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141.
Boonyatumanond R Wattayakorn G Amano A Inouchi Y Takada H 《Marine pollution bulletin》2007,54(5):554-565
This paper reports the first reconstruction of a pollution history in tropical Asia from sediment cores. Four sediment core samples were collected from an offshore transect in the upper Gulf of Thailand and were analyzed for organic micropollutants. The cores were dated by measurement of (137)Cs and geochronometric molecular markers (linear alkylbenzenes, LABs; and tetrapropylene-type alkylbenzenes, TABs). Polychlorinated biphenyl (PCB) concentrations showed a subsurface maximum in layers corresponding to the 1970s, indicating the effectiveness of regulation of PCBs in Thailand. LAB concentrations increased over time, indicating the increase in input of sewage into the Gulf during the last 30 years. Hopanes, biomarkers of petroleum pollution, also increased over time, indicating that the inputs of automobile-derived hydrocarbons to the coastal zone has been increasing owing to the increased number of cars in Thailand since the 1950s. Polycyclic aromatic hydrocarbons (PAHs) increased in the layers corresponding to the 1950s and 1960s, probably because of the increased inputs of automobile-derived PAHs. PAH concentrations in the upper layers corresponding to the 1970s and later remained constant or increased. The absence of a subsurface maximum of PAHs contrasts with results observed in industrialized countries. This can be explained by the facts that the Thai economy did not depend on coal as an energy source in the 1960s and that economic growth has continued since the 1970s to the present. The deposition flux of PAHs and hopanes showed a dramatic offshore decrease, whereas that of LABs was uniform. 相似文献
142.
Occurrence and seasonal variations of algal toxins in water, phytoplankton and shellfish from North Stradbroke Island, Queensland, Australia 总被引:4,自引:0,他引:4
Takahashi E Yu Q Eaglesham G Connell DW McBroom J Costanzo S Shaw GR 《Marine environmental research》2007,64(4):429-442
A number of marine microalgae are known to produce toxins that can accumulate in shellfish and when eaten, lead to toxic and potentially fatal reactions in humans. This paper reports on the occurrence and seasonal variations of algal toxins in the waters, phytoplankton and shellfish of Southeast Queensland, Australia. These algal toxins include okadaic acid (OA), domoic acid (DA), gymnodimine (GD), pectenotoxin-2 (PTX-2) and pectenotoxin-2-seco acid (PTX-2-SA), which were detected in the sampled shellfish and phytoplankton, via HPLC-MS/MS. Dissolved OA, PTX-2 and GD were also detected in the samples collected from the water column. This was the first occasion that DA and GD have been reported in shellfish, phytoplankton and the water column in Queensland waters. Phytoplankton tows contained both the toxic Dinophysis and Pseudo-nitzschia algae species, and are suspected of being the most likely producers of the OA, PTX-2s and DA found in shellfish of this area. The number of cells, however, did not correlate with the amount of toxins present in either shellfish or phytoplankton. This indicates that toxin production by algae varies with time and the species present and that number of cells alone cannot be used as an indicator for the presence of toxins. The presence of OA and PTX-2s were more frequently seen in the summer, while DA and GD were detected throughout the year and without any obvious seasonal patterns. 相似文献
143.
M. Chernyakova A. Neronov F. Aharonian Y. Uchiyama T. Takahashi 《Monthly notices of the Royal Astronomical Society》2009,397(4):2123-2132
PSR B1259−63 is a 48-ms radio pulsar in a highly eccentric 3.4-yr orbit with a Be star SS 2883. Unpulsed γ-ray, X-ray and radio emission components are observed from the binary system. It is likely that the collision of the pulsar wind with the anisotropic wind of the Be star plays a crucial role in the generation of the observed non-thermal emission. The 2007 periastron passage was observed in unprecedented details with Suzaku , Swift , XMM–Newton and Chandra missions. We present here the results of this campaign and compare them with previous observations. With these data we are able, for the first time, to study the details of the spectral evolution of the source over a 2-month period of the passage of the pulsar close to the Be star. New data confirm the pre-periastron spectral hardening, with the photon index reaching a value smaller than 1.5, observed during a local flux minimum. If the observed X-ray emission is due to the inverse Compton (IC) losses of the 10-MeV electrons, then such a hard spectrum can be a result of Coulomb losses, or can be related to the existence of the low-energy cut-off in the electron spectrum. Alternatively, if the X-ray emission is a synchrotron emission of very high-energy electrons, the observed hard spectrum can be explained if the high-energy electrons are cooled by IC emission in Klein–Nishina regime. Unfortunately, the lack of simultaneous data in the TeV energy band prevents us from making a definite conclusion on the nature of the observed spectral hardening and, therefore, on the origin of the X-ray emission. 相似文献
144.
145.
Yoko KEBUKAWA Satoru NAKASHIMA Takahiro OTSUKA Keiko NAKAMURA‐MESSENGER Michael E. ZOLENSKY 《Meteoritics & planetary science》2009,44(4):545-557
Abstract— Organic contamination (?2965 and ?1260 cm?1peaks) was found on Tagish Lake (C2) and Murchison (CM2) carbonaceous chondrites containing abundant hydrous minerals by Fourier transform infrared (FTIR) microspectroscopy on the samples pressed on Al plates. On the other hand, anhydrous chondrite (Moss, CO3) was not contaminated. This contamination occurred within one day of storage, when the samples pressed on Al were stored within containers including silicone rubber mats. Volatile molecules having similar peaks to the contaminants were detected by long‐path gas cell FTIR measurements for the silicone rubber mat. Rapid adsorption of the volatile contaminants also occurred when silica gel and hydrous minerals such as serpentine were stored in containers including silicone rubber, silicone grease, or adhesive tape. However, they did not show any contamination when stored in glass and polystyrene containers without these compounds. Therefore, precious astronomical samples such as meteorites, interplanetary dust particles (IDPs), and mission‐returned samples from comets, asteroids, and Mars, should be measured by micro FTIR within one day of storage in glass containers without silicone rubber, silicone grease, or adhesive tape. 相似文献
146.
