Theoretical calculation of equilibrium Mg isotope fractionation between silicate melt and its vapor     

Haiyang Luo  Huiming Bao  Yuhong Yang  Yun Liu 《中国地球化学学报》2018,37(5):655-662

Isotope fractionation during the evaporation of silicate melt and condensation of vapor has been widely used to explain various isotope signals observed in lunar soils, cosmic spherules, calcium–aluminum-rich inclusions, and bulk compositions of planetary materials. During evaporation and condensation, the equilibrium isotope fractionation factor (α) between high-temperature silicate melt and vapor is a fundamental parameter that can constrain the melt’s isotopic compositions. However, equilibrium α is difficult to calibrate experimentally. Here we used Mg as an example and calculated equilibrium Mg isotope fractionation in MgSiO₃ and Mg₂SiO₄ melt–vapor systems based on first-principles molecular dynamics and the high-temperature approximation of the Bigeleisen–Mayer equation. We found that, at 2500 K, δ²⁵Mg values in the MgSiO₃ and Mg₂SiO₄ melts were 0.141?±?0.004 and 0.143?±?0.003‰ more positive than in their respective vapors. The corresponding δ²⁶Mg values were 0.270?±?0.008 and 0.274?±?0.006‰ more positive than in vapors, respectively. The general \(\alpha - T\) equations describing the equilibrium Mg α in MgSiO₃ and Mg₂SiO₄ melt–vapor systems were: \(\alpha_{{{\text{Mg}}\left( {\text{l}} \right) - {\text{Mg}}\left( {\text{g}} \right)}} = 1 + \frac{{5.264 \times 10^{5} }}{{T^{2} }}\left( {\frac{1}{m} - \frac{1}{{m^{\prime}}}} \right)\) and \(\alpha_{{{\text{Mg}}\left( {\text{l}} \right) - {\text{Mg}}\left( {\text{g}} \right)}} = 1 + \frac{{5.340 \times 10^{5} }}{{T^{2} }}\left( {\frac{1}{m} - \frac{1}{{m^{\prime}}}} \right)\), respectively, where m is the mass of light isotope ²⁴Mg and m′ is the mass of the heavier isotope, ²⁵Mg or ²⁶Mg. These results offer a necessary parameter for mechanistic understanding of Mg isotope fractionation during evaporation and condensation that commonly occurs during the early stages of planetary formation and evolution.  相似文献   

Geochemistry and geochronology of Late Jurassic and Early Cretaceous intrusions related to some Au (Sb) deposits in southern Anhui: a case study and review     

Qing Hu  Huangling Gu  Xiaoyong Yang  Yisu Ren  Ergen Gao  Zhangxing Nie 《中国地球化学学报》2018,37(3):360-383

Some Au deposits in southern Anhui Province have recently been found to be closely associated with Late Mesozoic intrusions. Typical examples include the Huashan Au (Sb) deposit and Au deposits at Zhaojialing, Wuxi, and Liaojia. In order to understand the mechanisms that led the formation of these Au deposits, we make detailed reviews on the geological characteristics of these Au deposits. Specifically, we present new LA-ICP-MS zircon U–Pb dating, along with elemental and Hf isotopic data from the Huashan Au (Sb) deposit. Our data suggests that the Huashan ore-related intrusions were emplaced during the Late Jurassic and Early Cretaceous periods (144–148 Ma). They are characterized by arc-magma features and high oxygen fugacity and are rich in inherited zircons. Zircon U–Pb ages and Lu–Hf isotopes from intrusions suggest that Proterozoic juvenile lithosphere is the main source of these intrusions. The regional geological history implies that lithosphere beneath southern Anhui was produced during a Proterozoic subduction and was fertilized with Au (Cu) in the process. Integrated with the results of previous studies, we inferred that Late Mesozoic intrusions formed by the remelting of the lithosphere could provide the metal endowment for the Au-rich deposits in southern Anhui.  相似文献   

Late Cenozoic Sedimentary Evolution of Pagri‐Duoqing Co graben,Southern End of Yadong‐Gulu Rift,Southern Tibet   总被引：1，自引：0，他引：1  

HA Guanghao  WU Zhonghai  HE Lin  WANG Shubing 《《地质学报》英文版》2018,92(3):972-987

The north trending rifts in southern Tibet represent the E–W extension of the plateau and confirming the initial rifting age is key to the study of mechanics of these rifts. Pagri–Duoqing Co graben is located at southern end of Yadong–Gulu rift, where the late Cenozoic sediments is predominately composed of fluvio-lacustrine and moraine. Based on the sedimentary composition and structures, the fluvio-lacustrine could be divided into three facies, namely, lacustrine, lacustrine fan delta and alluvial fan. The presence of paleo-currents and conglomerate components and the provenance of the strata around the graben indicate that it was Tethys Himalaya and High Himalaya. Electron spin resonance (ESR) dating and paleo-magnetic dating suggest that the age of the strata ranges from ca. 1.2 Ma to ca. 8 Ma. Optically stimulated luminescence (OSL) dating showed that moraine in the graben mainly developed from around 181–109 ka (late Middle Pleistocene). Combining previous data about the Late Cenozoic strata in other basins, it is suggested that 8–15 Ma may be the initial rifting time. Together with sediment distribution and drainage system, the sedimentary evolution of Pagri could be divided into four stages. The graben rifted at around 15–8 Ma due to the eastern graben-boundary fault resulting in the appearance of a paleolake. Following by a geologically quiet period about 8–2.5 Ma, the paleolake expanded from east to west at around 8–6 Ma reaching its maximum at ca. 6 Ma. Then, the graben was broken at about 2.5 Ma. At last, the development of the glacier separated the graben into two parts that were Pagri and Duoqing Co since the later stages of the Middle Pleistocene. The evolution process suggested that the former three stages were related to the tectonic movement, which determined the basement of the graben, while the last stage may have been influenced by glacial activity caused by climate change.  相似文献   

