Long-term change in eelgrass distribution at Bahía San Quintín,Baja California,Mexico, using satellite imagery     

David?H.?WardEmail author  Alexandra?Morton  T.?Lee?Tibbitts  David?C.?Douglas  Eduardo?Carrera-González 《Estuaries and Coasts》2003,26(6):1529-1539

Seagrasses are critically important components of many marine coastal and estuarine ecosystems, but are declining worldwide. Spatial change in distribution of eelgrass,Zostera marina L., was assessed at Bahía San Quintín, Baja California, Mexico, using a map to map comparison of data interpreted from a 1987 Satellite Pour l'Observation de la Terre multispectral satellite image and a 2000 Landsat Enhanced Thematic Mapping image. Eelgrass comprised 49% and 43% of the areal extent of the bay in 1987 and 2000, respectively. Spatial extent of eelgrass was 13% less (−321 ha) in 2000 than in 1987 with most losses occurring in subtidal areas. Over the 13-yr study period, there was a 34% loss of submerged eelgrass (−457 ha) and a 13% (+136 ha) gain of intertidal eelgrass. Within the two types of intertidal eelgrass, the patchy cover class (<85% cover) expanded (+250 ha) and continuous cover class (≥85% cover) declined (−114 ha). Most eelgrass losses were likely the result of sediment loading and turbidity caused by a single flooding event in winter of 1992–1993. Recent large-scale agricultural development of adjacent uplands may have exacerbated the effects of the flood. Oyster farming was not associated with any detectable losses in eelgrass spatial extent, despite the increase in number of oyster racks from 57 to 484 over the study period.  相似文献   

Changes in benthos following the clean-up of a severely metalpolluted cove in the Hudson River estuary: Environmental restoration or ecological disturbance?     

Brendan?P.?Kelaher  Jeffrey?S.?LevintonEmail author  Jamina?Oomen  Bengt?J.?Allen  Wai?Hing?Wong 《Estuaries and Coasts》2003,26(6):1505-1516

We studied changes in macrobenthic communities following the environmental clean-up of metal-polluted (cadmium, nickel, and cobalt) sediments in Foundry Cove, a small inlet within the Hudson River estuary of New York. We used a BACI-style experiment to test the hypotheses that high levels of cadmium in sediments change macrobenthic assemblages relative to unpolluted areas, and removal of metals (especially cadmium) by dredging will restore the benthos, such that benthic fauna in Foundry Cove are not different from unpolluted areas. In 1984, prior to the restoration work, there were no significant differneces between macrobenthic assemblages in polluted and unpolluted locations, indicating that cadmium had little effect on community structure. The lack of an observed toxicity effect may have been caused by the compensatory evolution of resistance to cadmium in dominant organisms. Six years after the restoration work and despite a substantial reduction in metal pollution, there were lower abundances of oligochaetes, nematodes, and chironomids and a higher abundance of polychaetes at Foundry Cove relative to reference locations. Correlative analyses identified greater sediment compaction caused by dredging at Foundry, Cove as a possible cause of faunal differences. The results demonstrate that it is difficult to accurately predict, the effects of anthropogenic disturbances and restorations in complex natural systems and that unforeseen side effects are inevitable. Documenting these unpredicted effects and experimentally understanding their causes in past restorations will greatly improve the success and cost-effectiveness of future projects of a similar type.  相似文献   

Network analysis of nitrogen inputs and cycling in the Neuse River estuary,North Carolina,USA     

Robert?R.?ChristianEmail author  Cassondra?R.?Thomas 《Estuaries and Coasts》2003,26(3):815-828

The Neuse River estuary, North Carolina, United States, has demonstrated various symptoms of eutrophication during the past 20 yr. We contributed to an environmental assessment program, through ecological network analysis, a group of algorithms to evaluate networks of material flows within a structured system. Networks of nitrogen (N) cycling for 16 consecutive seasons were constructed based on previous field and laboratory studies. Network analysis provided understanding of the relationship between N loading and recycling, the fates of N and the expected interseasonal variation of both model inputs and outputs. Various indices indicated that recycling of imported N was very high, supporting measured observations. There was little correlation between estimates of loading and N uptake by phytoplankton, although loading of total and particulate N did correlate positively with export. Because of the high degree of recycling of N, the rate of loading of new N is a small fraction of the total processing of N or of the needs for primary production alone. We predict that on a short-term basis the controls on primary production tend to be associated with conditions in the estuary rather than import. This condition is likely to postpone easily observable responses to loading reduction over the entire estuary and in the short term, although improvements in water quality should occur over time.  相似文献   

