Depositional and diagenetic history of limestones and dolostones of the Oligo‐Miocene Kujung Formation in the Northeast Java Basin,Indonesia     

Muhlash Hada Firman Syah  Akihiro Kano  Tsuyoshi Iizuka  Yoshihiro Kakizaki 《Island Arc》2019,28(6)

Lithological and geochemical features of platformal carbonates record the signatures of the global climates and the regional environmental settings and also reconstruct the diagenetic history and porosity evolution, which are essential to evaluate the potential of hydrocarbon reservoirs. This study investigates the platformal carbonates of the Oligo‐Miocene Krunji Formation of North East Java Basin, which are potentially significant hydrocarbon reservoirs. The carbonate sequence in a 283 m thick section at Kranji in East Java is subdivided into three lithological units: limestone unit 1, dolostone unit 2, and limestone unit 3, in ascending order. The strontium‐isotope ratios of well‐preserved calcite samples indicate the depositional period from Chattian (late Oligocene) to Burdigalian (early Miocene), which is consistent with ages of the foraminifer assemblages. Unit 1 consists of low‐porosity limestone, in which two horizons of subaerial exposure are recognized by the occurrence of red‐colored matrix and lower δ¹³C values. Unit 2 consists of dolomitic rock and exhibits coarse‐grained calcitic grains and cross‐stratified structure. Considering that this unit has been subject to dolomitization, the sediment of unit 2 was initially permeable and was likely deposited in a shoal setting. The overlying unit 3 of Aquitanian–Burdigalian age is characterized by a highly granular texture. High porosity and uniformly low δ¹³C and δ¹⁸O values indicate that Unit 3 was subjected to more intense meteoric diagenesis than the Chattian unit 1. This was likely a consequence of the Antarctic ice‐sheet expansion during the Oligocene/Miocene transition, which amplified sea level change. The unit 2 dolomite has high δ¹³C and δ¹⁸O values and a high ⁸⁷Sr/⁸⁶Sr ratio which resulted from the reflux of seawater into permeable the sediment body in middle‐late Miocene (Burdigalian Tortonian) following the deposition of unit 3. The porosity and permeability of the Kujung Formation were initially controlled by sedimentological processes, but largely modified by later diagenetic processes.  相似文献   

Natural and experimental structural evolution of dispersed organic matter in mudstones: The Shimanto accretionary complex,southwest Japan     

Yoshihiro Nakamura  Hidetoshi Hara  Hiroyuki Kagi 《Island Arc》2019,28(5)

Structural changes induced by thermal maturation of dispersed organic matter (OM) in the Shimanto accretionary complex, southwest Japan, were investigated using micro‐Fourier‐transform infrared spectroscopy and micro‐Raman spectroscopy. Natural dispersed OM exhibits systematic structural changes inferred from D1‐ and G‐band FWHM values, Raman band separation (RBS), and intensity ratios of the D1‐ and G‐bands (I_D1/I_G ratio) from diagenetic zone to anchizone (IC values: 0.75–0.30). Infrared spectra indicate a loss of aliphatic CH _x, aromatic CH _x, and oxygen‐containing structures as temperature increases. These changes are consistent with discontinuities in thermal structures bounded by out‐of‐sequence thrusts. Kinetic pyrolysis experiments indicate that the I_D1/I_G ratio of synthesized OM has a power law relationship with heat treatment time. Kinetic models of temperature dependence were fitted using the I_D1/I_G ratio, and an effective activation energy of 106 ±17 kJ/mol was estimated using an Arrhenius equation. The activation energies estimated by power law rate and Avrami models have a least‐square correlation coefficient of 0.93, indicating the temperature dependence of carbonization. The estimated effective activation energy is consistent with that of coal, lignin, cellulose, and hemicellulose during thermal degradation. On the other hand, RBS, and D1‐ and G‐band FWHM values of OM display more complex changes with increasing heating temperature and time, and it is difficult to constrain rate parameters during pyrolysis experiments. Our data indicate that the I_D1/I_G ratio is controlled by a simple thermally activated process, whereas RBS and D1‐ and G‐band FWHM values can be affected by lithostatic pressure, fluid activity, hydrogen index, and host lithology, as well as temperature. Structural evolution of dispersed OM in mudstones differs between natural and anhydrous closed experimental systems. Natural carbonization based on micro‐Raman spectroscopy should be applied for a limited indicator of thermal maturation, especially for dispersed OM in diagenetic zone.  相似文献   

