五硼酸铷溶液的物化性质及物种分布          下载免费PDF全文

苗军涛  房艳  房春晖  朱发岩  刘红艳  周永全  戈海文  孙鹏超  赵晓婵 《盐湖研究》2016,24(1)

碳酸铷、硼酸化学计量比混合,蒸发溶液,直至五硼酸铷RbB5O8·4H2O晶体析出。经粉末X射线衍射（XRD）、拉曼光谱（Raman spectroscopy）、热重/微商热重/差示扫描量热（TG/DTG/DSC）、原子吸收光谱等实验方法,确定其化学组成及结构。298.15、333.15K时测量溶液的物理化学性质（密度、电导、pH）,并与经验方程进行拟合,研究五硼酸铷溶液的物化性质随浓度、温度的变化规律。根据文献报道的平衡常数,实验测量的pH数据,采用牛顿迭代法进一步研究五硼酸铷溶液中主要存在的硼酸根离子对类型、含量以及物种的形成。  相似文献   

Discussion on applying an analytical method to optimize the anti-freeze design parameters for underground water pipelines in seasonally frozen areas     

Ji Chen  JingYi Zhao  Kun Li  Yu Sheng 《寒旱区科学》2016,8(6):467-476

Adopting the quasi-three-dimensional (Quasi-3D) numerical method to optimize the anti-freeze design parameters of an underground pipeline usually involves heavy numerical calculations. Here, the fitting formulae between the safe conveyance distance (SCD) of a water pipeline and six influencing factors are established based on the lowest water temperature (LWT) along the pipeline axis direction. With reference to the current widely used anti-freeze design approaches for underground pipelines in seasonally frozen areas, this paper first analyzes the feasibility of applying the maximum frozen penetration (MFP) instead of the mean annual ground surface temperature (MAGST) and soil water content (SWC) to calculate the SCD. The results show that the SCD depends on the buried depth if the MFP is fixed and the variation of the MAGST and SWC combination does not significantly change the SCD. A comprehensive formula for the SCD is established based on the relationships between the SCD and several primary influencing factors and the interaction among them. This formula involves five easy-to-access parameters: the MFP, buried depth, pipeline diameter, flow velocity, and inlet water temperature. A comparison between the analytical method and the numerical results based on the Quasi-3D method indicates that the two methods are in good agreement overall. The analytic method can be used to optimize the anti-freeze design parameters of underground water pipelines in seasonally frozen areas under the condition of a 1.5 safety coefficient.  相似文献   

Spatio-temporal evolution of urban innovation structure based on zip code geodatabase: An empirical study from Shanghai and Beijing     

Dezhong Duan  Debin Du  Chengliang Liu  Seamus Grimes 《地理学报(英文版)》2016,26(12):1707-1724

In today’s world, the innovation of science and technology has become the key support for improving comprehensive national strength and changing the mode of social production and lifestyle. The country that possesses world-class scientific and technological innovation cities maximizes the attraction of global innovation factors and wins a strategic initiative in international competition. Based on the urban zip code geodatabase, an evaluation system of urban innovation with the perspective of innovation outputs, and the spatial evolutionary mode, concerning the structure of innovation space of Shanghai and Beijing from 1991 to 2014, was developed. The results of the research indicated that the zip code geodatabase provided a new perspective for studying the evolving spatial structure of urban innovation. The resulting evaluation of the spatial structure of urban innovation using the urban zip code geodatabase established by connecting random edge points, was relatively effective. The study illustrates the value of this methodology. During the study period, the spatial structure of innovation of Shanghai and Beijing demonstrated many common features: with the increase in urban space units participating in innovation year by year, the overall gap of regional innovation outputs has narrowed, and the trend towards spatial agglomeration has strengthened. The evolving spatial structure of innovation of Shanghai and Beijing demonstrated differences between the common features during the 25 years as well: in the trend towards the suburbanization of innovation resources, the spatial structure of innovation of Shanghai evolved from a single-core to a multi-core structure. A radiation effect related to traffic arteries as spatial diffusion corridors was prominent. Accordingly, a spatial correlation effect of its innovation outputs also indicated a hollowness in the city center; the spatial structure of innovation of Beijing had a single-core oriented structure all the way. Together with the tendency for innovation resources to be agglomerated in the city center, the spatial correlation effect of innovation outputs reflected the characteristics of the evolutionary feature where “rural area encircles cities”. The innovation spatial structure of Shanghai and Beijing have intrinsic consistency with the spatial structure of their respective regions (Yangtze River Delta urban agglomeration and Beijing-Tianjin-Hebei metropolitan region), which suggested that the principle of proportional and disproportional distribution of a city-scale pattern of technological and innovational activities is closely related to its regional innovation pattern.  相似文献   

