Detailed geochemical studies of a He-U lake anomaly in permafrost, Baker Lake Area, N.W.T.     

Willy Dyck  Dwaine Car 《Journal of Geochemical Exploration》1987,28(1-3)

A strong He-U anomaly, discovered in the Thelon basin of the N.W.T. during a regional U exploration program in 1981, was studied in detail in 1982. The anomaly is confined to a 3-km² lake situated 160 km northwest of Baker Lake. Lake bottom water and sediment samples taken in June through the ice on a 50 m × 50 m grid, were analyzed for a number of trace and minor elements.In the lake sediments He and U were highly anomalous and parallel the strong anomaly patterns of He observed in the water. Median and maximum values in the sediments were 57 ppm and 396 ppm U, and 296 nL/L and 13870 nL/L He. Regional medians were 4.3 ppm U and 50 nL/L He. Se and V in sediments gave weak but similar anomaly patterns to those observed for U and He.The anomaly is somewhat of an enigma. The unusually high U content indicates an oxidizing, hence, near surface, water regime, and the highly anomalous He flux into the lake and a thick cover of permafrost in the region indicate a very deep source where conditions are normally reducing, rendering U immobile.Coincident anomaly patterns and increasing concentrations with depth of minor and trace elements and gases in the lake water prove that groundwater is the source of the anomalies. Contoured element maps indicate that this groundwater enters the lake in at least four places.The fact that up to 35 ppb U, 6 ppm dissolved O₂ and virtually no Fe and Mn, were detected in lake waters above groundwater entry points indicates that the groundwaters were oxidizing with respect to these elements. This is indeed surprising because permafrost is believed to be about 300 m thick in the region; at such depths groundwaters are usually rich in Fe and void of U.The highly anomalous He in this lake indicates deep fractures which serve as conduits for mineralized water entering the lake from depth and creating a frost-free window in the permafrost. The fractures probably penetrate well into the basement for only major deep fractures are known to produce such strong He anomalies. The additional presence of anomalous U suggests U mineralization at depth.  相似文献   

Elemental Composition of Mineral Aerosol Generated from Sudan Sahara Sand     

Mohamed A. H. Eltayeb  Jasna Injuk  Willy Maenhaut  René E. Van Grieken 《Journal of Atmospheric Chemistry》2001,40(3):247-273

Eighteen soil samples from central Sudan were fractionated by dry sieving ina size fraction from <45 m to >300 m while aerosols generatedfrom these soils were fractionated in the particle size range from 0.25 mto >16 m. The elemental concentrations of soil samples were determinedby energy-dispersive X-ray fluorescence, while the elemental concentrationsof generated aerosols were analysed by particle-induced X-ray emission. Theelements Al, K and Rb show a slight positive fractionation with decreasingparticle size throughout the particle size range studied. The concentrationsof Ca, Mn, Fe, Sr and Y are maximum in the small soil size fraction (<45m) and decrease for the coarse soil size fractions, while in the mineralaerosol particle sizes (0.25– > 16 m) the concentrations remainmore or less constant. The size distributions for Cr, Ti and Zr show a maximumin the particle size range 45–100 m and the concentrations of theseelements decrease sharply in the aerosol fraction down to 16 m to remainconstant in the smaller aerosol fractions.Enrichment factors for the elements were calculated relative to five referencematerials: average crustal rock, average soil, the investigated Sahara bulksoil, the finest fraction of this soil and the aerosol generated from thissoil, and using four reference elements: Al, Si, Ti and Fe. The enrichmentfactors were found to vary significantly depending on the choice of thereference material or the reference element. The enrichment factors for theSudan mineral aerosol were almost identical to those for Khartoum atmosphericaerosol but different from those for Namib mineral aerosol and Israelatmospheric aerosol following dust storms. Multivariate display methods(cluster analysis, principal component analysis and linear discriminantanalysis) were applied to the element ratios in the mineral aerosol from theSahara and Namib and this showed that these mineral aerosol can bedifferentiated into different groups. An attempt was also made to relate themineral aerosol to its parent soil through the use of these multivariatetechniques and the elemental ratios in both the mineral aerosols and the bulksoils (Namib and Sahara). It was also possible using the elemental ratios andthe multivariate display methods to associate the crustal component to themineral aerosol generated from the Sahara.  相似文献   

