Calcite crystals were grown in a closed system by recrystallization of synthetic and natural aragonite crystals, in the presence of various CaCl2-MgCl2 solutions with and without NaCl.The distribution of Mg2+ between calcite and solution at the entire temperature range is heterogeneous, closely following the Doerner-Hoskins (Doerner and Hoskins, 1925) distribution law. λMg2+C is strongly dependent on temperature, being: 0·0573 ± 0·0017 at 25°C, 0·0681 ± 0·0019 at 35°C, 0·0778 ± 0.0022 at 50°C, 0·0973 ± 0·0021 at 70°C, and 0·1163 ±0 ·0034 at 90°C. λMg2+C is independent of the absolute concentration of Ca2+ in solution as well as of the presence of NaCl.Relatively high λMg2+C values are obtained during the initial reaction stages when too-highly reactive synthetic aragonites are recrystallized. SEM micrographs show that calcite crystals grown from such aragonites are imperfect and that their earlier formed Mg-rich cores redissolve later, resulting in apparently inconsistent λMg2+C values.Calculations applying the new λMg2+C value for 25°C and the solubility data for magnesian calcites (Chaveet al., 1962) demonstrate that although no calcite should be expected to precipate directly from open sea water, its direct precipitation (or recrystallization from aragonite) is possible in closed diagenetic systems which still contain marine solutions, provided a temporary increase in the dissolved calcium concentration takes place.The λMg2+C values obtained allow for a new insight into processes of calcite cementation of reefs and a variety of other carbonate sediments, and for a more precise definition of dedolomitization chemistry. 相似文献
This work studies the effects of long human habitation on site geotechnical conditions. It is focused on the city of Zefat that is located on the borders of the Dead Sea Transform in northern Israel. The city of Zefat, suffered severe damage and loss of life in historical earthquakes, as a consequence of earthquake induced landslides (EILS). In this work we evaluate the current EILS hazard for the city of Zefat using a GIS-based regional Newmark analysis, with calibration of the calculated Newmark displacement (representing EILS hazard) using maps of field evidence and historical documents testifying to slope instability that occurred in historical earthquakes.
We found that the core city of Zefat is built on a layered anthropogenic material, few meters deep which, was deposited as a result of more than 2000 years of human habitation. The anthropogenic material is mechanically weak, susceptible to slope failure and to amplification of seismic-shaking. It is responsible for the city's devastation in historical earthquakes and it is the source for the current high seismic hazard as well.
Our model shows that earthquakes of magnitudes (Mw) 5, 6 and 7 at distances of up to 10 km, 50 km and more than 100 km, respectively, are likely to induce landslides in the core city of Zefat. The current engineering status of the city is poor, and as a consequence severe damage and loss of life are expected in future earthquakes due to EILS, unless major engineering efforts are made. Cities in the Eastern Mediterranean with comparable long habitation histories (e.g., Jerusalem, Tiberias, Nablus, Amman) are expected to have similar geotechnical problems in their old sections and are advised to take appropriate engineering steps to reduce damage and loss of life in future earthquakes.
Evaluation of historical earthquake magnitudes based on reported local-damage may, however, lead to overestimated magnitudes where the damaged sites are built on anthropogenic talus (a common setting in the vicinity of the Dead Sea Transform). 相似文献
Turbulent flow in a corn canopy is simulated using large-eddy simulation (LES) with a Lagrangian dynamic Smagorinsky model.