Reconciling fluid inclusion types,fluid processes,and fluid sources in skarns: an example from the Bismark Deposit,Mexico   总被引：4，自引：0，他引：4  

Timothy?BakerEmail author  James?R.?Lang 《Mineralium Deposita》2003,38(4):474-495

The Bismark deposit (8.5 Mt at 8% Zn, 0.5% Pb, 0.2% Cu, and 50 g/t Ag) located in northern Mexico is an example of a stock-contact skarn end member of a continuum of deposit types collectively called high-temperature, carbonate-replacement deposits. The deposit is hosted by massive sulfide within altered limestone adjacent to the Bismark quartz monzonite stock (~42 Ma) and the Bismark fault. Alteration concurrently developed in both the intrusion and limestone. The former contains early potassic alteration comprising K-feldspar and biotite, which was overprinted by kaolinite-rich veins and alteration and later quartz, sericite, and pyrite with minor sphalerite and chalcopyrite. Prograde exoskarn alteration in the limestone consists of green andradite and diopside, and transitional skarn comprising red-brown andradite, green hedenbergite and minor vesuvinite, calcite, fluorite, and quartz. The main ore stage post-dates calc-silicate minerals and comprises sphalerite and galena with gangue pyrite, pyrrhotite, calcite, fluorite, and quartz. The entire hydrothermal system developed synchronously with faulting. Fluid inclusion studies reveal several distinct temporal, compositional, and thermal populations in pre-, syn- and post-ore quartz, fluorite, and calcite. The earliest primary fluid inclusions are coexisting vapor-rich (type 2A) and halite-bearing (type 3A; type 3B contain sylvite) brine inclusions (32 to >60 total wt% salts) that occur in pre-ore fluorite. Trapping temperatures are estimated to have been in excess of 400 °C under lithostatic pressures of ~450 bar (~1.5 km depth). Primary fluid inclusions trapped in syn-ore quartz display critical to near critical behavior (type 1C), have moderate salinity (8.4 to 10.9 wt% NaCl equiv.) and homogenization temperatures (Th) ranging from 351 to 438 °C. Liquid-rich type 1A and 1B (calcite-bearing) inclusions occur as primary to secondary inclusions predominantly in fluorite and show a range in Th (104–336 °C) and salinity (2.7–11.8 wt% NaCl equiv.), which at the higher Th and salinity ranges overlap with type 1C inclusions. Oxygen isotope analysis was carried out on garnet, quartz, and calcite (plus carbon isotopes) in pre-, syn-, post-ore, and peripheral veins. Pre-ore skarn related garnets have a δ¹⁸O_mineral range between 3.9 and 8.4‰. Quartz from the main ore stage range between 13.6 and 16.0‰. Calcite from the main ore stage has δ¹³C values of –2.9 to –5.1‰ and δ¹⁸O values of 12.3 to 14.1‰, which are clearly distinct from post-ore veins and peripheral prospects that have much higher δ¹⁸O (16.6–27.3‰) and δ¹³C (1.3–3.1‰) values. Despite the numerous fluid inclusion types, only two fluid sources can be inferred, namely a magmatic fluid and an external fluid that equilibrated with limestone. Furthermore, isotopic data does not indicate any significant mixing between the two fluids, although fluid inclusion data may be interpreted otherwise. Thus, the various fluid types were likely to have formed from varying pressure–temperature conditions through faulting during exsolution of magmatic fluids. Late-stage hydrothermal fluid activity was dominated by the non-magmatic fluids and was post-ore.  相似文献   

Platinum deposits—further thoughts: a thematic issue dedicated to Professor Eugen F. Stumpfl on the occasion of his 70th birthday     

Oskar?R.?A.?ThalhammerEmail author 《Mineralium Deposita》2003,38(3):259-260

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Chromite composition and platinum-group mineral assemblage in the Uktus Uralian-Alaskan-type complex (Central Urals,Russia)     

Giorgio?GarutiEmail author  Evgeny?V.?Pushkarev  Federica?Zaccarini  Roberto?Cabella  Elena?Anikina 《Mineralium Deposita》2003,38(3):312-326