Petrogenesis and Tectonic Significance of the Three‐Period Porphyries from the Daruoluolong Cu (Au) Deposit,Tibet, China     

GAO Ke  SONG Yang  LIU Zhibo  FANG Xiang  LI Faqiao  LI Haifeng 《《地质学报》英文版》2018,92(3):1267-1269

正Objective The Daruoluolong deposit is the first high-grade Cu(Au)deposit discovered in the middle section of the Bangonghu-Nujiang(herein after referred to as Ban-Nu)metallogenic belt,which has not been documented about previously.This deposit is located in Shuanghu County of northern Tibet,and its geotectonic position belongs to the  相似文献   

Borehole Stability in Deep Bedding Formations     

Wang Z.Q.  Ding L.Q.  Yang J.  Liu B.L. 《《地质学报》英文版》2018,92(Z1):196-196

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A brief review of the interaction between tectonic, climatic and surface processes over multiple temporal and spatial scales     

Jing Liu Zeng  Jinyu Zhang  Yukui Ge  Wei Wang  Linsen Zeng  Gen Li  Xu Lin 《《地质学报》英文版》2018,92(Z1):151-151

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Comparative Study of Hydrogen and Carbon Isotopic Composition of Gases Generated from the Pyrolysis of a Peat under Saltwater and Freshwater Conditions     

WU Yingzhong  DUAN Yi  ZHAO Yang  CAO Xixi  MA Lanhu  QIAN Yaorong  LI Zhongping  XING Lantian 《《地质学报》英文版》2018,92(5):1879-1887

To understand the influence of the diagenetic water medium on the isotopic compositions of thermogenic coalbed gas, both hydrous and anhydrous closed-system pyrolyses were performed at temperatures of 250°C to 650°C on an herbaceous marsh peat. Compared to the results of anhydrous pyrolysis, the hydrocarbon gases generated from hydrous pyrolyses have very different hydrogen isotopic compositions. However, the carbon isotopic compositions of the hydrocarbon gases became only slightly heavier in hydrous pyrolysis, compared to that from anhydrous pyrolysis. With the progress of thermal evolution from peat to a more advanced thermal maturity of vitrinite reflectance values (Ro) of 5.5% during the pyrolysis, the difference in the average δD value increased from 52‰ to 64‰ between the hydrous pyrolysis with saltwater and anhydrous pyrolysis and increased from 18‰ to 29‰ between the hydrous pyrolysis with freshwater and anhydrous pyrolysis, respectively. The difference in the average δ13C value was only 1‰–2‰ between the hydrous and anhydrous pyrolysis. The relationships between the δD values of the generated hydrocarbon gases and Ro values as well as among δD values of the hydrocarbon gas species are established. The close relationships among these parameters suggest that the water medium had a significant effect on the hydrogen isotopic composition and a minimal effect on the carbon isotopic composition of the hydrocarbon gases. The results of these pyrolyses may provide information for the understanding of the genesis of coalbed gas from herbaceous marsh material with the participation of different diagenetic water media.  相似文献   

湖北宜昌地区奥陶系五峰组-志留系龙马溪组获页岩气高产工业气流   总被引：2，自引：1，他引：1       下载免费PDF全文

陈孝红  张保民  张国涛  陈林  张淼  李培军 《中国地质》2018,45(1):199-200

正1研究目的(Objective)湖北宜昌王家湾是全球上奥陶统赫南特阶底界全球界线层型剖面所在地,也是世界上开展奥陶系和志留系界线对比研究的典型地区,具有很高的地层学研究水平。该地奥陶系五峰组—志留系龙马溪组下部以碳硅泥质页岩发育为特点,沉积连续,化石丰富,具有与中国已经建成的重庆涪陵焦石坝和长宁威远国家级页岩气勘探示范区页岩气勘探主力层系相似的地层和古生物发育特点。区域构造稳定,地层产状平缓,页岩气富集地质条件优越,但志留系页岩气的  相似文献   

“老脚印”对自升式钻井平台插桩滑移的影响研究          下载免费PDF全文

刘阳  冮鹏  赵少伟  王菲菲 《探矿工程》2018,45(6):40-46

渤海海域自升式钻井平台作业频率高,在同一区块多次插桩作业情况多,为自升式平台插桩作业带来严重的滑移风险。通过建立常用的两种类型桩靴的有限元分析模型,采用模拟计算和对比分析的研究方法,对在“老脚印”不同距离位置插桩时,桩基土体的塑性破坏特性、运移规律及桩靴所受侧向滑移力进行了模拟研究,得出了在不同土质条件下,桩基土和桩靴的受力特性及规律,分析了不同位置的“老脚印“对自升式平台插桩滑移风险的影响。  相似文献   

微型桩结合灰土桩在黄土地区纠倾加固工程中的应用          下载免费PDF全文

李清泉  程晓伟  肖洋 《水文地质工程地质》2018,(3):106-110

黄土地区高层建筑纠倾加固的工程实例研究目前较少,虽然既有地基基础加固措施很多,但是它们在黄土地区的应用有一定局限性。文章在工程实践基础上,将微型桩与灰土桩两种结构有机地结合在一起,对该加固结构的布置形式、施工工艺、技术要求等方面进行了研究;充分发挥各自优点,提高微型桩承载力,控制建筑沉降。通过纠倾加固工程实例,对微型桩结合灰土桩的加固效果进行研究,结果显示加固建筑从纠倾结束到沉降稳定,最大沉降量仅5.6 mm,表明微型桩结合灰土桩在黄土地区高层建筑加固工程中加固效果良好,可为相似工程提供借鉴经验。  相似文献