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Strontium isotope ratios and rare-earth element abundances have been measured in acid, intermediate and basic rocks from three late to postglacial volcanic complexes, and several other postglacial basalts in Iceland. Late and postglacial basalts in Iceland have been generated from a source region which is essentially homogeneous with respect to87Sr/86Sr. The mean87Sr/86Sr ratio for the basalts analysed is 0.70328 and the range is from 0.70317 ± 6to0.70334 ± 5 (2σ).Acid rocks from the Kerlinganfjöll and Namafjall volcanic complexes have87Sr/86Sr ratios which are indistinguishable from analysed basalts from the same complexes. However, intermediate and acid rocks from the Torfajökull complex have significantly higher87Sr/86Sr ratios and could not have been derived by fractional crystallization from basaltic magmas similar to those found in the same complex. These latter rocks have most probably been produced by remelting of Tertiary gabbroic rocks in Layer 3. Most of the basalts analysed have higher total rare-earth element abundances than typical dredged ocean-ridge tholeiites, and show less light rare-earth depletion. Intermediate and acid compositions show overall higher abundances and light rare-earth enrichments. The measured rare-earth abundances are compared with abundances generated by differential partial melting of various model source regions.It is shown that both the tholeiitic and alkali basalt compositions could be generated from the same source material by different degrees of partial melting. Variable partial melting of gabbroic material may account for the rare-earth element abundances of both the rhyolitic rocks (small degrees of melting) and the intermediate rocks (more extensive melting).  相似文献   
34.
A new complex earth system model consisting of an atmospheric general circulation model, an ocean general circulation model, a three-dimensional ice sheet model, a marine biogeochemistry model, and a dynamic vegetation model was used to study the long-term response to anthropogenic carbon emissions. The prescribed emissions follow estimates of past emissions for the period 1751–2000 and standard IPCC emission scenarios up to the year 2100. After 2100, an exponential decrease of the emissions was assumed. For each of the scenarios, a small ensemble of simulations was carried out. The North Atlantic overturning collapsed in the high emission scenario (A2) simulations. In the low emission scenario (B1), only a temporary weakening of the deep water formation in the North Atlantic is predicted. The moderate emission scenario (A1B) brings the system close to its bifurcation point, with three out of five runs leading to a collapsed North Atlantic overturning circulation. The atmospheric moisture transport predominantly contributes to the collapse of the deep water formation. In the simulations with collapsed deep water formation in the North Atlantic a substantial cooling over parts of the North Atlantic is simulated. Anthropogenic climate change substantially reduces the ability of land and ocean to sequester anthropogenic carbon. The simulated effect of a collapse of the deep water formation in the North Atlantic on the atmospheric CO2 concentration turned out to be relatively small. The volume of the Greenland ice sheet is reduced, but its contribution to global mean sea level is almost counterbalanced by the growth of the Antarctic ice sheet due to enhanced snowfall. The modifications of the high latitude freshwater input due to the simulated changes in mass balance of the ice sheet are one order of magnitude smaller than the changes due to atmospheric moisture transport. After the year 3000, the global mean surface temperature is predicted to be almost constant due to the compensating effects of decreasing atmospheric CO2 concentrations due to oceanic uptake and delayed response to increasing atmospheric CO2 concentrations before.  相似文献   
35.
We report on dust measurements obtained during the seventh orbit of the Galileo spacecraft about Jupiter. The most prominent features observed are highly time variable dust streams recorded throughout the Jovian system. The impact rate varied by more than an order of magnitude with a 5 and 10 hour periodicity, which shows a correlation with Galileo's position relative to the Jovian magnetic field. This behavior can be qualitatively explained by strong coupling of nanometer-sized dust to the Jovian magnetic field. In addition to the 5 and 10 h periodicities, a longer period which is compatible with Io's orbital period is evident in the dust impact rate. This feature indicates that Io most likely is the source of the dust streams. During a close (3,095 km altitude) flyby at Ganymede on 5 April 1997 an enhanced rate of dust impacts has been observed, which suggests that Ganymede is a source of ejecta particles. Within a distance of about 25 RJ(Jupiter radius, RJ= 71,492 km) from Jupiter impacts of micrometer-sized particles have been recorded which could be particles on bound orbits about Jupiter. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
36.
From wind profile and wave measurements performed during the JONSWAP II experiment, relations between the dimensionless profile slope and the significant wave height are derived. It is shown that the wind profile is distorted by the waves especially in the vicinity of the water surface. The wave influence on the profile seems to be restricted to heights below about three wave heights. Above this level, the dimensionless profile slope is an approximately constant value corresponding to a drag coefficient of about 1.15 × 10–3.  相似文献   
37.
