Seismic evidence for pervasive deformation of oceanic sediments in the Eastern Equatorial Atlantic     

E.?J.?W.?JonesEmail author 《Geo-Marine Letters》2003,23(2):102-109

Seismic reflection profiles from the equatorial Atlantic off Africa between 12°N and 1°N reveal remarkably widespread deformation of oceanic sediments in an area lacking teleseismic activity. Uplift of abyssal plain sequences has occurred along the eastern extensions of large-offset fracture zones on the Mid-Atlantic Ridge. Between the major transforms pervasive deformation is imaged in the sedimentary column. Diapirism and faulting may have been associated with extensive fluid migration and sediment mobilization. The deformation occurred during the late Cenozoic and was probably related to reactivation of Cretaceous transforms.  相似文献   

Simple determination of dimethylsulfide (DMS) and dimethylsulfoniopropionate (DMSP) using solid-phase microextraction and gas chromatography-mass spectrometry     

Takushi?NikiEmail author  Taiki?Fujinaga  Mariyo?F.?Watanabe  Junji?Kinoshita 《Journal of Oceanography》2004,60(5):913-917

Solid-phase microextraction (SPME) is a simple, sensitive and less destructive method for the determination of dimethylsulfide (DMS) in seawater. Combined with detection by gas chromatography-mass spectrometry (GC-MS), the method had sufficient sensitivity (minimum detectable concentration of DMS was 0.05 nM), and practical levels of reproducibility (relative standard deviation ≤7%) and linearity (r ² > 0.995) over a wide concentration range (0.5 to 910 nM). The protocol developed was applied to a Sagami Bay water sample to determine concentrations of DMS and DMSP, and in situ DMSP-lyase activity.  相似文献   

Environmental change and oyster colonization within the Hudson River estuary linked to Holocene climate   总被引：4，自引：0，他引：4  

S.?M.?CarbotteEmail author  R.?E.?Bell  W.?B.?F.?Ryan  C.?McHugh  A.?Slagle  F.?Nitsche  J.?Rubenstone 《Geo-Marine Letters》2004,24(4):212-224

Geophysical mapping and sampling data provide a record of changing environmental and faunal conditions within the Hudson River estuary during the mid- to late Holocene. On the shallow, broad marginal flats of the mesohaline Hudson, fossil oyster beds (Crassostrea virginica) are found exposed on the river bottom and buried by sediment. The shallowest beds are well imaged in chirp sub-bottom and side-scan sonar data and form discrete flow-perpendicular bands, 0.6–1.0 km wide and up to 3 km long, which cover 30% of the river bottom. Radiocarbon-dated sediment cores indicate oysters thrived within two time periods from ~500–2,400 and ~5,600–6,100 cal. years b.p. Sediment and physical property data indicate a changing depositional regime consistent with the oyster chronology. Similar changes in oyster presence are found in local shell midden sites of the Lower Hudson Valley as well as elsewhere along the Atlantic coast, and may reflect climatic controls associated with warm–cool cycles during the Holocene. Oysters flourished during the mid-Holocene warm period, disappeared with the onset of cooler climate at 4,000–5,000 cal. years b.p., and returned during warmer conditions of the late Holocene. The most recent demise of oysters within the Hudson at 500–900 cal. years b.p. may have accompanied the Little Ice Age.  相似文献   

Modeling groundwater quality in an agriculturally used water catchment     

F. Aschenbrenner  G. M. Richter  J. Richter 《Environmental Geology》1992,20(1):43-55

The sulfate pollution in an agriculturally used watershed has been investigated with respect to the transport in the saturated zone and the development of sulfate in the unsaturated zone. Besides of other sources such as acid wet and dry deposition or sulfate input by agricultural activities, most of the sulfate originates from oxidation of pyrite by either NO₃ or O₂. High sulfate concentrations coincided with high nitrate leaching caused by plowing of former grassland or by vegetable crop residues and with former wet lands that have become dry. By using soil water concentration data and maps showing the extension of former wetlands and grassland as well as agricultural land use, it was possible to delineate regions of high sulfate input. The transport of sulfate in the aquifer was analyzed with a modified version of the USGS MOC model, which takes into account the nonlinearity of the underlying equation describing unconfined groundwater flow. The calibration of the transport model showed good agreement between the estimated and modeled sulfate input rates. A prediction of future sulfate concentrations in the aquifer was feasible by using worst-case parameters.  相似文献   

Cathodoluminescence of authigenic albite     

Detlev K. Richter  Thomas G  tte  Dirk Habermann 《Sedimentary Geology》2002,150(3-4):367-374

Authigenic albites in carbonate rocks typically grow in a high-grade diagenetic to low-grade metamorphic environment and often show Roc-Tourné-twinning sensu Füchtbauer. Based on an investigation of four Middle to South European occurrences, they show Mn²⁺- and Fe³⁺-activated cathodoluminescence (CL), as revealed by combined high resolution spectroscopy of cathodoluminescence emission (HRS-CL), electron paramagnetic resonance (EPR), and proton-induced X-ray emission (μPIXE).  相似文献   

