Theoretical infrared spectra of some model polycyclic aromatic hydrocarbons: effect of ionization     

De Frees DJ  Miller MD  Talbi D  Pauzat F  Ellinger Y 《The Astrophysical journal》1993,408(2):530-538

In order to test the hypothesis of ionized polycyclic aromatic hydrocarbons (PAHs) as possible carriers of the UIR bands, we realized a computational exploration on selected PAHs of small dimension in order to identify which changes ionization would induce on their IR spectra. In this study we performed ab initio calculations of the spectra of neutral and positively ionized naphthalene, anthracene, and pyrene. The results are significantly important. The frequencies in the cations are slightly shifted with respect to the neutral species, but no general conclusion can be reached from the three molecules considered. By contrast, the relative intensities of most vibrations are strongly affected by ionization, leading to a much better agreement between the calculated CH/CC vibration intensity ratios and those deduced from observations.  相似文献   

Interregional migration in socialist countries: the case of China   总被引：1，自引：0，他引：1  

Wei Y 《GeoJournal》1997,43(3):205-214

This paper analyzes changing interregional migration in China and reveals that the recent eastward migration reverses patterns of migration under Mao. It finds that investment variables are more important than the conventional variables of income and job opportunities in determining China's recent interregional migration. It suggests that both state policy and the global force influence interregional migration, challenging the popular view that the socialist state is the only critical determinant. This paper also criticizes Mao's approach to interregional migration and discusses the impact of migration on development.  相似文献   

Age — heaping: contrasting patterns from china     

Jowett AJ  Li Y 《GeoJournal》1992,28(4):427-442

Detailed examination of China's 1982 census data confirms that the standard of age reporting among the Han Chinese, and among many of the ethnic minorities, is very good. Furthermore the quality of age reporting is unaffected by large variations in levels of literacy which exist between men and women, between young and old, and between rural and urban areas. Much of the credit for the high quality of China's age reporting stems from the distinctive nature of Chinese traditional calendars. However, in the far west of China, in the Xinjiang Autonomous Region, age heaping and age exaggeration are as bad as they are in many other developing countries. The authors show that the poor quality of age reporting in Xinjiang is confined to three of the region's ethnic communities, the Uygur, Kirgiz and Tajik, who appear to neither know, nor care, how old they are.  相似文献   

Attenuation of aqueous metal transport at two natural acid rock drainage occurrences in the Yukon Territory, Canada     

Y.T. John Kwong 《中国地球化学学报》2006,25(B08):229-230

Naturally acidic drainage associated with pyritic black shale has been observed in many locations in the Yukon Territory. While not necessarily linked to known mineral deposits, most of these natural acid rock drainage occurrences show elevated dissolved concentrations of trace elements, especially zinc, nickel, copper, cadmium and arsenic. Based on field observations, microbial investigation, chemical analyses and geochemical modeling, the fate and transport of potentially deleterious elements at two natural acid drainage occurrences with slightly different settings are examined. The Macintosh Creek is a small, acidic stream （pH 2.98-3.40）, 2 km long, located in the Macmillan Pass area of east-central Yukon amidst known sedimentary exhalative massive sulfide mineralization but remains undisturbed by exploration activities. Its trace metal content is apparently derived from groundwater discharges, which gave as much as 5.0, 2.5, 0.7, 0.13 and 0.03 mg/L ofZn, Ni, Cu and As, respectively. Interaction and sorption reactions with algal mats, biofilms and iron oxyhydroxides appear to be the dominant mechanisms attenuating aqueous contaminant transport along the stream. Cryogenic precipitation further consolidates the ferricrete formation and reduces the mobility of the sorbed metals. The tributaries of the Engineering Creek along the Dempster Highway in northern Yukon drain through a series of dolomite, phyllite, argillite, limestone, black shale, sandstone and conglomerate with no known concentration of mineralization. In this area, the water chemistry fully reflects the local geology with acidic streams invariably associated with black shale occurrences. Groundwater seeps in the headwaters area of the km-180 Creek completely enclosed in black shale gave pH 3.0 and as much as 148, 39, 2.9 and 9.1 mg/L of Zn, Ni, Cu and As, respectively. Sorption with iron oxyhydroxide and organic matter appear to dominate the attenuation of contaminant transport along the stream. However, once entered into carbonate-dominated terrains, secondary carbonate minerals exercise additional geochemical control on the local water chemistry as a result of neutralization.  相似文献   

