A search for endogenous amino acids in the Martian meteorite EETA79001     

McDonald GD  Bada JL 《Geochimica et cosmochimica acta》1995,59(6):1179-1184

The Antarctic shergottite EETA79001 is believed to be an impact-ejected fragment of the planet Mars. Samples of the carbonate (white druse) and the basaltic (lithology A) components from this meteorite have been found to contain amino acids at a level of approximately 1 ppm and 0.4 ppm, respectively. The detected amino acids consist almost exclusively of the L-enantiomers of the amino acids commonly found in proteins, and are thus terrestrial contaminants. There is no indication of the presence of alpha-aminoisobutyric acid, one of the most abundant amino acids in several carbonaceous chondrites. The relative abundances of amino acids in the druse material resemble those in Antarctic ice, suggesting that the source of the amino acids may be ice meltwater. The level of amino acids in EETA79001 druse is not by itself sufficient to account for the 600-700 ppm of volatile C reported in druse samples and suggested to be from endogenous martian organic material. However, estimates of total terrestrial organic C present in the druse material based on our amino acid analyses and the organic C content of polar ice can account for most of the reported putative organic C in EETA79001 druse.  相似文献   

Molecular indicators for palaeoenvironmental change in a Messinian evaporitic sequence (Vena del Gesso, Italy). II: High-resolution variations in abundances and 13C contents of free and sulphur-bound carbon skeletons in a single marl bed     

Kenig F  Damsté JS  Frewin NL  Hayes JM  De Leeuw JW 《Organic Geochemistry》1995,23(6):485-526

The extractable organic matter of 10 immature samples from a marl bed of one evaporitic cycle of the Vena del Gesso sediments (Gessoso-solfifera Fm., Messinian, Italy) was analyzed quantitatively for free hydrocarbons and organic sulphur compounds. Nickel boride was used as a desulphurizing agent to recover sulphur-bound lipids from the polar and asphaltene fractions. Carbon isotopic compositions (delta vs PDB) of free hydrocarbons and of S-bound hydrocarbons were also measured. Relationships between these carbon skeletons, precursor biolipids, and the organisms producing them could then be examined. Concentrations of S-bound lipids and free hydrocarbons and their delta values were plotted vs depth in the marl bed and the profiles were interpreted in terms of variations in source organisms, 13 C contents of the carbon source, and environmentally induced changes in isotopic fractionation. The overall range of delta values measured was 24.7%, from -11.6% for a component derived from green sulphur bacteria (Chlorobiaceae) to -36.3% for a lipid derived from purple sulphur bacteria (Chromatiaceae). Deconvolution of mixtures of components deriving from multiple sources (green and purple sulphur bacteria, coccolithophorids, microalgae and higher plants) was sometimes possible because both quantitative and isotopic data were available and because either the free or S-bound pool sometimes appeared to contain material from a single source. Several free n-alkanes and S-bound lipids appeared to be specific products of upper-water-column primary producers (i.e. algae and cyanobacteria). Others derived from anaerobic photoautotrophs and from heterotrophic protozoa (ciliates), which apparently fed partly on Chlorobiaceae. Four groups of n-alkanes produced by algae or cyanobacteria were also recognized based on systematic variations of abundance and isotopic composition with depth. For hydrocarbons probably derived from microalgae, isotopic variations are well correlated with those of total organic carbon. A resistant aliphatic biomacromolecule produced by microalgae is, therefore, probably an important component of the kerogen. These variations reflect changes in the depositional environment and early diagenetic transformations. Changes in the concentrations of S-bound lipids induced by variations in conditions favourable for sulphurization were discriminated from those related to variations in primary producer assemblages. The water column of the lagoonal basin was stratified and photic zone anoxia occurred during the early and middle stages of marl deposition. During the last stage of the marl deposition the stratification collapsed due to a significant shallowing of the water column. Contributions from anaerobic photoautotrophs were apparently associated with variations in depth of the chemocline.  相似文献   

