Hydrogen isotopic substitution of solid methylamine through atomic surface reactions at low temperatures: A potential contribution to the D/H ratio of methylamine in molecular clouds     

Yasuhiro Oba  Takeshi Chigai  Yoshihiro Osamura  Naoki Watanabe  Akira Kouchi 《Meteoritics & planetary science》2014,49(1):117-132

We experimentally studied hydrogen (H)–deuterium (D) substitution reactions of solid methylamine (CH₃NH₂) under astrophysically relevant conditions. We also calculated the potential energy surface for the H–D substitution reactions of methylamine isotopologues using quantum chemical methods. Despite the relatively large energy barrier of more than 18 kJ mol^?1, CH₃NH₂ reacted with D atoms to yield deuterated methylamines at 10 K, suggesting that the H–D substitution reaction proceeds through quantum tunneling. Deuterated methylamines reacted with H atoms as well. On the basis of present results, we propose that methylamine has potential for D enrichment through atomic surface reactions on interstellar grains at very low temperatures in molecular clouds. D enrichment would occur in particular in the methyl group of methylamine.  相似文献   

A low cost meteor observation system using radio forward scattering and the interferometry technique     

Waleed Madkour  Masa-yuki Yamamoto  Yoshihiro Kakinami  Satoshi Mizumoto 《Experimental Astronomy》2016,41(1-2):243-257

We present a low cost meteor observation system based on the radio forward scattering and interferometry technique at Kochi University of Technology (KUT). The system can be a suitable model for low budget educational institutes that target practical learning of astronomical objects and upper atmospheric characteristics. The system methodology for the automatic counting of meteor echoes, filtering noise and detecting meteor echo directions is described. Detection of the meteor echo directions, which is the basic element for determining the meteor trajectories and the orbital parameters of parent comets, is based on a software system developed for analysis of phase differences detected by interferometry. Randomly selected observation samples measured by the radio interferometer are compared to simultaneous optical observations by video cameras to verify the system accuracy. Preliminary error analysis revealed that the system accuracy is directly related to the duration of observed meteor echoes. Eighty percent of meteor echo samples with durations longer than 3 s showed agreement in azimuth and elevation angles measurements to within a 10° error range, while meteor echo samples with shorter durations showed lower agreement levels probably due to the low system sampling resolution of 0.1 s. The reasonable agreement level of meteor echoes with duration longer than 3 s demonstrated the applicability of the system methodology. Accurate observation of shorter duration meteor echoes could possibly be achieved by improving the system resolution.  相似文献   

Geochemistry and geodynamics of the Mawat mafic complex in the Zagros Suture zone, northeast Iraq     

Hossein Azizi  Ayten Hadi  Yoshihiro Asahara  Youssef Osman Mohammad 《Central European Journal of Geosciences》2013,5(4):523-537

The Iraqi Zagros Orogenic Belt includes two separate ophiolite belts, which extend along a northwest-southeast trend near the Iranian border. The outer belt shows ophiolite sequences and originated in the oceanic ridge or supra-subduction zone. The inner belt includes the Mawat complex, which is parallel to the outer belt and is separated by the Biston Avoraman block. The Mawat complex with zoning structures includes sedimentary rocks with mafic interbedded lava and tuff, and thick mafic and ultramafic rocks. This complex does not show a typical ophiolite sequences such as those in Penjween and Bulfat. The Mawat complex shows evidence of dynamic deformation during the Late Cretaceous. Geochemical data suggest that basic rocks have high MgO and are significantly depleted in LREE relative to HREE. In addition they show positive ? _Nd values (+5 to+8) and low 87Sr/86Sr ratios. The occurrence of some OIB type rocks, high Mg basaltic rocks and some intermediate compositions between these two indicate the evolution of the Mawat complex from primary and depleted source mantle. The absence of a typical ophiolite sequence and the presence of good compatibility of the source magma with magma extracted from the mantle plume suggests that a mantle plume from the D″ layer is more consistent as the source of this complex than the oceanic ridge or supra-subduction zone settings. Based on our proposed model the Mawat basin represents an extensional basin formed during the Late Paleozoic to younger along the Arabian passive margin oriented parallel to the Neo-Tethys oceanic ridge or spreading center. The Mawat extensional basin formed without creation of new oceanic basement. During the extension, huge volumes of mafic lava were intruded into this basin. This basin was squeezed between the Arabian Plate and Biston Avoraman block during the Late Cretaceous.  相似文献   

Depositional process of the Byk-E tephra bed in the Chiba section,central Japan: A marker bed defining the Global Boundary Stratotype Section and Point for the Chibanian Stage     

Yasufumi Satoguchi  Yoshihiro Takeshita  Hiroomi Nakazato  Yusuke Suganuma 《Island Arc》2021,30(1):e12432

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Geologic Core Holder with a CFR PEEK Body for the X-ray CT-Based Numerical Analysis of Fracture Flow Under Confining Pressure   总被引：1，自引：0，他引：1  

Noriaki Watanabe  Takuya Ishibashi  Noriyoshi Tsuchiya  Yutaka Ohsaki  Tetsuya Tamagawa  Yoshihiro Tsuchiya  Hiroshi Okabe  Hisao Ito 《Rock Mechanics and Rock Engineering》2013,46(2):413-418

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Ecological variations in diatom assemblages in the Paleo-Kathmandu Lake linked with global and Indian monsoon climate changes for the last 600,000 years     

Tatsuya Hayashi  Yoshihiro Tanimura  Yoshihiro Kuwahara  Masao Ohno  Mami Mampuku  Rie Fujii  Harutaka Sakai  Toshiro Yamanaka  Takeshi Maki  Masao Uchida  Wataru Yahagi  Hideo Sakai 《Quaternary Research》2009,72(3):377-387

