Episodic refertilization and metasomatism of Archean mantle: evidence from an orogenic peridotite in North Qaidam (NE Tibet,China)     

Qing Xiong  William L. Griffin  Jian-Ping Zheng  Suzanne Y. O’Reilly  Norman J. Pearson 《Contributions to Mineralogy and Petrology》2015,169(3):1-24

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Linking continental deep subduction with destruction of a cratonic margin: strongly reworked North China SCLM intruded in the Triassic Sulu UHP belt   总被引：1，自引：0，他引：1  

J. P. Zheng  H. Y. Tang  Q. Xiong  W. L. Griffin  S. Y. O’Reilly  N. Pearson  J. H. Zhao  Y. B. Wu  J. F. Zhang  Y. S. Liu 《Contributions to Mineralogy and Petrology》2014,168(1):1-21

The collision between the North and South China cratons in Middle Triassic time (240–225 Ma) created the world’s largest belt of ultrahigh-pressure (UHP) metamorphism. U–Pb ages, Hf isotope systematics and trace element compositions of zircons from the Xugou, Yangkou and Hujialing peridotites in the Sulu UHP terrane mainly record a ~470 Ma tectonothermal event, coeval with the Early Paleozoic kimberlite eruptions within the North China craton. This event is interpreted as the result of metasomatism by fluids/melts derived from multiple sources including a subducting continental slab. The peridotites also contain zircons with ages of ~3.1 Ga, and Hf isotope data imply a component ≥3.2 Ga old. Most zircon Hf depleted mantle model ages are ~1.3 Ga, suggesting that the deep subcontinental lithospheric mantle beneath the southeastern margin of the North China craton experienced a intense mid-Mesoproterozoic metasomatism by asthenospheric components, similar to the case for the eastern part of this craton. Integrating data from peridotites along the southern margin of the craton, we argue that the deep lithosphere of the cratonic margin (≥3.2 Ga old), from which the Xugou, Yangkou and Hujialing peridotites were derived, experienced Proterozoic metasomatic modification, followed by a strong Early Paleozoic (~470 Ma) tectonothermal event and the Early Mesozoic (~230 Ma) collision and northward subduction of the Yangtze craton. The Phanerozoic decratonization of the eastern North China craton, especially along its southern margin, was not earlier than the Triassic continental collision. This work also demonstrates that although zircons are rare in peridotitic rocks, they can be used to unravel the history of specific lithospheric domains and thus contribute to our understanding of the evolution of continental cratons and their margins.  相似文献   

Presence, infectivity, and stability of enteric viruses in seawater: relationship to marine water quality in the Florida Keys     

Wetz JJ  Lipp EK  Griffin DW  Lukasik J  Wait D  Sobsey MD  Scott TM  Rose JB 《Marine pollution bulletin》2004,48(7-8):698-704

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Composite spectra: XVII. 12 Comae,a member of the Coma open cluster     

R.E.M. Griffin  R.F. Griffin 《Astronomische Nachrichten》2011,332(2):105-115

The components of binary stars offer the potential to examine the predictions of stellar‐evolution theory with particularly tight constraints. Those constraints are further tightened when the binary belongs to a cluster whose properties have been well determined independently. 12 Comae presents both advantages, belonging as it does to the Coma Cluster, Melotte 111. The orbit of 12 Comae has an eccentricity of nearly 0.6 and a period of 13 months. By a process of subtraction we separate the spectra of the component stars, derive a precise double‐lined orbit solution, and by modelling the photometry we extract the individual stellar photometric and physical properties, ages and rotation. By fitting theoretical evolutionary tracks to the positions of the stars in the H‐R diagram we confirm their individual masses, and derive a ZAMS of ∼0.65 Gyr, which accords well with measurements published for the cluster itself. We show that the primary of 12 Comae is an evolving giant of spectral type ∼G7 and mass 2.6 M_⊙, while its secondary (whose spectrum could be isolated particularly cleanly) is an A3 dwarf which has a mass of 2.05 M_⊙ and has commenced its evolution away from the main sequence. There is evidence that both stars are slightly metal‐weak (–0.25 < [Fe/H] < 0.0), well in keeping with analyses of other members of this cluster (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

Melt/mantle mixing produces podiform chromite deposits in ophiolites: Implications of Re-Os systematics in the Dongqiao Neo-tethyan ophiolite, northern Tibet   总被引：8，自引：0，他引：8  

Rendeng Shi  William L. Griffin  Suzanne Y. O'ReillyQishuai Huang  Xiaoran ZhangDeliang Liu  Xiachen ZhiQiongxia Xia  Lin Ding 《Gondwana Research》2012,21(1):194-206