An evaluation of solar radiation pressure strategies for the GPS constellation     

Ant Sibthorpe  Willy Bertiger  Shailen D. Desai  Bruce Haines  Nate Harvey  Jan P. Weiss 《Journal of Geodesy》2011,85(8):505-517

The subtle effects of different Global Positioning System (GPS) satellite force models are becoming apparent now that mature processing strategies are reaching new levels of accuracy and precision. For this paper, we tested several approaches to solar radiation pressure (SRP) modeling that are commonly used by International GNSS Service (IGS) analysis centers. These include the GPS Solar Pressure Model (GSPM; Bar-Sever and Kuang in The Interplanetary Network Progress Report 42-160, 2005) and variants of the so-called DYB model (Springer et al. in Adv Space Res 23:673–676, 1999). Our results show that currently observed differences between GPS orbit solutions from the various IGS analysis centers are in large part explained by differences between their respective approaches to modeling SRP. DYB-based strategies typically generate orbit solutions that have the smallest differences with respect to the IGS final combined solution, largely because the DYB approach is most commonly used by the contributing analysis centers. However, various internal and external metrics, including ambiguity resolution statistics and satellite laser ranging observations, support continued use of the GSPM-based approach for precise orbit determination of the GPS constellation, at least when using the GIPSY-OASIS software.  相似文献   

Trace metal behaviour in riverine sediments: Role of organic matter and sulfides     

Adeline CharriauLudovic Lesven  Yue GaoMartine Leermakers  Willy BaeyensBaghdad Ouddane  Gabriel Billon 《Applied Geochemistry》2011,26(1):80-90

Three sediment cores were collected in the Scheldt, Lys and Spiere canals, which drain a highly populated and industrialized area in Western Europe. The speciation and the distribution of trace metals in pore waters and sediment particles were assessed through a combination of computational and experimental techniques. The concentrations of dissolved major and trace elements (anions, cations, sulfides, dissolved organic C, Cd, Co, Fe, Mn, Ni, Pb and Zn) were used to calculate the thermodynamic equilibrium speciation in pore waters and to evaluate the saturation of minerals (Visual Minteq software). A sequential extraction procedure was applied on anoxic sediment particles in order to assess the main host phases of trace elements. Manganese was the most labile metal in pore waters and was mainly associated with carbonates in particles. In contrast, a weak affinity of Cd, Co, Ni, Pb and Zn with carbonates was established because: (1) a systematic under-saturation was noticed in pore waters and (2) less than 10% of these elements were extracted in the exchangeable and carbonate sedimentary fraction. In the studied anoxic sediments, the mobility and the lability of trace metals, apart from Mn, seemed to be controlled through the competition between sulfidic and organic ligands. In particular, the necessity of taking into account organic matter in the modelling of thermodynamic equilibrium was demonstrated for Cd, Ni, Zn and Pb, the latter element exhibiting the strongest affinity with humic substances. Consequently, dissolved organic matter could favour the stabilization of trace metals in the liquid phase. Conversely, sulfide minerals played a key role in the scavenging of trace metals in sediment particles. Finally, similar trace metal lability rankings were obtained for the liquid and solid phases.  相似文献   

Dynamic patterns of dissolved nitrogen in the Southern Bight of the North Sea     

Willy Baeyens  Jean-Paul Mommaerts  Leo Goeyens  Frank Dehairs  Hugues Dedeurwaerder  Ghislain Decadt 《Estuarine, Coastal and Shelf Science》1984,18(5):499-510

