may initially be regarded as the result of easy and common, low temperature interaction between meteoric water and Late Messinian evaporites, which produce Ca-bicarbonate and Na-chloride passing through Ca-sulfate waters. However, a closer inspection reveals a more complicated geochemical setting consisting of: (1) two further Na-sulfate and Ca(Mg)-sulfate waters; (2) the existence of different meteoric recharge areas; (3) the mixing between the different groundwaters and allochthonous fluids from terrestrial mud volcanoes. The salinization mechanism and the local mineralogy were inferred by classical and novel ternary and binary diagrams. The presence of MgSO₄- and Na₂SO₄-bearing minerals of non-marine or mixed origin other than gypsum and halite within the local evaporites suggests a mineralogical heterogeneity within the local Messinian evaporites. The paleoenvironment of this sector of the Gessoso–Solfifera Formation might have been composed of relatively small playa-lakes fed by seawater but also large amounts of continental waters of meteoric origin.  相似文献   

Re-assessment of foundation settlements for the Burj Khalifa, Dubai     

Gianpiero Russo  Vincenzo Abagnara  Harry G. Poulos  John C. Small 《Acta Geotechnica》2013,8(1):3-15

This paper deals with the re-assessment of foundation settlements for the Burj Khalifa Tower in Dubai. The foundation system for the tower is a piled raft, founded on deep deposits of calcareous rocks. Two computer programs, Geotechnical Analysis of Raft with Piles (GARP) and Non-linear Analysis of Piled Rafts (NAPRA) have been used for the settlement analyses, and the paper outlines the procedure adopted to re-assess the foundation settlements based on a careful interpretation of load tests on trial piles in which the interaction effects of the pile test set-up are allowed for. The paper then examines the influence of a series of factors on the computed settlements. In order to obtain reasonable estimates of differential settlements within the system, it is found desirable to incorporate the effects of the superstructure stiffness which act to increase the stiffness of the overall foundation system. Values of average and differential settlements for the piled raft calculated with GARP and NAPRA were found to be in reasonable agreement with measured data on settlements taken near the end of construction of the tower.  相似文献   

Cave clastic sediments as a tool for refining the study of human occupation of prehistoric sites: insights from the cave site of La Cala (Cilento,southern Italy)          下载免费PDF全文

Ivan Martini  Annamaria Ronchitelli  Simona Arrighi  Giulia Capecchi  Stefano Ricci  Sem Scaramucci  Vincenzo Spagnolo  Paolo Gambassini  Adriana Moroni 《第四纪科学杂志》2018,33(5):586-596

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Hercynian subduction-related processes within the metamorphic continental crust in Calabria (southern Italy)     

Fabrizio Tursi  Richard Spiess  Vincenzo Festa  Rosa Anna Fregola 《Journal of Metamorphic Geology》2020,38(7):771-793

Linking the deformation history of mylonitized continental rocks to the progress of devolatilization reactions that trigger reaction softening is critical for the understanding of crustal scale processes. We have analysed the field geometries and microstructures of deformed rocks within the southern Hercynian belt in Calabria, as well as modelled the pressure–temperature–deformation (P–T–d) trajectory of a main ductile shear zone that tectonically coupled the deeper crustal Mammola Paragneiss Unit with the upper crustal Stilo–Pazzano Phyllite Unit. P–T modelling of the mylonitic Mammola Paragneiss Unit was performed through calculation of phase equilibrium diagrams with the software thermocalc in the MnNCKFMASHTO model system. The prograde P–T–d trajectory is based on the zoning profiles of garnet porphyroblasts and their mineral inclusions, primarily barroisite and epidote. P–T modelling shows that peak metamorphic conditions of ~0.9 GPa and 585°C were reached during a D_n-1 under-thrusting event. The following exhumation during the D_n mylonitic event, and contact metamorphism during D_n+1 and D_n+2 folding events, have also been modelled because they are essential to restore the previous tectono-metamorphic history. The exhumation trajectory was modelled down to 0.3 GPa with temperatures of 440–460°C, under fluid-deficient conditions, as well as the final late Carboniferous contact metamorphism up to T_max of 680–720°C. The prograde path shows clear evidence for thermal buffering during garnet growth at the expense of chlorite, with a heating-dominated stage after chlorite breakdown. Subsequently, a rheological change associated with epidote breakdown (i.e. reaction softening) occurred, highlighted by a net steepening of the P/T trajectory towards the pressure peak. On the basis of the barroisite inclusions within garnet porphyroblasts as well as the ‘hairpin’ shape of the reconstructed P–T–d path (before contact metamorphism), we infer that the unusual low T/P gradient for the Hercynian crust exposed in the Mammola Paragneiss Unit records its involvement in the Palaeotethys–Gondwana subduction beneath Laurussia during D_n-1 under-thrusting. We present a new palaeotectonic interpretation along the southern Hercynian belt in Calabria during the Upper Mississippian–Lower Pennsylvanian, that is consistent with previous geochronology studies.  相似文献   

Hypersaline groundwater genesis assessment through a multidisciplinary approach: the case of Pozzo del Sale Spring (southern Italy)   总被引：1，自引：1，他引：0  

Fulvio Celico  Paolo Capuano  Vincenzo De Felice  Gino Naclerio 《Hydrogeology Journal》2008,16(7):1441-1451

