Study on the kinetics of iron oxide leaching by oxalic acid   总被引：2，自引：0，他引：2  

Suong Oh Lee  Tam Tran  Yi Yong Park  Seong Jun Kim  Myong Jun Kim   《International Journal of Mineral Processing》2006,80(2-4):144-152

The presence of iron oxides in clay or silica raw materials is detrimental to the manufacturing of high quality ceramics. Although iron has been traditionally removed by physical mineral processing, acid washing has been tested as it is more effective, especially for extremely low iron (of less than 0.1% w/w). However, inorganic acids such as sulphuric or hydrochloric acids easily contaminate the clay products with SO₄²⁻ and Cl⁻, and therefore should be avoided as much as possible. On the other hand, if oxalic acid is used, any acid left behind will be destroyed during the firing of the ceramic products. The characteristics of dissolution of iron oxides were therefore investigated in this study.The dissolution of iron oxides in oxalic acid was found to be very slow at temperatures within the range 25–60 °C, but its rate increases rapidly above 90 °C. The dissolution rate also increases with increasing oxalate concentration at the constant pH values set within the optimum range of pH2.5–3.0. At this optimum pH, the dissolution of fine pure hematite (Fe₂O₃) (105–140 μm) follows a diffusion-controlled shrinking core model. The rate expression expressed as 1 − (2 / 3)x − (1 − x)^2 / 3 where x is a fraction of iron dissolution was found to be proportional to [oxalate]^1.5.The addition of magnetite to the leach liquor at 10% w/w hematite was found to enhance the dissolution rate dramatically. Such addition of magnetite allows coarser hematite in the range 0.5–1.4 mm to be leached at a reasonable rate.  相似文献   

藏西北三岔口地区泥瓮系生物礁特征及其意义          下载免费PDF全文

夏军钟华明  童劲松鲁如魁 《沉积与特提斯地质》2006,26(2):34-41

在羌塘西部的三岔口一带泥盆系拉竹龙组中发现规模较大的生物礁——台地前缘礁。下层礁体厚7．28m，上层礁体厚40.98m。两个礁体均为叠置礁，礁体由礁基、礁核、礁顶组成。剖面显示发育有礁前垮塌角砾、礁格架、礁间及礁后环境。泥盆纪生物礁的发现为羌塘盆地寻找油气资源提供了新思路。  相似文献   

CQK-50型车载化钻机的研制          下载免费PDF全文

孙建华赵海涛  张阳明王德平刘秀美  张永勤 《探矿工程》2006,33(11):41-44

在分析研究小型地质车载钻机的形式、功能与特点的基础上，提出了钻机车载化的新思路。根据地质调查工作现状，结合国内现有小型地质取样钻机，研制了CQK-50型全液压多功能车载取样钻机，并在野外物化探遥感异常验证钻探中取得了良好效果。  相似文献   

重力取样器取样技术研究          下载免费PDF全文

毛志新  刘宝林  夏柏如 《探矿工程》2006,33(2):52-53,62

在湖泊环境研究中，淤泥质沉积物取样是一项很重要的工作，样品的取心率和原状性直接影响了环境研究的结果。重力取样器是获取湖泊、水库等水域浅层湖泊沉积物的一种经济有效、操作简单的常用工具。因此研究重力取样器的取样技术对环境研究具有积极的意义。研究了重力取样器的取样技术，并在此基础上成功设计了一种便携式的重力式取样器，非常适合环境研究机构的沉积物取样工作。  相似文献   

快速城市化过程中城市土地覆被的时空动态特征     

龚建周  夏北成 《福建地理》2006,(4)

1990~2005年间,是广州市经济快速发展和城市景观变化最大的时期,以同时段TM影像解译得到广州市的土地覆被类型图,从数量结构、空间信息及位置转移和景观等方面,分析了广州市土地覆被的动态特征.数量结构的研究结果显示:在快速城市化过程中广州市的耕地、林地等自然资源的利用程度在加大,自1995年起,这种变化的趋势开始减缓;土地覆被类型之间的信息与位置的转移变化频繁,并且表现出空间位置分异的特征.景观特征指数分析结果表明:广州市城市土地覆被向破碎化方向发展,城市建设用地呈扩展之势.  相似文献   

Estimating the minimum in-stream flow requirements via wetted perimeter method based on curvature and slope techniques     

LIU Suxia  MO Xingguo  XIA Jun  LIU Changming  LIN Zhonghui  MEN Baohui  JI Lina 《地理学报》2006,16(2):242-250