Spatial and temporal variations of dissolved inorganic nitrogen (DIN) have been assessed in onshore and offshore areas of the Southern Bight on the basis of several years' measurements. They indicate that both the residual flow lines and DIN isoconcentration lines run parallel with the coast except in the vicinity of important freshwater discharge points such as the Scheldt estuary. Evidence was found that the seasonal DIN oscillations are not created through fluctuations in input conditions at the lateral boundaries, despite considerable fluctuations in these inputs which include the English Channel (from 500 tons(t) N day^?1 in June up to approximately 2000 t N day^?1 in February) and also rivers such as the Scheldt estuary (up to 50 t N day^?1 in January but less than 5 t N day^?1 in June–July). In both the onshore and offshore areas the sum of daylight phytoplanktonic nitrogen intake and sediment release of nitrogen corresponds to the observed DIN variations during most of the year. Pelagic N-mineralization from natural or grazing mortality of phytoplankton (220 mg N m^?2 day^?1 onshore at its maximum) can account for the differences (200 mg N m^?2 day^?1 onshore at its maximum), especially at the end of the phytoplankton spring bloom. Although the causes of DIN oscillations onshore and offshore are the same, the results differ because offshore (1) the vegetative season lasts longer, and (2) DIN is exhausted at the end of the phytoplankton spring bloom.  相似文献   

Elastic and isostatic subsidence of the Blåsjø artificial lake, Southern Norway     

Willy Fjeldskaar 《地学学报》1990,2(4):377-381

When a load is applied to the surface of the Earth, there is an immediate elastic deformation followed by a time-dependent isostatic subsidence. The two processes on the Blåsjø artifical lake, Southern Norway are modelled. The isostatic subsidence turns out to be negligible. A comparison of the modelled elastic deformation and the relative land levelling data gives valuable information about the elastic properties of the Earth's upper layers. The elastic parameters inferred from this study are lower than those from seismic investigations, and more in accordance with laboratory experiments.  相似文献   

Holocene vegetation and land‐use changes in response to climatic changes in the forelands of the southwestern Alps,Italy     

Walter Finsinger  Willy Tinner 《第四纪科学杂志》2006,21(3):243-258

The Holocene sediment of Lago Piccolo di Avigliana (Piedmont, Italy, 356 m a.s.l.) was dated by ¹⁴C and analysed for pollen to reconstruct the vegetation history of the area. The early‐ and mid‐Holocene pollen record shows environmental responses to centennial‐scale climatic changes as evidenced by independent palaeoclimatic proxies. When human impact was low or negligible, continental mixed‐oak forests decreased at ca. 9300 BC in response to the early‐Holocene Preboreal climatic oscillation. Abies alba expanded in two phases, probably in response to higher moisture availability at ca. 6000 and ca. 4000 BC , while Fagus expanded later, possibly in response to a climatic change at 3300 BC . During and after the Bronze Age five distinct phases of intensified land use were detected. The near synchroneity with the land‐use phases detected in wetter regions in northern and southern Switzerland points to a common forcing factor in spite of cultural differences. Increasing minerogenic input to the lake since 1000 BC coincided with Late Bronze—Iron Age technical innovations and probably indicate soil erosion as a consequence of deforestation in the lake catchment. The highest values for cultural indicators occurred at 700–450 and at 300–50 BC , coinciding with periods of high solar activity (inferred from Δ¹⁴C). This suggests that Iron Age land use was enhanced by high solar activity, while re‐occupation of partly abandoned areas after crises in earlier periods match better with the GRIP stable isotope record. On the basis of our data and comparison with independent palaeoclimatic proxies we suggest that precipitation variation was much more important than temperature oscillations in driving vegetation and societal changes throughout the Holocene. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

A hit-and-run giant impact scenario     

Andreas Reufer  Matthias M.M. Meier  Willy Benz  Rainer Wieler 《Icarus》2012,221(1):296-299

The formation of the Moon from the debris of a slow and grazing giant impact of a Mars-sized impactor on the proto-Earth (Cameron and Ward [1976]. Lunar Planet. Sci. Conf.; Canup and Asphaug [2001]. Nature 412, 708) is widely accepted today. We present an alternative scenario with a hit-and-run collision (Asphaug [2010]. Chem. Erde 70, 199) with a fractionally increased impact velocity and a steeper impact angle.  相似文献   

Early to mid‐Holocene climate change at Lago dell'Accesa (central Italy): climate signal or anthropogenic bias?     