Elemental and isotopic fractionation of Type B calcium-, aluminum-rich inclusions: experiments, theoretical considerations, and constraints on their thermal evolution     

Frank M. Richter  Andrew M. Davis  Denton S. EbelAkihiko Hashimoto 《Geochimica et cosmochimica acta》2002,66(3):521-540

Experiments exposing Type B calcium-, aluminum-rich inclusion (CAI)-like melts at high temperatures to high vacuum or reducing hydrogen-rich gas mixtures were used to determine the rates and consequences of elemental and isotopic fractionation by evaporation. Silicon and magnesium were found to evaporate much faster than calcium and aluminum, and the resulting residual liquid trajectories in composition space are reproduced via a thermodynamic model for the saturation vapor pressure of the evaporating species. Isotopic fractionations associated with evaporation were measured for magnesium. The resulting relationship between fraction of magnesium lost and enrichment of the residue in the heavy isotopes of magnesium follows a Rayleigh fractionation curve with a fractionation factor that is close to, but not exactly, the theoretically expected value. The rate of evaporation is found to be a strong function of temperature, oxygen fugacity, and melt composition, which can be understood and modeled in terms of the dependence of the saturation vapor pressures on these variables. The relationship between evaporation rate, which we measure, and calculated saturation vapor involves empirical evaporation coefficients that we find to be significantly less than one (∼0.1). Analytical and numerical models are used to characterize how diffusion in both the melt and in the surrounding gas affects evaporation rates and the degree of chemical and isotopic fractionation. The experimental data and theoretical considerations are combined to give a parameterization of the rates and consequences of evaporation of Type B CAI-like liquids, which is then used to translate the measured isotopic fractionation of Type B CAIs into constraints on their thermal history. Cooling rates of the order of 10°C per hour are indicated.  相似文献   

Correlation of seismic activity and fumarole temperature at the Mt. Merapi volcano (Indonesia) in 2000     

Gudrun Richter  Joachim Wassermann  Martin Zimmer  Matthias Ohrnberger 《Journal of Volcanology and Geothermal Research》2004,135(4):331-342

In this paper we present densely sampled fumarole temperature data, recorded continuously at a high-temperature fumarole of Mt. Merapi volcano (Indonesia). These temperature time series are correlated with continuous records of rainfall and seismic waveform data collected at the Indonesian–German multi-parameter monitoring network. The correlation analysis of fumarole temperature and precipitation data shows a clear influence of tropical rain events on fumarole temperature. In addition, there is some evidence that rainfall may influence seismicity rates, indicating interaction of meteoric water with the volcanic system. Knowledge about such interactions is important, as lava dome instabilities caused by heavy-precipitation events may result in pyroclastic flows. Apart from the strong external influences on fumarole temperature and seismicity rate, which may conceal smaller signals caused by volcanic degassing processes, the analysis of fumarole temperature and seismic data indicates a statistically significant correlation between a certain type of seismic activity and an increase in fumarole temperature. This certain type of seismic activity consists of a seismic cluster of several high-frequency transients and an ultra-long-period signal (<0.002 Hz), which are best observed using a broadband seismometer deployed at a distance of 600 m from the active lava dome. The corresponding change in fumarole temperature starts a few minutes after the ultra-long-period signal and simultaneously with the high-frequency seismic cluster. The change in fumarole temperature, an increase of 5 °C on average, resembles a smoothed step. Fifty-four occurrences of simultaneous high-frequency seismic cluster, ultra-long period signal and increase of fumarole temperature have been identified in the data set from August 2000 to January 2001. The observed signals appear to correspond to degassing processes in the summit region of Mt. Merapi.  相似文献   

Dynamics of an active rock glacier (Ötztal Alps, Austria)     

Jana Berger  Karl Krainer  Wolfram Mostler 《Quaternary Research》2004,62(3):233-242

The rock glacier Innere Ölgrube, located in a small side valley of the Kauner Valley (Ötztal Alps, Austria), consists of two separate, tongue-shaped rock glaciers lying next to each other. Investigations indicate that both rock glaciers contain a core of massive ice. During winter, the temperature at the base of the snow cover (BTS) is significantly lower at the active rock glacier than on permafrost-free ground adjacent to the rock glacier. Discharge is characterized by strong seasonal and diurnal variations, and is strongly controlled by the local weather conditions. Water temperature of the rock glacier springs remains constantly low, mostly below 1°C during the whole melt season. The morphology of the rock glaciers and the presence of meltwater lakes in their rooting zones as well as the high surface flow velocities of >1 m/yr point to a glacial origin. The northern rock glacier, which is bounded by lateral moraines, evolved from the debris-covered tongue of a small glacier of the Little Ice Age with its last highstand around A.D. 1850. Due to the global warming in the following decades, the upper parts of the steep and debris-free ice glacier melted, whereas the debris-covered glacier tongue transformed into an active rock glacier. Due to this evolution and due to the downslope movement, the northern rock glacier, although still active, at present is cut off from its ice and debris supply. The southern rock glacier has developed approximately during the same period from a debris-covered cirque glacier at the foot of the Wannetspitze massif.  相似文献   