Geochronology and geochemistry of eclogites from the Mariánské Lázně Complex,Czech Republic: Implications for Variscan orogenesis     

Brian L. Beard  L. Gordon Medaris Jr  Clark M. Johnson  Emil Jelínek  J. Tonika  Lee R. Riciputi 《International Journal of Earth Sciences》1995,84(3):552-567

The Mariánské Lázn complex (MLC) is located in the Bohemian Massif along the north-western margin of the Teplá-Barrandian microplate and consists of metagabbro, amphibolite and eclogite, with subordinate amounts of serpentinite, felsic gneiss and calcsilicate rocks. The MLC is interpreted as a metaophiolite complex that marks the suture zone between the Saxothuringian rocks to the north-west and the Teplá-Barrandian microplate to the south-east. Sm-Nd geochronology of garnet-omphacite pairs from two eclogite samples yields ages of 377±7, and 367±4 Ma. Samples of eclogite and amphibolite do not define a whole rock Sm-Nd isochron, even though there is a large range in Sm/Nd ratio, implying that the suite of samples may not be cogenetic. Eclogites do not have correlated _Nd values and initial ⁸⁷Sr/⁸⁶Sr ratios. Five of the eight eclogite samples have high _Nd values (+10.2 to +7.1) consistent with derivation from a MORB-like source, but variable ⁸⁷Sr/⁸⁶Sr ratios (0.7033 to 0.7059) which probably reflect hydrothermal seawater alteration. Three other eclogite samples have lower _Nd values (+ 5.4 to –0.8) and widely variable ⁸⁷Sr/⁸⁶Sr ratios (0.7033 to 0.7096). Such low _Nd values are inconsistent with derivation from a MORB, source and may reflect a subduction or oceanic island basalt component in their source. The MLC is an important petrotectonic element in the Bohemian Massif, providing evidence for Cambro-Ordovician formation of oceanic crust and interaction with seawater, Late Devonian (Frasnian-Famennian) high- and medium-pressure metamorphism related to closure of a Saxothuringian ocean basin, Early Carboniferous (Viséan) thrusting of the Teplá terrane over Saxothuringian rocks and Late Viséan extension.  相似文献   

Analysis of COMPTEL gamma-ray burst locations and spectra     

R. M. Kippen  J. Ryan  A. Connors  M. McConnell  C. Winkler  L. O. Hanlon  V. Schönfelder  J. Greiner  M. Varendorff  W. Collmar  W. Hermsen  L. Kuiper 《Astrophysics and Space Science》1995,231(1-2):231-234

In its first three years of operation, the COMPTEL instrument on theCompton Gamma-Ray Observatory has measured the locations (mean accuracy 1°) and spectra (0.75-30 MeV) of 18 gamma-ray bursts and continues to observe new events at a rate of 1/month. With good angular resolution and sensitivity at MeV energies, the growing COMPTEL burst catalog is an important new piece of evidence in the on-going GRB mystery. The COMPTEL burst locations are consistent with an isotropic distribution of sources, yet the spatial coincidence of two of the bursts indicates the possibility of repetition. The COMPTEL burst spectra are in most cases consistent with a single power law model with spectral index in the range 2–3. However, two bursts show evidence of a spectral break in the MeV range. Measurement of rapid variability at MeV energies in the stronger bursts provides evidence that either the sources are nearby (within the Galaxy) or the gamma-ray emission is relativistically beamed. We present an overview of analysis results obtained from the COMPTEL burst catalog concentrating on the search for burst repetition and the implications of highly variable MeV emission.  相似文献   

Search for low energyν e,μ,τ andv e,μ,τ in coincidence with BATSE gamma ray bursts     

M. Aglietta  P. Antonioli  G. Badino  G. Bologna  C. Castagnoli  A. Castellina  V. L. Dadykin  W. Fulgione  P. Galeotti  F. F. Khalchukov  E. V. Korolkova  P. V. Kortchaguin  V. B. Kortchaguin  V. A. Kudryavtsev  A. S. Malguin  L. Periale  V. G. Ryassny  O. G. Ryazhskaya  O. Saavedra  G. Trinchero  S. Vernetto  C. Vigorito  V. F. Yakushev  G. T. Zatsepin 《Astrophysics and Space Science》1995,231(1-2):355-358