Podiform chromite deposits occur in the mantle sequences of many ophiolites that were formed in supra-subduction zone (SSZ) settings. We have measured the Re-Os isotopic compositions of the major chromite deposits and associated mantle peridotites of the Dongqiao Ophiolite in the Bangong-Nujiang suture, Tibet, to investigate the petrogenesis of these rocks and their genetic relationships.The ¹⁸⁷Os/¹⁸⁸Os ratios of the chromite separates define a narrow range from 0.12318 to 0.12354, less variable than those of the associated peridotites. Previously-reported ¹⁸⁷Os/¹⁸⁸Os ratios of the Os-rich alloys enclosed in the chromitites define two clusters: 0.12645 ± 0.00004 (2 s; n = 145) and 0.12003 to 0.12194. The ultra-depleted dunites have much lower ¹⁸⁷Os/¹⁸⁸Os (0.11754, 0.11815), and the harzburgites show a wider range from 0.12107 to 0.12612. The average isotopic composition of the chromitites (¹⁸⁷Os/¹⁸⁸Os: 0.12337 ± 0.00001) is low compared with the carbonaceous chondrite value (¹⁸⁷Os/¹⁸⁸Os: 0.1260 ± 0.0013) and lower than the average value measured for podiform chromitites worldwide (0.12809 ± 0.00085). In contrast, the basalts have higher ¹⁸⁷Os/¹⁸⁸Os, ranging from 0.20414 to 0.38067, while the plagioclase-bearing harzburgite and cumulates show intermediate values of ¹⁸⁷Os/¹⁸⁸Os (0.12979 ~ 0.14206). Correspondingly, the basalts have the highest ¹⁸⁷Re/¹⁸⁸Os ratios, up to 45.4 ± 3.2, and the chromites have the lowest ¹⁸⁷Re/¹⁸⁸Os ratios, down to 0.00113 ± 0.00008. We suggest that melts/fluids, derived from the subducting slab, triggered partial melting in the overlying mantle wedge and added significant amounts of radiogenic Os to the peridotites. Mass-balance calculations indicate that a melt/mantle ratio of approximately 15:1 (melt: ¹⁸⁷Re/¹⁸⁸Os: 45.4, ¹⁸⁷Os/¹⁸⁸Os: 0.34484; mantle peridotite: ¹⁸⁷Re/¹⁸⁸Os: 0.0029, ¹⁸⁷Os/¹⁸⁸Os: 0.11754) is necessary to increase the Os isotopic composition of the chromitite deposits to its observed average value. This value implies a surprisingly low average melt/mantle ratio during the formation of the chromitite deposits. The percolating melts probably were of variable isotopic composition. However, in the chromitite pods the Os from many melts was pooled and homogenized, which is why the chromitite deposits show such a small variation in their Os isotopic composition. The results of this study suggest that the ¹⁸⁷Os/¹⁸⁸Os ratios of chromitites may not be representative of the DMM, but only reflect an upper limit. Importantly, the Os-isotope compositions of chromitites strongly suggest that such deposits can be formed by melt/mantle mixing processes.  相似文献   

Platelet development in cuboid diamonds: insights from micro-FTIR mapping   总被引：1，自引：1，他引：0  

D. Howell  C. J. O’Neill  K. J. Grant  W. L. Griffin  S. Y. O’Reilly  N. J. Pearson  R. A. Stern  T. Stachel 《Contributions to Mineralogy and Petrology》2012,164(6):1011-1025

Fourier transform infrared mapping of diamonds can reveal detailed information on impurities, with a spatial context. We apply this technique, combined with in situ isotopic analysis of carbon, to the study of cuboid diamond growth in a sample that exhibits some mixed-habit growth. While there has been some uncertainty in the literature regarding sectoral differences in nitrogen aggregation and subsequent platelet development, the data from this study appear far more conclusive. We show that despite nitrogen being concentrated in octahedral sectors, there is no detectable difference in the concentration-adjusted rate of nitrogen aggregation within octahedral and cuboid sectors. However, the resultant platelet development is significantly reduced in cuboid sectors compared to contemporaneously formed octahedral sectors. This finding has significant implications for the classification of diamonds using the relationship between their platelet intensity and the absorption caused by B centres. It means that cuboid diamonds naturally fall below the linear relationship that has been termed regular, which would lead to them being incorrectly interpreted as having experienced heating or deformation. The data also support earlier suggestions that large hydrogen concentrations in the diamond-forming fluid may be required for cuboid growth. We further suggest that high nitrogen and hydrogen concentrations are required for mixed-habit diamond growth, which might be the product of specific fluid chemistries that occur in reducing mantle environments.  相似文献   

Petrology and geochemistry of peridotite xenoliths from the Lianshan region: Nature and evolution of lithospheric mantle beneath the lower Yangtze block     

Jianggu Lu  Jianping Zheng  William L. Griffin  Chunmei Yu 《Gondwana Research》2013,23(1):161-175

