Nonracemic isovaline in the Murchison meteorite: chiral distribution and mineral association     

Sandra Pizzarello  Michael Zolensky 《Geochimica et cosmochimica acta》2003,67(8):1589-1595

The enantiomeric and carbon-isotopic composition of the amino acid isovaline have been analyzed in several samples of the Murchison meteorite and one sample of the Murray meteorite. l-Enantiomeric excesses of the amino acid were found to range from 0 to 15.2%, varying significantly both between meteorite stones and at short distances within a single stone. The upper limit of this range is the largest enantiomeric excess measured to date for a biologically rare meteoritic amino acid and raises doubts that circularly polarized light irradiation could have been the sole cause of amino acids chiral asymmetry in meteorites. Individual d- and l-isovaline δ¹³C values ware found to be about +18‰, with no significant differences between the two enantiomers to suggest terrestrial contamination. The amino acid relative abundance also varied between samples, with isovaline/alanine ratios of 0.5 to 6.5. X-ray diffraction analyses of contiguous meteorite fragments suggest a possible correlation between isovaline and hydrous silicates abundances.  相似文献   

Mid-holocene climate change in Lake Bosumtwi, Ghana     

James Russell  Michael R TalbotBrian J Haskell 《Quaternary Research》2003,60(2):133-141

Lake Bosumtwi is one of the most widely studied palaeoclimate archives in West Africa. Results from numerous AMS ¹⁴C dates of samples from four piston cores from Lake Bosumtwi show that an abrupt sedimentary transition from a mid-Holocene sapropel to calcareous laminated muds occurred at about 3200 cal yr B.P. High-resolution analyses of the nitrogen isotopic composition of organic matter across this transition confirm its abrupt nature, and suggest that the change may signal a step toward increased aridity and intensified surface winds that affected western equatorial Africa from Ghana to the Congo basin. Northern and Eastern Africa experienced a similar abrupt shift toward aridity during the late Holocene, but at about 5000 cal yr B.P., a difference in timing that illustrates the regional nature of climate changes during the Holocene and the importance of feedback mechanisms in regulating Holocene climate variability. Furthermore, an abrupt change at about 3000 cal yr B.P. occurs at several sites adjacent to the tropical and subtropical Atlantic, which may hint at major changes in the surface temperatures of the tropical Atlantic and/or Pacific at this time.  相似文献   

Accessibility in space and time: A theme in spatially integrated social science   总被引：4，自引：0，他引：4  

Mei-Po Kwan  Donald G. Janelle  Michael F. Goodchild 《Journal of Geographical Systems》2003,5(1):1-3

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Recent advances in accessibility research: Representation,methodology and applications   总被引：22，自引：0，他引：22  

Mei-Po Kwan  Alan T. Murray  Morton E. O'Kelly  Michael Tiefelsdorf 《Journal of Geographical Systems》2003,5(1):129-138

 In this article we examine recent advances in accessibility research and their implications for future studies. We base our discussion on three intersecting dimensions that are useful for evaluating the contribution of recent studies: representation, methodology and applications. Various examples are selected to show that research concerned with representation and methodological problem solving is often applied to issues of broad concern in policy and planning. It is, however, not clear that the simultaneous treatment of representation, methodological and application issues has ever been fully worked out. The questions raised in this article may serve as a foundation for addressing issues pertinent to accurate representation, improved model building, and more rigorous applications in accessibility research. Received: 9 December 2002 / Accepted: 10 February 2003  相似文献   

Understanding Climatic Impacts, Vulnerabilities, and Adaptation in the United States: Building a Capacity for Assessment     

Edward A. Parson  Robert W. Corell  Eric J. Barron  Virginia Burkett  Anthony Janetos  Linda Joyce  Thomas R. Karl  Michael C. MacCracken  Jerry Melillo  M. Granger Morgan  David S. Schimel  Thomas Wilbanks 《Climatic change》2003,57(1-2):9-42

