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11.
R. L. Withers J. G. Thompson Y. Xiao R. J. Kirkpatrick 《Physics and Chemistry of Minerals》1994,21(7):421-433
The results of a detailed TEM study of the low frequency modes of distortion of high temperature SiO2-tridymite and their relationship to the extensive structural polymorphism of tridymite are presented. It is found that low energy modes of distortion of the ideal tridymite tetrahedral framework structure give rise to a strong and extremely characteristic diffuse intensity distribution (which can be broken into two component types) for the two highest temperature polymorphs of tridymite. Experimental results strongly suggest that this observed diffuse distribution is not a result of irreversible beam damage but is rather an intrinsic property of the ideal tridymite tetrahedral framework structure. The diffuse intensity distribution is closely related to the lower temperature polymorphs of tridymite — in particular, the primary modulation wave-vectors of these low temperature polymorphs always fall on the higher temperature diffuse distribution. The first type of diffuse distribution appears to result from coupled tetrahedral edge rotation of 〈110〉 columns of corner-connected SiO4 tetrahedra (uncorrelated from column to column as a result of the tetrahedral connectivity of the ideal tridymite framework structure). The real space structural origin of the second curved type of diffuse distribution, however, remains unclear. 相似文献
12.
The use of two-dimensional fourier transforms of reservoir topography allows substantial increases in the speed of computation of loading effects on layered elastic models of the earth and on porous fluid-filled models of the earth. It is possible to solve the compaction equations for arbitrary reservoirs filled at an arbitrary rate in time. The delay involved in the associated diffusion of pressure can be computed and the theory allows for the computation of the effective stress needed to assess seismic risk associated with the filling of large artificial lakes. A numeric example is given for the vertical deflection and the pore pressure as functions of time and depth below a two-dimensional cross-section of a typical lake profile. 相似文献
13.
S. H.?Withers R. E.?PealeEmail author A. F.?Schulte G.?Braunstein K. M.?Beck W. P.?Hess R. J.?Reeder 《Physics and Chemistry of Minerals》2003,30(7):440-448
Calcite crystals were grown from solution with single-crystal dimensions up to 3 mm and doped up to 0.1 at% with Nd3+ ions. Phase purity was verified by powder X-ray diffraction. The concentration of Nd3+ was measured by energy-dispersive spectrometry and Rutherford backscattering spectrometry. Micro X-ray fluorescence mapping of the calcite grains indicates uniform Nd distribution in as-grown crystal grains. X-ray absorption fine structure suggests that Nd3+ is substituted for Ca2+ with local lattice distortion. Temperature-dependent near-infrared spectroscopy of Nd3+ impurities in calcite reveals large inhomogeneous linewidths and smooth line profiles that are characteristic of glassy hosts, though the samples are well crystallized. 相似文献
14.
M. T. Dove K. D. Hammonds V. Heine R. L. Withers Y. Xiao R. J. Kirkpatrick 《Physics and Chemistry of Minerals》1996,23(1):56-62
Calculations of the rigid unit mode (RUM) spectrum of the high-temperature phase of SiO2 tridymite are used to explain the patterns of diffuse scattering seen in transmission electron microscopy experiments. These results show that RUM's can occur with wave vectors on curved surfaces in reciprocal space rather than being confined to symmetry points, lines or planes. The fact that the calculations reproduce the detail seen in the diffuse scattering provides a striking nontrivial confirmation of the validity of the rigid unit mode model. 相似文献
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Wenjun?YongEmail author Edgar?Dachs Artur?Benisek Anthony?C.?Withers Richard?A.?Secco 《Physics and Chemistry of Minerals》2012,39(3):259-267
The heat capacity (C
p
) of dmitryivanovite synthesized with a cubic press was measured in the temperature range of 5–664 K using the heat capacity
option of a physical properties measurement system and a differential scanning calorimeter. The entropy of dmitryivanovite
at standard temperature and pressure (STP) was calculated to be 110.1 ± 1.6 J mol−1 K−1 from the measured C
p
data. With the help of new phase equilibrium experiments done at 1.5 GPa, the phase transition boundary between krotite and
dmitryivanovite was best represented by the equation: P (GPa) = −2.1825 + 0.0025 T (K). From the temperature intercept of this phase boundary and other available thermodynamic data
for krotite and dmitryivanovite, the enthalpy of formation and Gibbs free energy of formation of dmitryivanovite at STP were
calculated to be −2326.7 ± 2.1 and −2,208.1 ± 2.1 kJ mol−1, respectively. It is also inferred that dmitryivanovite is the stable CaAl2O4 phase at STP and has a wide stability field at high pressures whereas the stability field of krotite is located at high temperatures
and relatively low pressures. This conclusion is consistent with natural occurrences (in Ca–Al-rich inclusions) of dmitryivanovite
and krotite, where the former is interpreted as the shock metamorphic product of originally present krotite. 相似文献
17.
