A comparison of streamflow,salt and water balances in adjacent farmland and forest catchments in south‐western Victoria,Australia          下载免费PDF全文

S. Michael Adelana  P. Evan Dresel  Peter Hekmeijer  Hanna Zydor  John A. Webb  Michael Reynolds  Matthew Ryan 《水文研究》2015,29(6):1630-1643

A study of the hydrologic effects of catchment change from pasture to plantation was carried out in Gatum, south‐western Victoria, Australia. This study describes the hydrologic characteristics of two adjacent catchments: one with 97% grassland and the other one with 62% Eucalyptus globulus plantations. Streamflow from both catchments was intermittent during the 20‐month study period. Monthly streamflow was always greater in the pasture‐dominated catchment compared with the plantation catchment because of lower evapotranspiration in the pasture‐based catchment. This difference in streamflow was also observed even during summer 2010/2011 when precipitation was 74% above average (1954–2012) summer rainfall. Streamflow peaks in the plantation‐based catchment were smaller than in the pasture‐dominated system. Flow duration curves show differences between the pasture and plantation‐dominated catchments and affect both high‐flow and low‐flow periods. Groundwater levels fell (up to 4.4 m) in the plantation catchment during the study period but rose (up to 3.2 m) in the pasture catchment. Higher evapotranspiration in the plantation catchment resulted in falling groundwater levels and greater disconnection of the groundwater system from the stream, resulting in lower baseflow contribution to streamflow. Salt export from each catchment increases with increasing flow and is higher at the pasture catchment, mainly because of the higher flow. Reduced salt loading to streams due to tree planting is generally considered environmentally beneficial in saline areas of south‐eastern Australia, but this benefit is offset by reduced total streamflow. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Distributed empirical algorithms to estimate catchment scale sediment connectivity and yield in a subtropical region          下载免费PDF全文

Reza Jamshidi  Deirdre Dragovich  Ashley A. Webb 《水文研究》2014,28(4):2671-2684

The intensity of soil loss and sediment delivery, representing hydrologic and geomorphic processes within a catchment, accelerates with rapid changes in land cover and rainfall events. An underlying component of sustainable management of water resources is an understanding of spatial and temporal variability and the adverse influences of regional parameters involved in generating sediment following widespread changes in land cover. A calibrated algorithm of soil loss coupled with a sediment delivery ratio (SDR) was applied in raster data layers to improve the capability of a combined model to estimate annual variability in sediment yields related to changes in vegetation cover identified by analyses of SPOT imagery. Four catchments in Kangaroo River State forest were assessed for annual changes in sediment yields. Two catchments were selectively logged in 2007, while the two other sites remained undisturbed. Results of SDR estimates indicated that only a small proportion of total eroded sediment from hillslopes is transported to catchment outlets. Larger SDR values were estimated in regions close to catchment outlets, and the SDR reduced sharply on hillslopes further than 200–300 m from these areas. Estimated sediment yield increased by up to 30% two years after land cover change (logging) in 2009 when more storm events were recorded, despite the moderate density of vegetation cover in 2009 having almost recovered to its initial pre‐logging (2005) condition. Rainfall had the most significant influence on streamflow and sediment delivery in all catchments, with steeply sloping areas contributing large amounts of sediment during moderate and high rainfall years in 2007 and 2009. It is concluded that the current scenario of single‐tree selection logging utilized in the study area is an acceptable and environmentally sound land management strategy for preservation of soil and water resources. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Origins of differences in climate sensitivity, forcing and feedback in climate models     

Mark J. Webb  F. Hugo Lambert  Jonathan M. Gregory 《Climate Dynamics》2013,40(3-4):677-707

We diagnose climate feedback parameters and CO₂ forcing including rapid adjustment in twelve atmosphere/mixed-layer-ocean (“slab”) climate models from the CMIP3/CFMIP-1 project (the AR4 ensemble) and fifteen parameter-perturbed versions of the HadSM3 slab model (the PPE). In both ensembles, differences in climate feedbacks can account for approximately twice as much of the range in climate sensitivity as differences in CO₂ forcing. In the AR4 ensemble, cloud effects can explain the full range of climate sensitivities, and cloud feedback components contribute four times as much as cloud components of CO₂ forcing to the range. Non-cloud feedbacks are required to fully account for the high sensitivities of some models however. The largest contribution to the high sensitivity of HadGEM1 is from a high latitude clear-sky shortwave feedback, and clear-sky longwave feedbacks contribute substantially to the highest sensitivity members of the PPE. Differences in low latitude ocean regions (30°N/S) contribute more to the range than those in mid-latitude oceans (30–55°N/S), low/mid latitude land (55°N/S) or high latitude ocean/land (55–90°N/S), but contributions from these other regions are required to account fully for the higher model sensitivities, for example from land areas in IPSL CM4. Net cloud feedback components over the low latitude oceans sorted into percentile ranges of lower tropospheric stability (LTS) show largest differences among models in stable regions, mainly due to their shortwave components, most of which are positive in spite of increasing LTS. Differences in the mid-stability range are smaller, but cover a larger area, contributing a comparable amount to the range in climate sensitivity. These are strongly anti-correlated with changes in subsidence. Cloud components of CO₂ forcing also show the largest differences in stable regions, and are strongly anticorrelated with changes in estimated inversion strength (EIS). This is qualitatively consistent with what would be expected from observed relationships between EIS and low-level cloud fraction. We identify a number of cases where individual models show unusually strong forcings and feedbacks compared to other members of the ensemble. We encourage modelling groups to investigate unusual model behaviours further with sensitivity experiments. Most of the models fail to correctly reproduce the observed relationships between stability and cloud radiative effect in the subtropics, indicating that there remains considerable room for model improvements in the future.  相似文献   

