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41.
Tamer Coskun Asuman Yildirim Cigdem Balcik Neslihan Manav Demir Eyup Debik 《洁净——土壤、空气、水》2013,41(5):463-468
In the following study, two methods were employed in which olive mill wastewaters were treated by using reverse osmosis membranes (BW30 and XLE). In the first, wastewater was centrifuged and then passed through the reverse osmosis whereas in the second, an ultrafiltration was placed between the centrifuge and the reverse osmosis. The reverse osmosis experiments were conducted under 10, 15, 20, and 25 bar. The chemical oxygen demand (COD) removal efficiencies under 25 bar were found to be 97.5% for both BW30 and XLE membranes. The highest conductivity removal rates obtained under 25 bar for BW30 and XLE membranes were found to be 95.6 and 96.2%, respectively. As for the highest permeation flux values obtained under 25 bar, they were separately determined for BW30 and XLE as 15.3 and 21.2 L m?2 h?1, respectively. The performances of the membranes were also evaluated in terms of their mass transfer coefficients. According to this, all mass transfer coefficients were found to be <1 and also in proximate to one another; this clearly reflects the results as COD and conductivity removals were approximate and there was a lack of any significant difference, whether ultrafiltration was applied or not. 相似文献
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We combine a geological, geochemical and tectonic dataset from 118 ophiolite complexes of the major global Phanerozoic orogenic belts with similar datasets of ophiolites from 111 Precambrian greenstone belts to construct an overview of oceanic crust generation over 4 billion years. Geochemical discrimi- nation systematics built on immobile trace elements reveal that the basaltic units of the Phanerozoic ophiolites are dominantly subduction-related （75%）, linked to backarc processes and characterized by a strong MORB component, similar to ophiolites in Precambrian greenstone sequences （85%）. The remaining 25% Phanerozoic subduction-unrelated ophiolites are mainly （74%） of Mid-Ocean-Ridge type （MORB type）, in contrast to the equal proportion of RiftlContinental Margin, Plume, and MORB type ophiolites in the Precambrian greenstone belts. Throughout the Phanerozoic there are large geochemical variations in major and trace elements, but for average element values calculated in 5 bins of 100 million year intervals there are no obvious secular trends. By contrast, basaltic units in the ophiolites of the Precambrian greenstones （calculated in 12 bins of 250 million years intervals）, starting in late Paleo- to early Mesoproterozoic （ca. 2.0-1.8 Ga）, exhibit an apparent decrease in the average values of incom- patible elements such as Ti, P, Zr, Y and Nb, and an increase in the compatible elements Ni and Cr with deeper time to the end of the Archean and into the Hadean. These changes can be attributed to decreasing degrees of partial melting of the upper mantle from HadeanJArchean to Present. The onset of geochemical changes coincide with the timing of detectible changes in the structural architecture of the ophiolites such as greater volumes of gabbro and more common sheeted dyke complexes, and lesser occurrences of ocelli （varioles） in the pillow lavas in ophiolites younger than 2 Ga. The global data from the Precambrian ophiolites, representative of nearly 50% of all known worldwide greenston 相似文献
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Havvanur Kılıç Saadet Arzu Berilgen Perihan Biçer Mustafa Yildirim 《Marine Georesources & Geotechnology》2013,31(4):303-323
Istanbul, the largest city in Turkey and one of the major metropolitan areas in the world, cleaned one of its environmentally polluted areas—Golden Horn—by dredging 5 million m3 of the bottom sediments and pumping the resulting sludge to a storage area behind a dam built at an abandoned rock quarry site in Alibey district. The reclamation of the land that formed over the storage area of Golden Horn dredged material is socially and economically very desirable. In this paper, results from experimental studies that are focused on determining the shear strength behavior of the dredge material and undisturbed soil are presented. Slurry consolidometer test, large model tests and small model tests are used to consolidate the dredged soil samples from Halic to simulate the natural consolidation behavior of these soils. Shear strength parameters are determined by laboratory vane tests; unconfined compression tests; undrained-unconsolidated (UU) and consolidated-undrained (CU) triaxial tests on samples that are obtained through in situ undisturbed samples and laboratory model tank and slurry consolidation. Moreover, the effects of fly ash and lime additives on the undrained shear strength were determined by mixing the materials with the dredged clay from Golden Horn during the model experiments conducted in the laboratory. Based on these findings, equations are proposed that govern the relationships between undrained shear strength and water content value. 相似文献
45.