Factors driving riverbed scouring and sedimentation in the Bayangaole to Toudaoguai reaches of the Upper Yellow River     

Suzhen Hou  Ping Wang  Yan Guo  Tian Hu 《地理学报(英文版)》2016,26(9):1305-1320

The Inner Mongolia reaches of the Yellow River face problems of severe sedimentation caused by a variety of complex factors. The sedimentation process in those reaches has been characterized using the sediment balance method, and the key factors affecting the process have been analyzed using the correlation analysis method. The results show that during the period 1952–2012 the Bayangaole (Bayan Gol) to Toudaoguai reaches in Inner Mongolia have undergone successive processes of accumulative sedimentation, then relative balance, and then accumulative sedimentation once again. The total annual sedimentation is 12.0341×10⁸ m³, of which accumulations from July to October account for 95.1% and the reaches from Sanhuhekou to Toudaoguai account for 98.5%. The main factor affecting scouring and sedimentation of the Bayangaole to Sanhuhekou reaches is the combined water and sediment condition. The critical conditions for equilibrium are an incoming sediment coefficient < 0.007 kg·s·m^–6 and a flow discharge > 700 m³·s^–1. The main factor affecting scouring and sedimentation of the Sanhuhekou to Toudaoguai reaches is the incoming sediment from the tributaries on the south bank and the combined water and sediment condition of the main stream. The critical conditions of the main stream for maintaining equilibrium status are a flow discharge of the main stream exceeding 800 m³·s^–1 and a comprehensive incoming sediment coefficient < 0.005 kg·s·m^–6. The incoming sediment from the tributaries has little impact on the main stream when the annual sediment load is less than 0.1×10⁸ t. The incoming sediment coefficient of the main stream and the incoming sediment from the tributaries both play vital roles in the riverbed evolution of the Inner Mongolia reaches, but the latter contributes the most.  相似文献   

Identification of the “source” and “sink” patterns influencing non-point source pollution in the Three Gorges Reservoir Area   总被引：6，自引：0，他引：6  

Jinliang Wang  Jing’an Shao  Dan Wang  Jiupai Ni  Deti Xie 《地理学报(英文版)》2016,26(10):1431-1448

Non-point source pollution is one of the primarily ecological issues affecting the Three Gorges Reservoir Area. In this paper, landscape resistance and motivation coefficient, which integrated various landscape elements, such as land use, soil, hydrology, topography, and vegetation, was established based on the effects of large-scale resistance and motivation on the formation of non-point source pollution. In addition, cost models of the landscape resistance and motivation coefficients were constructed based on the distances from the landscape units to the sub-basin outlets in order to identify the “source” and “sink” patterns affecting the formation of non-point source pollution. The results indicated that the changes in the landscape resistance and motivation coefficients of the 16 sub-basins exhibited inverse relationships to their spatial distributions. The landscape resistance and motivation cost curves were more volatile than the landscape resistance and motivation coefficient curves. The landscape resistance and motivation cost trends of the 16 sub-basins became increasingly apparent along the flow of the Yangtze River. The landscape resistance and motivation cost models proposed in this paper could be used to identify large-scale non-point source pollution “source” and “sink” patterns. Moreover, the proposed model could be used to describe the large-scale spatial characteristics of non-point source pollution formation based on “source” and “sink” landscape pattern indices, spatial localization, and landscape resistance and motivation coefficients.  相似文献   