A search for low energy neutrinos of all flavours in correlation with 553 ray bursts detected by BATSE aboard the Compton Observatory has been performed by the LSD (Liquid Scintillator Detector) neutrino telescope. No excess ofe,, orv _e,, candidate has been detected by LSD during the time interval in which BATSE detected the 90% of the photon flux for any of the GRBs analyzed. Upper limits on the neutrino fluxes are given in the paper.  相似文献   

Measurements in N2-CH4(C2H2) discharges of reaction rates and thermochemical constants for Titan atmosphere study     

Ricard A  Cernogora G  Fitaire M  Hochard L  Kouassi N  Speller C  Vacher JR 《Planetary and Space Science》1995,43(1-2):41-46

The kinetic reactions in N2-xCH4(C2H2) gas discharges with x less than 1% have been studied by emission spectroscopy in the afterglow of D.C. discharges and by mass spectroscopy from radiolysis ionization using alpha particles. The pressure range is from several Torr to 100 Torr. At the end of N2 D.C. discharges at room temperature, for a residence time of about 10(-2) s, the dominant active species are the N atoms with density of 10(14)-10(15) cm-3 for N2 density of about 10(17) cm-3 (3 Torr), the N2(X,V) vibrational molecules with for example [N2(X,V = 10)] approximately 10(14) cm-3 and the electronic metastable molecules N2(A 3 sigma u +) with a density of 10(12) cm-3. In such conditions, the following kinetic reactions have been studied: N2(A) + N2(A) --> N2(C,B,V') + N2(X), N2(A) + N2(X,V>5) --> N2(X) + N2(B,V') in pure N2 post-discharges and N2(A) + CH4 --> products, C + N + M2 --> CN(B,V') + M2, N2(X,V>4) + CN --> N2(X) + CN(B,A,V'), in N2-1% CH4 post-discharges. The clustering reactions of N2-(1-5%)CH4(C2H2) gas mixtures after radiolysis ionization have been studied for the H2CN+ nN2 ions and the equilibrium constants have been determined in the temperature range T = 140-300 K.  相似文献   

A topological approach to understand a multiple-loop solar flare     

L. G. Bagalá  C. H. Mandrini  M. G. Rovira  P. Démoulin  J. C. Hénoux 《Solar physics》1995,161(1):103-121

We analyze the UV and X-ray data obtained by the SMM satellite for the flare starting at 02:36 UT on November 12, 1980 in AR 2779. From a detailed revision of the Ov emission, we find that the observations are compatible with energy being released in a zone above the magnetic inversion line of the AR intermediate bipole. This energy is then transported mainly by conduction towards the two distant kernels located in the AR main bipole. One of these kernels is first identified in this paper. Accelerated particles contribute to the energy transport only during the impulsive phase.We model the observed longitudinal magnetic field by means of a discrete number of subphotospheric magnetic poles, and derive the magnetic field overall topology. As in previous studies of chromospheric flares, the Ov kernels are located along the intersection of the computed separatrices with the photosphere. Especially where the field-line linkage changes discontinuously, these kernels can be linked in pairs by lines that extend along separatrices. Our results agree with the hypothesis of magnetic energy released by magnetic reconnection occurring on separatrices.  相似文献   

Plasma processing of interstellar PAHs into solar system kerogen     

Wdowiak TJ  Lee W  Cronin J  Beegle LW  Robinson MS 《Planetary and Space Science》1995,43(10-11):1175-1182

