Ternary geochemical-tracing system in natural gas accumulation     

Liu WenHui  Chen MengJin  Guan Ping  Zheng JianJing  Jin Qiang  Li Jian  Wang WanChun  Hu GuoYi  Xia YanQing  Zhang DianWei 《中国科学D辑(英文版)》2007,50(10):1494-1503

The establishment of geochemical-tracing system of gas generation and accumulation is helpful to re-elucidating the gas migration and accumulation in time and space. To deduce the complex process of gas accumulation, a ternary geochemical-tracing system is set up, according to stable isotope inheritance of source rocks, kinetic fractionation of stable isotopes, time-accumulating effect of noble gas isotopes, mantle-derived volatile inheritance, and organic molecule inheritance of light hydrocarbons and thermally kinetic fractionation in their generation, in combination with the previous achievements of gas geochemistry and geochemical parameters of gas-source correlation. There are tight interactions for the geochemical parameters with much information about parent inheritance and special biomarkers, in which they are confirmed each other, reciprocally associated and preferentially used for the requirement so that we can use these geochemical parameters to effectively demonstrate the sources of natural gas, sedimentary environments and thermal evolution of source rocks, migration and accumulation of natural gas, and rearrangement of natural gas reservoirs. It is necessary for the ternary geochemical-tracing system to predict the formation of high efficient gas reservoir and their distribution in time and space.  相似文献   

Soil organic carbon storage and soil CO<Subscript>2</Subscript> flux in the alpine meadow ecosystem     

Tao Zhen  Shen ChengDe  Gao QuanZhou  Sun YanMin  Yi WeiXi  Li YingNian 《中国科学D辑(英文版)》2007,50(7):1103-1114

High-resolution sampling, measurements of organic carbon contents and ¹⁴C signatures of selected four soil profiles in the Haibei Station situated on the northeast Tibetan Plateau, and application of ¹⁴C tracing technology were conducted in an attempt to investigate the turnover times of soil organic carbon and the soil-CO₂ flux in the alpine meadow ecosystem. The results show that the organic carbon stored in the soils varies from 22.12×10⁴ kg C hm⁻² to 30.75×10⁴ kg C hm⁻² in the alpine meadow ecosystems, with an average of 26.86×10⁴ kg C hm⁻². Turnover times of organic carbon pools increase with depth from 45 a to 73 a in the surface soil horizon to hundreds of years or millennia or even longer at the deep soil horizons in the alpine meadow ecosystems. The soil-CO₂ flux ranges from 103.24 g C m⁻² a⁻¹ to 254.93 gC m⁻² a⁻¹, with an average of 191.23 g C m⁻² a⁻¹. The CO₂ efflux produced from microbial decomposition of organic matter varies from 73.3 g C m⁻² a⁻¹ to 181 g C m⁻² a⁻¹. More than 30% of total soil organic carbon resides in the active carbon pool and 72.8%281.23% of total CO₂ emitted from organic matter decomposition results from the topsoil horizon (from 0 cm to 10 cm) for the Kobresia meadow. Responding to global warming, the storage, volume of flow and fate of the soil organic carbon in the alpine meadow ecosystem of the Tibetan Plateau will be changed, which needs further research. Supported by the National Natural Science Foundation of China (Grant Nos. 40231015, 40471120 and 40473002) and the Guangdong Provincial Natural Science Foundation of China (Grant No. 06300102)  相似文献   

安徽省地电监测能力综合评价     

何康  郑兆苾  刘泽民 《地震地磁观测与研究》2007,28(3):62-66

以影响地电观测质量的主要因素及映震能力作为地电台站监测能力的主要评价指标,对安徽省5个地电台站的监测能力进行了综合评价,得到了安徽省地电前兆的基本情况,为安徽省未来的地电台站建设奠定了基础.  相似文献   

基于高阶局部模态的弹性地基上框架结构物理参数识别研究     

易伟建  周云 《地震工程与工程振动》2007,27(1):117-124

利用框架结构的整体振动模态信息进行局部损伤的判别具有明显的局限性。高阶模态逐渐被人们认识并用来进行局部物理参数识别并用来进行损伤判别。本文以弹性地基上独立基础的框架结构底层柱为研究对象,利用增加的质量块对柱子进行局部损伤的制造,利用脉冲锤击法和激振器扫频实验进行高阶模态对比测试,利用PolyMAX模态分析方法进行损伤前后高阶模态的识别,发现了“高灵敏度高阶模态”的存在。最后通过两端约束Euler梁的计算模型,通过高阶模态来识别物理参数以及地基参数,其中物理参数结果具有较好的可靠性。  相似文献   

矿山人均保有储量:我国金属矿山合理经济开发的一个标量     

吕古贤  郭涛  武际春  韩屹  孙之夫  郑小礼  姜新强  赵可广 《地质找矿论丛》2007,22(2):81-86

文章分析对比了我国国有及非国有规模以上矿山企业的主要经济指标,认为矿业开发要走可持续发展的途径,促进矿产资源的充分、合理、有效开发,实现满足市场需求、兼顾环境保护和社会稳定的目标,就必须积极探索和慎重考虑矿山企业从业人数的合理控制问题;依据胶东大型金矿山实际资料的初步分析,明确提出"矿山人均保有储量"是制约矿山合理开发和矿业可持续发展的重要指标;矿山人均储量的合理配置和适度调控问题不仅值得进一步研究,而且应该引起有关部门的广泛注意和高度重视.  相似文献   