Paleochannels and Patches: A Geoarchaeological Assessment of Silcrete Sources in the Cumberland Plain,Eastern Australia     

T. Doelman  J. Webb  A. Williams  J. May  F. Barry 《Geoarchaeology》2015,30(6):495-510

Although Aboriginal occupation dates to the Pleistocene, silcrete artifacts only begin to dominate archaeological sites found in the Cumberland Plain of western Sydney, eastern Australia, during the mid‐late Holocene. These assemblages routinely include large numbers of backed artifacts. A geoarchaeological survey of five potential silcrete source areas found that silcrete is irregularly distributed along ridgelines within gravel patches that represent paleochannel remnants. Thus, particular parts of the landscape, dictated by the geological history, were more likely to be targeted for stone procurement. The quality of silcrete differs between and within the sources due to variations in grain‐size, degree of silicification, and presence of inclusions/fractures, as well as the destructive influence of bush fires on exposed cobbles, resulting in an overall low abundance of high‐quality silcrete across the Cumberland Plain. Furthermore, a rind or chalky weathering cortex on many cobbles means that testing was required to assess the internal raw material quality. The difficulty in locating suitable raw material for artifact manufacture meant that when good silcrete sources were found, they were heavily targeted. This contextual information provides an essential backdrop in which to understand the archaeology of the Cumberland Plain and broader patterns of landscape use.  相似文献   

Coupled biotic-abiotic Mn(II) oxidation pathway mediates the formation and structural evolution of biogenic Mn oxides     

D.R. Learman  S.M. Webb  A.S. Madden 《Geochimica et cosmochimica acta》2011,75(20):6048-6063

Manganese (Mn) oxides are among the strongest oxidants and sorbents in the environment, impacting the transport and speciation of metals, cycling of carbon, and flow of electrons within soils and sediments. The oxidation of Mn(II) to Mn(III/IV) oxides has been primarily attributed to biological processes, due in part to the faster rates of bacterial Mn(II) oxidation compared to observed mineral-induced and other abiotic rates. Here we explore the reactivity of biogenic Mn oxides formed by a common marine bacterium (Roseobacter sp. AzwK-3b), which has been previously shown to oxidize Mn(II) via the production of extracellular superoxide. Oxidation of Mn(II) by superoxide results in the formation of highly reactive colloidal birnessite with hexagonal symmetry. The colloidal oxides induce the rapid oxidation of Mn(II), with dramatically accelerated rates in the presence of organics, presumably due to mineral surface-catalyzed organic radical generation. Mn(II) oxidation by the colloids is further accelerated in presence of both organics and light, implicating reactive oxygen species in aiding abiotic oxidation. Indeed, the enhancement of Mn(II) oxidation is negated when the colloids are reacted with Mn(II) in the presence of superoxide dismutase, an enzyme that scavenges the reactive oxygen species (ROS) superoxide. The reactivity of the colloidal phase is short-lived due to the rapid evolution of the birnessite from hexagonal to pseudo-orthogonal symmetry. The secondary particulate triclinic birnessite phase exhibits a distinct lack of Mn(II) oxidation and subsequent Mn oxide formation. Thus, the evolution of initial reactive hexagonal birnessite to non-reactive triclinic birnessite imposes the need for continuous production of new colloidal hexagonal particles for Mn(II) oxidation to be sustained, illustrating an intimate dependency of enzymatic and mineral-based reactions in Mn(II) oxidation. Further, the coupled enzymatic and mineral-induced pathways are linked such that enzymatic formation of Mn oxide is requisite for the mineral-induced pathway to occur. Here, we show that Mn(II) oxidation involves a complex network of abiotic and biotic processes, including enzymatically produced superoxide, mineral catalysis, organic reactions with mineral surfaces, and likely photo-production of ROS. The complexity of coupled reactions involved in Mn(II) oxidation here highlights the need for further investigations of microbially-mediated Mn oxide formation, including identifying the role of Mn oxide surfaces, organics, reactive oxygen species, and light in Mn(II) oxidation and Mn oxide phase evolution.  相似文献   

