Synthesis of γ-Mg₂SiO₄     

Eiji Ito  Yoshito Matsui  Kaichi Suito  Naoto Kawai 《Physics of the Earth and Planetary Interiors》1974,8(4):342-344

Magnesium orthosilicate with spinel structure (γ-Mg₂SiO₄) was synthesized at about 250 kbar and 1000°C. Unit cell dimension was established to be 8.076 ± 0.001Å. X-ray powder diffraction pattern revealed a significant difference between γ-Mg₂SiO₄ and other γ-M₂SiO₄ spinels (M = Fe, Co, and Ni) in the intensities of (111) and (331) reflections, both of which are virtually absent in the Mg₂SiO₄ spinel. This feature could be thoroughly understood by the calculation of the intensities for several silicate spinels.  相似文献   

δC and δD identification of sources of lipid biomarkers in sediments of Lake Haruna (Japan)     

Yoshito Chikaraishi  Hiroshi Naraoka 《Geochimica et cosmochimica acta》2005,69(13):3285-3297

Organic materials in lacustrine sediments are from multiple terrestrial and aquatic sources. In this study, carbon (δ¹³C) and hydrogen isotopic compositions (δD) of phytol, various sterols, and major n-fatty acids in sediments at Lake Haruna, Japan, were determined in their solvent-extractable (free) and saponification-released forms (bound). The δ¹³C-δD distributions of these lipid molecules in sediments are compared with those of terrestrial C3 and C4 plants, aquatic C3 plants, and plankton to evaluate their relative contributions. δ¹³C-δD of free phytol in sediments is very close to that of phytol in plankton samples, whereas δ¹³C-δD of bound phytol in sediments is on a mixing line between terrestrial C3 plant and plankton material. Unlike phytol, no significant δ¹³C-δD difference between free and bound forms was found in sterols and n-fatty acids. δ¹³C-δD values of algal sterols such as 24-methylcholesta-5,22-dien-3β-ol in sediments are close to those of plankton, whereas δ¹³C-δD of multiple-source sterols such as 24-ethylcholest-5-en-3β-ol and of major n-fatty acids such as n-hexadecanoic acid in sediments are between those of terrestrial C3 plants and plankton samples. Thus, δ¹³C-δD distributions clearly indicate the specific source contributions of biomarkers preserved in a lacustrine environment. Free phytol and algal sterols can be attributed to phytoplankton, and bound phytol, multiple source sterols, and major n-fatty acids are contributed by both terrestrial C3 plants and phytoplankton.  相似文献   

A new type of orthopyroxenite xenolith from Takashima, Southwest Japan: silica enrichment of the mantle by evolved alkali basalt     

Shoji Arai  Yohei Shimizu  Tomoaki Morishita  Yoshito Ishida 《Contributions to Mineralogy and Petrology》2006,152(3):387-398

We found fine-grained Fe-rich orthopyroxene-rich xenoliths (mainly orthopyroxenite) containing partially digested dunite fragments of Group I from Takashima, Southwest Japan. Orthopyroxenite veinlets, some of which contain plagioclase at the center, also replace olivine in dunite and wehrlite xenoliths of Group I. This shows high reactivity with respect to olivine of the melt involved in orthopyroxenite formation, indicating its high SiO₂ activity. The secondary orthopyroxene of this type is characterized by low Mg# [= Mg/(Mg + total Fe) atomic ratio] (down to 0.73) and high Al₂O₃ contents (5–6 wt%). It is different in chemistry from other secondary orthopyroxenes found in peridotite xenoliths derived from the mantle wedge. Clinopyroxenes in the Fe-rich orthopyroxenite show a convex-upward REE pattern with a crest around Sm. This pattern is strikingly similar to that of clinopyroxenes of Group II pyroxenite xenoliths and of phenocrystal and xenocrystal clinopyroxenes, indicating involvement of similar alkali basaltic melts. The Fe-rich orthopyroxenite xenoliths from Takashima formed by reaction between evolved alkali basalt melt and mantle olivine; alkali basalt initially slightly undersaturated in silica might have evolved to silica-oversaturated compositions by fractional crystallization at high-pressure conditions. The Fe-rich orthopyroxenites occur as dikes within the uppermost mantle composed of dunite and wehrlite overlying pockets of Group II pyroxenites. The orthopyroxene-rich pyroxenites of this type are possibly common in the uppermost mantle beneath continental rift zones where alkali basalt magmas have been prevalent.  相似文献   