Apostolos A. Christou Jeremie Vaubaillon Paul Withers 《Earth, Moon, and Planets》2008,102(1-4):125-131
We have simulated the formation and evolution of comet 1P/Halley’s meteoroid stream by ejecting particles from the nucleus
5000 years ago and propagating them forward to the present. Our aim is to determine the existence and characteristics of associated
meteor showers at Mars and Venus and compare them with 1P/Halley’s two known showers at the Earth. We find that one shower
should be present at Venus and two at Mars. The number of meteors in those atmospheres would, in general, be less than that
at the Earth. The descending node branch of the Halley stream at Mars exhibits a clumpy structure. We identified at least
one of these clumps as particles trapped in the 7:1 mean motion resonance with Jupiter, potentially capable of producing meteor
ourbursts of ZHR∼1000 roughly once per century. 相似文献
18.
Paul S. Davison Paul J.A. Withers Eunice I. Lord Mark J. Betson Johan Strmqvist 《Journal of Hydrology》2008,350(3-4):290-302
PSYCHIC is a process-based model of phosphorus (P) and suspended sediment (SS) mobilisation in land runoff and subsequent delivery to watercourses. Modelled transfer pathways include release of desorbable soil P, detachment of SS and associated particulate P, incidental losses from manure and fertiliser applications, losses from hard standings, the transport of all the above to watercourses in underdrainage (where present) and via surface pathways, and losses of dissolved P from point sources. The model can operate at two spatial scales, although the scientific core is the same in both cases. At catchment scale, the model uses easily available national scale datasets to infer all necessary input data whilst at field scale, the user is required to supply all necessary data. The model is sensitive to a number of crop and animal husbandry decisions, as well as to environmental factors such as soil type and field slope angle. It is envisaged that the catchment-scale model would provide the first tier of a catchment characterisation study, and would be used as a screening tool to identify areas within the catchment which may be at elevated risk of P loss. This would enable targeted data collection, involving farm visits and stakeholder discussion, which would then be followed up with detailed field-scale modelling. Both tiers allow the effects of possible mitigation options at catchment scale (Tier 1) and field scale (Tier 2) to be explored. The PSYCHIC model framework therefore provides a methodology for identifying critical source areas of sediment and P transfer in catchments and assessing what management changes are required to achieve environmental goals. 相似文献
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The beginnings of hydrous mantle wedge melting 总被引：5，自引：3，他引：2
Christy?B.?TillEmail author Timothy?L.?Grove Anthony?C.?Withers 《Contributions to Mineralogy and Petrology》2012,163(4):669-688
This study presents new phase equilibrium data on primitive mantle peridotite (0.33 wt% Na2O, 0.03 wt% K2O) in the presence of excess H2O (14.5 wt% H2O) from 740 to 1,200°C at 3.2–6 GPa. Based on textural and chemical evidence, we find that the H2O-saturated peridotite solidus remains isothermal between 800 and 820°C at 3–6 GPa. We identify both quenched solute from
the H2O-rich fluid phase and quenched silicate melt in supersolidus experiments. Chlorite is stable on and above the H2O-saturated solidus from 2 to 3.6 GPa, and chlorite peridotite melting experiments (containing ~6 wt% chlorite) show that
melting occurs at the chlorite-out boundary over this pressure range, which is within 20°C of the H2O-saturated melting curve. Chlorite can therefore provide sufficient H2O upon breakdown to trigger dehydration melting in the mantle wedge or perpetuate ongoing H2O-saturated melting. Constraints from recent geodynamic models of hot subduction zones like Cascadia suggest that significantly
more H2O is fluxed from the subducting slab near 100 km depth than can be bound in a layer of chloritized peridotite ~ 1 km thick
at the base of the mantle wedge. Therefore, the dehydration of serpentinized mantle in the subducted lithosphere supplies
free H2O to trigger melting at the H2O-saturated solidus in the lowermost mantle wedge. Alternatively, in cool subduction zones like the Northern Marianas, a layer
of chloritized peridotite up to 1.5 km thick could contain all the H2O fluxed from the slab every million years near 100 km depth, which suggests that the dominant form of melting below arcs
in cool subduction zones is chlorite dehydration melting. Slab P–T paths from recent geodynamic models also allow for melts of subducted sediment, oceanic crust, and/or sediment diapirs to
interact with hydrous mantle melts within the mantle wedge at intermediate to hot subduction zones. 相似文献