Spatiotemporal distribution and historical evolution of polders in the Dongting Lake area,China     

Juanle Wang  Mengxu Gao  Haihui Guo  Eryang Chen 《地理学报(英文版)》2016,26(11):1561-1578

Dongting Lake is the largest lake in the middle reaches of the Yangtze River in China. For centuries, people inhabiting the Dongting Lake area have been reclaiming land and constructing dams for flood resistance, agricultural production, and rural settlement, forming geographical entities known as polders. In this study, the regional spatial distributions of polders in the Dongting Lake area in 1949, 1998, and 2013 were obtained using historical maps and modern remotely sensed data, revealing changes since the establishment of the People’s Republic of China. Nanxian County was then selected to demonstrate polder changes at the county level, because it has undergone the most dramatic changes in the area. Different polder change models for the Datonghu, Yule, and Renhe polders were analyzed for eight periods: 1644 (the early Qing Dynasty), 1911 (the late Qing Dynasty), 1930 (the Republic of China), 1949 (the People’s Republic of China), 1963, 1970, 1998, and 2013. Three resulting polder evolution models are: 1) reclaiming polders from lakes, 2) integrating polders by stream merging, and 3) abandoning polders for flood release. The polder evolution models demonstrate the wisdom of local people in using land resources according to the specific regional conditions. Throughout their long-term historical evolution, the spatial distribution of polders in the Dongting Lake area tended to be homogeneous, and the degree of human disturbance tended to be stable. However, a shift occurred, from pure polder area growth or removal to more comprehensive management and protection of the regional environment.  相似文献   

Progress in China’s sustainable development research: Contribution of Chinese geographers   总被引：2，自引：0，他引：2  

Yu Yang  Yi Liu 《地理学报(英文版)》2016,26(8):1176-1196

Sustainable development has always been a hotspot in Chinese geographical research. Herein, we conduct a systematic statistical analysis of the contribution of Chinese geographers to sustainable development research using bibliometric methods. Based on the review of a vast amount of literature, we identify the main research teams, research funding sources, journals, and key research fields. The findings are as follows: (1) the resources and environmental institutes of the Chinese Academy of Sciences have a significant influence on sustainable development research; (2) China’s central government foundations (the National Natural Science Foundation of China and National Social Sciences Fund) are the main research funding sources; (3) most of the highly cited articles are published in journals sponsored by the Geographical Society of China; and (4) sustainable development theory and its research areas are being constantly enriched and perfected. Based on the statistics of keywords, the theory, research methods, research regional scales, and key research areas are summarized and expounded.  相似文献   

Analysis of the contribution of multiple factors to the recent decrease in discharge and sediment yield in the Yellow River Basin,China   总被引：5，自引：1，他引：4  

Wenyi Yao  Peiqing Xiao  Zhenzhou Shen  Jinhua Wang  Peng Jiao 《地理学报(英文版)》2016,26(9):1289-1304

