A lunar soil evolution model     

W. W. Mendell  D. S. McKay 《Earth, Moon, and Planets》1975,13(1-3):285-292

Comminution, agglutination, and replenishment processes in a lunar soil are modeled by a system of time dependent, linear differential equations. In the model a soil is subdivided into coarse particle, fine particle, and agglutinate fractions. The relative mass abundance of each component in a mature soil is found to be proportional to rates for the reworking processes. Evolution of the grain size distribution from a fresh ejecta blanket to a mature soil is described quantitatively in terms of the changing proportions of the three soil constituents. If size data is available for an immature soil and a mature soil of the same system, rates for the various processes can be calculated under certain simplifying assumptions.  相似文献   

Bibliography     

Z. Kopal  M. Moutsoulas  J. W. Salisbury  F. B. Waranius 《Earth, Moon, and Planets》1975,13(4):495-519

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The hydrogeochemistry of methane: Evidence from English groundwaters   总被引：2，自引：0，他引：2  

W.G. Darling  D.C. Gooddy 《Chemical Geology》2006,229(4):293-312

The presence of methane (CH₄) in groundwater is usually only noticed when it rises to high concentrations; to date rather little is known about its production or natural ‘baseline’ conditions. Evidence from a range of non-polluted groundwater environments in England, including water supply aquifers, aquicludes and thermal waters, reveals that CH₄ is almost always detectable, even in aerobic conditions. Measurements of potable waters from Cretaceous, Jurassic and Triassic carbonate and sandstone aquifers reveal CH₄ concentrations of up to 500 μg/l, but a mean value of < 10 μg/l. However, aquiclude and thermal waters from the Carboniferous and Triassic typically contain in excess of 1500 μg/l. Such high concentrations have so far only been found at redox (Eh) potentials below 0 mV, but in general CH₄ concentration and Eh value are poorly correlated. This suggests a lack of thermodynamic equilibrium, which is confirmed by comparing pe values calculated from the redox couple C(4)/C(− 4) with those derived from Eh. Genesis of CH₄ appears to occur on two timescales: a rapid if low rate of production from labile carbon in anaerobic microsites in the soil, and a much longer, millennium scale of production from more refractory carbon. Methane is rarely measured in groundwater; there is no single ionic determinand which acts universally as a proxy, but a combination of high HCO₃ and low SO₄ concentrations, or the reverse, is an indication that high amounts of CH₄ may be present.  相似文献   

Na depletion in modern adakites via melt / rock reaction within the sub-arc mantle     

X.L. Xiong  B. Xia  J.F. Xu  H.C. Niu  W.S. Xiao 《Chemical Geology》2006,229(4):273-292

Interaction between slab-derived melt and mantle peridotite and the role of slab melt as a metasomatizing agent in the sub-arc mantle is being increasingly recognized. Adakite, the slab melt erupted on the surface, usually exhibits anomalously high MgO, CaO, Cr and Ni contents that indicate interaction with mantle peridotitite. Here we note that Cenozoic adakites have Na₂O contents below 5.8 wt.% with ∼95% samples lower than 5.0 wt.%, and are generally depleted in this component relative to experimental basalt partial melts (mostly beyond 5.0 wt.% and up to 9.0 wt.% Na₂O) produced under 1.5-3.0 GPa conditions that are most relevant to adakite production. We interpret the adakite Na depletion to be also a consequence of the melt / rock reaction that takes place within the hot mantle wedge. During ascent and reaction with mantle peridotite, primary adakite melts gain mantle components MgO, CaO, Cr and Ni but lose Na₂O, SiO₂ and perhaps K₂O to the mantle, leading to Na-rich mantle metasomatism. Selective assimilation of predominately mantle clinopyroxene, some spinel and minor olivine at high T/P has been considered to be an important process in producing high-Mg adakites from primary low-Mg slab melts [Killian, R., Stern, C. R., 2002. Constraints on the interaction between slab melts and the mantle wedge from adakitic glass in peridotite xenoliths. Eur. J. Mineral. 14, 25-36]. In such a process, Na depletion in the assimilated melt is the result of dilution due to the increase in melt mass. Phase relationships in the reaction system siliceous melt + peridotite and quantitative calculation suggest that assimilation of mantle clinopyroxene, olivine and spinel and fractional crystallization of sodic amphibole and orthopyroxene, under conditions of moderate T/P and increasing melt mass, is also an important process that modifies the composition of adakites and causes the Na depletion.  相似文献   

