Contribution of long-term hydrothermal experiments for understanding the smectite-to-chlorite conversion in geological environments     

Régine?Mosser-RuckEmail author  Isabella?Pignatelli  Franck?Bourdelle  Mustapha?Abdelmoula  Odile?Barres  Damien?Guillaume  Delphine?Charpentier  Davy?Rousset  Michel?Cathelineau  Nicolas?Michau 《Contributions to Mineralogy and Petrology》2016,171(11):97

The smectite-to-chlorite conversion is investigated through long-duration experiments (up to 9 years) conducted at 300 °C. The starting products were the Wyoming bentonite MX80 (79 % smectite), metallic iron and magnetite in contact with a Na–Ca chloride solution. The predominant minerals in the run products were an iron-rich chlorite (chamosite like) and interstratified clays interpreted to be chlorite/smectite and/or corrensite/smectite, accompanied by euhedral crystals of quartz, albite and zeolite. The formation of pure corrensite was not observed in the long-duration experiments. The conversion of smectite into chlorite over time appears to take place in several steps and through several successive mechanisms: a solid-state transformation, significant dissolution of the smectite and direct precipitation from the solution, which is over-saturated with respect to chlorite, allowing the formation of a chamosite-like mineral. The reaction mechanisms are confirmed by X-ray patterns and data obtained on the experimental solutions (pH, contents of Si, Mg, Na and Ca). Because of the availability of some nutrients in the solution, total dissolution of the starting smectite does not lead to 100 % crystallization of chlorite but to a mixture of two dominant clays: chamosite and interstratified chlorite/smectite and/or corrensite/smectite poor in smectite. The role of Fe/(Fe + Mg) in the experimental medium is highlighted by chemical data obtained on newly formed clay particles alongside previously published data. The newly formed iron-rich chlorite has the same composition as that predicted by the geothermometer for diagenetic to low-grade metamorphic conditions, and the quartz + Fe-chlorite + albite experimental assemblage in the 9-year experiment is close to that fixed by water–rock equilibrium.  相似文献   

Simulation of damage–permeability coupling for mortar under dynamic loads     

Wen Chen  Christian La Borderie  Olivier Maurel  Gilles Pijaudier‐Cabot  Franck Rey‐Bethbeder 《国际地质力学数值与分析法杂志》2014,38(5):457-474

The results reported in this paper deal with the simulation of damage in cohesive geomaterials such as rocks or concrete subjected to dynamic loads. The practical objective is to stimulate the production of tight gas reservoirs with a technique that is an alternative to hydraulic fracturing. The principle is that when subjected to dynamic loads, cohesive materials such as concrete, rocks or ceramics exhibit distributed micro‐cracking as opposed to localised cracking observed under static loads. Hence, a low permeability rock containing gas trapped into occluded pores can be fragmented with the help of dynamic loads, and gas can be extracted in a much more efficient way compared with hydraulic fracturing, where only large macro cracks are formed with very few connections between occluded pores. At the stage of laboratory development of this technique, compressive underwater shock waves have been used to increase the intrinsic permeability of concrete specimens. In a previous study, pressure waves generated by pulsed arc electrohydraulic discharges in water were used in order to induce micro‐cracking and an increase of average permeability of concrete hollow cylinders subjected to confinement stresses (equivalent to geostatic stresses). We discuss here a 3‐D anisotropic constitutive model aimed at describing the dynamic response of these specimens. It is based on rate‐dependent continuum damage constitutive relations. Crack closure effects and damage‐induced anisotropy are included in the model. The directional growth of damage is related to the directional growth of material intrinsic permeability. Numerical simulations of damage induced by shock waves show good agreement with the experiments for various confinement levels of the specimens. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

A spectral comparison of (379) Huenna and its satellite     

Francesca E. DeMeo  Benoît Carry  Franck Marchis  Richard P. Binzel  Schelte J. Bus  Alin Nedelcu  Michael Busch 《Icarus》2011,212(2):677-681