The effect of pH and natural microbial phosphatase activity on the speciation of uranium in subsurface soils     

Melanie J. Beazley  Samuel M. Webb  Martial Taillefert 《Geochimica et cosmochimica acta》2011,75(19):5648-5663

The biomineralization of U(VI) phosphate as a result of microbial phosphatase activity is a promising new bioremediation approach to immobilize uranium in both aerobic and anaerobic conditions. In contrast to reduced uranium minerals such as uraninite, uranium phosphate precipitates are not susceptible to changes in oxidation conditions and may represent a long-term sink for uranium in contaminated environments. So far, the biomineralization of U(VI) phosphate has been demonstrated with pure cultures only. In this study, two uranium contaminated soils from the Department of Energy Oak Ridge Field Research Center (ORFRC) were amended with glycerol phosphate as model organophosphate source in small flow-through columns under aerobic conditions to determine whether natural phosphatase activity of indigenous soil bacteria was able to promote the precipitation of uranium(VI) at pH 5.5 and 7.0. High concentrations of phosphate (1-3 mM) were detected in the effluent of these columns at both pH compared to control columns amended with U(VI) only, suggesting that phosphatase-liberating microorganisms were readily stimulated by the organophosphate substrate. Net phosphate production rates were higher in the low pH soil (0.73 ± 0.17 mM d⁻¹) compared to the circumneutral pH soil (0.43 ± 0.31 mM d⁻¹), suggesting that non-specific acid phosphatase activity was expressed constitutively in these soils. A sequential solid-phase extraction scheme and X-ray absorption spectroscopy measurements were combined to demonstrate that U(VI) was primarily precipitated as uranyl phosphate minerals at low pH, whereas it was mainly adsorbed to iron oxides and partially precipitated as uranyl phosphate at circumneutral pH. These findings suggest that, in the presence of organophosphates, microbial phosphatase activity can contribute to uranium immobilization in both low and circumneutral pH soils through the formation of stable uranyl phosphate minerals.  相似文献   

Geophysical evidence on the structure of the Taupo Volcanic Zone and its hydrothermal circulation     

H.M. Bibby  T.G. Caldwell  F.J. Davey  T.H. Webb 《Journal of Volcanology and Geothermal Research》1995,68(1-3)

The Taupo Volcanic Zone (TVZ) of New Zealand is characterised by extensive volcanism and by high rates of magma production. Associated with this volcanism are numerous high-temperature (> 250 °C) geothermal systems through which the natural heat output of 4200 ± 500 MW is channelled. Outside the geothermal fields the heat flow is negligible. The average heat flux from the central 6000 km² of the TVZ, which contains most of the geothermal fields, is 700 mW/m³. This heat flux appears to be more concentrated along the eastern margin of the TVZ.Schlumberger resistivity measurements (AB/2 of 500 m and 1000 m) have identified 17 distinct geothermal fields with natural heat outputs greater than 20 MW. An additional six, low-heat-output geothermal fields also occur, and may represent formerly more active systems now in decline. Two extinct fields have also been identified. The average spacing between fields is 10–15 km. The distribution of geothermal fields does not appear to be directly associated with individual volcanic features except for the geothermal system that occurs within Lake Taupo and which occupies the vent of the 1800 yr.B.P. Taupo eruption. The positions of the geothermal fields do not appear to have varied for at least the last 200,000 years. These data are consistent with a model of large-scale convection occurring throughout the TVZ, in which the geothermal fields represent the upper portion of the rising, high-temperature, convective plumes. The majority of the recharge to the convection system is provided by the downward movement of cold meteoric water between the fields which suppresses the heat flow in these regions.Gravity measurements indicate that to a depth of about 2.5 km the upper layers of the TVZ consist of low-density pyroclastic infill. A seismic refraction interface with velocity change from 3.2 km/s to 5.5 km/s occurs at a similar depth. The cross-sectional area of the convection plumes (identified electrically) appears to increase at depths of 1–2 km, consistent with a decrease in permeability at the depth at which the velocity and density increase.The seismicity is dominated by swarm activity which accounts for about half of all earthquakes and is highly variable in both space and time. The small number of seismic events (and swarms) that have well determined depths show a cut off of seismicity at depths of 7–9 km. The depth of the transition from brittle to ductile behaviour of the rocks is identified with the transition from a regime where heat is transported by (hydrothermal) convection and pore pressures are near-hydrostatic to a regime where heat transport is dominantly conductive and pore pressures are lithostatic. Within the convective region, temperatures are moderated by the circulation of water so that the depth of the transition from convective to conductive heat transfer can be linked to the bottom of the seismogenic zone. Rocks must become ductile within about 1 km of the bottom of the overlying convective zone.Seismic refraction studies suggest that the crust beneath the TVZ is highly thinned with a seismic velocity of about 7.5 km/ s, typical of the upper mantle, occurring at depth of 15 km. Seismological studies indicate the upper mantle is highly attenuating beneath the TVZ. Conductive heat transfer between the bottom of the convective system, at about 8 km, and the base of the material with crustal velocities, at 15 km, is not able to provide all the heat that is discharged at the surface. Repeated intrusion from the mantle may provide the additional heat transport required.  相似文献   