Lithospheric thinning beneath the North China Craton is widely recognized, but whether the Yangtze block has undergone the same process is a controversial issue. Based on a detailed petrographic study, a suite of xenoliths from the Lianshan Cenozoic basalts have been analyzed for the compositions of minerals and whole rocks, and their Sr–Nd isotopes to probe the nature and evolution of the subcontinental lithospheric mantle beneath the lower Yangtze block. The Lianshan xenoliths can be subdivided into two Types: the main Type 1 xenoliths (9–15% clinopyroxene and olivine-Mg# < 90) and minor Type 2 peridotites (1.8–6.2% clinopyroxene and olivine-Mg# > 90). Type 1 peridotites are characterized by low MgO, high levels of basaltic components (i.e., Al₂O₃, CaO and TiO₂), LREE-depleted patterns in clinopyroxenes and whole rocks, and relatively high ¹⁴³Nd/¹⁴⁴Nd (0.513219–0.513331) and low ⁸⁶Sr/⁸⁷Sr (0.702279–0.702789). These features suggest that Type 1 peridotites represent fragments of the newly accreted fertile lithospheric mantle that have undergone ~ 1% of fractional partial melting and later weak silicate–melt metasomatism, similar to Phanerozoic lithospheric mantle beneath the eastern North China Craton. Type 2 peridotites may be shallow relics of the older lithospheric mantle depleted in basaltic components, with LREE-enriched and HREE-depleted patterns, relatively low ¹⁴³Nd/¹⁴⁴Nd (0.512499–0.512956) and high ⁸⁶Sr/⁸⁷Sr (0.703275–0.703997), which can be produced by 9–14% partial melting and subsequent carbonatite–melt metasomatism. Neither type shows a correlation between equilibration temperatures and Mg# in olivine, indicating that the lithospheric mantle is not compositionally stratified, but both types coexist at similar depths. This coexistence suggests that the residual refractory lithospheric mantle (i.e., Type 2 peridotites) may be irregularly eroded by upwelling asthenosphere materials along weak zones and eventually replaced to create a new and fertile lithosphere mantle (i.e., Type 1 xenoliths) as the asthenosphere cooled. Therefore, the subcontinental lithospheric mantle beneath the lower Yangtze block shared a common evolutional dynamic environment with that beneath the eastern North China Craton during late Mesozoic–Cenozoic time.  相似文献   

Two age populations of zircons from the Timber Creek kimberlites,Northern Territory,as determined by laser ablation ICP MS analysis     

E. A. Belousova  W. L. Griffin  S. R. Shee  S. E. Jackson  S. Y. O'Reilly 《Australian Journal of Earth Sciences》2013,60(5):757-765

Two populations of kimberlitic zircon are present in the Timber Creek kimberlites, Northern Territory. Laser ablation ICP MS U—Pb dating yields an age of 1483 ± 15 (2σ) Ma for the main group and an age of 179 ± 2 Ma for the other group. This distinction of two age groups is strongly supported by Hf isotope data on the same zircons. Although the trace element patterns of both populations are typical of mantle derived zircons, the ‘young’ population has slightly higher concentrations of most trace elements, but has lower Hf, Nb, Ta and Pb contents. The distinct differences in trace element contents and Hf isotopic composition of the two zircon populations indicate that they were derived from different magma sources. The dating results indicate that the emplacement age of the Timber Creek kimberlites cannot be older than the age of the ‘young’ zircon population (i.e. 179 ± 2 Ma). This clarifies the inconsistency between the previously reported SHRIMP age of the Timber Creek zircons (1462 ± 53 Ma) and the much younger age (1200 Ma) of the sediments of the Victoria River Basin into which these kimberlites have intruded. The Timber Creek kimberlites are a newly recognised extension of the widespread Jurassic kimberlite activity known in Western Australia and South Australia (Wandagee, Orroroo, Cleve and Eurelia kimberlites).  相似文献   

A Paleoproterozoic orogeny recorded in a long-lived cratonic remnant (Wuyishan terrane), eastern Cathaysia Block, China   总被引：12，自引：0，他引：12  

Jin-Hai Yu  Lijuan Wang  S.Y. O&#x;Reilly  W.L. Griffin  Ming Zhang  Chunzhong Li  Liangshu Shu 《Precambrian Research》2009,174(3-4):347-363

