The effects of soil sand contents on characteristics of humic acids along soil profiles     

Xinyue Di  Hui Dong  Xianjin An  Haiming Tang  Baohua Xiao 《中国地球化学学报》2016,35(3):251-261

It is generally accepted that the compositions and properties of soil organic matter (SOM) are influenced by many factors. In order to reveal the effects of soil texture on characteristics and dynamics of SOM and its sub-fraction, humic acid (HA), along two soil profiles, a yellow soil profile and a purplish soil profile, under the same climate and vegetation conditions were determined. Results indicate that the decomposition and humification degrees of SOM and HA of the purplish soils are higher than those of the corresponding yellow soils indicated by A/O–A ratios of HAs, TOCs and HA yields of bulk soil samples, nevertheless, the development degree of the purplish soil is lower than that of the yellow soil. The variations of E₄/E₆ ratios of HAs along the soil profiles indicate the overall molecular sizes of HAs decreased downward along the soil profiles. A/O–A ratios of HAs decreased downward along both the soil profiles indicate that humification processes decrease downward along both the soil profiles. Leaching of SOM shows significant effects on the distribution and characteristics of HAs in the yellow soil profile but the purplish soil profile, which is consistent with the higher hydrophobicity of HAs in purplish soils, shows that the distribution characteristics of SOM along the soil profiles are a complex result of the combination of soil texture and characteristics of SOM itself. The remarkably different sand contents are concluded tentatively as one of reasons to the different distributions and dynamics of HAs along the soil profiles, however, to profoundly understand the evolution and transport of SOM along soil profiles needs more researches.  相似文献   

Fractionation characteristics of rare earth elements (REEs) linked with secondary Fe,Mn, and Al minerals in soils     

Chunying Chang  Fangbai Li  Chengshuai Liu  Jianfeng Gao  Hui Tong  Manjia Chen 《中国地球化学学报》2016,35(4):329-339

Soil secondary minerals are important scavengers of rare earth elements (REEs) in soils and thus affect geochemical behavior and occurrence of REEs. The fractionation of REEs is a common geochemical phenomenon in soils but has received little attention, especially fractionation induced by secondary minerals. In this study, REEs (La to Lu and Y) associated with soil-abundant secondary minerals Fe-, Al-, and Mn-oxides in 196 soil samples were investigated to explore the fractionation and anomalies of REEs related to the minerals. The results show right-inclined chondrite-normalized REE patterns for La–Lu in soils subjected to total soil digestion and partial soil extraction. Light REEs (LREEs) enrichment features were negatively correlated with a Eu anomaly and positively correlated with a Ce anomaly. The fractionation between LREEs and heavy REEs (HREEs) was attributed to the high adsorption affinity of LREEs to secondary minerals and the preferred activation/leaching of HREEs. The substantial fractions of REEs in soils extracted by oxalate and Dithionite-Citrate-Bicarbonate buffer solutions were labile (10 %–30 %), which were similar to the mass fraction of Fe (10 %–20 %). Furthermore, Eu was found to be more mobile than the other REEs in the soils, whereas Ce was less mobile. These results add to our understanding of the distribution and geochemical behavior of REEs in soils, and also help to deduce the conditions of soil formation from REE fractionation.  相似文献   

Fifteen Years of Ocean Observations with China Argo     

Liu Zenghong  Wu Xiaofen  Xu Jianping  Li Hong  Lu Shaolei  Sun Chaohui  Cao Minjie 《地球科学进展》2016,31(5):445-460

For 15 years since the beginning of China Argo project, China has deployed over 350 profiling floats in Pacific and Indian ocean, and constructed China Argo ocean observing network. Moreover, we have setup the Argo data receiving, processing and distributing system, and developed various Argo data products using Argo observations, which has promoted the progress of ocean data sharing in China. The abundant Argo data have become a main data source in oceanic and atmospheric basic researches and operational applications. A batch of important achievements in basic research and operational application have been brought, e.g. in aspects of tropical cyclone (typhoon), ocean circulation, meso-scale eddy, turbulence, heat/salt storage and transport and water mass, as well as in ocean, atmosphere/climate operational forecasting and predicting. With the extension of the international Argo program from “Core Argo” to “Global Argo”, we are faced with great challenges in the long-term maintaining and sustained developing of our Argo ocean observing network. It is suggested that we should take the opportunity to construct China regional Argo ocean observing network as soon as possible in adjacent northwestern Pacific and Indian ocean using Chinese BeiDou profiling floats, which will make us to take responsibility and obligation of a big country for addressing global climate changes and preventing natural disasters.  相似文献   

Active Characteristics and Paleoearthquakes in the West Kalpin Nappe Since the Holocene,SW Tianshan Mountain     

