Mineralisation of amethyst-bearing geodes in Ametista do Sul (Brazil) from low-temperature sedimentary brines: evidence from monophase liquid inclusions and stable isotopes     

H. Albert Gilg  Yves Krüger  Heinrich Taubald  Alfons M. van den Kerkhof  Martin Frenz  Giulio Morteani 《Mineralium Deposita》2014,49(7):861-877

Fluid inclusion studies in combination with hydrogen, oxygen and sulphur isotope data provide novel insights into the genesis of giant amethyst-bearing geodes in Early Cretaceous Paraná continental flood basalts at Amestita do Sul, Brazil. Monophase liquid inclusions in colourless quartz, amethyst, calcite, barite and gypsum were analysed by microthermometry after stimulating bubble nucleation using single femtosecond laser pulses. The salinity of the fluid inclusions was determined from ice-melting temperatures and a combination of prograde and retrograde homogenisation temperatures via the density maximum of the aqueous solutions. Four mineralisation stages are distinguished. In stage I, celadonite, chalcedony and pyrite formed under reducing conditions in a thermally stable environment. Low δ³⁴S_V-CDT values of pyrite (?25 to ?32?‰) suggest biogenic sulphate reduction by organotrophic bacteria. During the subsequent stages II (amethyst, goethite and anhydrite), III (early subhedral calcite) and IV (barite, late subhedral calcite and gypsum), the oxidation state of the fluid changed towards more oxidising conditions and microbial sulphate reduction ceased. Three distinct modes of fluid salinities around 5.3, 3.4 and 0.3 wt% NaCl-equivalent characterise the mineralisation stages II, III and IV, respectively. The salinity of the stage I fluid is unknown due to lack of fluid inclusions. Variation in homogenisation temperatures and in δ¹⁸O values of amethyst show evidence of repeated pulses of ascending hydrothermal fluids of up to 80–90 °C infiltrating a basaltic host rock of less than 45 °C. Colourless quartz and amethyst formed at temperatures between 40 and 80 °C, while the different calcite generations and late gypsum precipitated at temperatures below 45 °C. Calculated oxygen isotope composition of the amethyst-precipitating fluid in combination with δD values of amethyst-hosted fluid inclusions (?59 to ?51?‰) show a significant ¹⁸O-shift from the meteoric water line. This ¹⁸O-shift, high salinities of the fluid inclusions with chloride-sulphate composition, and high δ³⁴S values of anhydrite and barite (7.5 to 9.9?‰) suggest that sedimentary brines from deeper parts of the Guaraní aquifer system must have been responsible for the amethyst mineralisation.  相似文献   

The SUMER Data in the SOHO Archive     

W. Curdt  D. Germerott  K. Wilhelm  U. Schühle  L. Teriaca  D. Innes  K. Bocchialini  P. Lemaire 《Solar physics》2014,289(6):2345-2376

We have released an archive of all observational data of the VUV spectrometer Solar Ultraviolet Measurements of Emitted Radiation (SUMER) on SOHO that have been acquired until now. The operational phase started with ‘first light’ observations on 27 January 1996 and will end in 2014. Future data will be added to the archive when they become available. The archive consists of a set of raw data (Level 0) and a set of data that are processed and calibrated to the best knowledge we have today (Level 1). This communication describes step by step the data acquisition and processing that has been applied in an automated manner to build the archive. It summarizes the expertise and insights into the scientific use of SUMER spectra that has accumulated over the years. It also indicates possibilities for further enhancement of the data quality. With this article we intend to convey our own understanding of the instrument performance to the scientific community and to introduce the new, standard FITS-format database.  相似文献   

Winter-to-spring temperature dynamics in Turkey derived from tree rings since AD 1125   总被引：2，自引：1，他引：1  

Ingo Heinrich  Ramzi Touchan  Isabel Dorado Liñán  Heinz Vos  Gerhard Helle 《Climate Dynamics》2013,41(7-8):1685-1701

In the eastern Mediterranean in general and in Turkey in particular, temperature reconstructions based on tree rings have not been achieved so far. Furthermore, centennial-long chronologies of stable isotopes are generally also missing. Recent studies have identified the tree species Juniperus excelsa as one of the most promising tree species in Turkey for developing long climate sensitive stable carbon isotope chronologies because this species is long-living and thus has the ability to capture low-frequency climate signals. We were able to develop a statistically robust, precisely dated and annually resolved chronology back to AD 1125. We proved that variability of δ¹³C in tree rings of J. excelsa is mainly dependent on winter-to-spring temperatures (January–May). Low-frequency trends, which were associated with the medieval warm period and the little ice age, were identified in the winter-to-spring temperature reconstruction, however, the twentieth century warming trend found elsewhere could not be identified in our proxy record, nor was it found in the corresponding meteorological data used for our study. Comparisons with other northern-hemispherical proxy data showed that similar low-frequency signals are present until the beginning of the twentieth century when the other proxies derived from further north indicate a significant warming while the winter-to-spring temperature proxy from SW-Turkey does not. Correlation analyses including our temperature reconstruction and seven well-known climate indices suggest that various atmospheric oscillation patterns are capable of influencing the temperature variations in SW-Turkey.  相似文献   

