Heavy metal concentrations in surficial sediments from accreting and eroding areas along the coast of Guyana   总被引：1，自引：0，他引：1  

V. Lakhan  K. Cabana  P. LaValle 《Environmental Geology》2002,42(1):73-80

. Surficial sediments sampled from accreting and eroding areas along the coast of Guyana were examined for concentrations of heavy metals; aluminum, copper, chromium, iron, nickel, lead, vanadium and zinc. Twenty-four samples were collected, 12 from each of the eroding and accreting areas. For granulometric composition determination, samples were separated into particle-size fractions using sieving and hydrometer procedures. The consideration of three grain-size fractions (4.0, 5.0, and greater than 5.0 phi), plus 24 bulk samples less than 4.0 phi in diameter, required analyzing a total of 96 samples for the presence of heavy metals. The analysis employed was aquaregia digestion, followed by inductively coupled plasma optical emission spectroscopy. The statistical techniques of discriminant analysis, analysis of variance, and correlation and regression were used to analyze all obtained data. Discriminant analysis revealed that metal concentrations were statistically unique to each area. From the analysis of variance, and correlation and regression, it was discovered that the grain size of the sediment had a pronounced effect on the spatial distribution of heavy metals. The accreting area, with finer sediments, accumulated higher concentrations of heavy metals.  相似文献   

The effect of acoustic waves on spectral-line profiles in the solar atmosphere: Observations and theory     

R. I. Kostyk  E. V. Khomenko 《Astronomy Reports》2002,46(11):925-931

The fine structure of the FeI λ 532.4185-nm line of neutral iron is studied with high spatial (0.5″) and temporal (9.3 s) resolution using observations of a quiet region at the center of the solar disk. The character of the line asymmetry depends strongly on the nature of the velocity field, i.e., on whether it is due to convective or wave motions. The magnitude of the asymmetry due to acoustic waves is comparable to that due to convective motions. The propagation of acoustic waves in moving granules and intergranular lanes is studied by solving a system of hydrodynamical equations in a three-dimensional model for the solar atmosphere. The temporal variations in the bisector of the line synthesized in a non-LTE approximation agree well with the observational data.  相似文献   

Disk wind in young binaries and its impact on the infrared excesses of young stars     

V. P. Grinin 《Astronomy Reports》2002,46(5):380-389

We consider the effect of binarity of young stars on the spectral energy distribution of the IR radiation from circumstellar dust. The formation of a common dust envelope in a binary system with a low-mass secondary component is strongly affected by the disk wind from the secondary. The small velocities in peripheral areas of the wind are such that it can be partially or entirely captured by the primary, even when the distance between the components is up to several astronomical units. As a result, an envelope with a rather complex spatial and kinematic structure is formed. Its mass is many orders of magnitude smaller than that of the accretion disk around the binary. However, the thermal radiation emitted by dust particles of the envelope can be comparable to the total radiation of the accretion disk. This result is discussed in the context of the deficit at near-IR wavelengths (2–10µm) in current models for accretion disks around young stars.  相似文献   

The possible formation of massive tori in white-dwarf binary systems     

D. P. Savokhin  E. I. Staritsyn 《Astronomy Reports》2002,46(6):481-488

Mass exchange in white-dwarf binary systems with mass ratios 0.35–0.55 and total masses exceeding the Chandrasekhar limit could lead to the disruption of the less massive component of the system and the formation of a torus around the more massive component.  相似文献   

A Model for the polar motion of the deformable Earth adequate for astrometric data     

L. D. Akulenko  S. A. Kumakshev  Yu. G. Markov  L. V. Rykhlova 《Astronomy Reports》2002,46(1):74-82

Refined analytical expressions for the frequencies corresponding to the Chandler motion of the pole and the diurnal rotation of the deformable Earth are derived. Numerical estimates of the period and amplitude of the polar oscillations are presented. The trajectory of the Chandler polar motion derived via numerical modeling is in qualitative and quantitative agreement with experimental data from the International Earth Rotation Service (IERS). An evolutionary model describing slow variations in the Earth’s rotation parameters under the action of the dissipative moments of the tidal gravitational forces on time scales considerably longer than the precession period of the Earth’s axis is constructed. The axis of the Earth’s figure tends to approach the angular momentum vector of the proper rotation.  相似文献   

Groundwater abstraction and contamination in Lithuania as geoindicators of environmental change   总被引：1，自引：0，他引：1  

A. Klimas  M. Gregorauskas 《Environmental Geology》2002,42(7):767-772

Groundwater abstraction not only affects subsurface water, but also causes changes in the hydrosphere, lithosphere, and biosphere. There are certain symptoms of these environmental changes that might be designated as geoindicators. Geoindicators related to groundwater abstraction and contamination in Lithuania have been classified into three groups related to: (1) the decline/rise of groundwater levels, (2) the deterioration of groundwater quality, and (3) the intensification of water-rock interaction. On the basis of hydrogeological and hydrological investigations carried out over many years, different environmental impacts of intensive groundwater use are demonstrated. The most important among them are the formation of depression cones, intensification of groundwater pollution, saltwater encroachment, and the intensification of karst.  相似文献   

Visualization and modeling of sub-populations of compositional data: statistical methods illustrated by means of geochemical data from fumarolic fluids     

Vera Pawlowsky-Glahn  Antonella Buccianti 《International Journal of Earth Sciences》2002,91(2):357-368

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Rare gas isotopes and parent trace elements in ultrabasic-alkaline-carbonatite complexes, Kola Peninsula: identification of lower mantle plume component   总被引：2，自引：0，他引：2  

I.N. Tolstikhin  I.L. KamenskyB. Marty  V.A. NivinV.R. Vetrin  E.G. BalaganskayaS.V. Ikorsky  M.A. GannibalD. Weiss  A. VerhulstD. Demaiffe 《Geochimica et cosmochimica acta》2002,66(5):881-901