Aeromagnetic surveys in the seas around Japan in 1980     

S. Utashiro  S. Oshima  T. Kaneko 《Surveys in Geophysics》1984,6(3-4):271-290

Aeromagnetic surveys in the seas around Japan were carried out in 1979 to 1980 by a YS-11 aircraft of the Maritime Safety Agency of Japan using a new type of airborne magnetometer system. The new type of airborne magnetometer system consists of a ring-core type three-component fluxgate magnetometer, an inertial sensing system, a fish-eye camera to measure the true north, an 8-bit microcomputer and a proton magnetometer. The VLF/OMEGA system is used to fix the position of the aircraft. Tracks extended to about 600 nautical miles off the coast of the Japanese islands in the Sea of Japan and the North-West Pacific Ocean. Average spacing between tracks was about 80 miles. The flights were carried out at an altitude of 9500 feet. From the survey results, magnetic charts of the seven geomagnetic elements for 1980 over the sea around Japan were compiled by the method of least squares using a polynomial. Also, the contour charts of secular variation in 1980 were compiled.  相似文献   

Buoyancy-driven propagation of an isolated fluid-filled crack in rock: implication for fluid transport in metamorphism   总被引：1，自引：0，他引：1  

Yoshito Nakashima 《Contributions to Mineralogy and Petrology》1993,114(3):289-295

A new model for upward transport of buoyant fluid released during metamorphism is proposed. The model is fluid transport by buoyancy-driven propagation of isolated fluid-filled cracks. The mechanical behavior of a two-dimensional, isolated, vertical, and fluid-filled crack in impermeable rock is investigated using linear fractire mechanics and fluid dynamics. The results show that steady-state crack propagation which causes long-distance transport of the fluid occurs when the vertical cross-sectional area of the crack exceeds a critical value. Propagation velocity and average thickness of the crack under the steady-state propagation regime are expressed explicitly by the following seven parameters: vertical crack length; rigidity, Poisson's ratio, and fracture toughness of the rock; fluid viscosity; density difference between the rock and the fluid; gravitational acceleration. An isolated H₂O-filled crack of vertical length 100 m, for example, propagates upwards in the crust at 0.3 m/s with the average thickness 0.2 mm when the following likely values are assumed: 0.1 mPa s for the H₂O viscosity; 3 MPa m^1/2 for the fracture toughness of the crustal rock. The application of the obtained results to the transport of H₂O released during metamorphism suggests that the number density of isolated cracks propagating in the crust is very low. Since the propagation velocity is high, our model is suitable particularly for fluid transport through hot quartz-rich rock where fluid-filled cracks have geologically short lifetimes.  相似文献   

Degradation of algal lipids by deep-sea benthic foraminifera: An in situ tracer experiment     

Hidetaka Nomaki  Naohiko Ohkouchi  Petra Heinz  Hisami Suga  Yoshito Chikaraishi  Nanako O. Ogawa  Kouhei Matsumoto  Hiroshi Kitazato 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(9):1488-1503

