壳聚糖/纳米铜复合微球的制备及其对刚果红染料的脱色性能     

李瑞明  李瑾  钟莲  朱巧雅 《中国海洋大学学报(自然科学版)》2022,52(2):77-86

以壳聚糖和CuCl₂·2H₂O为原料,分别采用直接负载法和吸附法成功制备了壳聚糖/纳米铜复合微球,运用傅里叶变换红外光谱(FT-IR)、X-射线衍射(XDR)和扫描电镜(SEM)对催化剂结构进行了表征。以刚果红(CR)染料为目标污染物,评价了催化剂的制备方法、制备条件及氢转移催化反应条件对其催化性能的影响。结果表明,由直接负载法(CS/CuNPs)和吸附法(CS/CuNPs-X)制备的壳聚糖/纳米铜复合微球在CR染料浓度为100 mg/L,催化剂投加量为0.05 g,供氢体浓度为0.05 mol/L的氢转移催化反应条件下,催化反应进行180和60 min时CR脱色率可分别达95.8%和96.8%。CS/CuNPs-X比CS/CuNPs表现了更高的对CR氢转移催化反应的催化速率。两种催化剂催化还原CR染料的反应均符合准一级动力学模型。在连续循环使用10次后,CS/CuNPs和CS/CuNPs-X对CR的脱色率分别为93.9%和89.4%,表明催化剂具有良好的重复使用性能。  相似文献   

基于生态文明思想的围填海历史遗留问题处理理论与实践——以大连港太平湾港区和中新天津生态城为例          下载免费PDF全文

朱德洲  李耀如  温国义  徐谦 《海洋开发与管理》2022,39(1):31-37

长期大规模围填海活动在振兴沿海地区经济的同时,也严重破坏了海岸带生态系统。文章梳理了关于加强滨海湿地保护、严格管控围填海的一系列政策要求与技术指南;以大连港太平湾港区和中新天津生态城为例,分别分析了港口工业区和滨海生态旅游区的围填海历史遗留问题处理与生态保护修复实践,并提出了生态优先,绿色发展;自然恢复为主,人工修复为辅;陆海统筹,生态融合;问题导向,科学修复;科技支撑,示范带动等新发展阶段下海洋生态保护修复的建议。  相似文献   

养殖贝类碳汇价格核算研究          下载免费PDF全文

温瑞  张继伟  高超  高宇  羊艳 《海洋开发与管理》2022,39(3):16-23

养殖贝类是最有效的生物固碳方式之一,其碳汇功能作为海洋生态系统功能的一部分,兼具生态和经济属性,碳汇价格的核算可为海水贝类养殖产业补贴提供数据参考,提高碳汇养殖产业的生产积极性,对海洋GEP核算等提供一定借鉴。目前碳汇价格研究较为缺乏,碳汇价格受限于碳汇计量方法的不完善,因此文章基于碳储量变化原理,对养殖环境中的养殖贝类固碳基础公式进行改进,补充了附着贝类固碳与生物沉积物固碳两个计算参数,以此为切入点选取并改进海洋牧场碳汇定价方法,以东方云溪海洋牧场作为研究区进行案例计算,结果为：海湾扇贝、栉孔扇贝与褶牡蛎的碳汇价格分别为165元/t、185元/t和272元/t;使用改进后的碳汇计量方法得到的养殖贝类单位个体固碳量较高,其中生物沉积固碳对提高单位个体固碳量的作用最为突出,约占贝类自身固碳的91%,主要与养殖海域的水文条件有关;较高的固碳量形成了较低的碳汇价格,固碳量与成本收益因素共同影响养殖贝类的碳汇价格;长远来看,碳汇价格会随着固碳计量的愈加完善而降低。  相似文献   

Simulating urban land-use change based on the multi-hierarchal planning–environment interaction process     

Jing Yang  Yizhong Sun  Jie Zhu  Shuying Song 《Transactions in GIS》2023,27(1):152-175