Spatially controlled Fe and Si isotope variations: an alternative view on the formation of the Torres del Paine pluton     

Norbert?A.?GajosEmail author  Craig?C.?Lundstrom  Alexander?H.?Taylor 《Contributions to Mineralogy and Petrology》2016,171(11):93

We present new Fe and Si isotope ratio data for the Torres del Paine igneous complex in southern Chile. The multi-composition pluton consists of an approximately 1 km vertical exposure of homogenous granite overlying a contemporaneous 250-m-thick mafic gabbro suite. This first-of-its-kind spatially dependent Fe and Si isotope investigation of a convergent margin-related pluton aims to understand the nature of granite and silicic igneous rock formation. Results collected by MC-ICP-MS show a trend of increasing δ⁵⁶Fe and δ³⁰Si with increasing silica content as well as a systematic increase in δ⁵⁶Fe away from the mafic base of the pluton. The marginal Torres del Paine granites have heavier Fe isotope signatures (δ⁵⁶Fe = +0.25 ± 0.02 2se) compared to granites found in the interior pluton (δ⁵⁶Fe = +0.17 ± 0.02 2se). Cerro Toro country rock values are isotopically light in both Fe and Si isotopic systems (δ⁵⁶Fe = +0.05 ± 0.02 ‰; δ³⁰Si = ?0.38 ± 0.07 ‰). The variations in the Fe and Si isotopic data cannot be accounted for by local assimilation of the wall rocks, in situ fractional crystallization, late-stage fluid exsolution or some combination of these processes. Instead, we conclude that thermal diffusion or source magma variation is the most likely process producing Fe isotope ratio variations in the Torres del Paine pluton.  相似文献   

Initiation of large-volume silicic centers in the Yellowstone hotspot track: insights from H<Subscript>2</Subscript>O- and F-rich quartz-hosted rhyolitic melt inclusions in the Arbon Valley Tuff of the Snake River Plain     

Dana?L.?DrewEmail author  Ilya?N.?Bindeman  Matthew?W.?Loewen  Paul?J.?Wallace 《Contributions to Mineralogy and Petrology》2016,171(1):10

During the onset of caldera cluster volcanism at a new location in the Snake River Plain (SRP), there is an increase in basalt fluxing into the crust and diverse silicic volcanic products are generated. The SRP contains abundant and compositionally diverse hot, dry, and often low-δ¹⁸O silicic volcanic rocks produced through time during the formation of individual caldera clusters, but more H₂O-rich eruptive products are rare. We report analyses of quartz-hosted melt inclusions from pumice clasts from the upper and lower Arbon Valley Tuff (AVT) to gain insight into the initiation of caldera cluster volcanism. The AVT, a voluminous, caldera-forming rhyolite, represents the commencement of volcanism (10.44 Ma) at the Picabo volcanic field of the Yellowstone hotspot track. This is a normal δ¹⁸O rhyolite consisting of early and late erupted members (lower and upper AVT, respectively) with extremely radiogenic Sr isotopes and unradiogenic Nd isotopes, requiring that ~50 % of the mass of these elements is derived from melts of Archean upper crust. Our data reveal distinctive features of the early erupted lower AVT melt including: variable F concentrations up to 1.4 wt%, homogenous and low Cl concentrations (~0.08 wt%), H₂O contents ranging from 2.3 to 6.4 wt%, CO₂ contents ranging from 79 to 410 ppm, and enrichment of incompatible elements compared to the late erupted AVT, subsequent Picabo rhyolites, SRP rhyolites, and melt inclusions from other metaluminous rhyolites (e.g., Bishop Tuff, Mesa Falls Tuff). We couple melt inclusion data with Ti measurements and cathodoluminescence (CL) imaging of the host quartz phenocrysts to elucidate the petrogenetic evolution of the AVT rhyolitic magma. We observe complex and multistage CL zoning patterns, the most critical being multiple truncations indicative of several dissolution–reprecipitation episodes with bright CL cores (higher Ti) and occasional bright CL rims (higher Ti). We interpret the high H₂O, F, F/Cl, and incompatible trace element concentrations in the context of a model involving melting of Archean crust and mixing of the crustal melt with basaltic differentiates, followed by multiple stages of fractional crystallization, remelting, and melt extraction. This multistage process, which we refer to as distillation, is further supported by the complex CL zoning patterns in quartz. We interpret new Δ¹⁸O(Qz-Mt) isotope measurements, demonstrating a 0.4 ‰ or ~180 °C temperature difference, and strong Sr isotopic and chemical differences between the upper and lower AVT to represent two separate eruptions. Similarities between the AVT and the first caldera-forming eruptions of other caldera clusters in the SRP (Yellowstone, Heise and Bruneau Jarbidge) suggest that the more evolved, lower-temperature, more H₂O-rich rhyolites of the SRP are important in the initiation of a caldera cluster during the onset of plume impingement.  相似文献