We conducted an in situ feeding experiment using ¹³C-labeled unicellular algae in Sagami Bay, Japan (water depth, 1450 m), in order to understand the fate of lipid compounds in phytodetritus at the deep-sea floor. We examined the incorporation of excess ¹³C into lipid compounds extracted from bulk sediments and benthic foraminiferal cells. ¹³C-enriched fatty acids derived from ¹³C-labeled algae were exponentially degraded during 6 days of incubation in the sediment. Subsequent enrichments in ¹³C in sedimentary n-C_15, anteiso-C₁₇, and C₁₇ fatty acids indicated the microbial degradation of algal material and production of bacterial biomass in the sediment. We observed the incorporation of ¹³C-labeled algal phytol and fatty acids into foraminiferal cells. The compositions of ¹³C-labeled algal lipids in foraminiferal cells were different from those in the bulk sediments, indicating that foraminiferal feeding and digestion influenced the lipid distribution in the sediments. Furthermore, some sterols in Globobulimina affinis (e.g., 24-ethylcholesta-5,22-dien-3β-ol, 24-ethylcholest-5-en-3β-ol, and 23,24-dimethylcholesta-5,22E-dien-3β-ol) were newly produced via the modification of dietary algal sterols within 4–6 days. In addition to the effects of bacteria, feeding by benthic foraminifera can result in a significant reorganization of the composition of organic matter and influence benthic food webs and carbon cycling at the deep-sea floor.  相似文献   

Microbially induced formation of ooid-like coated grains in the Late Cretaceous methane-seep deposits of the Nakagawa area, Hokkaido, northern Japan     

Robert Gwyn  Jenkins  Yoshinori  Hikida  Yoshito  Chikaraishi  Naohiko  Ohkouchi  Kazushige  Tanabe 《Island Arc》2008,17(2):261-269

Abstract   Ooid-like coated grains are found in the Late Cretaceous methane-seep deposits in the Nakagawa area, Hokkaido, Japan. The coated grains were examined using macro- and microscopic observations, electron-probe microanalysis, and biomarker analysis. They are round- to oval-shaped, with nuclei consisting of fractured sediment and micritic envelopes. The fractures probably occurred as a result of increasing hydrostatic pressure when the sediment was still unconsolidated or weakly consolidated. Biomarker analysis revealed that two types of molecules, crocetane and PMI, are predominant in the hydrocarbon fraction with highly negative carbon isotopic composition as low as −122‰ ( vs Vienna Peedee Belemnite). These data suggest that the coated grains were formed under the influence of anaerobic oxidation of methane, near the sediment/seawater interface. The presence of such grains indicates that methane-containing pore water reached the sea floor at that time.  相似文献   

Foreword     

S. Aramaki  S. Matsuo  O. Oshima  T. Tiba  Y. Sawada 《Bulletin of Volcanology》1992,54(Z1):1-6

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Sulfur bacteria originating from the water and organisms in a hydrothermally active area of the mid-okinawa trough     

Takeshi Naganuma  Eiko Ikemoto  Shunji Sukizaki  Yoshito Tsuji  Hiroshi Hotta 《Journal of Oceanography》1990,46(3):111-117

Hydrothermal venting and associated fauna were observed in the mid-Okinawa Trough during deep-sea diving byShinkai 2000. Water and organisms were collected there for on-board cultivation of sulfur bacteria. Sulfur bacteria capable of growing on an inorganic medium containing thiosulfate were subcultured and isolated. The isolated chemoautotrophic sulfur bacteria were all rod- to beanshaped, nonsporing, and gram-negative. They could also grow on an organic medium and thus were shown to be facultative chemoautotrophs. Their facultative chemoautotrophy would result in synergetic metabolism of both inorganic and organic substrates; thus the sulfur bacteria could be highly adaptive to nutritional diversity of hydrothermal vent areas.  相似文献   

Vertical distribution of bacterial abundance in the northwest pacific ocean     

Takeshi Naganuma  Eiko Ikemoto  Shunji Sukizaki  Yoshito Tsuji  Hiroshi Hotta 《Journal of Oceanography》1990,46(3):107-110

Mixed populations of free-living marine bacteria were collected at depths from the surface to the bottom (1,960m in Suruga Bay and 1,585 m in the Japan Sea) in the northwest Pacific during deep-sea diving by the submersible,Shinkai 2000. Their abundance in total cell counts and in lipopolysaccharide (LPS) concentration was found to decrease with increasing depth, and the decreasing profiles were shown to be linear on logarithmic scales. The total cell counts and the LPS concentration showed a linear relationship on arithmetic scales, and the LPS content per cell was found to be 1.02×10^–14 g.  相似文献