Li An  Ran Yongkang  Liu Huaguo  Xu Liangxin 《地球科学进展》2016,31(4):377-390

the Kalpin nappe is an important multiple thrust system. It is important to study the Cenozoic tectonic of the Tianshan Mountain. Holocene active characteristics and paleoearthquake of the Kalpin nappe can be used to evaluate the neotectonic of this area. In this paper, we accurately measured the fault scarp in the front of three thrust-fold faults and analyzed paleoearthquake events in the trenches of the Kalpin nappe. Using the ¹⁰Be exposure age, we obtained those geomorphic surface ages and paleoearthquake times. The result showed that the slip rates of the west Kalpintag fault, aozitag fault and the tuoketag fault were 1.45(+1.68/-0.44) mm/a, 0.81(+0.35/-0.19) mm/a and (0.3±0.05) mm/a, respectively since the Holocene. The slip rate indicated that the increased activity transferred from back-row fault to front-row fault and accorded with the piggy-back propagation model in the Tianshan Mountain. Displacements and recurrence intervals of paleoearthquakes was similar to the slip rate characteristics. It also showed paleoearthquakes in the front row fault were stronger than paleoearthquakes of the back row fault. The strong paleoearthquake which caused the highest surface rupture happened in the Kalpintag fault. The interval of paleoearthquakes was about 4 ka and the displacement of every paleoearthquake was about 3 m in the west Kalpintag fault; the interval of paleoearthquakes was about 2 ka and the displacement of every paleoearthquake was about 1m in the aozitag fault; the tuoketag fault ruptured only one paleoearthquake since 7 ka. The Piqiang tear fault was the tectonic result of different shortening rate between the west Kalpin system and the east Kalpin system. The shortening rate of west Kalpin system was obviously stronger than the east Kalpin system. The huge separation distance was near 20 km between the east and the west back-row fault. Because the slip rate of system transferred to the front-row fault in the piggy-back propagation model, the separation distance (~4 km) between the east and the west front-row fault was increasing.  相似文献   

Using Geomechanical Method to Predict Tectonic Fractures in Low-Permeability Sandstone Reservoirs     

Feng Jianwei  Ren Qiqiang  Xu Ke 《地球科学进展》2016,31(9):946-967

Understanding and interpreting the timing, location, orientation, and intensity of natural fractures within a geological structure are commonly important to both exploration and production planning activities of low-porosity and low-permeability carbonate reservoirs. In this study, we explore the application of comprehensive geomechanical methods to quantitatively characterize the fracture parameters based on Strain Energy Density Theory, such as linear fracture density and volume fracture density. This study approach is based on the idea that energy generated by tectonic stress on brittle sandstone,which can be distinguished fracture surface energy, friction energy dissipation and residual strain energy and natural fractures can be interpreted or inferred from geomechanical-model-derived strains. For this analysis, we model an extension and compression compound fault block developed in a mechanically stratified sandstone and shale sequence because mechanics experimental data and drilling data exist that can be directly compared with model results.However, the results show that the approach and our study conclusion are independent of the specified structural geometry, which can correlate fracture parameters in different stages with different tectonic activities, and finally build and visualize fracture networks in sandstone. The presence or absence of filling minerals in fractures is shown to strongly control the destruction and transformation of low-permeability sandstone, and this control possesses crucial implications for interpreting fracture aperture and reservoir flow simulation.  相似文献   

大兴安岭北部新林石英二长岩-花岗岩的地球化学特征及其成因     

孙如江  孙德有  苟军  王广婷  杨东光  李旭 《世界地质》2016,35(2):309-323

对额尔古纳地块东南部新林镇附近的侵入岩进行了锆石U-Pb年龄测定、Lu-Hf同位素和岩石地球化学研究。结果表明,岩体形成于141.1~123.8 Ma,是早白垩世岩浆活动的产物。新林石英二长岩-花岗岩高硅较富铝贫镁,属于准铝质、高钾钙碱性系列;具有中等-弱负Eu异常(δEu=0.53~0.72),轻重稀土分异比较明显[(La/Yb)_N=12.42~25.38];相对富集大离子亲石元素Rb、Th、U和LREE,高场强元素Ti、Nb、Ta、P和HREE表现出亏损。新林石英二长岩-花岗岩具有高Sr、低Yb及低Y的特征,且相对富K,属于C型埃达克岩,形成于加厚下地壳的部分熔融。Lu-Hf同位素研究显示其ε_(Hf)(t)为2.1~6.2,二阶段模式年龄(T_(DM2))为1025~786 Ma,认为其岩浆源区为新元古代增生的地壳物质。  相似文献   