LIAN Dongyang YANG Jingsui Michael WIEDENBECK Yildirim DILEK Alexander ROCHOLL XIONG Fahui WU Weiwei 《《地质学报》英文版》2017,91(Z1):15-15
The Pozanti-Karsanti ophiolite(PKO)in Turkey’s eastern Tauride belt comprises mantle peridotites,ultramafic to mafic cumulates,isotropic gabbros,sheeted dikes and pillow lavas.The mantle peridotites are dominated by spinel harzburgites with minor dunites.The harzburgites and dunites have quite depleted mineral and whole-rock chemical composition,suggesting high degrees of partial melting.Their PGEs vary from Pd-depleted to distinct Pd-enriched patterns,implying the crystallization of interstitial sulphides from sulphur-saturated melts(e.g.MORB-like forearc basalt).U-shaped or spoon-shaped REE patterns indicate that the PKO peridotites may have also been metasomatized by the LREE-enriched fluids released from a subducting slab in a suprasubduction zone.Based on the mineral and whole-rock chemical compositions,the PKO peridotites show affinities to forearc peridotites.Chromitites occur both in the mantle peridotites and the mantle-crust transition zone horizon(MTZ).Chromitites from the two different horizons have different textures but similar mineral compositions,consistent with typical high-Cr chromitites.Chromitites hosted by mantle harzburgites generally have higher total platinum-group element(PGE)contents than those of the MTZ chromitites.However,both chromitites show similar chondritenormalized PGE patterns characterized by clear IPGEs,Rh-enrichments relative to Pt and Pd.Such PGE patterns indicate no or only minor crystallization of Pt-and Pd enriched sulphides during formation of chromitites from a sulphur-undersaturated melt(e.g.boninitic or island arc tholeiitic melt).Dunite enveloping chromitite lenses in the ho*s ting harzburgite resulted from melt-rock reaction.We have performed mineral separation work on samples of podiform chromitite hosted by harzburgites.So far,more than200 grains of microdiamond and more than 100 grains of moissanite(Si C)have been separated from podiform chromitites.These minerals have been identified by EDX and Laser Raman analyses.The diamonds and moissanite are accompanied by large amounts of rutile.Additionally,zircon,monazite and sulphides are also common phases within the heavy mineral separates.Both diamond and moissanite have been analyzed for carbon and nitrogen isotopic composition using the CARMECA 1280-HR large geometry Secondary Ion Mass Spectrometer at the Helmholtz Zentrum Potsdam.In total,61δ13CPDB results for diamond were acquired,exhibiting a range from-28.4‰to-18.8‰.31δ13CPDB results for Moissanite vary between-30.5‰to-27.2‰,with a mean value of-29.0‰.Diamond has relatively large variation in nitrogen isotopic composition with 40δ15NAIR results ranging from-19.1‰to 16.6‰.The discovery of diamond,moissanite and the other unusual minerals from podiform chromitite of the Pozanti-Karsanti ophiolite provides new support for the genesis of ophiolitic peridotites and chromitites under high-pressure and ultra-high reducing conditions.Considering the unusual minerals,the high Mg#silicate inclusions,and the needle-shaped exsolutions in the PKO chromitites,the parental melts of these chromitites may have been mixed with deep asthenospheric basaltic melts that had assimilated materials of the descending slab when passing through the slab in a subduction zone environment.We suggest melt-rock reactions,magma mixing and assimilation may have triggered the oversaturation of chromites and the formation of PKO chromitites. 相似文献
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Diamonds Discovered from High–Cr Podiform Chromitites of Bulqiza, Eastern Mirdita Ophiolite, Albania
XIONG Fahui YANG Jingsui ROBINSON Paul T. DILEK Yildirim MILUSHI Ibrahim XU Xiangzhen ZHOU Wen ZHANG Zhongming RONG He 《《地质学报》英文版》2017,91(2):455-468
Various combinations of diamond, moissanite, zircon, corundum, rutile and titanitehave been recovered from the Bulqiza chromitites. More than 10 grains of diamond have been recovered, most of which are pale yellow to reddish–orange to colorless. The grains are all 100–300 μm in size and mostly anhedral, but with a range of morphologies including elongated, octahedral and subhedral varieties. Their identification was confirmed by a characteristic shift in the Raman spectra between 1325 cm~(-1) and 1333 cm~(-1), mostly at 1331.51 cm~(-1) or 1326.96 cm~(-1). This investigation extends the occurrence of diamond and moissanite to the Bulqiza chromitites in the Eastern Mirdita Ophiolite. Integration of the mineralogical, petrological and geochemical data of the Bulqiza chromitites suggests their multi–stage formation. Magnesiochromite grains and perhaps small bodies of chromitite formed at various depths in the upper mantle, and encapsulated the ultra–high pressure, highly reduced and crustal minerals. Some oceanic crustal slabs containing the magnesiochromite and their inclusion were later trapped in suprasubduction zones, where they were modified by tholeiitic and boninitic arc magmas, thus changing the magnesiochromite compositions and depositing chromitite ores in melt channels. 相似文献