Processes resulting in the formation of hydrocarbons of carbonaceous chondrites and the identity of the interstellar molecular precursors involved are an objective of investigations into the origin of the solar system and perhaps even life on earth. We have combined the resources and experience of an astronomer and physicists doing laboratory simulations with those of a chemical expert in the analysis of meteoritic hydrocarbons, in a project that investigated the conversion of polycyclic aromatic hydrocarbons (PAHs) formed in stellar atmospheres into alkanes found in meteorites. Plasma hydrogenation has been found in the University of Alabama at Birmingham Astrophysics Laboratory to produce from the precursor PAH naphthalene, a new material having an IR absorption spectrum (Lee, W. and Wdowiak, T.J., Astrophys. J. 417, L49-L51, 1993) remarkably similar to that obtained at Arizona State University of the benzene-methanol extract of the Murchison meteorite (Cronin, J.R. and Pizzarello, S., Geochim. Cosmochim. Acta 54, 2859-2868, 1990). There are astrophysical and meteoritic arguments for PAH species from extra-solar sources being incorporated into the solar nebula, where plasma hydrogenation is highly plausible. Conversion of PAHs into alkanes could also have occurred in the interstellar medium. The synthesis of laboratory analogs of meteoritic hydrocarbons through plasma hydrogenation of PAH species is underway, as is chemical analysis of those analogs. The objective is to clarify this heretofore uninvestigated process and to understand its role during the origin of the solar system as a mechanism of production of hydrocarbon species now found in meteorites. Results have been obtained in the form of time-of-flight spectroscopy and chemical analysis of the lab analog prepared from naphthalene.  相似文献   

Linear current instability in loop prominences     

Y. H. Tang  C. Fang  L. S. Cui 《Solar physics》1995,158(1):71-80

By use of the dispersion equation given by Song, Wu, and Dryer (1987) for a cylinder plasma with mass motion and gravity included, we investigate the linear current instabilities developed in loop prominences. The results indicate that the mode of linear instability depends mainly on whetherv _s ² > or not, wherev _s is the sonic velocity at heightz, =GM/(R +z) is the gravity potential,G the gravitational constant,M andR the mass and the radius of the Sun respectively. Ifv _s ² > , then the sausage instability will be dominant. Otherwise, the kink instability will be more important. A possible explanation of knot structure, which appears sometimes in solar loop prominences has been given.  相似文献   

The impact cratering record of Fennoscandia     

L. J. Pesonen 《Earth, Moon, and Planets》1995,71(3):377-393

The current database of craterform structures in Fennoscandia contains 22 structures of impact origin and about fifty other structures which lack sufficient evidence for impact. The discovery rate of new structures has been one or two per year during the past ten years. The proven impact structures are located in southern Fennoscandia and the majority have been found in Proterozoic target rocks. The age of the structures varies from prehistoric to 1000 Ma and their diameters (D) from 0.04 km to 55 km. Nine of the structures contain impact melt. A characteristic feature of the Fennoscandian impact record is a relatively large number of small ( 5 km) but old (> 200 Ma) structures: this is a result of success of geophysical methods to discover small but old impact structures in an eroded shield covered with relatively thin overburden. Some of the large circular structures in satellite images and/or in geophysical maps may represent deeply eroded scars of very old impacts, but due to the lack of shock metamorphic features, impact-generated rocks or identified ejecta layers, they cannot yet be classified as impact sites. Two huge structures are proposed here as possible impact sites on the basis of circular satellite images and distinct geophysical anomalies: the Lycksele structure in northern Sweden (D ~ 120 km, see also Witschard, 1984) and the Valga structure in Latvia/Estonia (D ~ 180 km). However, endogeneous explanations, like buried granites, basement domings, or fault-bounded blocks are also possible for these structures. Hints, such as distal ejecta layers or impact produced breccia dykes, of an Archaean or Early Proterozoic impact structure have not been found in Fennoscandia so far. New ways of searching for these structures are proposed with particular emphasis on high-resolution integrated geophysical methods. The impact cratering rate in Fennoscandia is ~ 2.0 · 10^–14 km^–2 a^–1 (for craters with D > 3 km) corresponding to about two events per every 100 Ma for the last 700 Ma. Due to erosion, this is a minimal estimate but is higher than the global rate probably due to strong research activity for finding impact structures in Fennoscandia.  相似文献