大兴安岭北部额尔古纳地区塔木兰沟组火山岩岩石地球化学特征及成因     

毛安琦  孙德有  苟军  李旭  杨爱雪  杨东光 《世界地质》2016,35(3):641-652

额尔古纳地区塔木兰沟组火山岩的岩石地球化学成分显示其以粗安岩为主,少量安山岩和玄武安山岩。该组火山岩SiO_2含量为53.47%~58.50%,全碱含量为[w(K_2O+Na_2O)]4.27%~7.68%,w(MgO)=1.76%~4.03%,Mg~#=0.34~0.51;微量元素分析表明,稀土元素配分模式呈轻稀土富集右倾型,轻重稀土元素分馏较强[(La/Yb)_N=16.35~33.73],富集Rb、Ba、K、Sr等大离子亲石元素(LILE),亏损Nb、Ta等高场强元素(HFSE),Eu负异常不明显(δEu=0.89~0.92)。地球化学等特征表明塔木兰沟组火山岩未经受明显的地壳物质混染,岩浆来源于俯冲流体交代形成的富集岩石圈地幔,经历了以分离结晶作用为主导的演化过程。综合研究认为,额尔古纳地区塔木兰沟组火山岩形成于岩石圈伸展构造环境,与蒙古—鄂霍茨克洋闭合后的后造山伸展体制有关。  相似文献   

Late mesozoic A-Type granitoids in se China and paleo-pacific plate subduction and slab rollback北大核心CSCD     

Xia Y.  Liu L.  Xu X.-S. 《矿物岩石地球化学通报》2016,(6):1109-1119

This study has reviewed the distribution and pedogenesis of late Mesozoic A-Type granitoids in SE China. These A-Type granitoids belong to four belts ( S Jiangxi-SW Fujian belt, Xiang-Gui-Yue belt, Can-Hang belt and coastal belt) due to their temporal-spatial distribution. Based on the comparative analysis of chronology, geochemistry and magmatic association, this study has discussed the formation of A-Type granitoids and the subduction and slab rollback process of paleo-Pacific plate beneath SE China.  相似文献   

Rock associations and their spatial-Temporal variations of the early mesozoic igneous rocks in the NE Asia: Constraints on the initial subduction timing of the paleo-pacific plate北大核心CSCD     

Tang J.Xu W.-L.Wang F. 《矿物岩石地球化学通报》2016,(6):1181-1194

This paper summarizes rook associations and spatial-Temporal variations of the early Mesozoic igneous rocks in the NE Asia, with the aim of revealing the initial subduction timing of the Paleo-Pacific Plate beneath the Eurasia, and the relationships between the early Mesozoic magmatisms and the Paleo-Asian tectonic system, Mongol-Okhotsk tectonic system, and amalgamation of the Yangtze and North China cratons. Dating results indicate that the early Mesozoic magmatisms in the NE Asia can be subdivided into three stages, i.e., Early-Middle Triassic, Late Triassic, and Early Jurassic. The early Mesozoic calc-Alkaline magmatisms within the Erguna Massif reveal southward subduction of the Mongol-Okhotsk oceanic plate. The Triassic alkaline and bimodal magmatisms within the northern margin of the North China Craton indicate an extensional environment related to the final closure of the Paleo-Asian Ocean. The Late Triassic A-Type rhyo- lites and bimodal magmatisms, together with the Late Triassic stable sedimentary rocks, in eastern Heilongjiang-Jilin provinces, reveal an extensional environment and passive continental margin setting, whereas the Early Jurassic calc-Alkaline magmatisms and its compositional variations, together with the coeval accretionary complex, reveal the onset of the Paleo- Pacific plate beneath the Euirasian continent.  相似文献   

Rainfall over Oman and its teleconnection with El Niño Southern Oscillation     

Hamza Varikoden  Hilal Sulthan Ali Al-shukaili  C. A. Babu  A. A. Samah 《Arabian Journal of Geosciences》2016,9(8):520

The Sultanate of Oman is located in the south-eastern part of the Arabian Peninsula and covers the larger part of the southern coasts of the Arabian Peninsula in both arid and semi-arid environments except for the southern part which is swept by the monsoon affecting the Arabian Sea during the period from June to September. The summer rainfall over Oman shows year-to-year variability, and this is caused by oceanic and atmospheric influences. In the present study, we tried to explore the influence of El Niño on the rainfall over Oman using different data sets. The empirical orthogonal function (EOF) technique employed to the zonal wind at 850 hPa for the 30-year period shows that the second and third modes of EOF are showing high variability over the Oman regions. The corresponding PCs were subjected to FFT analysis, and it showed a peak about 5–6 years. In addition to this, the zonal wind over the Oman regions is correlated with the global zonal wind and found a significant correlation (1 % significant level). It has already been proved that the wind and rainfall during summer monsoon is in phase. Moreover, the spectral analysis of rainfall at Masirah station and the Niño3.4 index show the similar mode of variability indicating a direct relationship. The correlation between rainfall and the Niño3.4 index is also showing a positive significant value, and therefore, it can be concluded that the El Niño in the Pacific favours rainfall over the Oman region.  相似文献