Dissolved organic matter in surface runoff in the Loess Plateau of China: The role of rainfall events and land-use     

Zhongwu Li  Hao Peng  Binggeng Xie  Chun Liu  Xiaodong Nie  Danyang Wang  Mei Huang  Haibing Xiao  Lin Shi  Xuqin Zhang  Jieyu Jiang 《水文研究》2020,34(6):1446-1459

Exploring the chemical characterization of dissolved organic matter (DOM) is important for understanding the fate of laterally transported organic matter in watersheds. We hypothesized that differences in water-extractable organic matter (WEOM) in soils of varying land uses and rainfall events may significantly affect the quality and the quantity of stream DOM. To test our hypotheses, characteristics of rainfall-runoff DOM and WEOM of source materials (topsoil from different land uses and gullies, as well as typical vegetation) were investigated at two adjacent catchments in the Loess Plateau of China, using ultraviolet–visible absorbance and excitation emission matrix fluorescence with parallel factor analysis (PARAFAC). Results indicated that land-use types may significantly affect the chemical composition of soil WEOM, including its aromaticity, molecular weight, and degree of humification. The PARAFAC analysis demonstrated that the soils and stream water were dominated by terrestrial/allochthonous humic-like substances and microbial transformable humic-like fluorophores. Shifts in the fluorescence properties of stream DOM suggested a pronounced change in the relative proportion of allochthonous versus autochthonous material under different rainfall patterns and land uses. For example, high proportions of forestland could provide more allochthonous DOM input. This study highlights the relevance of soils and hydrological dynamics on the composition and fluxes of DOM issuing from watersheds. The composition of DOM in soils was influenced by land-use type. Precipitation patterns influenced the proportion of terrestrial versus microbial origins of DOM in surface runoff. Contributions of allochthonous, terrestrially derived DOM inputs were highest from forested landscapes.  相似文献   

Transient pressure response of fractured horizontal wells in tight gas reservoirs with arbitrary shapes by the boundary element method     

Yu-long Zhao  Shou-chang Xie  Xiao-long Peng  Lie-hui Zhang 《Environmental Earth Sciences》2016,75(17):1220

  相似文献   

Simulation of site-scale water fluxes in desert and natural oasis ecosystems of the arid region in Northwest China     

Mingjuan Xie  Geping Luo  Olaf Hellwich  Amaury Frankl  Wenqiang Zhang  Chunbo Chen  Chen Zhang  Philippe De Maeyer 《水文研究》2021,35(12):e14444

The study of water fluxes is important to better understand hydrological cycles in arid regions. Data-driven machine learning models have been recently applied to water flux simulation. Previous studies have built site-scale simulation models of water fluxes for individual sites separately, requiring a large amount of data from each site and significant computation time. For arid areas, there is no consensus as to the optimal model and variable selection method to simulate water fluxes. Using data from seven flux observation sites in the arid region of Northwest China, this study compared the performance of random forest (RF), support vector machine (SVM), back propagation neural network (BPNN), and multiple linear regression (MLR) models in simulating water fluxes. Additionally, the study investigated inter-annual and seasonal variation in water fluxes and the dominant drivers of this variation at different sites. A universal simulation model for water flux was built using the RF approach and key variables as determined by MLR, incorporating data from all sites. Model performance of the SVM algorithm (R² = 0.25–0.90) was slightly worse than that of the RF algorithm (R² = 0.41–0.91); the BPNN algorithm performed poorly in most cases (R² = 0.15–0.88). Similarly, the MLR results were limited and unreliable (R² = 0.00–0.66). Using the universal RF model, annual water fluxes were found to be much higher than the precipitation received at each site, and natural oases showed higher fluxes than desert ecosystems. Water fluxes were highest during the growing season (May–September) and lowest during the non-growing season (October–April). Furthermore, the dominant drivers of water flux variation were various among different sites, but the normalized difference vegetation index (NDVI), soil moisture and soil temperature were important at most sites. This study provides useful insights for simulating water fluxes in desert and oasis ecosystems, understanding patterns of variation and the underlying mechanisms. Besides, these results can make a contribution as the decision-making basis to the water management in desert and oasis ecosystems.  相似文献   

Multiple overpressure systems and their relationship with hydrocarbon accumulation in the Qikou Depression of the Bohai Bay Basin,China     

Xue‐Bin Du  Xi‐Nong Xie  Yong‐Chao Lu  Liang Zhang  Wei Peng  Yun‐Peng Li 《Geological Journal》2015,50(4):465-476