Under the assumptions of triangular cross section channel and uniform stable flow, an analytical solution of the minimum ecological in-stream flow requirement (MEIFR) is deduced. Based on the analytical solution, the uncertainty of the wetted perimeter method is analyzed by comparing the two techniques for the determination of the critical point on the relationship curve between wetted perimeter, P and discharge, Q. It is clearly shown that the results of MEIFR based on curvature technique (corresponding to the maximum curvature) and slope technique (slope being 1) are significantly different. On the P-Q curve, the slope of the critical point with the maximum curvature is 0.39 and the MEIFR varied prominently with the change of the slope threshold. This indicates that if a certain value of the slope threshold is not available for slope technique, curvature technique may be a better choice. By applying the analytical solution of MEIFR in the losing rivers of the Western Route South-to-North Water Transfer Project in China, the MEIFR value via curvature technique is 2.5%-23.7% of the multi-year average annual discharge, while that for slope technique is 11%-105.7%. General conclusions would rely on the more detailed research for all kinds of cross-sections.  相似文献   

遥感技术在煤炭地质中的应用现状及前景   总被引：6，自引：0，他引：6  

张文若  康高峰王永 《中国煤田地质》2006,18(2):5-8,59

介绍了遥感技术在煤炭资源调查和评价、煤矿区地质灾害调查和评估、生态环境及污染调查评价和监测以及煤矿三维可视化仿真规划系统建设方面的应用研究现状及所取得的主要成果，并结合遥感技术的发展方向，展望了其在煤炭地质中的应用前景。  相似文献   

Comparison of magnetic parameters with vehicular Br levels in urban roadside soils     

Xue-Song Wang  Yong Qin 《Environmental Geology》2006,50(6):787-791

Chemical methods are generally chosen to monitor soil pollution but magnetic measurements proved to yield additional information at low cost and less time consumption. In this investigation, the novel use of rapid and non-destructive magnetic measurements to characterize Br levels in Xuzhou (China) urban roadside soils was reported. X-ray fluorescence spectrometry (XRF) was used to quantify Br in the soil samples. Data from 21 roadside soil samples confirm Br contamination, with a mean level of 4.36 mg kg⁻¹ and a range of 2.4–8.7 mg kg⁻¹. These values are higher than that of unpolluted soils in Xuzhou that averages 1.1 mg kg⁻¹. Hierarchical clustering analysis shows Br in Xuzhou roadside soils is mainly from road traffic. Clear correlations between Br levels and simple magnetic parameters [mass specific susceptibility (χ _LF), susceptibility of anhysteretic remanent magnetization (χ _ARM), saturation isothermal remanence (SIRM)] are observed. The present study shows that these three magnetic parameters can be used as a proxy for Br levels in Xuzhou urban roadside soils.  相似文献   

华南下寒武统镍钼矿层中铜铅锌矿物的发现及意义     

陈益平  潘家永  夏菲  郭国林  陈少华  曹双林  严兆斌 《华东地质学院学报》2006,29(1):32-37

华南扬子地块是我国古热水沉积成矿作用最为发育的地区之一,其热水沉积特性最早引起我国学者的关注。华南下寒武统黑色岩系中赋存多个与热水沉积成矿作用相关的大型、超大型重晶石矿床与N i-Mo-U-V多金属富集层。进一步研究分布在华南扬子地块黑色岩系中的金属、非金属矿床成因及其地球化学特征,对认识华南乃至全球晚震旦—早寒武世生物与环境演化有着十分重要的意义。本文对华南下寒武统镍-钼富集层矿石进行电子探针研究,识别出黄铜矿、黝铜矿等铜的独立矿物;闪锌矿等锌的独立矿物;方铅矿、白铅矿等铅的独立矿物。研究表明,在镍-钼矿石中这些矿物的发现为镍-钼矿层是热水沉积作用产物提供了直接的矿物学证据。  相似文献   

探地雷达(GPR)在海南岛东北部海岸带调查中的应用 ^*   总被引：2，自引：0，他引：2  

殷勇  朱大奎  I.P.Martini 《第四纪研究》2006,26(3):462-469

对海南岛东北部海岸带调查采用了探地雷达(GPR)研究海岸带沙体的结构、展布和沉积序列,取得了很好的效果。文章通过和有限的露头资料对比以及对反射波形态、结构的研究,确定了海滩脊、海岸沙丘的反射特征以及潜水面的位置。雷达图像显示五龙港古海滩脊由亚水平、不连续、高振幅和透镜状反射波组成;木兰头海岸沙丘已受到人类活动的扰动,短的、陡倾斜反射可能代表未受扰动的海岸风成沙的前积层。研究表明探地雷达是一种可靠、快速和经济的地球物理方法,在砂砾质海岸可产生高质量、高分辨率和连续的反射剖面,值得加以推广。  相似文献