Walter Finsinger  Daniele Colombaroli  Jacques‐Louis De Beaulieu  Verushka Valsecchi  Boris Vannière  Elisa Vescovi  Emmanuel Chapron  André F. Lotter  Michel Magny  Willy Tinner 《第四纪科学杂志》2010,25(8):1239-1247

Despite the high potential of pollen records for climate reconstruction, pollen–climate relationships may be biased due to past and present human activities on the landscape. We use (i) transfer functions based on modern pollen–climate relationships to infer seasonal temperature and summer precipitation for the period 11 500–4500 cal. a BP and (ii) lake‐level change records based on different sedimentary proxies in multiple cores that are mainly indicative for summer hydrology at Lago dell'Accesa (central Italy). Quantitative reconstructions indicate lowest summer precipitation during two phases (8500–7700 cal. a BP and after 6000 cal. a BP) and a gradual winter temperature increase from 11 500 to ca. 8000 cal. a BP. Lowest summer precipitation was reconstructed during these phases characterised by vegetation shifts from open forests dominated by summergreen oaks (Quercus) to forests dominated by evergreen oaks (Quercus ilex), which are at present most abundant where summer drought is stronger. Similarly, the lake‐level record indicates two long‐lasting low summer precipitation phases (8800–7700 and 6400–4400 cal. a BP) that were interrupted by short‐term high summer precipitation events. Based on the broad agreement between the pollen‐inferred summer precipitation and the low‐frequency lake‐level changes, we suggest that the duration of the high summer precipitation events may have been too short to maintain drought‐sensitive trees, which may have been affected by high mortality rates when summer dry conditions returned. Although past and modern pollen–climate relationships may very likely have been affected by human activities since the Neolithic (i.e. when exploitation of the landscape started), we reject the hypothesis of a significant anthropogenic bias in the pollen‐based climate reconstruction. In addition, we suggest that pollen‐based and lake‐level reconstructions may have different inherent abilities of capturing high‐ and low‐frequency precipitation signals. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Holocene hydrological changes in south-western Mediterranean as recorded by lake-level fluctuations at Lago Preola,a coastal lake in southern Sicily,Italy     

Michel Magny  Boris Vannière  Camilla Calo  Laurent Millet  Aurélie Leroux  Odile Peyron  Gianni Zanchetta  Tommaso La Mantia  Willy Tinner 《Quaternary Science Reviews》2011,30(19-20):2459-2475

This paper presents a high-resolution lake-level record for the Holocene at Lago Preola (Sicily, southern Italy) based on a specific sedimentological approach, with a chronology derived from AMS radiocarbon dates. It gives evidence of three major successive palaeohydrological periods, with (1) a pronounced dryness during the early Holocene until ca 10300 cal BP, (2) a highstand from ca 10300 to 4500 cal BP, and (3) a marked lowstand from 4500 cal BP to present. Large amplitude lake-level fluctuations characterise two transition phases at ca 10300–9000 and 6400–4500 cal BP. Period 2 was interrupted between 8300 and 7000 cal BP by a dry phase that was punctuated to ca 7300 cal BP by the deposition of a tephra from neighbouring Pantelleria Island. Comparisons of the Preola record with other palaeohydrological records along north–south and west–east transects in the Mediterranean show contrasting patterns of hydrological changes: north (south) of around 40°N latitude, the records highlight a mid-Holocene period characterised by lake-level minima (maxima). Humid mid-Holocene conditions over the Mediterranean south of 40°N were probably linked to a strong weakening of the Hadley cell circulation and of monsoon winds. We suggest that the maximum of humidity in the Mediterranean during the mid-Holocene was characterised by humid winters to the north of 40°N and humid summers to the south. On a multi-centennial scale, the high-resolution palaeohydrological reconstructions in the central Mediterranean area reveal a strong climate reversal around 4500–4000 cal BP, with contrasting changes in the hydrological cycle. In addition to seasonal and inter-hemispherical changes related to orbital forcing, this major oscillation might be related to non-linear responses of the climatic system to the gradual decrease in summer insolation at northern latitudes. Another major climate oscillation around 7500–7000 cal BP may have resulted from the combined effects of (1) a strong rate of change in insolation, and (2) variations in solar activity. Finally, comparisons of the Preola lake-level record with Sicilian pollen records suggest a strong influence of moisture availability on vegetation development in Sicily. Very dry early Holocene conditions probably prevented the expansion of coastal evergreen forests, while decreasing moisture availability since the onset of the late Holocene may have exacerbated effects of intensive land-use.  相似文献