四酸溶矿——电感偶合等离子体发射光谱法测定钼矿中的钼     

冯永明  邢应香  陈波  刘军  余兴  刘洪青 《安徽地质》2014,(1):60-62,69

为了适应地质找矿和地质大普查工作对矿样测定速度和正确度的要求,对钼矿样品中的钼的测定方法进行试验,探讨在敞开体系中用盐酸+硝酸+氢氟酸+高氯酸的四酸溶矿体系消解钼矿样品,使用电感耦合等离子发射光谱仪(ICP-AES)测定钼的方法。  相似文献   

磨抛光合成新材料在岩矿制片中的应用     

张树淮  郑杨  武育宁  明星  牛焕友 《华南地质与矿产》2014,(1):58-59

作者利用所研制出来的磨抛光合成新材料与传统磨抛光工艺进行了对比试验。通过对多种最常使用的矿物或岩石的反复试验,结果表明合成新材料不仅大大提高了工作效率,还具有抛光速度快(所需时间仅为传统工艺的1/3~1/2),而且抛光效果极佳(基本无糙面或麻点),经久耐用,耗材极低和基本无巴盘打片现象。  相似文献   

Surface characterization of maize-straw-derived biochars and their sorption performance for MTBE and benzene   总被引：2，自引：1，他引：1  

Liwei Xiao  Erping Bi  Beibei Du  Xiaoli Zhao  Chen Xing 《Environmental Earth Sciences》2014,71(12):5195-5205

Biochars generated at various temperatures might show significant differences in sorption for organic contaminants. In this study, a series of biochars, generated from pyrolyzing maize straws at different temperatures, were systematically characterized. The characterization results showed that with increasing pyrolysis temperature, the surface areas, micropore areas and aromaticity of biochars were enhanced. Batch experiments were conducted to study methyl tert-butyl ether (MTBE) and benzene sorption to biochars. The results indicated that the sorption capacity of benzene to biochars was higher than that of MTBE. The higher pyrolyzed temperature of biochars resulted in a stronger sorption affinity for target compounds, and the dominant sorption mechanisms varied for biochars pyrolyzed at different temperatures. The sorption to biochars pyrolyzed at 700 and 800 °C performed a high adsorption capacity, which indicated that they might be a promising sorbent to remove MTBE and benzene from water. Biochar pyrolyzed at 400 °C showed transitional sorption mechanisms from partition to adsorption for MTBE and benzene. Pore-filling was a possible sorption mechanism to biochars pyrolyzed at high temperature.  相似文献   

成藏期砂岩孔隙度对油气分布的控制作用——以东营凹陷牛庄洼陷沙三中亚段岩性油藏为例          下载免费PDF全文

刘明洁  刘震  王标  张旺  姚星  王新征  赵海燕 《地质科学》2014,(1):147-160

在具有相同储集砂体和相似断层输导情况下,牛庄洼陷沙三中亚段砂岩体油藏长期存在以下难以解释的现象：1）现今砂岩孔隙度分布与油气分布不一致,高孔隙砂岩不含油而低孔隙砂岩含油;2）相同物性砂岩有的含油而有的不含油,含油砂体现今物性接近,但含油级别却存在很大差异。本文从古孔隙度恢复方面分析了牛庄洼陷西部地区沙三中砂岩储层在成藏期的储集条件,并探讨了成藏期储层临界孔隙度。研究发现：1）虽然现今储层物性下限很低,部分砂岩已经致密化,但成藏期的古孔隙度分布在18%～25%范围内,远大于成藏期临界孔隙度13.9%。但由于埋藏过程的差异导致砂岩储层后期减孔幅度不同,因而现今储层物性不能反映成藏期储层物性,成藏期孔隙度高并不能代表现今孔隙度高;2）成藏期高孔隙度带与现今油气分布范围高度一致,表明在相似断层输导条件下,由于储层物性级差优势形成油气优势运移通道,导致高孔隙度带砂体含油,因此,沙三中亚段岩性油藏富集在成藏期高孔隙带中,成藏期砂岩古孔隙度是油气成藏的重要控制因素,而现今砂岩储层高孔隙带在成藏期并不一定高。牛庄洼陷西部地区沙三中亚段储层中具有高古孔隙度的砂岩仍有较大勘探潜力。  相似文献   

Assessment of the Excavation-Damaged Zone in a Tall Rock Slope Using Acoustic Testing Method     

Jia-wen Zhou  Xing-guo Yang  Hui-ge Xing  Yu-feng Xue  Gang He 《Geotechnical and Geological Engineering》2014,32(4):1149-1158