新疆塔里木托云盆地沉积环境与聚煤规律     

李翡  叶兰 《中国煤田地质》2005,17(2):8-10

以1：5万地质填图和钻探验证为基础，经分析研究塔里木托云盆地的地层特征、聚煤期、古地理环境，从而建立起该区的沉积模式，总结出该盆地煤层发育于下侏罗统康苏组上段地层之中，含煤11层，煤层为不稳定发育，但分布具有一定的规律可寻，对进一步找煤具有一定的指导意义。  相似文献   

适应我国经济社会发展需要调整战略性矿产资源勘查部署     

叶天竺 《国土资源通讯》2005,(5):53-56

矿产资源的获取,包括勘查、开发两个阶段,勘查是开发的前期工作,没有矿产勘查则矿产开发是盲目的,必然成为无源之水、无木之本.因此,矿产勘查在国民经济建设中具有基础性、前瞻性、长期性的作用.……  相似文献   

美国通量科学计划中的美国长期通量观测网（2／98）     

S．C．Wofsy D．Y．Hollinger 《辽宁气象》2002,(2):45-48

  相似文献   

高压旋喷复合地基在灰岩地区高层建筑地基基础中的应用     

叶永红  陈国新 《广东地质》2002,17(2):54-58

现代建筑工程中的高层、超高层建筑的基础类型，大部分采用桩基础。对于灰岩地区，由于工程地质条件较差，存在大量的土洞、软土层、溶洞、节理、裂隙等不良地质现象，往往极大地影响着桩基础的设计与施工。花都区人民医院新门诊大楼采用高压旋喷复合地基加箱型基础，克服了灰岩地区的各种不良地质现象的影响，增加了基础施工的安全性。实践证明，高压旋喷桩复合地基在灰岩地区高层建筑地基基础中的应用具有推广价值。  相似文献   

川滇密西西比河谷型铅锌矿床成矿流体来源研究:流体Na-Cl-Br体系的证据   总被引：11，自引：1，他引：11  

李泽琴  王奖臻  倪师军  李朝阳  胡晓强  李桃叶 《矿物岩石》2002,22(4):38-41

应用流体包裹体滤液分析方法，测定了川滇7个MVT铅锌矿床成矿流体的Na,Cl,Br含量，结果表明成矿流体的x(Na/Br)和x(Cl/Br)的平均值分别为185和73，并与高度蒸发浓缩的残留海水的x(Na/Br)和x(Cl/Br)相近。成矿流体的Na,Cl含量呈正相关，在lgNa-lgCl图解中呈线性分布。根据这些事实以及矿床地质特征，认为原始成矿卤水起源于蒸发浓缩的残留海水，原始含矿卤水与富含有机质的大气降水混合导致矿质沉淀而成矿。  相似文献   

青藏高原北羌塘半岛湖新生代粗面玄武岩橄榄石电子探针和激光探针分析   总被引：4，自引：0，他引：4  

赖绍聪  伊海生  刘池阳  O'Reilly S Y 《矿物学报》2002,22(2):107-112

利用电子探针和激光探针剥蚀系统（LA-ICP-MS），对北羌塘新第三纪粗面玄武岩中的橄榄石主元素和微量、稀土元素进行了系统分析。结果表明，本区橄榄石Fo平均为88，属贵橄榄石种属。相对富集Ni、Co和重稀土，而强烈亏损轻稀土及Rb、Sr、Ba、Zr等大离子亲石元素。其稀土元素配分型配分型式与粗面玄武岩全岩稀土配分型式呈互补状态。  相似文献