The Yellow River basin is well known for its high sediment yield. However, this sediment yield has clearly decreased since the 1980s, especially after the year 2000. The annual average sediment yield was 1.2 billion tons before 2000, but has significantly decreased to 0.3 billion tons over the last 10 years. Changes in discharge and sediment yield for the Yellow River have attracted the attention of both the Central Government and local communities. This study aimed to identify the individual contributions of changes in precipitation and human activities (e.g. water conservancy projects, terracing, silt dams, socio-economic and needs, and soil and water conservation measures) to the decrease in discharge and sediment yield of the Yellow River. The study used both improved the hydrological method and the soil and water conservation method. The study focused on discharge analysis for the upper reaches and the investigation of sediments for the middle reaches of the river. The results showed that discharge and sediment yield have both presented significant decreasing trends over the past 50 years. Precipitation showed an insignificant decreasing trend over the same period. The annual average discharge decreased by 5.68 billion m³ above Lanzhou reach of the Yellow River from 2000 to 2012; human activities (e.g. socio-economic water use) contributed 43.4% of the total reduction, whereas natural factors (e.g. evaporation from lakes, wetlands and reservoirs) accounted for 56.6%. The decrease in annual discharge and sediment yield of the section between Hekouzhen station and Tongguan station were 12.4 billion m³ and 1.24 billion tons, respectively. Human activities contributed 76.5% and 72.2% of the total reduction in discharge and sediment yield, respectively, and were therefore the dominant factors in the changes in discharge and sediment yield of the Yellow River.  相似文献   

Degrading river network due to urbanization in Yangtze River Delta   总被引：1，自引：0，他引：1  

Longfei Han  Youpeng Xu  Chaogui Lei  Liu Yang  Xiaojun Deng  Chunsheng Hu  Guanglai Xu 《地理学报(英文版)》2016,26(6):694-706

Evolution of river systems under the background of human activities has been a heated topic among geographers and hydrologists. Spatial and temporal variations of river systems during the 1960s–2010s in the Yangtze River Delta (YRD) were investigated based on streams derived from the topographic maps in the 1960s, 1980s and 2010s. A list of indices, drainage density (Dd), water surface ratio (WSR), ratio of area to length of main streams (R), evolution coefficient of tributaries (K) and box dimension (D), were classified into three types (quantitative, structural, and complex indices) and used to quantify the variations of stream structure. Results showed that: (1) quantitative indices (Dd, WSR) presented decreasing trend in the past 50 years, and Dd in Wuchengxiyu, Hangjiahu and Yindongnan have decreased most, about 20%. Structurally, the Qinhuai River basin was characterized by significant upward R, and K value in Hangjiahu went down dramatically by 46.8% during the 1960s–2010s. Decreasing tendency in D was found dominating across the YRD, and decreasing magnitude in Wuchengxiyu and Hangjiahu peaks for 7.8% and 6.5%, respectively in the YRD. (2) Urbanization affected the spatial pattern of river system, and areas with high level of urbanization exhibited least Dd (2.18 km/km²), WSR (6.52%), K (2.64) and D (1.42), compared to moderate and low levels of urbanization. (3) Urbanization also affected the evolution of stream system. In the past 50 years, areas with high level of urbanization showed compelling decreasing tendency in quantitative (27.2% and 19.3%) and complex indices (4.9%) and trend of enlarging of main rivers (4.5% and 7.9% in periods of the 1960s–1980s and the 1980s–2010s). In the recent 30 years, areas with low level of urbanization were detected with significant downward trend in Dd and K. (4) Expanding of urban land, construction of hydraulic engineering and irrigation and water conservancy activities were the main means which degraded the river system in the YRD.  相似文献   

Uncertainty analysis of space–time prisms based on the moment-design method     

Yee Leung  Zi Zhao  Jiang-Hong Ma 《International journal of geographical information science》2016,30(7):1336-1358

Space–time prism (STP) is an important concept for the modeling of object movements in space and time. An STP can be conceptualized as the result of the potential path of a moving object revolving around in the three-dimensional space. Though the concept has found applications in time geography, research on the analysis and propagation of uncertainty in STPs, particularly under high degree of nonlinearity, is scanty. Based on the efficiency and effectiveness of the moment-design (M-D) method, this paper proposes an approach to deal with nonlinear error propagation problems in the potential path areas (PPAs) of STPs and their intersections. Propagation of errors to the PPA and its boundary, and to the intersection of two PPAs is investigated. Performance of the proposed method is evaluated via a series of experimental studies. In comparison with the Monte Carlo method and the implicit function method, simulation results show the advantages of the M-D method in the analysis of error propagation in STPs.  相似文献