During slope excavation, high stresses can become concentrated in the rock mass because of stress redistribution. Failure of the rock mass creates an excavation-damaged zone (EDZ) in the slope. The damage reduces the acoustic wave velocity in the rock mass. Results of field tests measuring acoustic wave velocity at the Jinping I Hydropower Station are used here to study the EDZ in a tall rock slope. Two acoustic testing methods were adopted in the field tests: single-hole acoustic testing (SAT) and cross-hole acoustic testing (CAT). The acoustic wave velocity was lower in the EDZ, and the depth of the EDZ increased with decreasing slope elevation. Statistical analysis shows that the acoustic wave velocity obtained by the SAT method is larger than that obtained by the CAT method, and the relative difference between the SAT- and CAT-derived velocities is lower for a high quality rock mass than for a low quality rock mass. The integrity ratio and severity of damage can also be determined by acoustic wave velocity test results, revealing that the integrity ratio and elastic modulus of a rock mass are reduced in the EDZ.  相似文献   

新疆阿合奇地区晚石炭世-早二叠世筵类动物群     

黄兴  朱飞  张雄华  刘晓煌  赵志刚  寇晓虎  杨宝忠 《中国区域地质》2014,(1):33-41

在塔里木盆地西北缘的阿合奇地区晚石炭世-早二叠世地层中发现大量的筵类化石,共计18属61种,另有较多未定种,自下而上建立了4个筵带,依次为Pseudostaffella带、Profusulinella带、Fusulinella—Fusulina带和Pseudoschwagerma带。各篷带与华南、帕米尔达尔瓦兹等地能很好的对比,且筵类动物群面貌与华南地区相似。根据筵类化石确定别根他乌组为晚石炭世早中期罗苏期-达拉期,康克林组为晚石炭世晚期小独山期一早二叠世紫松期,将该区石炭系、二叠系的界线置于71层底部。石炭纪末期区域上海退和古地形的影响导致筵带Triticites带的缺失。  相似文献   

阿尔泰南缘可可托海地区二厂房岩体LA-ICP-MS锆石U-Pb年代学、岩石成因及其地质意义     

张亚峰  蔺新望  郭岐明  吕军利  赵端昌  王星  王旭 《岩石矿物学杂志》2014,33(1):13-28

对出露于阿尔泰造山带南缘可可托海地区二厂房岩体中的黑云母花岗闪长岩进行了LA-ICP-MS锆石U-Pb定年和岩石地球化学分析。结果显示,锆石的²⁰⁶Pb/²³⁸U年龄加权平均值为398.0±3.5 Ma（MSWD=1.3）,表明该岩体形成于早中泥盆世。岩体的SiO₂含量介于65.40%～69.31%之间,里特曼指数值为1.27～1.65,A/CNK值为0.92～1.02,属中钾、钙碱性、准铝质岩石。具有富集Cs、Rb、Th、U等大离子亲石元素和轻稀土元素,相对亏损重稀土元素和Nb、Ta、Zr、Hf等高场强元素,负Eu异常明显（δEu=0.48～0.65）的岛弧岩浆岩特征。结合区域地质资料,认为二厂房岩体形成于陆缘弧构造环境,是在古亚洲洋俯冲过程中,幔源的基性岩浆底侵下地壳后使之熔融并发生了岩浆混合作用的产物。  相似文献   

扬子克拉通东南缘新元古代陆缘弧型TTG的厘定及其构造意义   总被引：4，自引：0，他引：4  

姜杨  赵希林  林寿发  Donald W DAVIS  邢光福  李龙明  段政 《地质学报》2014,88(8):1461-1474

在扬子克拉通东南缘的江山-绍兴结合带沿线多处出露新元古代深成杂岩,以往被认为是沿扬子克拉通和华夏地块碰撞缝合带侵入的板内型深成岩类。本文选择其中的浙江金华罗店中酸性深成杂岩进行了系统的岩石学、年代学和地球化学研究,提出它们属TTG岩石组合,包括英云闪长岩-奥长花岗岩-花岗闪长岩组合(T1T2G1)和二长花岗岩-花岗岩组合(G2QM)两类,普遍以明显富集Rb、Ba、K、Pb等大离子亲石元素而强烈亏损Nb、Ta、Ti、P等高场强元素为特征,δCe为弱负异常或无异常,属典型的弧岩浆岩类。T1T2G1组合富钠贫钾,εNd(t)值=+2.6~+9.4,Mg#值为41.5~63.1,推断由玄武质俯冲板片脱水部分熔融而成,并受到地幔楔橄榄岩熔体的混染。G2QM组合与T1T2G1组合地球化学特征类似,但又明显富K2O(2.75%~5.08%)、LILE和LREE,低Mg#值(27.2~52.31)和εNd(t)值(+1.7~+2.0),应是T1T2G1源区继续部分熔融的产物,可能未受到明显的地幔楔橄榄岩混染。测得花岗闪长岩(G1)锆石SHRIMP U-Pb年龄为841±10Ma,奥长花岗岩(T2)锆石LA-ICPMS U-Pb年龄为793±13Ma,前人报道之花岗岩(G2)年龄为832±44Ma,结合上述地球化学特征,说明T1T2G1和G2QM组合是由新元古代古华南洋向扬子东南缘持续俯冲形成的。综合区域地质资料及前人研究结果,提出金华罗店与诸暨璜山、绍兴平水等地的深成杂岩共同构成了扬子克拉通东南缘一条长达200km的青白口纪(930~793Ma)陆缘弧型深成杂岩带,反映迟至793Ma前仍存在强烈的洋壳俯冲,扬子克拉通尚未与华夏地块发生碰撞拼合,且T1T2G1-G2QM组合的出现指示洋壳俯冲正处于早-中期阶段。  相似文献   