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Structural and geomorphological aspects of the Kat landslides (Tokat—Turkey) and susceptibility mapping by means of GIS 总被引：3，自引：0，他引：3
Kat County, which is located in a slope of hilly region and constructed in the side of a mountain along the North Anatolian Fault Zone, is frequently subject to landslides. The slides occur during periods of heavy rainfall, and these events cause destruction to property, roads, agricultural lands and buildings. In the last few decades, a lot of houses and buildings have been damaged and destroyed. Settlement areas have remained evacuated for a long time. The slope instabilities in the study area are a complex landslide extending from north to south containing a lot of landslides. Field investigations, interpretation of aerial photography, analyses of geological data and laboratory tests suggest that some factors have acted together on the slopes to cause the sliding. In the wet season, the slopes became saturated. As the saturation of the earth material on the slope causesa rise in water pressure, the shear strength (resisting forces) decreases and the weight (driving forces) increases; thus, the net effect was to lower the safety factor. Previous failures have affected the rock mass, leading to the presence of already sheared surfaces at residual strengths. The relation between the joint planes and the instability of the slope in the study area was discussed and it was found that the potential slope instabilities are mainly in the directions of NW–SE, NE–SW and N–S. The landslide susceptibility map obtained by using the geographical information system showed that a large area is susceptible and prone to landslides in the northern part of the study area.An erratum to this article can be found at 相似文献
48.
Counterclockwise P-T-t trajectory from the metamorphic sole of a Neo-Tethyan ophiolite (Turkey) 总被引：2，自引：0，他引：2
The Kiziltepe ophiolitic thrust sheet in the Bolkar Mountains of Turkey occurs between two subparallel ophiolite belts bounding the Tauride carbonate platform and represents a remnant of the Cretaceous Neo-Tethyan oceanic lithosphere. It is underlain by foliated amphibolite that represents a metamorphic sole developed at the inception of an intra-oceanic subduction zone in the Neo-Tethys 92-90 Ma. Blueschist-facies overprinting of the amphibolite indicates that the metamorphic sole was dragged deeper into the subduction zone where it experienced increasing P/T with cooling. Regional tectonic constraints suggest a Maastrichtian age for the timing of this blueschist-facies metamorphism. Sodic amphibole-rich veins and crossite/Mg-riebeckite rims on hornblende suggest that growth of blueschist-facies minerals was facilitated by infiltration of fluid along fractures and grain boundaries. We infer a counterclockwise P-T-t trajectory during which metamorphism was accompanied/succeeded by rapid uplift along the northern edge of the Tauride belt in Late Cretaceous-early Tertiary time. 相似文献
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The Late Ordovician Solund-Stavfjord ophiolite in western Norway represents a remnant of the Iapetus oceanic lithosphere that developed in a Caledonian marginal basin. The ophiolite contains three structural domains that display distinctively different crustal architecture that reflects the mode and nature of magmatic and tectonic processes operated during the multi-stage seafloor spreading evolution of this marginal basin. Domain I includes, from top to bottom, an extensive extrusive sequence, a transition zone consisting of dike swarms with screens of pillow breccias, a sheeted dike complex, and plutonic rocks composed mainly of isotropic gabbro and microgabbro. Extrusive rocks include pillow lavas, pillow breccias, and massive sheet flows and are locally sheared and mineralized, containing epidosites, sulfide-sulfate deposits, Fe-oxides, and anhydrite veins, reminiscent of hydrothermal alteration zones on the seafloor along modern mid-ocean ridges. A fossil lava lake in the northern part of the ophiolite consists of a >65-m-thick volcanic sequence composed of a number of separate massive lava units interlayered with pillow lavas and pillow breccia horizons. The NE-trending sheeted dike complex contains multiple intrusions of metabasaltic dikes with one- and two-sided chilled margins and displays a network of both dike-parallel normal and dike-perpendicular oblique-slip faults of oceanic origin. The dike-gabbro boundary is mutually intrusive and represents the root zone of the sheeted dike complex. The internal architecture and rock types of Domain I are analogous to those of intermediate-spreading oceanic crust at modern mid-ocean ridge environments. The ophiolitic units in Domain II include mainly sheeted dikes and plutonic rocks with a general NW structural grain and are commonly faulted against each other, although primary intrusive relations between the sheeted dikes and the gabbros are locally well preserved. The exposures of this domain occur only in the northern and southern parts of