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91.
对20个氯代苯酚类化合物进行了CNDO/2量子化学计算,讨论了化合物电子结构与其对水生物翻车鱼(Bluegill)、花鳉鱼(Guppy)、和虾(Shrimp)半致死量之间的关系,分别获得了表示其构效关系的三个线性方程,它们的显著性均远高于α=0.01水平。结果表明:氯代苯酚化合物苯环上碳原子的兀电荷之和(∑Qπ_R)越大苯环上碳原子的净电荷之和(∑Q_R)越大,或LUMO轨道能(E_(LUMO))越低,均使化合物对Bluegill和Guppy水生物的毒性增大;而化合物苯环上羟基邻位的碳原子的兀电荷布居(P_3)越大,同时HOMO轨道能E_(HOMO)越高,则化合物对Shrimp毒性也越大。据此,可预测氯代苯酚类化合物对上述三种水生物的毒性。  相似文献   
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One zone modeling of the irregular variability of red super-giants is intended with regard to the nonlinear coupling of finite amplitude pulsation with convection. The nonlocal mixing length is employed for the evaluation of the convective flux, the turbulent pressure and the turbulent power of temperature fluctuations. The radial pulsation and the Boussinesq convection are assumed for simplicity. The one zone is defined as the layer having the entropy maximum and the minimum at the bottom and at the top, respectively. The quasi-adiabatic approximation is consistent with this definition in fixing the zone to the same mass range. The spatial derivatives are evaluated under the assumption of homologous changes with the equilibrium homologous parameters. Then, a set of 6 simultaneous first order nonlinear ordinary differential equations are obtained as the one zone representation of the irregular variability of the convective envelope.  相似文献   
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Theoretical line ratios involving 2s 2 S - 3p 2 P, 2p 2 P - 3s 2 S, and 2p 2 S - 3d 2 D transitions inCiv between 312 and 420 Å are presented. A comparison of these with solar active region observational data obtained during a rocket flight by the Solar EUV Rocket Telescope and Spectrograph (SERTS) reveals good agreement between theory and experiment, with discrepancies that average only 22%. This provides experimental support for the accuracy of the atomic data adopted in the line ratio calculations, and also resolves discrepancies found previously when the theoretical results were compared with solar data from the S082A instrument on boardSkylab. The potential usefulness of theCIV line ratios as electron temperature diagnostics for the solar transition region is briefly discussed.  相似文献   
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In the Southampton Water estuary (southern England, U.K.), red-tides caused by the planktonic, phototrophic ciliateMesodinium rubrum(=Myrionecta rubra) occur during most summers and sometimes in autumn. These events were investigated in detail between 1985 and 1987 and were characterized by levels of chlorophylla(chl a) of over 100 μg l−1, cell numbers ofM. rubrumof over 1×103 ml−1, oxygen saturations of around 150%, and depleted numbers of macrozooplankton. Initiation of red-water did not appear to be triggered by irradiance or nutrients, but coincided with an increase in temperature and water column stability. This enhanced stability was promoted by increased surface to bottom gradients of both temperature and salinity, and by reduced mixing during neap tides. Development of red-water was accompanied by removal of most of the dissolved NH+4from the water column, whereas some NO3persisted, presumably maintained by freshwater input. NO3and NH+4gradually returned to pre-bloom concentrations as the red-water declined in late summer. Maximal biomass ofM. rubrumappeared to be limited by irradiance, and self-shading probably imposed an upper limit of around 300 mg chl a m−2within the water column. At the observed levels of chl a, irradiance values within the population maximum between 1 and 3 m depth were only just of the order (≈15 μmol photons m−2 s−1) required to balance estimated respiratory demands. Oxygen concentration became undersaturated during the late bloom phase, with minimal values of 20–30% saturation recorded in deeper waters; however, despite this and reduced numbers of macrozooplankton, direct deleterious effects on other organisms were not observed.  相似文献   
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使用中国科学院紫金山天文台青海站13.7米射电望远镜于1996年12月至1997年1月对富碳拱星IRC 10216和CIT6的CO J=1-0跃迁(115GHz)进行了观测。在观测谱线的基础上得到了IRC 10216的视向速度和膨胀速度分别为一26.1km s~(-1)和14.8km s~(-1),CIT6的视向速度和膨胀速度分别为0.6km s~(-1)和13.8kms~(-1)。并对望远镜的射束及指向精度进行了研究。  相似文献   
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In this paper we present the kinematics of the gas and/or the stars of a sample of 20 disc galaxies. We investigate whether there is any relation between the kinematics of the gas and stars and the classical morphological type of the galaxies in the sample. We deduce that, in most of the late-type spirals we have studied, the stars and the ionized gas are moving with virtually circular velocity, except when the spectroscopic slit crosses a bar region. On the other hand, we found in the central parts of early-type disc galaxies a wider variety of different behaviour of stars and gas. We find many possible factors that complicate the classification of the kinematical properties of the galaxies by their morphological type: the presence of counter-rotations (star vs. stars or star vs. gas), misalignment between the different kinematic components present in the galaxy, the presence of a bar structure and its orientation with respect to the line of nodes of the galaxy, and interactions and mergers or external accretion processes are some of the problems we find in the study of the kinematics of a galaxy.  相似文献   
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