Chromitite segregations in dunites of the Uktus Uralian-Alaskan-type complex (Central Urals, Russia) display large variation of the chromite composition: Cr/(Cr+Al)=0.46-0.77, Fe²⁺/(Fe²⁺+Mg)=0.28-0.66, and Fe³⁺/(Fe³⁺+Fe²⁺)=0.23-0.59. Three types of PGM assemblages have been recognized, varying in accordance with chromite composition: type I, dominated by Ru-Os-Ir (sulfides), is associated with magnesiochromite having Fe³⁺/(Fe³⁺+Fe²⁺)<0.30, in the southern dunite body. Type II, containing abundant Pt-Ir (alloys, minor sulfides), is found in magnesiochromite with Fe³⁺/(Fe³⁺+Fe²⁺)=0.40-0.44; type III, consisting of Ir-Rh-Pt-Pd (alloys, sulfarsenides, antimonides) in Fe-rich chromite having Fe²⁺/(Fe²⁺+Mg)=0.66 and Fe³⁺/(Fe³⁺+Fe²⁺)=0.59. Positive anomalies of Ir and Pt, and a negative peak of Ru characterize the PGE patterns of chromitites with type II and III PGM assemblages, whereas a positive Pt anomaly is observed in their dunite host. Intensive fractionation of Pt-Fe alloys in the Uktus chromitites reflects the anomalous behavior of Pt which is decoupled from Rh and Pd. Among other factors, the high iron activity and oxygen fugacity in the parent melt appear to exert a major control on precipitation of Pt-Fe alloys, below sulfur saturation. The strong Pt anomaly in chromitites from Uktus may indicate that Uralian-Alaskan-type magmas were derived from a Pt-rich mantle source.  相似文献   

Iron oxide-copper-gold deposits: an Andean view   总被引：22，自引：2，他引：20  

Richard?H.?SillitoeEmail author 《Mineralium Deposita》2003,38(7):787-812

Iron oxide-copper-gold (IOCG) deposits, defined primarily by their elevated magnetite and/or hematite contents, constitute a broad, ill-defined clan related to a variety of tectono-magmatic settings. The youngest and, therefore, most readily understandable IOCG belt is located in the Coastal Cordillera of northern Chile and southern Peru, where it is part of a volcano-plutonic arc of Jurassic through Early Cretaceous age. The arc is characterised by voluminous tholeiitic to calc-alkaline plutonic complexes of gabbro through granodiorite composition and primitive, mantle-derived parentage. Major arc-parallel fault systems developed in response to extension and transtension induced by subduction roll-back at the retreating convergent margin. The arc crust was attenuated and subjected to high heat flow. IOCG deposits share the arc with massive magnetite deposits, the copper-deficient end-members of the IOCG clan, as well as with manto-type copper and small porphyry copper deposits to create a distinctive metallogenic signature.The IOCG deposits display close relations to the plutonic complexes and broadly coeval fault systems. Based on deposit morphology and dictated in part by lithological and structural parameters, they can be separated into several styles: veins, hydrothermal breccias, replacement mantos, calcic skarns and composite deposits that combine all or many of the preceding types. The vein deposits tend to be hosted by intrusive rocks, especially equigranular gabbrodiorite and diorite, whereas the larger, composite deposits (e.g. Candelaria-Punta del Cobre) occur within volcano-sedimentary sequences up to 2 km from pluton contacts and in intimate association with major orogen-parallel fault systems. Structurally localised IOCG deposits normally share faults and fractures with pre-mineral mafic dykes, many of dioritic composition, thereby further emphasising the close connection with mafic magmatism. The deposits formed in association with sodic, calcic and potassic alteration, either alone or in some combination, reveal evidence of an upward and outward zonation from magnetite-actinolite-apatite to specular hematite-chlorite-sericite and possess a Cu-Au-Co-Ni-As-Mo-U-(LREE) (light rare earth element) signature reminiscent of some calcic iron skarns around diorite intrusions. Scant observations suggest that massive calcite veins and, at shallower palaeodepths, extensive zones of barren pyritic feldspar-destructive alteration may be indicators of concealed IOCG deposits.The balance of evidence strongly supports a genetic connection of the central Andean IOCG deposits with gabbrodiorite to diorite magmas from which the ore fluid may have been channelled by major ductile to brittle fault systems for several kilometres vertically or perhaps even laterally. The large, composite IOCG deposits originated by ingress of the ore fluid to relatively permeable volcano-sedimentary sequences. The mafic magma may form entire plutons or, alternatively, may underplate more felsic intrusions, as witnessed by the ore-related diorite dykes, but in either case the origin of the ore fluid at greater, unobserved depths may be inferred. It is concluded that external 'basinal' fluids were not a requirement for IOCG formation in the central Andes, although metamorphic, seawater, evaporitic or meteoric fluids may have fortuitously contaminated the magmatic ore fluid locally. The proposed linkage of central Andean and probably some other IOCG deposits to oxidised dioritic magmas may be compared with the well-documented dependency of several other magmatic-hydrothermal deposit types on igneous petrochemistry. The affiliation of a spectrum of base-metal poor gold-(Bi-W-Mo) deposit styles to relatively reduced monzogranite-granodiorite intrusions may be considered as a closely analogous example.Editorial handling: B. Lehmann  相似文献   