During the Devonian magmatism (370 Ma ago) ∼20 ultrabasic-alkaline-carbonatite complexes (UACC) were formed in the Kola Peninsula (north-east of the Baltic Shield). In order to understand mantle and crust sources and processes having set these complexes, rare gases were studied in ∼300 rocks and mineral separates from 9 UACC, and concentrations of parent Li, K, U, and Th were measured in ∼70 samples. ⁴He/³He ratios in He released by fusion vary from pure radiogenic values ∼10⁸ down to 6 × 10⁴. The cosmogenic and extraterrestrial sources as well as the radiogenic production are unable to account for the extremely high abundances of ³He, up to 4 × 10⁻⁹ cc/g, indicating a mantle-derived fluid in the Kola rocks. In some samples helium extracted by crushing shows quite low ⁴He/³He = 3 × 10⁴, well below the mean ratio in mid ocean ridge basalts (MORB), (8.9 ± 1.0) × 10⁴, indicating the contribution of ³He-rich plume component. Magnetites are principal carriers of this component. Trapped ³He is extracted from these minerals at high temperatures 1100°C to 1600°C which may correspond to decrepitation or annealing primary fluid inclusions, whereas radiogenic ⁴He is manly released at a temperature range of 500°C to 1200°C, probably corresponding to activation of ⁴He sites degraded by U, Th decay.Similar ⁴He/³He ratios were observed in Oligocene flood basalts from the Ethiopian plume. According to a paleo-plate-tectonic reconstruction, 450 Ma ago the Baltica (including the Kola Peninsula) continent drifted not far from the present-day site of that plume. It appears that both magmatic provinces could relate to one and the same deep-seated mantle source.The neon isotopic compositions confirm the occurrence of a plume component since, within a conventional ²⁰Ne/²²Ne versus ²¹Ne/²²Ne diagram, the regression line for Kola samples is indistinguishable from those typical of plumes, such as Loihi (Hawaii). ²⁰Ne/²²Ne ratios (up to 12.1) correlate well with ⁴⁰Ar/³⁶Ar ones, allowing to infer a source ⁴⁰Ar/³⁶Ar ratio of about 4000 for the mantle end-member, which is 10 times lower than that of the MORB source end-member. In (³He/²²Ne)_PRIM versus (⁴He/²¹Ne)_RAD plot the Kola samples are within array established for plume and MORB samples; almost constant production ratio of (⁴He/²¹Ne)_RAD ≅ 2 × 10⁷ is translated via this array into (³He/²²Ne)_PRIM ∼ 10. The latter value approaches the solar ratio implying the non-fractionated solar-like rare gas pattern in a plume source.The Kola UACC show systematic variations in the respective contributions of in situ-produced radiogenic isotopes and mantle-derived isotopes. Since these complexes were essentially plutonic, we propose that the depth of emplacement exerted a primary control on the retention of both trapped and radiogenic species, which is consistent with geological observations. The available data allow to infer the following sequence of processes for the emplacement and evolution of Kola Devonian UACC: 1) Ascent of the plume from the lower mantle to the subcontinental lithosphere; the plume triggered mantle metasomatism not later than ∼700 to 400 Ma ago. 2) Metasomatism of the lithosphere (beneath the central part of the Kola Peninsula), including enrichment in volatile (e.g., He, Ne) and in incompatible (e.g., U, Th) elements. 3) Multistage intrusions of parental melts, their degassing, and crystallisation differentiation ∼370 Ma ago. 4) Postcrystallisation migration of fluids, including loss of radiogenic and of trapped helium. Based on model compositions of the principle terrestrial reservoirs we estimate the contributions (by mass) of the plume material, the upper mantle material, and the atmosphere (air-saturated groundwater), into the source of parent melt at ∼2%, 97.95%, and ∼0.05%, respectively.  相似文献   

Effect of fluid-sediment reaction on hydrothermal fluxes of major elements, eastern flank of the Juan de Fuca Ridge     

Emily R. Giambalvo  Carl I. SteefelAndrew T. Fisher  Nina D. RosenbergC.Geoffrey Wheat 《Geochimica et cosmochimica acta》2002,66(10):1739-1757

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Microbial respiration and diffusive transport of O₂, O₂, and OO in unsaturated soils: a mesocosm experiment     

M.Jim HendryLeonard I Wassenaar  Tyler K Birkham 《Geochimica et cosmochimica acta》2002,66(19):3367-3374

Although the flux of molecular O₂ between the atmosphere and the subsurface is intrinsically linked to the net soil production of greenhouse gasses, few studies have focused on the controls affecting the isotopic composition of O₂ in the subsurface. Here, we developed and tested a stable oxygen isotope tracer technique and gas transport modeling approach to evaluate O₂ cycling and fluxes from the subsurface that used an environmentally controlled soil mescosm. We measured the O₂ and δ¹⁸O₂ profiles in a model unsaturated soil zone and quantified the O₂ consumption rates and the O₂ isotope fractionation factors resulting from the combined processes of subsurface microbial (including bacteria, fungi, and protozoa) consumption of O₂ and diffusive influx of O₂ from the atmosphere. We found that at high respiration rates in the mesocosm, there appeared to be very little isotope fractionation of O₂ by soil microorganisms. Although the mesocosm respiration rates are not typical of natural soils in northern temperate climes, they may be more representative of soils in warm and moist tropical environments. Our findings caution against the indiscriminate application of laboratory-determined oxygen isotope fractionation factors to field settings. The oxygen isotope tracer and modeling approach demonstrated here may be applied to gain a better understanding of biogenic gas production and O₂ cycling in subsurface systems and soils.  相似文献