Based on the experience of the U.S. National Assessment, we propose a program of research and analysis to advance capability for assessment of climate impacts, vulnerabilities, and adaptation options. We identify specific priorities for scientific research on the responses of ecological and socioeconomic systems to climate and other stresses; for improvement in the climatic inputs to impact assessments; and for further development of assessment methods to improve their practical utility to decision-makers. Finally, we propose a new institutional model for assessment, based principally on regional efforts that integrate observations, research, data, applications, and assessment on climate and linked environmental-change issues. The proposed program will require effective collaboration between scientists, resource managers, and other stakeholders, all of whose expertise is needed to define and prioritize key regional issues, characterize relevant uncertainties, and assess potential responses. While both scientifically and organizationally challenging, such an integrated program holds the best promise of advancing our capacity to manage resources and the economy adaptively under a changing climate.  相似文献   

Geographic Objects with Indeterminate Boundaries: By Peter A Burrough and Andrew U Frank (Eds)     

Michael Ridland 《Transactions in GIS》1997,2(4):377-378

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Politics, Geography, and 'Political Geography By Joe Painter. Arnold Press, London, 1995     

Michael Brown 《New Zealand geographer》1997,53(2):67-68

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Palaeosecular variation over the past 5 Myr based on a new generalized database   总被引：1，自引：0，他引：1  

Michael W. McElhinny  Phillip L. McFadden 《Geophysical Journal International》1997,131(2):240-252

A generalized database of global palaeomagnetic data from 3719 lava flows and thin dykes of age 0–5 Ma has been constructed for use with a relational database management system. The database includes all data whose virtual geomagnetic poles (VGP) lie within 45 of the spin axis and can be used for studies of palaeosecular variation and for geomagnetic field modelling. Because many of these data were collected and processed more than 15–20 years ago, each result has been characterized according to the demagnetization procedures carried out. Analysis of these data in terms of the latitude variation of the angular dispersion of VGPs (palaeosecular variation from lavas) strongly suggests that careful data selection is required and that many of the older studies may need to be redone using more modern methods. Differences between the angular dispersions for separate normal- and reverse-polarity data sets confirm that many older studies have not been adequately cleaned magnetically. Therefore, the use of the database for geomagnetic field modelling should be carried out with some caution. Using a VGP cut-off angle that varies with latitude, the best data set consists of 2636 results that show a smooth increase of VGP angular dispersion with latitude. Model G for palaeosecular variation, which is based on modelling of the antisymmetric (dipole) and symmetric (quadrupole) dynamo families, provides a good fit to these results.  相似文献   

Time-domain electromagnetic migration in the solution of inverse problems   总被引：5，自引：0，他引：5  

Michael S. Zhdanov  Oleg Portniaguine 《Geophysical Journal International》1997,131(2):293-309

Time-domain electromagnetic (TDEM) migration is based on downward extrapolation of the observed field in reverse time. In fact, the migrated EM field is the solution of the boundary-value problem for the adjoint Maxwell's equations. The important question is how this imaging technique can be related to the solution of the geoelectrical inverse problem. In this paper we introduce a new formulation of the inverse problem, based on the minimization of the residual-field energy flow through the surface or profile of observations. We demonstrate that TDEM migration can be interpreted as the first step in the solution of this specially formulated TDEM inverse problem. However, in many practical situations this first step produces a very efficient approximation to the geoelectrical model, which makes electromagnetic migration so attractive for practical applications. We demonstrate the effectiveness of this approach in inverting synthetic and practical TDEM data.  相似文献   

Permo-Triassic magnetostratigraphy in China: the type section near Taiyuan, Shanxi Province, North China   总被引：7，自引：0，他引：7  

Brian J. J. Embleton  Michael W. McElhinny  Xinghua Ma  Zhengkun Zhang  Zheng Xiang Li 《Geophysical Journal International》1996,126(2):382-388

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