Different age response of zircon and monazite during the tectono-metamorphic evolution of a high grade paragneiss from the Ruhla Crystalline Complex,central Germany   总被引：5，自引：0，他引：5  

Armin?ZehEmail author  Ian?S.?Williams  Helene?Br?tz  Ian?L.?Millar 《Contributions to Mineralogy and Petrology》2003,145(6):691-706

Results of TIMS, SIMS and SEM analyses show that zircon and monazite in a high-grade paragneiss of the Ruhla Crystalline Complex, central Germany, were formed and/or altered during different stages of a tectono-metamorphic history between Early Devonian and Permian times. Detrital zircon cores of >460 Ma place an older limit on the age of anatexis, and show that the paragneiss sequence contains rocks at least as young as early Cambrian. Metamorphic zircon growth commenced at ~365 Ma, peaking at ~360–355 Ma at the same time that granite dykes were emplaced. In contrast, monazite in the paragneiss preserves little record of the metamorphic peak. Most monazite grains grew or were recrystallised in the Lower Carboniferous at ~339 Ma, contemporaneous with the emplacement of voluminous diorite and granite bodies. These intrusions and related tectonics caused some of the high-U zircon overgrowths to undergo moderate to severe Pb loss. A second Pb loss event, between 300 and 280 Ma, can be related to Late Carboniferous/Early Permian large-scale block faulting.Editorial responsibility: J. Hoefs  相似文献   

Vibrational spectroscopy of beta-eucryptite (LiAlSiO<Subscript>4</Subscript>): optical phonons and phase transition(s)     

M.?ZhangEmail author  H.?Xu  E. K. H.?Salje  P. J.?Heaney 《Physics and Chemistry of Minerals》2003,30(8):457-462

The structural behavior of -eucryptite (LiAlSiO₄) has been investigated using infrared (IR) spectroscopy over a temperature range of 20 to 900 K and FT-Raman spectroscopy at room temperature. IR reflectance measurements show that -eucryptite possesses high reflectivity in the far-IR region, as is consistent with its reported superionic conductivity along the c-axis. On heating, the Li-related IR bands near 246 and 300 cm^–1 (with A₂ symmetry) broadened and weakened dramatically, presumably as a result of Li⁺ positional disordering along the structural channels parallel to c. The disordering process appears to induce a framework distortion, as is evidenced by the broadening of some vibrations of Si(Al)–O with increasing temperature. A change in slope in the temperature dependence of the phonon frequency near 300 cm^–1 and the linewidth of the 760 cm^–1 band at 715 K indicates that Li becomes completely disordered above this temperature. In addition, the temperature dependence of the linewidth for the 760 cm^–1 band exhibits an additional change in slope at 780 K, implying the existence of an intermediate state within this temperature range. The detailed structure of this intermediate phase, however, needs further study. Our IR data provide no indication of structural changes between room temperature and 20 K.  相似文献   

Strong magnetic linear dichroism in Fe <Emphasis Type="Italic">L</Emphasis><Subscript>23</Subscript> and O <Emphasis Type="Italic">K</Emphasis> electron energy-loss near-edge spectra of antiferromagnetic hematite α-Fe<Subscript>2</Subscript>O<Subscript>3</Subscript>     

P. A.?van AkenEmail author  S.?Lauterbach 《Physics and Chemistry of Minerals》2003,30(8):469-477

We report strong magnetic linear dichroism (MLD) at the Fe L₂₃ and O K edges of the antiferromagnetic compound hematite -Fe₂ O₃ in high-resolution orientation- and temperature-dependent electron energy-loss spectroscopy (EELS). Large intensity differences of corresponding spectral features are observed when the Fe L₂₃ and O K edges are measured with momentum transfer either parallel or perpendicular to the magnetization. The resultant difference spectra for the Fe L₂₃ edges is consistent with the MLD observed in X-ray absorption spectroscopy. For the first time we have observed MLD at the O K edge, where the magnetic origin of this dichroism is demonstrated by temperature-dependent investigations across the Morin transition temperature T_M= 263 K, at which the Fe electron spins, i.e. the magnetic moments, rotate by 90°. The O K edge MLD is interpreted in terms of superexchange between the spins of the Fe 3d and O 2p electrons through overlapping Fe 3d and O 2p orbitals. The experiments were performed in a transmission electron microscope (TEM), yielding information about the anisotropic electronic structure at nanoscale spatial resolution when operated with a focused electron probe. The effects of MLD at the Fe L₂₃ edges on the determination of Fe³⁺/Fe in hematite at submicrometre scale using different independent quantification methods are discussed.  相似文献