We present near-infrared spectral measurements of Themis family Asteroid (379) Huenna (D ∼ 98 km) and its 6 km satellite using SpeX on the NASA IRTF. The companion was farther than 1.5″ from the primary at the time of observations and was approximately 5 magnitudes dimmer. We describe a method for separating and extracting the signal of a companion asteroid when the signal is not entirely resolved from the primary. The spectrum of (379) Huenna has a broad, shallow feature near 1 μm and a low slope, characteristic of C-type asteroids. The secondary’s spectrum is consistent with the taxonomic classification of C-complex or X-complex. The quality of the data was not sufficient to identify any subtle feature in the secondary’s spectrum.  相似文献   

It starts at home? Climate policies targeting household consumption and behavioral decisions are key to low-carbon futures     

Ghislain Dubois  Benjamin Sovacool  Carlo Aall  Maria Nilsson  Carine Barbier  Alina Herrmann  Sébastien Bruyère  Camilla Andersson  Bore Skold  Franck Nadaud  Florian Dorner  Karen Richardsen Moberg  Jean Paul Ceron  Helen Fischer  Dorothee Amelung  Marta Baltruszewicz  Jeremy Fischer  Françoise Benevise  Valérie R. Louis  Rainer Sauerborn 《Chemie der Erde / Geochemistry》2010

Through their consumption behavior, households are responsible for 72% of global greenhouse gas emissions. Thus, they are key actors in reaching the 1.5 °C goal under the Paris Agreement. However, the possible contribution and position of households in climate policies is neither well understood, nor do households receive sufficiently high priority in current climate policy strategies. This paper investigates how behavioral change can achieve a substantial reduction in greenhouse gas emissions in European high-income countries. It uses theoretical thinking and some core results from the HOPE research project, which investigated household preferences for reducing emissions in four European cities in France, Germany, Norway and Sweden. The paper makes five major points: First, car and plane mobility, meat and dairy consumption, as well as heating are the most dominant components of household footprints. Second, household living situations (demographics, size of home) greatly influence the household potential to reduce their footprint, even more than country or city location. Third, household decisions can be sequential and temporally dynamic, shifting through different phases such as childhood, adulthood, and illness. Fourth, short term voluntary efforts will not be sufficient by themselves to reach the drastic reductions needed to achieve the 1.5 °C goal; instead, households need a regulatory framework supporting their behavioral changes. Fifth, there is a mismatch between the roles and responsibilities conveyed by current climate policies and household perceptions of responsibility. We then conclude with further recommendations for research and policy.  相似文献   

9. Life On Earth... And Elsewhere?     

Thierry Montmerle  Philippe Claeys  Muriel Gargaud  Purificatión López-García  Hervé Martin  Robert Pascal  Jacques Reisse  Franck Selsis 《Earth, Moon, and Planets》2006,98(1-4):299-312

This concluding chapter is divided into two main parts. The first part is a summary of the main facts and events which constitute the present body of knowledge of the chronology of life in the solar system, in the form of “highlights” in astronomy, geology, chemistry and biology. The second part raises the interrogation “Is life universal?”, and tries to provide answers based on these facts and events. These answers turn out to differ widely among the various disciplines, depending on how far they feel able to extrapolate their current knowledge.  相似文献   

Dynamic Habitability Of Extrasolar Planetary Systems     

W. Von. Bloh  C. Bounama  S. Franck 《Celestial Mechanics and Dynamical Astronomy》2005,92(1-3):287-300

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Split Comet C/2001 A2 (LINEAR)     

Jehin  Emmanuel  Boehnhardt  Hermann  Sekanina  Zdenek  Bonfils  Xavier  Schütz  Oliver  Beuzit  Jean-Luc  Billeres  Malvina  Garradd  Gordon J.  Leisy  Pierre  Marchis  Franck  Más  Antonio  Origlia  Livia  Scarpa  Daniel  Thomas  Daniel  Tozzi  Gian Paolo 《Earth, Moon, and Planets》2002,90(1-4):147-151

Comet C/2001 A2 experienced several splitting events duringits 2001 perihelion passage. The first break-upevent was observed in March 2001 (IAUC 7616).In this paper we report the first results of ourextensive imaging and spectroscopic monitoring campaignwith ESO telescopes over several weeks before andafter the perihelion passage on May 25 2001.  相似文献   