北秦岭二郎坪群重晶石岩热水沉积地球化学证据及其成矿意义   总被引：10，自引：0，他引：10  

冯胜斌  邢矿  周洪瑞  燕长海  彭翼  赵吉梅  胡绍斌  任建光 《世界地质》2007,26(2):199-207

北秦岭二郎坪群中存在与地层整合产出的层状重晶石岩和铜多金属矿床。重晶石岩贫Al2O3、TiO2组分含量;富集热液组分As、Sb、Ba、Ag和Hg;微量元素U/Th>1;低ΣREE(平均值27.78×10-6)、富集轻稀土(LREE)、亏损重稀土(HREE)、具明显Eu正异常、Ce负异常及与大西洋TAG热液区热液沉积物相似的球粒陨石标准化的稀土元素配分模式特征。这些特征揭示研究区重晶石岩是热水沉积成因型。热水沉积重晶石岩与铜多金属矿床的紧密联系说明,研究区铜金属矿床是海底热液喷流沉积成岩成矿作用的产物。  相似文献   

GDX-502树脂富集高效液相色谱法测定地表水中酚类化合物   总被引：2，自引：2，他引：2  

何淼  饶竹  苏劲  黄毅 《岩矿测试》2007,26(2):101-104

采用自制GDX-502固相萃取小柱萃取水中苯酚、对硝基酚、间甲酚、2，4-二氯酚、2，4，6-三氯酚、五氯酚等6种酚类化合物，以乙腈作为洗脱剂，选择280nm和290nm双波长紫外高效液相色谱进行检测。结果表明，方法检出限为0．01-0．05mg／L，IL水的平均加标回收率为82．5％-95．0％，精密度（RSD，n=7）为3．6％-9．2％。方法用于实际地表水中痕量酚类化合物的检测，操作简单，有机溶剂用量少，分析效率高；萃取小柱可多次重复使用，分析成本低。  相似文献   

青藏高原北部新生代湖相碳酸盐岩碳氧同位素特征及古环境意义   总被引：3，自引：2，他引：3  

伊海生  林金辉  周恳恳  李军鹏 《古地理学报》2007,9(3):303-312

对青藏高原北部地区新生代陆相地层中湖相碳酸盐岩进行了系统采样分析，以碳氧同位素作为古环境和古气候变化的替代指标,试图从古湖泊演化的角度，阐明高原新生代早期环境演变历史和过程。研究结果表明，该区所有分析样品中生物碎屑灰岩类样品的δ¹⁸O和δ¹³C显示最低值，反映它们沉积在一个水体滞留时间短的开放性淡水湖泊系统中。泥晶灰岩类样品的δ¹⁸O和δ¹³C之间具有正相关关系，表明它们发育在蒸发作用明显的封闭性咸水湖泊体系中，而叠层石灰岩类明显富集13C可能与微生物活动有关。从始新世到渐新世至中新世，湖相碳酸盐岩δ¹⁸O值具有逐渐增大的趋势，δ¹³C则由古近纪的负值变为新近纪的正值，反映该区古湖泊系统经历了一个由开放到封闭的过程，预示古近纪到新近纪之交高原古气候格局发生了重大变革。  相似文献   

水平电极发射光谱法测试多目标生态地球化学土壤样品中的钼     

郑瑞华 《福建地质》2007,26(2):126-130

以K2SO4、S粉、C粉、聚三氟氯乙烯粉、Al2O3、MgO混合物作为缓冲剂,以Sb为内标,电极发射光谱法测试多目标地球化学土壤样品中的钼。方法的检出限为0.28μg/g(3S),方法的精密度(RSD)为7.25%~8.66%。测试了国家一级地球化学标准物质,结果与标准值相符合。该方法已用于10000多件土壤样品的分析,并取得满意的结果。  相似文献   

Secondary hydrocarbon generation potential from heavy oil, oil sand and solid bitumen during the artificial maturation   总被引：1，自引：0，他引：1  

Qu Zhang  Haiping Huang  Lunjun Zheng  Jianzhong Qin 《Organic Geochemistry》2007,38(12):2024-2035

Secondary hydrocarbon generation potentials from natural bitumen, oil sand and heavy oil, representing different residual oil accumulations, were determined by artificial maturation in a closed pyrolysis system. Simulated results indicate that their thermal behavior and reactivity are similar to those of kerogen, and that they can generate hydrocarbons once subjected to suitable geological processes. Overall differences in oil and gas generation potentials among the samples result from differences in the chemical structure of precursor components, physical compaction status, and mineral matrices. Hydrogen rich precursors, such as oil sand and heavy oil, have greater potential to generate hydrocarbons than hydrogen poor ones. Naturally compacted oil sand has slightly higher conversion efficiency than artificially compacted heavy oil as indicated by lower residual bitumen content. However, total gas and liquid oil recovery from oil sand is lower than from heavy oil due to the poor release of pyrolytic products from well compacted and cemented networks in the experiments. Mineral matrices of previous oil deposits also affect further hydrocarbon generation potential. Carbonate matrices inhibit total oil and gas generation, which consequently retains high gas potential at the postmature stage. Traditional oil generation models mainly consider the thermal alteration of kerogen; this study provides supplemental information for superimposed basins where previous oil accumulations may have been destroyed and reburied to serve as secondary sources of oil and gas. Consideration of previous oil residues as potential source rock allows better estimates of available oil resources and the risks associated with their exploration.  相似文献