the ophiolite complex and are separated by the ENE-trending Domain III, in which isotropic to pegmatitic gabbros and dike swarms are plastically deformed along ENE-striking sinistral shear zones. These shear zones, which locally include fault slivers of serpentinite intrusions, are crosscut by N20°E-striking undeformed basaltic dike swarms that contain xenoliths of gabbroic material. The NW-trending sheeted dike complex in the northern part of Domain II curves into an ENE orientation approaching Domain III in the south. The anomalous nature of deformed crust in Domain III is interpreted to have developed within an oceanic fracture zone or transform fault boundary.REE chemistry of representative extrusive and dike rocks from all three domains indicates N- to E-MORB affinities of their magmas with high Th/Ta ratios that are characteristic of subduction zone environments. The magmatic evolution of Domain I encompasses closed-system fractional crystallization of high-Mg basaltic magmas in small ephemeral chambers, which gradually interconnected to form large chambers in which mixing of primary magmas with more evolved and fractionated magma caused resetting of magma compositions through time. The compositional range from high-Mg basalts to ferrobasalts within Domain I is reminiscent of modern propagating rift basalts. We interpret the NE-trending Domain I as a remnant of an intermediate-spread rift system that propagated northeastwards (in present coordinate system) into a pre-existing oceanic crust, which was developed along the NW-trending doomed rift (Domain II) in the marginal basin. The N20°E dikes laterally intruding into the anomalous oceanic crust in Domain III represent the tip of the rift propagator. The inferred propagating rift tectonics of the Solund-Stavfjord ophiolite is similar to the evolutionary history of the modern Lau back-arc basin in the SW Pacific and suggests a complex magmatic evolution of the Caledonian marginal basin via multi-stage seafloor spreading tectonics. 相似文献
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Guram S. Zakariadze Yildirim Dilek S.A. Adamia R.E. Oberhnsli S.F. Karpenko B.A. Bazylev N. Solov'eva 《Gondwana Research》2007,11(1-2):92
The Transcaucasian Massif (TCM) in the Republic of Georgia includes Neoproterozoic–Early Cambrian ophiolites and magmatic arc assemblages that are reminiscent of the coeval island arc terranes in the Arabian–Nubian Shield (ANS) and provides essential evidence for Pan-African crustal evolution in Western Gondwana. The metabasite–plagiogneiss–migmatite association in the Oldest Basement Unit (OBU) of TCM represents a Neoproterozoic oceanic lithosphere intruded by gabbro–diorite–quartz diorite plutons of the Gray Granite Basement Complex (GGBC) that constitute the plutonic foundation of an island arc terrane. The Tectonic Mélange Zone (TMZ) within the Middle-Late Carboniferous Microcline Granite Basement Complex includes thrust sheets composed of various lithologies derived from this arc-ophiolite assemblage. The serpentinized peridotites in the OBU and the TMZ have geochemical features and primary spinel composition (0.35) typical of mid-ocean ridge (MOR)-type, cpx-bearing spinel harzburgites. The metabasic rocks from these two tectonic units are characterized by low-K, moderate-to high-Ti, olivine-hypersthene-normative, tholeiitic basalts representing N-MORB to transitional to E-MORB series. The analyzed peridotites and volcanic rocks display a typical melt-residua genetic relationship of MOR-type oceanic lithosphere. The whole-rock Sm–Nd isotopic data from these metabasic rocks define a regression line corresponding to a maximum age limit of 804 ± 100 Ma and εNdint = 7.37 ± 0.55. Mafic to intermediate plutonic rocks of GGBC show tholeiitic to calc-alkaline evolutionary trends with LILE and LREE enrichment patterns, Y and HREE depletion, and moderately negative anomalies of Ta, Nb, and Ti, characteristic of suprasubduction zone originated magmas. U–Pb zircon dates, Rb–Sr whole-rock isochron, and Sm–Nd mineral isochron ages of these plutonic rocks range between 750 Ma and 540 Ma, constraining the timing of island arc construction as the Neoproterozoic–Early Cambrian. The Nd and Sr isotopic ratios and the model and emplacement ages of massive quartz diorites in GGBC suggest that pre-Pan African continental crust was involved in the evolution of the island arc terrane. This in turn indicates that the ANS may not be made entirely of juvenile continental crust of Neoproterozoic age. Following its separation from ANS in the Early Paleozoic, TCM underwent a period of extensive crustal growth during 330–280 Ma through the emplacement of microcline granite plutons as part of a magmatic arc system above a Paleo-Tethyan subduction zone dipping beneath the southern margin of Eurasia. TCM and other peri-Gondwanan terranes exposed in a series of basement culminations within the Alpine orogenic belt provide essential information on the Pan-African history of Gondwana and the rift-drift stages of the tectonic evolution of Paleo-Tethys as a back-arc basin between Gondwana and Eurasia. 相似文献