X-ray absorption via Kα resonance complexes in oxygen ions     

Anil K. Pradhan  Guo Xin Chen  Franck Delahaye  Sultana N. Nahar  Justin Oelgoetz 《Monthly notices of the Royal Astronomical Society》2003,341(4):1268-1271

  相似文献   

It starts at home? Climate policies targeting household consumption and behavioral decisions are key to low-carbon futures     

Ghislain Dubois  Benjamin Sovacool  Carlo Aall  Maria Nilsson  Carine Barbier  Alina Herrmann  Sébastien Bruyère  Camilla Andersson  Bore Skold  Franck Nadaud  Florian Dorner  Karen Richardsen Moberg  Jean Paul Ceron  Helen Fischer  Dorothee Amelung  Marta Baltruszewicz  Jeremy Fischer  Françoise Benevise  Valérie R. Louis  Rainer Sauerborn 《Chemie der Erde / Geochemistry》2011

Through their consumption behavior, households are responsible for 72% of global greenhouse gas emissions. Thus, they are key actors in reaching the 1.5 °C goal under the Paris Agreement. However, the possible contribution and position of households in climate policies is neither well understood, nor do households receive sufficiently high priority in current climate policy strategies. This paper investigates how behavioral change can achieve a substantial reduction in greenhouse gas emissions in European high-income countries. It uses theoretical thinking and some core results from the HOPE research project, which investigated household preferences for reducing emissions in four European cities in France, Germany, Norway and Sweden. The paper makes five major points: First, car and plane mobility, meat and dairy consumption, as well as heating are the most dominant components of household footprints. Second, household living situations (demographics, size of home) greatly influence the household potential to reduce their footprint, even more than country or city location. Third, household decisions can be sequential and temporally dynamic, shifting through different phases such as childhood, adulthood, and illness. Fourth, short term voluntary efforts will not be sufficient by themselves to reach the drastic reductions needed to achieve the 1.5 °C goal; instead, households need a regulatory framework supporting their behavioral changes. Fifth, there is a mismatch between the roles and responsibilities conveyed by current climate policies and household perceptions of responsibility. We then conclude with further recommendations for research and policy.  相似文献   

On the iron isotope heterogeneity of lithospheric mantle xenoliths: implications for mantle metasomatism, the origin of basalts and the iron isotope composition of the Earth     

Franck Poitrasson  Guillaume Delpech  Michel Grégoire 《Contributions to Mineralogy and Petrology》2013,165(6):1243-1258

With the aim to better understand the cause of the iron isotope heterogeneity of mantle-derived bulk peridotites, we compared the petrological, geochemical and iron isotope composition of four xenolith suites from different geodynamic settings; sub-arc mantle (Patagonia); subcontinental lithospheric mantle (Cameroon), oceanic mantle (Kerguelen) and cratonic mantle (South Africa). Although correlations were not easy to obtain and remain scattered because these rocks record successive geological events, those found between δ⁵⁷Fe, Mg#, some major and trace element contents of rocks and minerals highlight the processes responsible for the Fe isotope heterogeneity. While partial melting processes only account for moderate Fe isotope variations in the mantle (<0.2 ‰, with bulk rock values yielding a range of δ⁵⁷Fe ± 0.1 ‰ relative to IRMM-14), the main cause of Fe isotope heterogeneity is metasomatism (>0.9 ‰). The kinetic nature of rapid metasomatic exchanges between low viscosity melts/fluids and their wall-rocks peridotite in the mantle is the likely explanation for this large range. There are a variety of responses of Fe isotope signatures depending on the nature of the metasomatic processes, allowing for a more detailed study of metasomatism in the mantle with Fe isotopes. The current database on the iron isotope composition of peridotite xenoliths and mafic eruptive rocks highlights that most basalts have their main source deeper than the lithospheric mantle. Finally, it is concluded that due to a complex geological history, Fe isotope compositions of mantle xenoliths are too scattered to define a mean isotopic composition with enough accuracy to assess whether the bulk silicate Earth has a mean δ⁵⁷Fe that is chondritic, or if it is ~0.1 ‰ above chondrites as initially proposed.  相似文献