Partitioning of halogens between mantle minerals and aqueous fluids: implications for the fluid flow regime in subduction zones     

Diego Bernini  Michael Wiedenbeck  David Dolejš  Hans Keppler 《Contributions to Mineralogy and Petrology》2013,165(1):117-128

We have performed phase equilibrium experiments in the system forsterite–enstatite–pyrope-H₂O with MgCl₂ or MgF₂ at 1,100 °C and 2.6 GPa to constrain the solubility of halogens in the peridotite mineral assemblage and the fluid–mineral partition coefficients. The chlorine solubility in forsterite, enstatite and in pyrope is very low, 2.1–3.9 and 4.0–11.4 ppm, respectively, and it is independent of the fluid salinity (0.3–30 wt% Cl), suggesting that some intrinsic saturation limit in the crystal is reached already at very low chlorine concentrations. Chlorine is therefore exceedingly incompatible in upper-mantle minerals. The fluorine solubility is 170–336 ppm in enstatite and 510–1,110 ppm in pyrope, again independent of fluid salinity. Forsterite dissolves 1,750–1,900 ppm up to a fluid salinity of 1.6 wt% F. At higher fluorine contents in the system, forsterite is replaced by the minerals of the humite group. The lower solubility of chlorine by three orders of magnitude when compared to fluorine is consistent with increasing lattice strain. Fluid–mineral partition coefficients are 10⁰–10² for fluorine and 10³–10⁵ for chlorine. Since the latter values are orders of magnitude higher than those for hydroxyl partitioning, fluid flow from the subducting slab through the mantle wedge will lead to an efficient sequestration of H₂O into the nominally anhydrous minerals in the wedge, whereas chlorine becomes enriched in the residual fluid. Simple mass balance calculations reveal that rock–fluid ratios of up to >3,000 are required to produce the elevated Cl/H₂O ratios observed in some primitive arc magmas. Accordingly, fluid flow from the subducted slab into the zone of melting in the mantle wedge does not only occur rapidly in narrow channels, but at least in some subduction zones, fluid pervasively infiltrates the mantle peridotite and interacts with a large volume of the mantle wedge. Together with the Cl/H₂O ratios of primitive arc magmas, our data therefore constrain the fluid flow regime below volcanic arcs.  相似文献   

Intercomparison of Boron Isotope and Concentration Measurements. Part II: Evaluation of Results   总被引：3，自引：1，他引：3  

Roberto Gonfiantini  Sonia Tonarini  Manfred Grning  Alessandra Adorni‐Braccesi  Assad S. Al‐Ammar  Marcus Astner  Sebastien Bchler  Ramon M. Barnes  Randy L. Bassett  Alain Cocherie  Annette Deyhle  Andrea Dini  Giorgio Ferrara  Jrme Gaillardet  Judith Grimm  Catherine Guerrot  Urs Krhenbühl  Graham Layne  Damien Lemarchand  Anette Meixner  D. Jack Northington  Maddalena Pennisi  Eva Reitznerov  Ilia Rodushkin  Naoji Sugiura  Regina Surberg  Sabine Tonn  Michael Wiedenbeck  Samuel Wunderli  Yingkai Xiao  Thomas Zack 《Geostandards and Geoanalytical Research》2003,27(1):41-57

The Istituto di Geoscienze e Georisorse (IGG), on behalf and with the support of the International Atomic Energy Agency (IAEA), prepared eight geological materials (three natural waters and five rocks and minerals), intended for a blind interlaboratory comparison of measurements of boron isotopic composition and concentration. The materials were distributed to twenty seven laboratories - virtually all those performing geochemical boron isotope analyses in the world -which agreed to participate in the intercomparison exercise. Only fifteen laboratories, however, ultimately submitted the isotopic and/or concentration results they obtained on the intercomparison materials. The results demonstrate that interlaboratory reproducibility is not well reflected by the precision values reported by the individual laboratories and this observation holds true for both boron concentration and isotopic composition. The reasons for the discrepancies include fractionations due to the chemical matrix of materials, relative shift of the zero position on the δ¹¹B scale and a lack of well characterized materials for calibrating absolute boron content measurements. The intercomparison materials are now available at the IAEA (solid materials) and IGG (waters) for future distribution.  相似文献   

Comment on: The F,Cl, Br and I Contents of Reference Glasses BHVO‐2G,BIR‐1G,BCR‐2G,GSD‐1G,GSE‐1G,NIST SRM 610 and NIST SRM 612 by Marks et al. This Issue          下载免费PDF全文

Michael Wiedenbeck 《Geostandards and Geoanalytical Research》2017,41(1):147-152

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GGR Biennial Critical Review: Analytical Developments Since 2012     

Michael Wiedenbeck  L. Paul Bédard  Roxana Bugoi  Mary Horan  Kathryn Linge  Silke Merchel  Luiz F. G. Morales  Dany Savard  A. Kate Souders  Paul Sylvester 《Geostandards and Geoanalytical Research》2014,38(4):467-512

Advances in the chemical, crystallographic and isotopic characterisation of geological and environmental materials can often be ascribed to technological improvements in analytical hardware or to innovative approaches to data acquisition and/or its interpretation. This biennial review addresses key laboratory methods that form much of the foundation for analytical geochemistry; again, this contribution is presented as a compendium of laboratory techniques. We highlight advances that have appeared since January 2012 and that are of particular significance for the chemical and isotopic characterisation of geomaterials. Prominent scientists from the selected analytical fields present publications they judge to be particular noteworthy, providing background information about the method and assessing where further opportunities might be anticipated. In addition to the well‐established technologies such as thermal ionisation mass spectrometry and plasma emission spectroscopy, this publication also presents new or rapidly growing methods such as electron backscattered diffraction analysis and atom probe tomography – a very sensitive method providing atomic scale information.  相似文献