Determination of thorium isotopes in seawater by moored MnO2-fiber method     

Nozaki  Yoshiyuki 《Journal of Oceanography》1983,39(3):129-135

A method is described for the determination of Th isotopes (²³²Th,²³⁰Th,²²⁸Th and²²⁷Th) in seawater through analysis of Th adsorbed on MnO₂-impregnated fiber that has been moored in the deep sea for up to 10 months. Since the MnO₂-fiber adsorbs Th from seawater at a constant rate, natural²³⁴Th can be used as a yield monitor by making a correction for its decay during the period of deployment. The results obtained by the method showed good reproducibility and accuracy. The method has the advantage over the chemical coprecipitation method that the time and labor for sampling and processing a large-volume of seawater is reduced.  相似文献   

Th and Pa isotopes in the waters of the western margin of the pacific near Japan: Evidence for release of228Ra and227Ac from slope sediments     

Yoshiyuki Nozaki  Han-Soeb Yangt 《Journal of Oceanography》1987,43(4):217-227

Using the moored MnO₂-fiber method, we have obtained 38 determinations of Th and Pa isotope concentrations from 18 sites along the margin of the western North Pacific near Japan, from water depths of 1,330 to 5,873 m. From our data, we are able to show that (1)²²⁸Ra and²²⁷Ac are being supplied to the seawater from the slope sediments of Honshu, Japan, (2) our²³⁰Th and²³¹Pa concentrations match those obtained byin situ pumping with a MnO₂-fiber adsorber in the Japan and Izu-Ogasawara trenches but are significantly higher than those from the Panama and Guatemala basins, and (3) our²³²Th concentrations show a similar systematic decrease with depth as do those of trace metals like Mn, Al, Te and Bi whose concentrations are strongly controlled by particulate matter scavenging.In contrast, our data fail to show (1) that enhanced removal of²³⁰Th and²³¹Pa by scavenging from the water column is taking place near the western margins and (2) that²³¹Pa is being removed in preference to²³⁰Th from the water column to the marginal sediments. This is probably due to rapid mixing of the deep waters as compared to the scavenging rates of²³⁰Th and²³¹Pa in the water column and at the sediment/seawater interface.  相似文献   

Radium isotopes in coastal and open ocean surface waters of the Western North Pacific   总被引：1，自引：0，他引：1  

Masatoshi Yamada  Yoshiyuki Nozaki 《Marine Chemistry》1986,19(4)

Using manganese-impregnated fiber extraction and high-efficiency gamma counting techniques, we measured the distribution of ²²⁸Ra and ²²⁶Ra in surface waters near the coast of Japan and in the western North Pacific. There is no evidence in our data that any significant amount of ²²⁸Ra is added to open ocean surface waters from the coastal waters around Tokyo Bay. High ²²⁸Ra concentrations (> 10 dpm/10³ kg), were observed along the Kuroshio Current as compared to < 2.5 dpm/10³ kg between 10° and 30°N of the central gyre, and hence the major source of ²²⁸Ra in the surface water is likely to be the East Asian continental shelf zones. A simple one-dimensional eddy diffusion and advection model is used to explain the observed decrease of ²²⁸Ra from coast to the open ocean. The model results indicate two mixing regimes across the Kuroshio Current System with apparent eddy diffusion coefficients of K_y = 4 × 10⁵ cm² s⁻¹ at distance y < 200 km from the coast, and K_y = 4 × 10⁷ cm² s⁻¹ at y > 200 km. Along 40°N where an eastward flow of the ‘Kuroshio Extension’ prevails, an advective flow of > 0.1 knot is consistent with the observation of nearly constant ²²⁸Ra along the track.The geographical distribution pattern of ²²⁸Ra is clearly different from that of atmospherically derived ²¹⁰Pb. Thus the ²²⁸Ra in surface water serves as a useful tracer that accompanies fluvially and coastally derived elements during their subsequent lateral transport toward the central gyre.  相似文献   

Reconstruction of pH in the Surface Seawater over the North Pacific Basin for All Seasons Using Temperature and Chlorophyll-<Emphasis Type="Italic">a</Emphasis>     

Yoshiyuki?NakanoEmail author  Yutaka?W.?Watanabe 《Journal of Oceanography》2005,61(4):673-680

We found a simple function of pH that relates to sea surface temperature (SST, K) and chlorophyll-a (Chl, µg l⁻¹) using measured surface seawater pH, SST and Chl data sets over the North Pacific: pH (total hydrogen scale at 2°C) = 0.01325 SST − 0.0253 Chl + 4.150 (R² = 0.95, p < 0.0001, n = 483). Moreover, evaluating the seasonal variation of pH based on this algorithm, we compared the measured pH with the predicted pH at the observational time series stations in subpolar and subtropical regions. The average of ΔpH (measured - predicted, n = 52) was 0.006 ± 0.022 pH. Therefore, the combination of SST and Chl can allow us to determine the spatiotemporal distribution of pH over the North Pacific. Using the climatological data sets of SST and Chl with our pH algorithms, we have described the seasonal distributions of pH at 25°C (pH₍₂₅₎) and pH in situ temperature (pH_(T)) over the North Pacific surface water.  相似文献   

Changes in the lower limit of mountain permafrost between 1973 and 2004 in the Khumbu Himal, the Nepal Himalayas   总被引：2，自引：0，他引：2  

Kotaro Fukui  Yoshiyuki Fujii  Yutaka Ageta  Katsuhiko Asahi 《Global and Planetary Change》2007,55(4):251-256