A. E. Ringwood (1930–1993)     

Heinrich Wnke 《Meteoritics & planetary science》1994,29(2):290-291

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Memorial for Hans Voshage     

Friedrich Begemann  Heinrich Wnke 《Meteoritics & planetary science》1989,24(4):354-354

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Identification et Dosages des Substances azotées obtenues par Hydrolyse d'un Acide humique après peracetique     

M.-C. Poliakow-Touvet  J.-B. Leleu  J.-C. Wilhelm  J.-M. Bloch 《洁净——土壤、空气、水》1978,6(3):191-197

A humic acid extracted from a peat was easily hydrolysed by 6N HCl after oxidation with peracetic acid. The proportion of amino-acids in the hydrolysate was high (11,7 g of aminoacids per 100 g of humic acid), when the proportion of NH₃ was relatively low. 17 aminoacids were identified and titrated. On the opposite, a humic acid with the same origin, which was not oxidised with peracetic acid, gave less amino-acids on hydrolysis, but tenfold more NH₃, which is probably produced by partial decomposition of the amino-acids.  相似文献   

Implementing the European Water Framework Directive: the debate continues..     

Borja A  Heinrich H 《Marine pollution bulletin》2005,50(4):486-488

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Phosphorus limitation of bacterial growth in high Arctic lakes and ponds   总被引：4，自引：0，他引：4  

Wilhelm?Granéli  Stefan?BertilssonEmail author  Aline?Philibert 《Aquatic Sciences - Research Across Boundaries》2004,66(4):430-439

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Silicon and oxygen self diffusion in enstatite polycrystals: the Milke et al. (2001) rim growth experiments revisited     

R. Abart  K. Kunze  R. Milke  R. Sperb  W. Heinrich 《Contributions to Mineralogy and Petrology》2004,147(6):633-646

Milke et al. (Contrib Mineral Petrol 142:15–26, 2001) studied the diffusion of Si, Mg and O in synthetic polycrystalline enstatite reaction rims. The reaction rims were grown at 1,000°C and 1 GPa at the contacts between forsterite grains with normal isotopic compositions and a quartz matrix extremely enriched in ¹⁸O and ²⁹Si. The enstatite reaction rim grew from the original quartz-forsterite interface in both directions producing an inner portion, which replaced forsterite and an outer portion, which replaced quartz. Here we present new support for this statement, as the two portions of the rim are clearly distinguished based on crystal orientation mapping using electron backscatter diffraction (EBSD). Milke et al. (Contrib Mineral Petrol 142:15–26, 2001) used the formalism of LeClaire (J Appl Phys 14:351–356, 1963) to derive the coefficient of silicon grain boundary diffusion from stable isotope profiles across the reaction rims. LeClaires formalism is designed for grain boundary tracer diffusion into an infinite half space with fixed geometry. A fixed geometry is an undesired limitation in the context of rim growth. We suggest an alternative model, which accounts for simultaneous layer growth and superimposed silicon and oxygen self diffusion. The effective silicon bulk diffusivity obtained from our model is approximately equal within both portions of the enstatite reaction rim: D _Si,En ^eff =1.0–4.3×10^–16 m² s^–1. The effective oxygen diffusion is relatively slow in the inner portion of the reaction rim, D _O,En ^eff =0.8–1.4×10^–16 m² s^–1, and comparatively fast, D _O,En ^eff =5.9–11.6×10^–16 m² s^–1, in its outer portion. Microstructural evidence suggests that transient porosity and small amounts of fluid were concentrated at the quartz-enstatite interface during rim growth. This leads us to suspect that the presence of an aqueous fluid accelerated oxygen diffusion in the outer portion of the reaction rim. In contrast, silica diffusion does not appear to have been affected by the spatial variation in the availability of an aqueous fluid.

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Interdecadal modulation of the relationship between ENSO,IPO and precipitation: insights from tree rings in Australia     

Ingo Heinrich  Kathrin Weidner  Gerhard Helle  Heinz Vos  Janette Lindesay  John C. G. Banks 《Climate Dynamics》2009,33(1):63-73

Australian climate-proxy reconstructions based on tree rings from tropical and subtropical forests have not been achieved so far due to the rarity of species producing anatomically distinct annual growth rings. Our study identifies the Australian Red Cedar (Toona ciliata) as one of the most promising tree species for tree-ring research in Australasia because this species exhibits distinct annual tree rings, a prerequisite for high quality tropical dendroclimatology. Based on these preliminary studies, we were able, for the first time in subtropical and tropical Australia, to develop a statistically robust, precisely dated and annually resolved chronology back to AD1854. We show that the variability in ring widths of T. ciliata is mainly dependent on annual precipitation. The developed proxy data series contains both high- and low-frequency climate signals which can be associated with the El Niño Southern Oscillation (ENSO) and the Interdecadal Pacific Oscillation (IPO). A comparison of different data sets (Brisbane precipitation, tree rings, coral luminescence record from the Great Barrier Reef, ENSO and IPO) revealed non-stationary correlation patterns throughout the twentieth century but little instability between the new tree-ring chronology and Brisbane precipitation.  相似文献