Rb-Sr whole-rock and mineral analyses are reported from Early Paleozoic sediments of the southern rim of the French Central Massif (Montagne Noire). The sediments—mainly pelites, silt- and sandstones—can be separated into three different zones (A, B, and C) according to their varying degrees of deformation and transformation, which took place during the Hercynian (= Variscan) orogeny (Carboniferous). For the least deformed, folded but not schistose, fossiliferous Lower Ordovician sediments (zone A), a scatter of the data points resulted, at least partly due to the varying amount of detrital muscovites, which did not equilibrate their Sr isotopes with those of the clay minerals. Fossiliferous Middle Cambrian sediments (zone B), however, are colinear in an isochron plot. The rocks are also folded, and show a beginning schistosity in the pelitic layers. The age of 333±16 m.y. therefore does not correspond to the time of sedimentation, as one would expect from most of the interpretations given in the literature. It is, however, in close agreement with the stratigraphically known time of folding and anchimetamorphism. The same result, within analytical error, of 326±17 m.y. was obtained for Lower Ordovician sediments (zone C), which show a schistosity not only in the pelites but also in some psammitic layers. As for the sediments of zone B, this result indicates open whole-rock systems for Rb and/or Sr during folding and anchimetamorphism. Minerals extracted from psammites of zones B and C gave the following results: albite coincides with the isochrons; detrital muscovites do not coincide and yield ages of about 650 m.y. (Cadomian orogeny) for both zone B and C sediments; detrital chlorites from zone B sediments seem to be only partly reset by anchimetamorphism and therefore plot closer to the whole-rock isochron. From this it must be concluded that an increasing amount of these detrital micas could significantly shift the position of the total-rock points, as might be the case for zone A sediments. From the whole-rock results of zone B and C sediments and the mineralogical and petrological changes during diagenesis and anchimetamorphism we conclude that many of the isochrons obtained from stratigraphically uncontrollable Precambrian sediments should be reinterpreted in favour of metamorphic and not sedimentary ages, especially if the metamorphism reached greenschist facies conditions. Devonian and Cambrian limestones intercalated between the pelites, silstones and sandstones contain Sr of a variable and slightly radiogenic isotopic composition in contrast to the expected ancient sea water Sr. This fact is interpreted again in favour of open whole-rock systems during the postdepositional history of the rock, rather than primary scatter of ancient, radiogenic sea water Sr.  相似文献   
38.
The noble gases He, Ne, Ar, Kr and Xe and also K and Ba were measured in the Apollo 11 igneous rocks 10017 and 10071, and in an ilmenite and two feldspar concentrates separated from rock 10071. Whole rock K/Ar ages of rocks 10017 and 10071 are (2350 ± 60) × 106 yr and (2880 ± 60) × 106 yr, respectively. The two feldspar concentrates of rock 10071 have distinctly higher ages: (3260 ± 60) × 106 yr and (3350 ± 70) × 106 yr. These ages are still 10 per cent lower than the Rb/Sr age obtained by Papanastassiouet al. (1970) and some Ar40 diffusion loss must have occurred even in the relatively coarse-grained feldspar.The relative abundance patterns of spallation Ne, Ar, Kr and Xe are in agreement with the ratios predicted from meteoritic production rates. However, diffusion loss of spallation He3 is evident in the whole rock samples, and even more in the feldspar concentrates. The ilmenite shows little or no diffusion loss. The isotopic composition of spallation Kr and Xe is similar to the one observed in meteorites. Small, systematic differences in the spallation Kr spectra of rocks 10017 and 10071 are due to variations in the irradiation hardness (shielding). The Kr spallation spectra in the mineral concentrates are different from the whole rock spectra and also show individual variations, reflecting the differences in target element composition. The relative abundance of cosmic ray produced Xe131 differs by nearly 50 per cent in the two rocks. The other Xe isotopes show no variations of similar magnitude. The origin of the Xe131 yield variability is discussed.Kr81 was measured in all the samples investigated. The Kr81/Kr exposure ages of rocks 10017 and 10071 are (480 ± 25) × 106 yr and (350 ± 15) × 106 yr, respectively. Exposure ages derived from spallation Ne21, Ar38, Kr83 and Xe126 are essentially in agreement with the Kr81/Kr ages. The age of rock 10071 might be somewhat low because of a possible recent exposure of our sample to solar flare particles.  相似文献   
39.
An interaction of dissolved natural organic matter (DNOM) with copper ions in the water column of the stratified Krka River estuary (Croatia) was studied. The experimental methodology was based on the differential pulse anodic stripping voltammetric (DPASV) determination of labile copper species by titrating the sample using increments of copper additions uniformly distributed on the logarithmic scale. A classical at-equilibrium approach (determination of copper complexing capacity, CuCC) and a kinetic approach (tracing of equilibrium reconstitution) of copper complexation were considered and compared. A model of discrete distribution of organic ligands forming inert copper complexes was applied. For both approaches, a home-written fitting program was used for the determination of apparent stability constants (Kiequ), total ligands concentration (LiT) and association/dissociation rate constants (ki1,ki- 1).A non-conservative behaviour of dissolved organic matter (DOC) and total copper concentration in a water column was registered. An enhanced biological activity at the freshwater–seawater interface (FSI) triggered an increase of total copper concentration and total ligand concentration in this water layer. The copper complexation in fresh water of Krka River was characterised by one type of binding ligands, while in most of the estuarine and marine samples two classes of ligands were identified. The distribution of apparent stability constants (log K1equ: 11.2–13.0, log K2equ:8.8–10.0) showed increasing trend towards higher salinities, indicating stronger copper complexation by autochthonous seawater organic matter.Copper complexation parameters (ligand concentrations and apparent stability constants) obtained by at-equilibrium model are in very good accordance with those of kinetic model. Calculated association rate constants (k11:6.1–20 × 103 (M s)− 1, k21: 1.3–6.3 × 103 (M s)− 1) indicate that copper complexation by DNOM takes place relatively slowly. The time needed to achieve a new pseudo-equilibrium induced by an increase of copper concentration (which is common for Krka River estuary during summer period due to the nautical traffic), is estimated to be from 2 to 4 h.It is found that in such oligotrophic environment (dissolved organic carbon content under 83 µMC, i.e. 1 mgCL− 1) an increase of the total copper concentration above 12 nM could enhance a free copper concentration exceeding the level considered as potentially toxic for microorganisms (10 pM).  相似文献   
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