Co-diagenesis of iron and phosphorus in hydrothermal sediments from the southern East Pacific Rise: Implications for the evaluation of paleoseawater phosphate concentrations     

Simon W. Poulton  Donald E. Canfield 《Geochimica et cosmochimica acta》2006,70(23):5883-5898

We present a detailed study of the co-diagenesis of Fe and P in hydrothermal plume fallout sediments from ∼19°S on the southern East Pacific Rise. Three distal sediment cores from 340-1130 km from the ridge crest, collected during DSDP Leg 92, were analysed for solid phase Fe and P associations using sequential chemical extraction techniques. The sediments at all sites are enriched in hydrothermal Fe (oxyhydr)oxides, but during diagenesis a large proportion of the primary ferrihydrite precipitates are transformed to the more stable mineral form of goethite and to a lesser extent to clay minerals, resulting in the release to solution of scavenged P. However, a significant proportion of this P is retained within the sediment, by incorporation into secondary goethite, by precipitation as authigenic apatite, and by readsorption to Fe (oxyhydr)oxides. Molar P/Fe ratios for these sediments are significantly lower than those measured in plume particles from more northern localities along the southern East Pacific Rise, and show a distinct downcore decrease to a depth of ∼12 m. Molar P/Fe ratios are then relatively constant to a depth of ∼35 m. The Fe and P speciation data indicate that diagenetic modification of the sediments is largely complete by a depth of 2.5 m, and thus depth trends in molar P/Fe ratios can not solely be explained by losses of P from the sediment by diffusion to the overlying water column during early diagenesis. Instead, these sediments are likely recording changes in dissolved P concentrations off the SEPR, possibly as a result of redistribution of nutrients in response to changes in oceanic circulation over the last 10 million years. Furthermore, the relatively low molar P/Fe ratios observed throughout these sediments are not necessarily solely due to losses of scavenged P by diffusion to the overlying water column during diagenesis, but may also reflect post-depositional oxidation of pyrite originating from the volatile-rich vents of the southern East Pacific Rise. This study suggests that the molar P/Fe ratio of oxic Fe-rich sediments may serve as a proxy of relative changes in paleoseawater phosphate concentrations, particularly if Fe sulfide minerals are not an important component during transport and deposition.  相似文献   

A critical look at iron paleoredox proxies: New insights from modern euxinic marine basins   总被引：2，自引：0，他引：2  

Timothy W. Lyons  Silke Severmann 《Geochimica et cosmochimica acta》2006,70(23):5698-5722

Enrichments in reactive iron occur under euxinic marine conditions, that is, where dissolved sulfide is present in the water column. These enrichments result primarily from the export of remobilized iron from the oxic shelf, which is scavenged from the euxinic water column during syngenetic pyrite formation and deposited in the underlying sediments. Strongly elevated ratios of highly reactive iron to total iron (Fe_HR/Fe_T) and total iron to aluminum (Fe_T/Al) and high degrees of pyritization (DOP) are each products of this enrichment process. These paleoredox proxies are among the most faithful recorders of ancient euxinia.Contrary to previous arguments, iron enrichment is decoupled from biogenic sediment inputs, but it does appear to be a uniquely euxinic phenomenon. In other words, we can rule out a major contribution from preferential physical transport of Fe_HR-rich detrital sediment to the deep basin, which could also operate under oxic conditions. Furthermore, enrichment via the shuttling of iron remobilized from oxic shelves appears to be limited by inefficient transport and trapping processes in deep oxic basins. Elevated Fe_T/Al ratios in the euxinic sediments also cannot be a product of internal enhancement of the reactivity of the detrital iron pool without net Fe_HR addition. These conclusions are supported by observations in the modern Black Sea, Orca Basin, and Effingham Inlet.Fe_T/Al ratios are unambiguous recorders of paleoredox even in sediments that have experienced high degrees of metamorphic alteration. However, this study suggests that high siliciclastic accumulation rates can swamp the enrichment mechanism, resulting in only intermediate DOP values for euxinic sediments and Fe_T/Al ratios that mimic the oxic shelf. Such dilution effects are well expressed in Black Sea basinal turbidites and rapidly accumulating muds on euxinic basin margins. Under conditions of persistent euxinia, varying extents of Fe_HR enrichment can illuminate spatial and temporal gradients in siliciclastic sedimentation. The magnitude of enrichment is a function of the source (shelf) to sink (ocean basin) areal ratio, suggesting that iron proxies can also record ocean-scale paleoenvironmental properties through muted enrichments at times of very widespread euxinia. For the first time, manganese data are interpreted in light of the redox shuttle model. As for the iron data, the Black Sea, Orca Basin, and Effingham Inlet show enrichments in total manganese in the deep euxinic basin, suggesting export from the suboxic porewaters of the oxic shelf and scavenging and burial in the basin. The Black Sea data reveal iron and manganese enrichment across the broad, deep euxinic basin, suggesting efficient lateral transport and deep-water mixing tied to the physical properties of the water column.  相似文献   