Nickel–bearing Djerfisherite in Gehlenite-Spurrite Skarn at Kushiro, Hiroshima Prefecture, Japan     

Yasushi TAKECHI  Isao KUSACHI  Yoshihiro NAKAMUTA  Katsuo KASE 《Resource Geology》2000,50(3):179-184

Abstract: Djerfisherite occurs intimately intergrown with troilite and pentlandite in gehlenite-spurrite skarn at Kushiro, mainly as inclusions in gehlenite and andradite grains. The mode of occurrence indicates that the djerfisherite formed in the culminated stage of the contact metamorphic-metasomatic process. The chemical compositions of the mineral are approximately represented by a formula of K₆Na(Fe, Ni, Cu)₂₄S₂₆Cl with Ni up to 4. 85. It is likely that high temperature condition corresponding to the formation of gehlenite-spurrite skarn as well as low f_O2 and f_S2 conditions are responsible for the formation of djerfisherite in the potassium-rich chemical environments.  相似文献   

Refinement of the age of the Middle Miocene Fort Ternan Beds,Western Kenya,and its implications for Old World biochronology     

Martin Pickford  Yoshihiro Sawada  Ryoichi Tayama  Yu-ko Matsuda  Tetsumaru Itaya  Hironobu Hyodo  Brigitte Senut 《Comptes Rendus Geoscience》2006,338(8):545-555

It has become increasingly obvious over the past two decades that the fossiliferous strata at Fort Ternan, Kenya, are probably somewhat younger than 14 Ma, an age which has long been attached to the deposits. This realisation flows from geological and biochronological observations. In order to test the hypothesis, resampling of all the lava flows in the region of Fort Ternan was undertaken in 2003, especially those underlying the Fort Ternan Beds in the Kipchorion Gorge where the sequence is the most complete. Samples obtained from lava flows underlying and overlying the fossil beds were analysed for anorthoclase K/Ar and ⁴⁰Ar/³⁹Ar and biotite ⁴⁰Ar/³⁹Ar age determinations. The results reveal that the age of the fossiliferous sediments is ca $13.7\pm 0.3\text{Ma}$. Since Fort Ternan yielded the ‘core fauna’ that defines Faunal Set IV of the East African biochronological sequence this refinement of its age will impact on age estimates of neighbouring Faunal Sets, as well as on other faunas correlated to Fort Ternan, including those in Europe belonging to MN Zones MN 5, MN 6 and MN 7/8. To cite this article: M. Pickford et al., C. R. Geoscience 338 (2006).  相似文献   

X-ray CT based numerical analysis of fracture flow for core samples under various confining pressures   总被引：1，自引：0，他引：1  

Noriaki Watanabe  Takuya Ishibashi  Yutaka Ohsaki  Yoshihiro Tsuchiya  Tetsuya Tamagawa  Nobuo Hirano  Hiroshi Okabe  Noriyoshi Tsuchiya 《Engineering Geology》2011,(4):338

The X-ray CT based numerical analysis of fracture flow for core samples, recently developed by the authors, was applied to two granite core samples having either a mated artificial or a mated natural fracture at confining pressures of 5 to 50 MPa. A third-generation medical X-ray CT scanner was used to image the samples within a core holder consisting of an aluminum liner and a carbon fiber overwrap. Fracture models (i.e., aperture distributions) were obtained by the CT images, the resolution of which was coarser than the apertures, and a single-phase flow simulation was performed using a local cubic law-based fracture flow model. Numerical results were evaluated by a fracture porosity measurement and a solution displacement experiment using NaCl and NaI aqueous solutions. These numerical results coincided only qualitatively with the experimental results, primarily due to image noise from the aluminum liner of the core holder. Nevertheless, the numerical results revealed flow paths within the fractures and their changes with confining pressure, whereas the experimental results did not provide such results. Different stress-dependencies in the flow paths were observed between the two samples despite the similar stress-dependency in fracture porosity and permeability. The changes in total area of the flow paths with confining pressure coincided qualitatively with changes in breakthrough points in the solution displacement experiment. Although the data is limited, the results of the present study suggest the importance of analyzing fluid flows within naturally fractured core samples under in situ conditions in order to better understand the fracture flow characteristics in a specific field. As demonstrated herein, X-ray CT-based numerical analysis is effective for addressing this concern. Using a multi-phase flow model, as well as a core holder constructed of an engineered plastic, should provide a useful, non-destructive, and non-contaminative X-ray CT-based fracture flow analysis for core samples under in situ conditions in future studies.  相似文献   