Urban land-use change is the result of coupling interaction between planning and environment systems. The aim of our study was to construct an effective model to show how the urban land-use changes under the planning–environment interaction system with multi-hierarchy and major function oriented zoning. Combining the Cellular automata (CA) model with logistic regression model, the proposed multi-hierarchal vector CA model (MH-VCA3) was constructed by mining multi-hierarchal land-use transition rules under the planning–environment interaction system. Taking Jiangyin City (China) as an example, we compared the simulated result of the proposed model to those of the well-accepted Logistic CA and traditional multi-level CA models to demonstrate the effectiveness of the consideration of top-down decomposition constraint and bottom-up updating. Furthermore, by simulating the land-use changes under different population regionalization scenarios, we found that in order to form the spatial pattern of “agglomeration in the north and ecology in the south,” the planned population growth at the global hierarchal level should be allocated to the district units according to the law of Central district > Chengxi district > Chengdong district > Chengnan district > Chengdongnan district. The proposed model is expected to provide scientific support for the formulation of urban planning schemes in the future.  相似文献   

Nitrogen and Phosphorus Budget of a Polyculture System of Sea Cucumber （Apostichopus japonicus）, Jellyfish （Rhopilema esculenta） and Shrimp （Fenneropenaeus chinensis）     

LI Junwei  DONG Shuanglin  GAO Qinfeng  ZHU Changbo 《中国海洋大学学报(英文版)》2014,13(3):503-508

The nitrogen(N) and phosphorus(P) budget and the ecological efficiency of a polyculture system of sea cucumber(Apostichopus japonicus), jellyfish(Rhopilema esculenta) and shrimp(Fenneropenaeus chinensis) were studied in a cofferdam, 120.2 ha in size. The nutrients were supplied by spring tide inflow. In total, 139600 kg N yr-1 and 9730 kg P yr-1 input to the system; while 118900 kg N yr-1 and 2840 kg P yr-1 outflowed from the system concurrently, thus the outflow was 85.7%(N) and 29.2%(P) of inflow. The production of N and P was 889.5 kg yr-1 and 49.28 kg yr-1(sea cucumber) and 204 kg yr-1 and 18.03 kg yr-1(jellyfish and shrimp), respectively. The utilization rate of N and P by polycultured animals was 7.8‰ and 6.9‰, respectively, 21.9% and 38% higher than that of monocultured sea cucumber. Our results indicated that the polyculture system was an efficient culture system of animals and a remediation system of coastal environment as well; it scavenged 14.3% and 70.8% of N and P, respectively. Such an ecological efficiency may be improved further by increasing either the stocking density or the size of sea cucumber or both.  相似文献   

Improvement of pseudo-static method for slope stability analysis   总被引：2，自引：0，他引：2  

Chang-wei Yang  Jian-jing Zhang  Xiao Fu  Chuan-bin Zhu  Jun-wei Bi 《山地科学学报》2014,11(3):625-633

traditional In this paper, two drawbacks pseudo-static method （vertical of the slice method） in the slope stability evaluation have been studied. First, the sliding mass is divided into vertical slices according to this method, which is irrational to some extent in the seismic design of slope. Second, only peak ground acceleration （PGA） is considered, and the effects of shaking frequency and duration on slope stability are neglected. And then, based on the theory of elastic wave and the summarized geological model, this paper put forwards an improved method of pseudo-method by using the theory of elastic wave and Hilbert-Huang transform. The improved pseudostatic method gives reasonable considerations to the time-frequency effects of seismic wave and its rationality has been verified by the shaking table test. This method can evaluate the safety of a slope, the happening time and the scale of landslides. At the same time, this method also can improve the high accuracy of the evaluation of the safety of the slope.  相似文献   

Temporal stability of apparent soil electrical conductivity measured by electromagnetic induction techniques     