Genesis study of high abundant 17a（H）-diahopanes in Lower Cretaceous lacustrine source rocks of the Lishu Fault Depression,Songliao Basin,Northeast China     

LIU Haiyu  ZHANG Min  LI Xing 《中国地球化学学报》2014,33(2):201-206

Relatively abundant 17α（H）-diahopanes have been detected in the lower cretaceous lacustrine source rocks from the Lishu Fault Depression in the Songliao Basin Northeast China. Rich long chain tricyclic terpanes （carbon number up to C35） and gammacerane have been observed in those source rocks with relatively abundant 17α（H）-diahopanes, which is rarely seen in previous reports. In this paper, the formation of 17α（H）-diahopanes has been discussed from three aspects including maturity, oxidation-reduction nature of depositional environment and parent material composition by the GC/MS analyses. The results reveal that maturity and oxidation-reduction nature of depositional environment have little effect on the formation of 1 7α（H）-diahopanes in the investigated area. How- ever, the positive correlation between long-chain tricyclic terpanes and 17α（H）-diahopanes argues strongly for a common origin, and the origin is related to the algaes in saline water environment. The algaes in saline water envi- ronment may be a kind of origin of 1 7α（H）-diahopanes.  相似文献   

Arsenic Distribution Pattern in Different Sources of Drinking Water and their Geological Background in Guanzhong Basin,Shaanxi, China     

LUO Kunli  ZHANG Shixi  TIAN Yuan  GAO Xing 《《地质学报》英文版》2014,88(3):984-994

To study arsenic(As) content and distribution patterns as well as the genesis of different kinds of water, especially the different sources of drinking water in Guanzhong Basin, Shaanxi province, China, 139 water samples were collected at 62 sampling points from wells of different depths, from hot springs, and rivers. The As content of these samples was measured by the intermittent flowhydride generation atomic fluorescence spectrometry method(HG-AFS). The As concentrations in the drinking water in Guanzhong Basin vary greatly(0.00–68.08 μg/L), and the As concentration of groundwater in southern Guanzhong Basin is different from that in the northern Guanzhong Basin. Even within the same location in southern Guanzhong Basin, the As concentrations at different depths vary greatly. As concentration of groundwater from the shallow wells(50 m deep, 0.56–3.87 μg/L) is much lower than from deep wells(110–360 m deep, 19.34–62.91 μg/L), whereas As concentration in water of any depth in northern Guanzhong Basin is 10 μg/L. Southern Guanzhong Basin is a newly discovered high-As groundwater area in China. The high-As groundwater is mainly distributed in areas between the Qinling Mountains and Weihe River; it has only been found at depths ranging from 110 to 360 m in confined aquifers, which store water in the Lishi and Wucheng Loess(Lower and Middle Pleistocene) in the southern Guanzhong Basin. As concentration of hot spring water is 6.47–11.94 μg/L; that of geothermal water between 1000 and 1500 m deep is 43.68–68.08 μg/L. The high-As well water at depths from 110 to 360 m in southern Guanzhong Basin has a very low fluorine(F) value, which is generally 0.10 mg/L. Otherwise, the hot springs of Lintong and Tangyu and the geothermal water in southern Guanzhong Basin have very high F values(8.07–14.96 mg/L). The results indicate that highAs groundwater in depths from 110 to 360 m is unlikely to have a direct relationship with the geothermal water in the same area. As concentration of all reservoirs and rivers(both contaminated and uncontaminated) in the Guanzhong Basin is 10 μg/L. This shows that pollution in the surface water is not the source of the high-As in the southern Guanzhong Basin. The partition boundaries of the high- and low-As groundwater area corresponds to the partition boundaries of the tectonic units in the Guanzhong Basin. This probably indicates that the high-As groundwater areas can be correlated to their geological underpinning and structural framework. In southern Guanzhong Basin, the main sources of drinking water for villages and small towns today are wells between 110–360 m deep. All of their As contents exceed the limit of the Chinese National Standard and the International Standard(10 μg/L) and so local residents should use other sources of clean water that are 50 m deep, instead of deep groundwater(110 to 360 m) for their drinking water supply.  相似文献