In situ Atomic Force Microscopy study of dissolution of the barite (0 0 1) surface in water at 30 °C     

Yoshihiro Kuwahara 《Geochimica et cosmochimica acta》2011,75(1):41-51

The dissolution behavior of the barite (0 0 1) surface in pure water at 30 °C was investigated using in situ Atomic Force Microscopy (AFM), to better understand the dissolution mechanism and the microtopographical changes that occur during the dissolution, such as steps and etch pits. The dissolution of the barite (0 0 1) surface started with the slow retreat of steps, after which, about 60 min later, the <hk0> steps of one unit cell layer or multi-layers became two-step fronts (fast “f” and slow “s” steps) with a half-unit cell layer showing different retreat rates. The “f” step had a fast retreat rate (≈(14 ± 1) × 10⁻² nm/s) and tended to have a jagged step edge, whereas the “s” step (≈(1.8 ± 0.1) × 10⁻² nm/s) had a relatively straight front. The formation of the “f” steps led to the formation of a new one-layer step, where the front of the “s” step was overtaken by that of the immediate underlying “f” step. The “f” steps also led to the decrease of the <hk0> steps and the increase in the percentage of stable steps parallel to the [0 1 0] direction during the dissolution.Etch pits, which could be observed after about 90 min, were of three types: triangular etch pits with a depth of a half-unit cell, shallow etch pits, and deep etch pits. The triangular etch pits were bounded by the step edges parallel to [0 1 0], [1 2 0], and [] and had opposite orientations in the upper half and lower half layers. Shallow etch pits that had a depth of two or more half-unit cell layers had any two consecutive pits pointing in the opposite direction of each other. The triangular etch pit appeared to grow by simultaneously removal of a row of ions parallel to each direction from the three step edges. At first, deep etch pits were elongated in the [0 1 0] direction with a curved outline and then gradually developed to an angular form bounded by the {1 0 0}, {3 1 0}, and (0 0 1) faces. The retreat rate of the (0 0 1) face was much slower than those of the {1 0 0} and {3 1 0} and tended to separate into two rates ((0.13 ± 0.01) × 10⁻² nm/s for the deep etch pits derived from a screw dislocation and (0.07 ± 0.01) × 10⁻² nm/s for those from other line defects).The changes in the dissolution rate of a barite (0 0 1) surface during the dissolution were estimated using the retreat rates and densities of the various steps as well as the growth rates, density, and areas of the lateral faces of the deep etch pits that were obtained from this AFM analysis. Our results showed that the dissolution rate of the barite (0 0 1) surface gradually increased and approached the bulk dissolution rate because of the change in the main factor determining the dissolution rate from the density of the steps to the growth and the density of the deep etch pits on the surface.  相似文献   

Lunar meteorite,Dhofar 1428: Feldspathic breccia containing KREEP and meteoritic components     

Yoshihiro Hidaka  Akira Yamaguchi  Mitsuru Ebihara 《Meteoritics & planetary science》2014,49(5):921-928

We have studied the feldspathic lunar meteorite Dhofar 1428 chemically and petrologically to better understand the evolution of the lunar surface. Dhofar 1428 is a feldspathic regolith breccia derived from the lunar highland. Bulk chemical and mineral compositions of Dhofar 1428 are similar to those of other feldspathic lunar meteorites. We found a few clasts of evolved lithologies, such as K‐rich plagioclases and quartz monzogabbro. Dhofar 1428 contains approximately 1 wt% of chondritic materials like CM chondrite on the basis of abundances of platinum group elements (Ru, Rh, Pd, Os, Ir, and Pt).  相似文献   