A tool, based on a multidisciplinary field investigation approach for studying the characteristics of a hypersaline spring, was developed and its effectiveness tested on a spring in southern Italy; a preliminary model of the aquifer system at medium and local scale was derived. Hydrologic measurements, vertical electric soundings, and chemical and isotopic (δ¹⁸O, δ²H, ³H) analyses were undertaken, along with microbiological analyses and species identification. These demonstrate the coexistence of hypersaline and fresh water, generating a significant diversification of the groundwater hydrochemical signature. The isotopic signature shows that both types of water have a meteoric origin. Microbial contamination of fecal origin indicates the mixing of hyper- and low- saline water related to local infiltration. The hypersaline groundwater flows in confined horizons within a sequence that is mainly of fractured clays. These horizons are probably concentrated where well-developed fracture network and dissolution openings within evaporitic rocks enhance fluid flow. In a wider context, this study determines that microbiological pollution of saline groundwater may not be detected if using nonhalophilic bacterial indicators such as fecal coliforms. Fecal enterococci are better indicators, due to their higher halotolerance.  相似文献   

Removal of Lead,Copper, Zinc and Cadmium from Water Using Phosphate Rock   总被引：2，自引：0，他引：2  

Alessia CORAMI  Silvano MIGNARDI  Vincenzo FERRINI 《《地质学报》英文版》2008,82(6):1223-1228

Removal of Pb^2＋, Cu^2＋, Zn^2＋ and Cd^2＋ from aqueous solutions by sorption on a natural phosphate rock （FAP） was investigated. The effects of the contact time and initial metal concentration were examined in the batch method. The percentage sorption of heavy metals from solution ranges generally between 50% and 99%. The amount of sorbed metal ions follows the order Cu〉Pb〉Cd〉Zn. Heavy metal immobilization was attributed to both surface complexation of metal ions on the surface of FAP grains and partial dissolution and precipitation of a heavy metal-containing phosphate. The very low desorption ratio of heavy metals further supports the effectiveness of FAP as an alternative and low-cost material to remove toxic Pb^2＋, Cu^2＋, Zn^2＋ and Cd^2＋ from polluted waters.  相似文献   

Mineralogy,chemistry, and grain size composition of recent sediments in the northern Tyrrhenian Sea: Contribution to the study of sediment transport and distribution     

Leonardo Leoni  Franco Sartori  Maurizio Saitta  Vincenzo Damiani  Ornella Ferretti  Monique Viel 《Environmental Geology》1991,17(1):23-46

As a contribution to an environmental study on Tuscany's marine shelf, textural, mineralogical, and chemical characteristics of recent sediments in the northern Tyrrhenian Sea between Elba Island and Livorno have been analyzed. The data provide clear information on sediment sources and movement patterns. The main sediment source appears to be the Cecina River; very subordinate is the contribution of the Fine River. As to sediment movement patterns, the surveyed basin appears to be divided into two subbasins: (1) a greater, southern subbasin, bounded by Tuscany mainland, Elba Island and Elba Ridge, and Capraia Isle, and Vada Shoals; and (2) a smaller, northern subbasin, enclosed between Vada Shoals and Meloria Shoals (off Livorno port).In the former the coarse-grade Cecina River sediments are transported southward along most of the mainland coast by littoral drift and coastal current; a northward flowing countercurrent seems to be active only in the southernmost part. Silts and clays are distributed in concentric belts around basin's central part, being transported mainly by slow circular water movements. In the marginal western zone, very little terrigenous influx is coupled with a high biologic productivity, and biogenic debris sedimentation prevails there.In the northern subbasin the sediment contribution from Fine River is more appreciable. Here the environmental energies are very low and the coarse sediments are restricted to a few small pocket beaches where they are deposited by local creeks. Most of the subbasin area is occupied by sapropelitic muds, again distributed by slow small-scale gyres.  相似文献   

Laboratory determination of mechanical and hydraulic properties of chemically grouted sands     

Daniela Porcino  Vito Nicola Ghionna  Raffaella Granata  Vincenzo Marcianò 《Geomechanics and Geoengineering》2016,11(2):164-175

The purpose of this paper is to investigate mechanical and hydraulic properties of sands treated with mineral-based grouts through the results of a laboratory test programme consisting of unconfined compression tests (UCS), triaxial bender element tests (BeT) and constant flow permeability tests in triaxial apparatus. An improved apparatus was set up for obtaining high quality, multiple grouted specimens from a single column. Two selected natural sands having different grain sizes were grouted with two mineral-based silica grouts, resulting in different levels of improvement. The behaviour of the sands treated by mineral grouts, in terms of strength, initial stiffness and permeability, was compared with that exhibited by more traditional silicate grouts. The results of this study indicate that sands treated with mineral grouts result in higher strengths, higher initial shear modulus and lower permeability values than the sands treated with the silicate solution. The effect of grout type, effective confining pressure, and sand particle-size on small-strain shear modulus of grouted sand specimens was evaluated. Based on test results, the small strain shear modulus increment from treated to untreated specimens has been correlated with the unconfined compressive strength, obtaining a unique relationship regardless of grout type and grain-size of tested sands.  相似文献   

Analysis of spatial and temporal rainfall trends in Sicily during the 1921–2012 period     

Lorena Liuzzo  Enrico Bono  Vincenzo Sammartano  Gabriele Freni 《Theoretical and Applied Climatology》2016,125(1-2):113-130

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Caisson breakwaters embodying an OWC with a small opening—Part II: A small-scale field experiment     

Paolo Boccotti  Pasquale Filianoti  Vincenzo Fiamma  Felice Arena 《Ocean Engineering》2007,34(5-6):820-841

A common and intuitive idea is that, before an absorbing breakwater, waves are smaller than before a conventional reflecting breakwater. The theory of Part I has shown that, on the contrary, before a breakwater converter, in some cases, the wave height may be greater than before a conventional reflecting breakwater. Now, an experiment off the eastern coast of the Straits of Messina provides a confirmation of the theory: some huge amplifications of swells are common at a breakwater converter, and as a consequence the energy absorption gets very large. Here, we show the results of the experiment, and, basing ourselves on these results and on the theory of Part I, we suggest some practical way of calculation.  相似文献