LIAO Kai-hua  ZHU Qing  James DOOLITTLE 《山地科学学报》2014,11(1):98-109

Assessing and managing the spatial variability of hydropedological properties are important in environmental,agricultural,and geological sciences.The spatial variability of soil apparent electrical conductivity（ECa） measured by electromagnetic induction（EMI） techniques has been widely used to infer the spatial variability of hydrological and pedological properties.In this study,temporal stability analysis was conducted for measuring repeatedly soil ECa in an agricultural landscape in 2008.Such temporal stability was statistically compared with the soil moisture,terrain indices（slope,topographic wetness index（TWI）,and profile curvature）,and soil properties（particle size distribution,depth to bedrock,Mn mottle content,and soil type）.Locations with great and temporally unstable soil ECa were also associated with great and unstable soil moisture,respectively.Soil ECa were greater and more unstable in the areas with great TWI（TWI 〉 8）,gentle and concave slope（slope 〈 3%; profile curvature 〉 0.2）.Soil ECa exponentially increased with depth to bedrock,and soil profile silt and Mn mottle contents（R2= 0.57）,quadratically（R2 = 0.47）,and linearly（R 2 = 0.47）,respectively.Soil ECa was greater and more unstable in Gleysol and Nitosol soils,which were distributed in areas with low elevation（〈 380 m）,thick soil solum（〉 3 m）,and fluctuated water table（shallow in winter and spring but deep in summer and fall）.In contrast,Acrisol,Luvisol,and Cambisol soils,which are distributed in the upper slope areas,had lower and more stable soil ECa.Through these observations,we concluded that the temporal stability of soil ECa can be used to interpret the spatial and temporal variability of these hydropedological properties.  相似文献   

鲁村煤矿井底车场钢管混凝土支架支护应用          下载免费PDF全文

文增生  史春芝 《山东国土资源》2014,30(1):51-54

沂源县鲁村煤矿-270m井底车场围岩为泥质粉砂岩,强度低,含粘土矿物,吸水膨胀,传统的支护方式难以保证巷道稳定,采用钢管混凝土支架进行支护试验。分析了-270m井底车场围岩地质特征,提出基于钢管混凝土支架的综合支护方案,最后通过理论验算证实钢管混凝土支架承载能力为U29型钢支架4倍,满足巷道支护要求。  相似文献   

Spatial and temporal variations of coastlines in northern China (2000-2012)     

XU Jinyong  ZHANG Zengxiang  ZHAO Xiaoli  WEN Qingke  ZUO Lijun  WANG Xiao  YI Ling 《地理学报》2014,24(1):18-32

This study examined the spatial distribution of the continent coastline in northern China using remote sensing and GIS techniques, and calculated the fractal dimension of the coastline by box-counting method, with a time span from 2000 to 2012. Moreover, we analyzed the characteristics of spatial-temporal changes in the coastline's length and fractal dimension, the relationship between the length change and fractal dimension change, and the driving forces of coastline changes in northern China. During the research period, the coastline of the study area increased by 637.95 km, at a rate of 53.16 km per year. On the regional level, the most significant change in coastline length was observed in Tianjin and Hebei. Temporally, the northern China coastline grew faster after 2008. The most dramatic growth was found between 2010 and 2011, with an increasing rate of 2.49% per year. The fractal dimension of the coastline in northern China was increasing during the research period, and the most dramatic increase occurred in Bohai Rim. There is a strong-positive linear relationship between the historical coastline length and fractal dimension (the correlation coefficient was 0.9962). Through statistical analysis of a large number of local coastline changes, it can be found that the increase (or decrease) of local coastline length will, in most cases, lead to the increase (or decrease) of the whole coastline fractal dimension. Civil-coastal engineering construction was the most important factor driving the coastline change in northern China. Port construction, fisheries facilities and salt factories were the top three construction activities. Compared to human activities, the influence of natural processes such as estuarine deposit and erosion were relatively small.  相似文献   

县域尺度下能源产区能源消费碳排放强度空间分异——以陕西省榆林市为例     

朱妮  张艳芳  位贺杰 《地域研究与开发》2014,(6)

以能源产区陕西省榆林市的12个区县为研究单元,在Geo Da和Arc GIS等软件的支持下,结合趋势分析和空间统计方法,分析2005—2010年榆林县域尺度下的能源消费碳排放强度的空间格局特征与空间分异机制。榆林各区县能源消费碳排放强度水平差异明显,总体差异呈扩大趋势,两极分化加剧。县域碳排放强度南北走向上表现出逐渐减小趋势,东西走向上具有微弱的"U"型变化态势。总体上,东北部区县碳排放强度高于西南部。各区县碳排放强度具有正的空间关联分布特征,且处于低水平非均衡空间分布状态,空间依赖性明显。结合相关性分析,榆林区县碳排放强度具有极化区、扩散区、塌陷区和传染区4个特征。"热点"主要分布在东北部三县,"冷点"主要分布于南部六县。能源资源分布不均、经济总量以及产业结构差异是造成榆林碳排放强度空间分布不均的主要原因。  相似文献