Variations in fossil diatom assemblages and their relationship with global and Indian monsoon climate changes for the last 600,000 yr were investigated using a core of ancient lake (Paleo-Kathmandu Lake) sediments drilled at the Kathmandu Basin, Nepal Himalaya. Chronological scales of the core were constructed by tuning pollen wet and dry index records to the SPECMAP δ¹⁸O stack record. Examinations of biogenic silica contents and fossil diatom assemblages revealed that variations in productivity and compositions of diatom assemblages were closely linked with global and Indian monsoon climate changes on glacial and interglacial time scales. When summer monsoonal rainfall increased during interglacials (interstadials), diatom productivity increased because of increased inputs of terrestrial nutrients into the lake. When summer monsoonal rainfall reduced and/or winter monsoonal aridification enhanced during glacials (stadials), productivity of the diatoms decreased and lake-level falling brought about changes in compositions of diatom assemblages. Monospecific assemblages by unique Cyclotella kathmanduensis and Puncticulata versiformis appeared during about 590 to 390 ka. This might be attributed to evolutionary fine-tuning of diatom assemblages to specific lake environmental conditions. Additionally, low-amplitude precessional variations in monsoon climate and less lake-level changes may have also allowed both species to dominate over the long periods.  相似文献   

Spatial distribution of unmonitored inland water discharges to the sea     

Jerker Jarsjö  Yoshihiro Shibuo  Georgia Destouni 《Journal of Hydrology》2008,348(1-2):59-72

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Siderophile element characteristics of acapulcoite–lodranites and winonaites: Implications for the early differentiation processes of their parent bodies     

Yoshihiro Hidaka  Naoki Shirai  Akira Yamaguchi  Mitsuru Ebihara 《Meteoritics & planetary science》2019,54(5):1153-1166

We have studied magnetic fractions of five acapulcoites, three lodranites, and two winonaites to investigate chemical compositions of their precursor materials and metallic partial melting processes occurring on their parent bodies. One winonaite metal is similar in composition to low Au, low Ni IAB iron subgroup, indicating genetic relationship between them. Magnetic fractions of chondrule‐bearing acapulcoite and winonaite have intermediate chemical compositions of metals between H chondrites and EL chondrites. This fact indicates that the precursor materials of acapulcoite–lodranites and winonaites were similar to H and/or EL chondrites in chemical compositions. Magnetic fractions in acapulcoite–lodranites have a large variety of chemical compositions. Most of them show enrichments of W, Re, Ir, Pt, Mo, and Rh, and one of them shows clear depletion in Re and Ir relative to those of chondrule‐bearing acapulcoite. Chemical compositional variations among acapulcoite–lodranite metals cannot be explained by a single Fe‐Ni‐S partial melting event, but a two‐step partial melting model can explain it.  相似文献   

Detrital zircon multi‐chronology,provenance, and low‐grade metamorphism of the Cretaceous Shimanto accretionary complex,eastern Shikoku,Southwest Japan: Tectonic evolution in response to igneous activity within a subduction zone          下载免费PDF全文

Hidetoshi Hara  Yoshihiro Nakamura  Kousuke Hara  Toshiyuki Kurihara  Hiroshi Mori  Hideki Iwano  Tohru Danhara  Shuhei Sakata  Takafumi Hirata 《Island Arc》2017,26(6)

Detrital zircon multi‐chronology combined with provenance and low‐grade metamorphism analyses enables the reinterpretation of the tectonic evolution of the Cretaceous Shimanto accretionary complex in Southwest Japan. Detrital zircon U–Pb ages and provenance analysis defines the depositional age of trench‐fill turbidites associated with igneous activity in provenance. Periods of low igneous activity are recorded by youngest single grain zircon U–Pb ages (YSG) that approximate or are older than the depositional ages obtained from radiolarian fossil‐bearing mudstone. Periods of intensive igneous activity recorded by youngest cluster U–Pb ages (YC1σ) that correspond to the younger limits of radiolarian ages. The YC1σ U–Pb ages obtained from sandstones within mélange units provide more accurate younger depositional ages than radiolarian ages derived from mudstone. Determining true depositional ages requires a combination of fossil data, detrital zircon ages, and provenance information. Fission‐track ages using zircons estimated YC1σ U–Pb ages are useful for assessing depositional and annealing ages for the low‐grade metamorphosed accretionary complex. These new dating presented here indicates the following tectonic history of the accretionary wedge. Evolution of the Shimanto accretionary complex from the Albian to the Turonian was caused by the subduction of the Izanagi plate, a process that supplied sediments via the erosion of Permian and Triassic to Early Jurassic granitic rocks and the eruption of minor amounts of Early Cretaceous intermediate volcanic rocks. The complex subsequently underwent intensive igneous activity from the Coniacian to the early Paleocene as a result of the subduction of a hot and young oceanic slab, such as the Kula–Pacific plate. Finally, the major out‐of‐sequence thrusts of the Fukase Fault and the Aki Tectonic Line formed after the middle Eocene, and this reactivation of the Shimanto accretionary complex as a result of the subduction of the Pacific plate.  相似文献   

A model of river flow forecasting for a small forested mountain catchment     

Yoshihiro Fukushima 《水文研究》1988,2(2):167-185

A model for quantitatively expressing the hydrological cycle in a forested mountain catchment is proposed as a HYCYMODEL. HYCYMODEL is able to predict both short- and long-term hydrographs because the model parameters remain independent of time. It shows a good applicability for ten years of continuous data at both hourly and daily intervals for the Kiryu catchment—a forested mountain basin. Since HYCYMODEL does not need hydrograph separation between storm flow and base flow, it is a particularly attractive model.  相似文献