147.
Kazuya Tanaka Yoshio Takahashi Kenji Horie Hiroshi Shimizu Takashi Murakami 《Physics and Chemistry of Minerals》2010,37(4):249-254
We examined the LIII-edge Pb X-ray absorption near-edge structure (XANES) of three natural zircon samples with different amounts of radiation
doses (1.9 × 1015 to 6.8 × 1015 α-decay events/mg). The results suggest that the oxidation state of radiogenic Pb in the zircon sample with the highest radiation
dose is divalent. The XANES spectra of the two other samples with lower radiation doses suggest that radiogenic Pb(II) is
present, and further that some Pb may be tetravalent. This is the first work on the determination of the oxidation state of
radiogenic Pb in natural zircon using XANES. 相似文献
148.
Yoko KEBUKAWA Satoru NAKASHIMA Michael E. ZOLENSKY 《Meteoritics & planetary science》2010,45(1):99-113
Abstract– To evaluate kinetic parameters for thermal degradation of organic matter, in situ heating experiments of insoluble organic matter (IOM) and bulk of Murchison (CM2) meteorite were conducted under Fourier transform infrared micro‐spectroscopy combined with a heating stage. Decreases of aliphatic C–H band area under Ar flow were well fitted with Ginstling‐Brounshtein three‐dimensional diffusion model, and the rate constants for decreases of aliphatic C–H were determined. Activation energies Ea and frequency factors A obtained from these rate constants at different temperatures using the Arrhenius equation were Ea = 109 ± 3 kJ mol?1 and A = 8.7 × 104 s?1 for IOM, and Ea = 61 ± 6 kJ mol?1 and A = 3.8 s?1 for bulk, respectively. Activation energy values of aliphatic C–H decrease are larger for IOM than bulk. Hence, the mineral assemblage of the Murchison meteorite might have catalytic effects for the organic matter degradation. Using obtained kinetic expressions, the time scale for metamorphism can be estimated for a given temperature with aliphatic C–H band area, or the temperature of metamorphism can be estimated for a given time scale. For example, using the obtained kinetic parameters of IOM, aliphatic C–H is lost approximately within 200 years at 100 °C and 100 Myr at 0 °C. Assuming alteration period of 7.5 Myr, alteration temperatures could be calculated to be <15 ± 12 °C. Aliphatic C–H decrease profiles in a parent body can be estimated using time–temperature history model. The kinetic expression obtained by the infrared spectral band of aliphatic C–H could be used as an alternative method to evaluate thermal processes of organic matter in carbonaceous chondrites. 相似文献
149.
Yoko Shibamoto Koh Harada 《Deep Sea Research Part I: Oceanographic Research Papers》2010,57(2):163-174
We investigated biogenic silica, several biological components, and silicate in pore-water in the abyssal sediment to determine silicon flux of western North Pacific during several cruises. The surficial sediment biogenic silica content was high at high latitudes with the boundary running along the Kuroshio Extension, and maximum values (exceeding 20%) were found in the Oyashio region. In the subtropical region to the south, most stations showed less than 5% biogenic silica content. This distribution pattern reflected primary production and ocean currents in the surface layer very well. Pore-water samples were collected from 4 stations along the east coast of Japan. The highest asymptotic silicic acid concentration (670 μmol L?1) in pore-water was observed at the junction of Kuroshio and Oyashio, followed by samples from the Oyashio region. It is at the southern station that the lowest value (450 μmol L?1) was observed, and the primary production is low under the influence of Kuroshio there. The diffusive flux followed the same geographic trend as the asymptotic silicic acid concentrations did, ranging 77–389 mmol m?2 yr ?1. Multiple sampling of pore-water was conducted throughout the year at one station at high latitude. The average annual biogenic silica rain flux observed using sediment traps was 373 mmol m?2 yr?1; the diffusive flux and burial flux at the sediment–water interface were 305 and 9 mmol m?2 yr?1, respectively. We concluded that most of the settling silica particles dissolved and diffused at the sediment–water interface and approximately 3% only were preserved in this area. In addition, the obvious time lag observed between the peak rain flux and the maximum diffusive flux suggested that primary production in the surface layer has a great influence on the sedimentation environment of abyssal western North Pacific. These transitions of Si flux at the sediment–water interface were considerably greater in northwestern North Pacific than in southwestern North Pacific. In addition, a station in the Philippine Sea indicated high biogenic silica content because of Ethmodiscus ooze, which are scattered randomly on the sea floor in the subtropical region. 相似文献
150.
Runup data in Biak Island and itsnearby islets are described with discussions oftsunami magnitude and a few characteristics such aswitnessed arrival times, wave periods and wavenumbers. From an engineering viewpoint, a relationbetween inundation depth and current velocity on landis also described with relations between inundationdepth and degree of damage to houses and between sanderosion depth and current velocity in backshoreregion, based on data collected from the present andpast tsunamis. 相似文献