The Precambrian basement of northern Wuyishan (southern Zhejiang Province, eastern Cathaysia Block, South China), consists mainly of Paleoproterozoic granites and metamorphic rocks of the Badu Complex, which are the oldest rocks found in the Cathaysia Block. LA-ICPMS zircon U–Pb ages for a gneiss and five gneissic granites from the Tianhou, Danzhu, Xiaji and Lizhuang plutons indicate that magmatism and metamorphism took place between 1888 and 1855 Ma. The Xiaji (1888 ± 7 Ma) and Lizhuang (1875 ± 9 Ma) granites have high SiO₂, K₂O and Rb contents, high A/CNK (1.09–1.40) and Rb/Sr, and low contents of Sr, REE and mafic components (Mg, Fe, Ti, Mn and other transition metals). They have the geochemical signature of S-type granites, and a sedimentary protolith is confirmed by the presence of abundant inherited zircons with a range of ages and Hf-isotope compositions. The Tianhou and Danzhu granites are metaluminous to weakly peraluminous (A/CNK = 0.80–1.07), and have low SiO₂ contents, high Ga/Al and FeO/(FeO + MgO) ratios, and Zn and HFSE concentrations typical of A-type granites. They also record high crystallization temperatures (885–920 °C), consistent with A-type granites. High Y/Nb ratios (>1.4) indicate that they belong to the A₂ subgroup, suggesting that they probably formed in a post-orogenic tectonic setting. Their ages range from 1867 to 1855 Ma, slightly later than the syn-collisional Lizhuang and Xiaji S-type granites. These granitic rocks and the metamorphic rocks of the Badu Complex define a late Paleoproterozoic orogenic cycle in the area. All the 1.86–1.90 Ga zircons, whether derived from S- or A-type granites, show similar Hf-isotopic compositions, with Hf model ages clustering at 2.8 Ga. These model ages, and inherited zircons (ca. 2.5–2.7 Ga) found in some rocks, indicate that the late Paleoproterozoic magmatism and tectonism of the eastern Cathaysia Block represent an overprint on an Archaean basement. This Paleoproterozoic orogeny in the Wuyishan terrane coincides with the assembly of the supercontinent Columbia, suggesting that the Wuyishan terrane was the part of this supercontinent.Zircon ages also record an early Mesozoic (Triassic) tectonothermal overprint that was very intensive in the northern Wuyishan area, leading to high-grade metamorphism of Paleoproterozoic basement, Pb loss from Paleoproterozoic zircons and overgrowth of new zircon. The central and southern parts of Wuyishan and the Chencai area (northern Zhejiang Province) also experienced strong reworking in Neoproterozoic and early Paleozoic times. The Wuyishan terrane (especially in the north) represents a long-lived remnant of the old craton, which has survived for at least one billion years. The compositions of the basement rocks, the Paleoproterozoic orogeny and the Triassic tectonothermal imprint in the Wuyishan terrane are similar to those recognized in the Yeongnam massif of South Korea, suggesting that the two terranes may have been connected from Paleoproterozoic to Triassic time.  相似文献   

On the Vp/Vs–Mg# correlation in mantle peridotites: Implications for the identification of thermal and compositional anomalies in the upper mantle     

Juan Carlos Afonso  Giorgio Ranalli  Manel Fernàndez  William L. Griffin  Suzanne Y. O'Reilly  Ulrich Faul 《Earth and Planetary Science Letters》2010,289(3-4):606-618

We use thermodynamically self-consistent and hybrid methods to analyze the correlation of important physical parameters (e.g. bulk density, elastic moduli) with bulk Mg# and modal composition in mantle peridotites at upper mantle conditions. Temperature (anharmonic and anelastic), pressure and compositional derivatives for all these parameters are evaluated. The results show that the widely used correlations between Vp/Vs and Mg# in peridotites are strictly valid only for garnet-bearing assemblages at temperatures < 900 °C. The correlation breaks down when: i) spinel is the stable Al-rich phase in the assemblage and ii) when anelastic attenuation of seismic velocities becomes important (T ? 900 °C). This implies that the range of applicability of published Vp/Vs–Mg# correlations for the upper mantle is limited to a depth interval between the spinel–garnet phase transition and the 900 °C isotherm. We use numerical simulations to show that this depth interval is virtually nonexistent in lithospheres thinner than ～ 140 km and can comprise up to ～ 50% of the lithospheric mantle in thick (> 220 km) lithospheric domains. In addition, we show that for most of the upper mantle the expected Δ(Vp/Vs) values associated with compositional variations are smaller than the resolution limit of current seismological methods. All these considerations suggest that the Vp/Vs ratio is not a reliable measure of compositional variations and that for large parts of the upper mantle compositional anomalies cannot be separated from thermal anomalies on the basis of seismological studies only. We further confirm that the only reliable indicator of compositional anomalies in a peridotitic mantle is the ratio of density to shear wave velocities (ρ/Vs). Our results demonstrate that geophysical–petrological models (forward or inverse) that model these two fields (i.e. density and Vs) self-consistently within a robust thermodynamic framework are necessary for characterizing the small-scale thermal and compositional structure of the lithosphere and sublithospheric upper mantle.  相似文献