Because the Khumbu Himal of the Nepal Himalayas lacks long-term climate records from weather stations, mountain permafrost degradation serves as an important indicator of climate warming. In 1973, the permafrost lower limit was estimated to be 5200–5300 m above sea level (ASL) on southern-aspect slopes in this region. Using ground-temperature measurements, we examined the mountain permafrost lower limit on slopes with the same aspect in 2004. The results indicate that the permafrost lower limit was 5400–5500 m ASL in 2004. The permafrost lower limit was estimated to be 5400 to 5500 m on slopes with a southern aspect in the Khumbu Himal in 1991 using seismic reflection soundings. Thus, it is possible that the permafrost lower limit has risen 100–300 m between 1973 and 1991, followed by a stable limit of 5400 to 5500 m over the last decade. An increase in mean annual air temperature of approximately 0.2 to 0.4 °C from the 1970s to the 1990s has indicated a rise in the permafrost lower limit of 40 to 80 m at the Tibetan Plateau. The rise in the mountain permafrost lower limit in the Khumbu Himal exceeds that of the Tibetan Plateau, suggesting the possibility of greater climate warming in the Khumbu Himal.  相似文献   

理学ZSX系列X荧光光谱仪中文软件开发   总被引：3，自引：1，他引：3  

邓赛文  片冈由行 《岩矿测试》2001,20(3):226-233

介绍了日本理学ZSX系列X荧光光谱仪的特点和新开发的中文版软件的功能。  相似文献   

Tectonic setting of high-Mg andesite magmatism in the SW Japan arc: K–Ar chronology of the Setouchi volcanic belt     

Yoshiyuki Tatsumi  Naoto Ishikawa  Ken Anno  Kyoichi Ishizaka  Tetsumaru Itaya 《Geophysical Journal International》2001,144(3):625-631

  相似文献   

Helium and carbon isotopes in fluorites: implications for mantle carbon contribution in an ancient subduction zone   总被引：1，自引：0，他引：1  

Junji Yamamoto  Makoto Watanabe  Yoshiyuki Nozaki  Yuji Sano   《Journal of Volcanology and Geothermal Research》2001,107(1-3)

The concentrations of helium and carbon in fluorite associated with Cretaceous to Neogene (90–13 Ma) granitic magmatism in the Japanese arc have been measured. Concentrations of Li, U, Th and Gd were measured to correct for secondary generated ³He. The CO₂/³He of fluorites are almost uniform (1.5×10¹⁰–4×10¹⁰) and in fair agreement with the range of present island arc volcanic gases. The calculated mantle C contribution in the Mesozoic subduction zone appear to have been identical to the present one (7–19%) indicating that the C flux from the mantle in supra-subduction zone environments has remained fairly constant during the past 70 million years.  相似文献   

Rapid and frequent turbidite accumulation in the bottom of Izu-Ogasawara Trench: Chemical and radiochemical evidence   总被引：1，自引：0，他引：1  

Yoshiyuki Nozaki  Yoichi Ohta 《Earth and Planetary Science Letters》1993,120(3-4):345-360

Two sediment cores (pilot gravity and piston) were obtained from the bottom of the Izu-Ogasawara Trench at 9750 m and analyzed for various elements and radioisotopes. The results showed a history of complex and frequent turbidite deposition: In the gravity core, eight layers rich in manganese were observed, of which five are enriched in Cu and Co as well. The other three are also enriched in Mo but no other heavy metals, suggesting the presence of at least two mechanisms of formation. Trapping of iron manganese micronodules can account for the enrichment of Mn, Cu and Co. The other three layers rich in Mn and Mo appear to be formed by a post-depositional diagenetic process of Mn mobilization and redeposition in the sediment column. A strong correlation between ²²⁶Ra and Cu in the gravity core suggests that the ²²⁶Ra was also carried into the bottom of the trench in turbidites in association with Mn micronodules. Little excess of ²¹⁰Pb over ²²⁶Ra was found at the top but the excess was significant at mid-depths from 30 to 70 cm, indicating that those sediments were deposited within the last 200 y.

In the piston core there is a sharp discontinuity of chemical and radiochemical composition around a depth of 250 cm. Below that depth the sediments appear to be dominated by materials derived from terrestrial sources, as compared with those in the upper layer which are of contemporary marine origin. ²²⁶Ra is deficient relative to ²³⁰Th throughout the sediment column down to 6 m. This finding is consistent with the finding that the average rate of sediment accumulation is 1–2 orders of magnitude faster than that in the western North Pacific abyssal plain, suggesting the convergence of materials into the bottom of the trench.  相似文献   

Magnesian andesite and basalt from Shodo-Shima Island,southwest Japan,and their bearing on the genesis of calc-alkaline andesites     

Yoshiyuki Tatsumi  Kyoichi Ishizaka 《Lithos》1982,15(2):161-172

Calc-alkaline andesites and olivine tholeiitic basalts are widely distributed on Shodo-Shima island, southwest Japan. The Fo content of olivine phenocrysts in the andesite is higher than in the basalt. The primary magma of the andesite, estimated on the basis of the olivine fractional crystallization model, is not basaltic but andesitic. The basalt contains both chromite and titanomagnetite as inclusions in olivine phenocrysts, while only chromite appears in the andesite. The Cr content of chromite in the andesite is higher than in the basalt. These facts again indicate that the andesite cannot be a fractionation product of the basalt, and that andesitic and basaltic primary magmas were generated independently.  相似文献