Pressure measurements using drill stem tests and estimates from log data calculation indicate that three vertically stacked regional pressure compartments exist in the Qikou Depression of Bohai Bay Basin, N. China. The compartments comprise hydrostatic, upper weak, and lower overpressure systems. Laterally, overpressure (pressure coefficient > 1.2) occurs in the deeper areas and weakens gradually from the centre to the margin of the depression. The accumulation of oil and gas exhibits the interesting characteristics of oil‐bearing layers above gas‐bearing layers in the Qikou Depression. The pattern can be accounted for by the evolution of overpressure system, the maturity process of the source rock and the main fault activity. In the late Dongying Formation (Ed, 30 Ma), the lower overpressure system began to form shape, and the hydrocarbon sources generated a large volume of oil. However, because there was no migration pathway, the oil only accumulated in the original strata. In the late Guantao Formation (Ng, 12 Ma), the gas was generated, the upper overpressure system formed gradually, and the activity of the main fault gradually increased. Then, the overpressure pushed the early gathered oil to flow from the lower overpressure system into the upper overpressure system. Afterwards, the activity of the main fault decreased again and remains weak until now. Thus, later generated natural gas cannot keep migrating along the main fault and can only accumulate in the lower overpressure system. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

An asynchronous Geoprocessing Workflow and its application to an Antarctic ozone monitoring and mapping service     

Chao Yang  Zhong Xie  Zhanya Xu 《International Journal of Digital Earth》2016,9(2):156-170

The integration of Sensor Web Enablement services with other Open Geospatial Consortium (OGC) Web Services as Geospatial Processing Workflows (GPW) is essential for future Sensor Web application scenarios. With the help of GPW technology, distributed and heterogeneous OGC Web Services can be organized and integrated as compound Web Service applications that can direct complicated earth observation tasks. Under the Sensor Web environment, asynchronous communications between Sensor Web Services are common. We have proposed an asynchronous GPW architecture for the integration of Sensor Web Services into a Web Service Business Process Execution Language workflow technology. We designed a Sensor Information Accessing and Processing workflow, an asynchronous GPW instance, to take an experiment of observing and mapping ozone over Antarctica. Based on our results, our proposed asynchronous workflow method shows the advantages of taking environmental monitoring and mapping tasks.  相似文献   

Thermal equation of state of natural tourmaline at high pressure and temperature     

Jingui Xu  Yunqian Kuang  Bo Zhang  Yonggang Liu  Dawei Fan  Xiaodong Li  Hongsen Xie 《Physics and Chemistry of Minerals》2016,43(5):315-326

Synchrotron-based in situ angle-dispersive X-ray diffraction experiments were conducted on a natural uvite-dominated tourmaline sample by using an external-heating diamond anvil cell at simultaneously high pressures and temperatures up to 18 GPa and 723 K, respectively. The angle-dispersive X-ray diffraction data reveal no indication of a structural phase transition over the P–T range of the current experiment in this study. The pressure–volume–temperature data were fitted by the high-temperature Birch–Murnaghan equation of state. Isothermal bulk modulus of K ₀ = 96.6 (9) GPa, pressure derivative of the bulk modulus of \(K_{0}^{\prime } = 12.5 \;(4)\), thermal expansion coefficient of α ₀ = 4.39 (27) × 10^?5 K^?1 and temperature derivative of the bulk modulus (?K/?T) _P  = ?0.009 (6) GPa K^?1 were obtained. The axial thermoelastic properties were also obtained with K _a0 = 139 (2) GPa, \(K_{a0}^{\prime }\) = 11.5 (7) and α _a0 = 1.00 (11) × 10^?5 K^?1 for the a-axis, and K _c0 = 59 (1) GPa, \(K_{c0}^{\prime }\) = 11.4 (5) and α _c0 = 2.41 (24) × 10^?5 K^?1 for the c-axis. Both of axial compression and thermal expansion exhibit large anisotropic behavior. Thermoelastic parameters of tourmaline in this study were also compared with that of the other two ring silicates of beryl and cordierite.  相似文献   