Memories of Fire: Eduardo Galeano and the Geography of Guatemala     

W. George Lovell 《Geoforum》2006,37(1):31-40

In Memory of Fire, a poetic narration of the history of the Americas from pre-Columbian times to the late 20th century, Eduardo Galeano furnishes readers with over 1200 of his trademark vignettes, some 35 of which pertain to Guatemala. Galeano evokes disparate aspects of the geography of Guatemala, past and present, in grounded miniatures of time, place, and episode. His sketches of the experiences of Maya peoples allow us to see them as survivors of three cycles of conquest: (1) conquest by imperial Spain; (2) conquest by local and international capitalism; and (3) conquest by state terror. Composed in the literary mode of creative non-fiction, Memory of Fire serves as an inspirational classroom text, exposing students not only to factual detail but also a powerful artistic imagination.  相似文献   

Upper Cretaceous palaeogeography of the British Isles and adjacent areas     

John C.W. Cope 《Proceedings of the Geologists' Association. Geologists' Association》2006,117(2):129-143

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Cosmogenic nuclide methods for measuring long-term rates of physical erosion and chemical weathering     

James W. Kirchner  Clifford S. Riebe  Kenneth L. Ferrier  Robert C. Finkel 《Journal of Geochemical Exploration》2006,88(1-3):296

Understanding the evolution of geochemical and geomorphic systems requires measurements of long-term rates of physical erosion and chemical weathering. Erosion and weathering rates have traditionally been estimated from measurements of sediment and solute fluxes in streams. However, modern sediment and solute fluxes are often decoupled from long-term rates of erosion and weathering, due to storage or re-mobilization of sediment and solutes upstream from the sampling point. Recently, cosmogenic nuclides such as ¹⁰Be and ²⁶Al have become important new tools for measuring long-term rates of physical erosion and chemical weathering. Cosmogenic nuclides can be used to infer the total denudation flux (the sum of the rates of physical erosion and chemical weathering) in actively eroding terrain. Here we review recent work showing how this total denudation flux can be partitioned into its physical and chemical components, using the enrichment of insoluble tracers (such as Zr) in regolith relative to parent rock. By combining cosmogenic nuclide measurements with the bulk elemental composition of rock and soil, geochemists can measure rates of physical erosion and chemical weathering over 1000- to 10,000-year time scales.  相似文献   

Cross-formational hydrocarbon fluid flows in the Tertiary deltaic system of the Beaufort–Mackenzie Basin     

Maowen Li  Yongqiang Xiong  Lloyd R. Snowdon  Dale Issler 《Journal of Geochemical Exploration》2006,89(1-3):214

Molecular and isotopic compositions of crude oils in the Beaufort–Mackenzie Basin confirm three genetic end-member oil groups and suggest extensive cross-formational hydrocarbon fluid flows in the Tertiary deltaic system. Inter- and intra-fractional variations in the geochemistry of the Tertiary-reservoired oils indicate that the oil source/maturity signatures were substantially masked by biomarkers that were picked up along migration pathways. Thus, many of the previously recognized “immature non-marine oils” are in fact thermally mature, probably derived from unpenetrated deeper marine source rocks. Although the effective source rock volumes have not been evaluated and their exact stratigraphic levels remain unknown, the relative timing of oil generation versus trap formation, rather than poor source quality, may be the cause of under-filled traps in the offshore area.  相似文献