Isotopic constraints on the genesis and age of autochthonous glaucony in the Oligo-Miocene Torquay Group, south-eastern Australia     

Jonathan C. Kelly  John A. Webb  & Roland Maas 《Sedimentology》2001,48(2):325-338

The Oligo‐Miocene Torquay Group at Bird Rock in south‐eastern Australia comprises a sequence of fine‐grained skeletal carbonates and argillaceous and glauconitic sandstones, deposited in a cool‐water, mid‐shelf environment. The Bird Rock glaucony is autochthonous and consists predominantly of randomly interstratified glauconitic smectite, which constitutes bioclast infills and faecal pellet replacements. The results of Rb–Sr and oxygen isotopic analysis of samples taken from a single glauconitic horizon (the BW horizon) indicate that the glaucony developed through a series of simultaneous dissolution–crystallization reactions, which occurred during very early diagenesis in a closed or isochemical system, isolated from the ambient marine environment. The constituent ions of the glaucony were derived primarily from terrigenous clay minerals, but considerable potassium may have been sourced indirectly from sea water, through potassium enrichment of clay precursors. The pore fluids associated with glauconitization were marine derived, but progressively modified by the dissolution–crystallization of detrital clay minerals and autochthonous glaucony. Rb–Sr data for the BW horizon indicate that dating glauconies may be somewhat problematic, as co‐genetic glauconitic minerals can show a range of initial strontium compositions, which reflect the incorporation of strontium derived from mineralogical precursors and/or contemporaneous sea water. Rb–Sr isochrons indicate that the glaucony of the BW horizon formed at 23 ± 3 Ma. This age is in good agreement with both the established biostratigraphy and a ⁸⁷Sr/⁸⁶Sr age for the horizon (23 ± 1 Ma), but could only be determined using the independent age constraint and the estimate of the ⁸⁷Sr/⁸⁶Sr ratio of contemporaneous sea water provided by analysis of associated biogenic carbonate.  相似文献   

Drought and famine in Ethiopia and Sudan: An ongoing tragedy     

Patrick Webb  Joachim Von Braun  Tesfaye Teklu 《Natural Hazards》1991,4(1):85-86

Published with permission from Drought Network News, Vol. 2(3), 1990.  相似文献   

Seasonal variations of the clear-sky greenhouse effect: the role of changes in atmospheric temperatures and humidities     

MJ Webb  A Slingol  GL Stephens 《Climate Dynamics》1993,9(3):117-129

We present an analysis of the factors which control the seasonal variations of the clear-sky greenhouse effect, based on satellite observations and radiative transfer simulations. The satellite observations include the radiation budget at the top of the atmosphere from the Earth Radiation Budget Experiment and the total column moisture content derived from the Special Sensor Microwave/Imager. The simulations were performed with the SAMSON system described in an earlier paper, using atmospheric temperatures and humidities from operational analyses produced by the European Centre for Medium Range Weather Forecasts. At low latitudes, the magnitude of the clear-sky greenhouse effect is dominated by the strong thermodynamic link between the total column moisture content of the atmosphere and sea surface temperatures, with minimal seasonal variations. In contrast, at middle to high latitudes there are strong seasonal variations, the clear-sky greenhouse effect being largest in winter and smallest in summer. These variations cannot be explained by the seasonal cycle in the total column moisture content, as this is largest in summer and smallest in winter. The variations are controlled instead by the seasonal changes in atmospheric temperatures. The colder atmosphere in winter enhances the temperature differential between the atmosphere and the sea surface, leading to a larger greenhouse effect despite the lower moisture contents. The magnitude of the clear-sky greenhouse effect is thus controlled by atmospheric humidity at low latitudes, but by atmospheric temperature at middle and high latitudes. These controls are illustrated by results from sensitivity experiments with SAMSON and are interpreted in terms of a simple model.  相似文献