南美Oriente盆地北部海绿石砂岩油藏特征及成藏规律          下载免费PDF全文

阳孝法  谢寅符  张志伟  陈和平  马中振  周玉冰  王丹丹  刘亚明  贺正军  赵永斌 《地质科学》2016,(1):189-203

南美厄瓜多尔Oriente盆地斜坡带发育的白垩系Napo组高伽马特征的UT海绿石砂岩段是成熟探区新发现的隐蔽含油层段。本文分析了海绿石砂岩储层的矿物组成、孔隙结构、成岩作用、物性特点,并结合烃源岩评价与石油空间分布探讨海绿石砂岩油藏的成藏特征。海绿石粘土矿物以颗粒形式存在,与石英共同构成海绿石砂岩的颗粒组分,海绿石砂岩的孔隙结构具有双峰特征,束缚水含量高,属于中-低孔、中-低渗储层类型,孔隙类型主要是剩余粒间孔。海绿石砂岩储层中石英次生加大属Ⅱ级,长石碎屑颗粒发生溶蚀作用,含铁碳酸盐类胶结物发育,结合泥岩低的I/S混层比和高的最高峰温值T_max,指示海绿石砂岩层段属于中成岩阶段A期的产物。与海绿石砂岩油藏紧邻的大面积分布的Ⅱ₁腐泥型成熟烃源岩就是缓翼斜坡带的生烃中心,大面积连续发育的海绿石砂岩与之构成优越的源储组合,有利于上生下储式成藏。海绿石砂岩油藏表现为近源性、成藏晚期性等特点,规模发育的海绿石砂岩储层得以成藏的主要运聚机制是体积流和扩散流运聚机制。这对盆地其它油区同类油藏的发现具有重要的借鉴意义。  相似文献   

甘肃兰州盆地古近系泥岩的古盐度分析          下载免费PDF全文

李智超  李永项  李文厚  张云翔  谢坤  马瑶 《地质科学》2016,(4):1344-1356

兰州盆地位于青藏高原东北部,祁连山以东,黄土高原以西,古近纪出露地层为细柳沟组、野狐城组和咸水河组下段。作为青藏高原寒区、东部季风区及西北干旱区的交汇地带,兰州地区新生代环境研究受到越来越多的关注,因此有必要对其沉积环境进行研究。本文通过对兰州盆地黄羊头地区古近系进行分段采样,并对泥岩样品的主量元素、微量元素及X射线衍射进行测定,运用硼法、B/Ga值及Sr/Ba值等方法定量—半定量分析兰州盆地古近系沉积时的古盐度特征,同时结合风化指数CIA值的变化特征,综合分析古近系的沉积环境。研究结果表明兰州盆地古近系细柳沟组、野狐城组及咸水河组下段Adams法古盐度值为9.5‰～14.0‰,平均值为11.8‰;Couch法古盐度值为8.2‰～12.8‰,平均值为10.8‰,为内陆半咸水—淡水湖泊。Adams法古盐度值与B/Ga值具有良好的正相关关系,而Adams古盐度值与Sr/Ba值相关性不明显,主要由于地层中生物对Sr的富集作用,导致Sr/Ba值偏大,表明Sr/Ba值不适用于生物富集地层的古盐度恢复。环境研究认为细柳沟期,气候湿润,以冲积扇沉积为主,水体较浅,盐度值较大;到野狐城中期水体加深,变为湖相沉积,气候温暖湿润,盐度值降低,同时存在明显的干冷气候间隙,该间隙期湖盆蒸发量大于补给量,盐度值升高;从野狐城晚期开始湖盆逐渐萎缩,以滨湖相沉积为主,到韩家井期变为河流相沉积,至甘家滩期再次转为湖相沉积,盐度值先升高后降低,但整体风化程度明显降低,表明从野狐城组晚期开始气候逐渐变冷变干。  相似文献   

朝不楞多金属矿外围1∶5万地电化学勘查应用     

谢邦廷 《地质与勘探》2016,52(5):885-892

运用地电化学技术在内蒙古半干旱草原风成砂浅覆盖区朝不楞多金属矿外围开展了1∶50000面积性勘查工作,并与常规土壤测量开展了对比研究。结果表明:(1)从元素异常强度、衬度、规模及与已知矿体空间对应性等方面对比,地电化学测量比常规土壤测量具有显著优越性;(2)地电化学测量在区域上显现出Ag-Pb-Zn-Bi-Cd及Cu-Co-Cr-Fe-La-Mo-Ni两套元素异常组合,与已知见矿钻孔中探测到的矽卡岩型铁矿及热液型铅锌矿均有出现具有较好的对应性;(3)在工区东部及东南部未知区发现多处异常强度、规模较大的多元素组合异常,建议开展进一步的勘查工作,以实现该矿区找矿突破。  相似文献   

Preface to the Special Issue “Unified Perspective of Climate Variability and Change”     

Shang-Ping Xie 《大气科学进展》2016,33(4):409-410

正Forty years ago,Klaus Wyrtki(1975)of University of Hawaii discovered that El Nino warming off South America is not a result of local wind change but a response to the relaxed equatorial trade winds some 10 000 km away near the international dateline.The Kelvin wave mechanism was quickly verified from wind-forced ocean model simulations.Consequent  相似文献