A new numerical representation of plant canopies is presented that resolves approximately the local structure of plants and
takes into account their spatial arrangement. As a validation, computational results are compared with experimental data from
recent field particle image velocimetry (PIV) measurements and two previous experimental campaigns. Numerical simulation using
the traditional modelling method to represent the canopy (field-scale approach) is also conducted as a comparison to the plant-scale
approach. The combination of temporal PIV data, LES and spatial PIV data allows us to couple a wide range of relevant turbulence
scales. There is good agreement between experimental data and numerical predictions using the plant-scale approach in terms
of various turbulence statistics. Within the canopy, the plant-scale approach also allows the capture of more details than
the field-scale approach, including instantaneous gusts that penetrate deep inside the canopy. 相似文献
Particle image velocimetry (PIV) data obtained in a wind-tunnel model of a canopy boundary layer is used to examine the characteristics
of mean flow and turbulence. The vector spacing varies between 1.7 and 2.5 times the Kolmogorov scales. Conditional sampling
based on quadrants, i.e. based on the signs of velocity fluctuations, reveals fundamental differences in flow structure, especially
between sweep and ejection events, which dominate the flow. During sweeps, the downward flow generates a narrow, highly turbulent,
shear layer containing multiple small-scale vortices just below canopy height. During ejections, the upward flow expands this
shear layer and the associated small-scale flow structures to a broad region located above the canopy. Consequently, during
sweeps the turbulent kinetic energy (TKE), Reynolds stresses, as well as production and dissipation rates, have distinct narrow
peaks just below canopy height, whereas during ejections these variables have broad maxima well above the canopy. Three methods
to estimate the dissipation rate are compared, including spectral fits, measured subgrid-scale (SGS) energy fluxes at different
scales, and direct measurements of slightly underresolved instantaneous velocity gradients. The SGS energy flux is 40–60%
of the gradient-based (direct) estimates for filter sizes inside the inertial range, while decreasing with scale, as expected,
within the dissipation range. The spectral fits are within 5–30% of the direct estimates. The spectral fits exceed the direct
estimates near canopy height, but are lower well above and below canopy height. The dissipation rate below canopy height increases
with velocity magnitude, i.e. it has the highest values during sweep and quadrant 1 events, and is significantly lower during
ejection and quadrant 3 events. Well above the canopy, ejections are the most dissipative. Turbulent transport during sweep
events acts as a source below the narrow shear layer within the canopy and as a sink above it. Transport during ejection events
is a source only well above the canopy. The residual term in the TKE transport equation, representing mostly the effect of
pressure–velocity correlations, is substantial only within the canopy, and is dominated by sweeps. 相似文献
A method for the automatic inversion of resistivity soundings is presented. The procedure consists of two main stages. First, application of linear filters which transforms the apparent resistivity curve into the kernel function, and vice versa. In the second stage the first and second derivatives of the kernel function are calculated and used in a second-order modified Newton-Raphson iterative fitting procedure. The model obtained is optimal in the least squares sense. The method has been tried on some field examples and produced resistivity models which show a good agreement with the geological well logs. 相似文献
Jerusalem was hit by earthquakes several times in its history, in the course of which none of the holy sites of the three
main faiths of the western world escaped damage. Intensities of the last ML 6.2, July 11, 1927 Dead Sea earthquake, reached MSK VIII in the Old City of Jerusalem and the surrounding villages. As future
strong earthquakes are inevitable, the need for the evaluation of earthquake-related hazards is obvious. Only general geotechnical
properties of the section exposed in the mountainous area of Jerusalem are available; therefore, the hazard assessment was
conducted from a geological perspective. The hazards identified in this study are: (1) amplification of seismic acceleration
due to soft rock and soil conditions; (2) amplification due to mountainous topography; (3) dynamic instability of natural
slopes; and (4) potential failure of slopes that have undergone engineering development and were weakened due to damaging,
steepening, overloading, and wetting beyond their natural state. We formulated relative grades of vulnerability for each of
the hazards and delineated the zones that require further specific investigation. For practical use we constructed a summary
map that combines the different hazard categories. Looking at the summary map, the ground at the central N–S axis zone across
Jerusalem is the least vulnerable. The bedrock there is mostly hard carbonate, the topography is mild, and thus only the alluvial
cover, if thicker than 3 m, should be considered sensitive. Yet although the natural hazard in this area is limited, the risk
should not be underrated. Much of the city lies there, including buildings constructed before antiseismic codes were regulated,
and traditional engineering practice should not be taken for granted as antiseismic proof either. Eastwards, the shear wave
velocity (Vs) contrast between the hard and soft rocks as well as the notable topography in places, impose the potential for
amplification. Slopes, either naturally or artificially cutting into the soft chalk, may expose the area to dynamic instability;
thus, the ongoing extensive development of the city in this direction should certainly take into account all of this. West
of the central axis, the potential of failure of both steep natural and urbanized slopes appears. Being a plausible direction
for future urban expansion, these areas specifically call for careful environmental and engineering planning. For engineering
purposes, however, a specific site investigation is still necessary. Nevertheless, the summary map established in this study
sets up for Jerusalem, for the first time, a practical tool for environmental and municipal planning, emergency response planning,
and civil protection. 相似文献