Cold air formation and advection over Eurasia during “dzud” cold disaster winters in Mongolia   总被引：1，自引：0，他引：1  

Yoshihiro Iijima  Masatake E. Hori 《Natural Hazards》2018,92(1):45-56

Large negative temperature anomalies due to cold air advection have been observed over the Eurasian continent in recent years. During the 2009/2010 winter, a large amount of snow accumulated across Central Asia and China, which along with a strong cold air outbreak, resulted in extremely high livestock mortality in Mongolia. The present study examined the surface inversion development over the Eurasian continent in terms of the cold air advection, accumulation, and breaking processes at ground level. Meteorological analyses shown trends toward earlier onsets of snow and subsequent cold air advection from the Arctic through western Siberia during the last decade, which is a possible driver of the persistent enhanced surface cooling observed in mid-winter in Mongolia. Cyclones are shown to be drivers of early snowfall onset at the beginning of winter and the subsequent migration of cold air from the Arctic, and are thus the key to understanding and predicting the frequency and intensity of persistent surface cooling, which is a substantial physical precursor for the cold disaster in Mongolia “dzud.”  相似文献   

Analysis of long‐term water balance in the source area of the Yellow River basin     

Yoshinobu Sato  Xieyao Ma  Jianqing Xu  Masayuki Matsuoka  Hongxing Zheng  Changming Liu  Yoshihiro Fukushima 《水文研究》2008,22(11):1618-1629

To analyse the long‐term water balance of the Yellow River basin, a new hydrological model was developed and applied to the source area of the basin. The analysis involved 41 years (1960–2000) of daily observation data from 16 meteorological stations. The model is composed of the following three sub‐models: a heat balance model, a runoff formation model and a river‐routing network model. To understand the heat and water balances more precisely, the original model was modified as follows. First, the land surface was classified into five types (bare, grassland, forest, irrigation area and water surface) using a high‐resolution land‐use map. Potential evaporation was then calculated using land‐surface temperatures estimated by the heat balance model. The maximum evapotranspiration of each land surface was calculated from potential evaporation using functions of the leaf area index (LAI). Finally, actual evapotranspiration was estimated by regulating the maximum evapotranspiration using functions of soil moisture content. The river discharge estimated by the model agreed well with the observed data in most years. However, relatively large errors, which may have been caused by the overestimation of surface flow, appeared in some summer periods. The rapid decrease of river discharge in recent years in the source area of the Yellow River basin depended primarily on the decrease in precipitation. Furthermore, the results suggested that the long‐term water balance in the source area of the Yellow River basin is influenced by land‐use changes. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Radio imaging of the Subaru/XMM–Newton Deep Field – I. The 100-μJy catalogue, optical identifications, and the nature of the faint radio source population     

Chris Simpson  Alejo Martínez-Sansigre  Steve Rawlings  Rob Ivison  Masayuki Akiyama  Kazuhiro Sekiguchi  Tadafumi Takata  Yoshihiro Ueda  Mike Watson 《Monthly notices of the Royal Astronomical Society》2006,372(2):741-757

We describe deep radio imaging at 1.4 GHz of the 1.3-deg² Subaru/ XMM–Newton Deep Field (SXDF), made with the Very Large Array in B and C configurations. We present a radio map of the entire field, and a catalogue of 505 sources covering 0.8 deg² to a peak flux density limit of 100 μJy. Robust optical identifications are provided for 90 per cent of the sources, and suggested identifications are presented for all but 14 (of which seven are optically blank, and seven are close to bright contaminating objects). We show that the optical properties of the radio sources do not change with flux density, suggesting that active galactic nuclei (AGN) continue to contribute significantly at faint flux densities. We test this assertion by cross-correlating our radio catalogue with the X-ray source catalogue and conclude that radio-quiet AGN become a significant population at flux densities below 300 μJy, and may dominate the population responsible for the flattening of the radio source counts if a significant fraction of them are Compton-thick.  相似文献