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91.
Compressional wave velocities (VP) at above-solidus temperatures and at 1 GPa were obtained for a granite and amphibolite, which are considered to be major constituents of the continental crust. The temperature variation of velocities showed that the VP values of granite decreased with rising temperature, but substantially increased beyond the melting temperature (850–900 °C). Such an increase may be caused by the α–β transition of quartz. The velocities of amphibolite decreased linearly with increasing temperature and dropped sharply at temperatures above the solidus (700 °C), indicating that partial melting of amphibolite acts to significantly lower the seismic velocities.  相似文献   
92.
In order to evaluate the mechanism of production of unusual high-Mg andesite (HMA) magmas, Pb–Nd–Sr isotopic compositions were determined for HMAs and basalts from the Miocene Setouchi volcanic belt in the SW Japan arc. The isotopic compositions of Setouchi rocks form mixing lines between local oceanic sediments and Japan Sea backarc basin basalts, suggesting a significant contribution of the subducting sediment component to the HMA magma generation. Mixing calculations using compositions of an inferred original mantle and local oceanic sediments suggest that a sediment-derived melt, neither an H2O-rich fluid nor an amphibolite/eclogite-derived melt, could have been produced first and served as a plausible metasomatic agent for the HMA magma source. The unusual tectonic setting, including subduction of a newly-borne hence hot plate, may be responsible for melting of subducting sediments.  相似文献   
93.
 An unspiked K–Ar dating method using a mass-fractionation correction procedure was applied to a Quaternary independent group of monogenetic volcanoes, Ojikajima Volcano Group, located in northwestern Kyushu in Southwest Japan, in order to clarify in detail secular variations in eruptive volume, locations of eruptive vents, and magma compositions in a single monogenetic volcano group. The major results were as follows: (a) K–Ar ages of monogenetic volcanoes distribute from 1.08 to 0.30 Ma, with voluminous peaks at approximately 1.0 and 0.6 Ma. (b) The volcanic activity commenced in the central part of the field, expanded to the whole field at approximately 0.6 Ma, and then shrank to the central area. (3) Concentrations of incompatible elements, such as Ba, K, and Nb, increase with decreasing age, whereas P, Y, and Zr concentrations remain constant. These concentrations suggest gradual decrease in the degree of partial melting from an identical mantle source with residual garnet. Received: 15 December 1997 / Accepted: 23 May 1998  相似文献   
94.
Two methods have been developed to measure indium (In) in natural waters by flow injection inductively coupled plasma mass spectrometry (ICPMS). One is the isotope dilution technique using an113In enriched spike and the other utilizes natural yttrium present in the sample as an internal standard. In the former, optimization of the113In spike to minimize error is often difficult for samples in which In concentrations are variable, whereas in the latter method, a separate determination of Y in the sample is necessary and hence more sample is required. Using about 1 liter of a water sample, 200 fold preconcentration of In was performed by solvent extraction and back extraction technique and then introduced into the ICPMS to measure the113In/115In or115In/89Y ratios. The detection limits were 0.01–0.02 pmol kg−1 for both methods. Application of the methods to seawater samples yielded the concentrations of 0.06–0.15 pmol kg−1 for the Pacific and 0.6–1.5 pmol kg−1 for the Atlantic. The large inter-oceanic variation of In best resembles that of Al amongst the 3B group of elements in the periodic table. River and estuarine samples gave a more variable range of concentrations of 0.01–15 pmol kg−1. Most of the In supplied by rivers is removed by scavenging in the estuarine mixing zone, suggesting that the fluvial input of In to the ocean is small.  相似文献   
95.
Vertical profiles for the uranium-series radioisotopes 210Pb and 210Po were obtained at thetwo hydrothermal vent sites, the Iheya Ridge and the Minami-Ensei Knoll, in the Mid-Okinawa Trough in 1993 and 1994, respectively. In 1995, both radioisotopes were measured at the Minami-Ensei Knoll a-gain. At the Iheya Ridge, where the hydrothermal activity is not active as reflected by the CH_4, and 222Rn data, both the total 210Pb and 210Po activities show deficiency relative to their parents, and the mean residence time of 210Pb and 210Po is approximately equal to 20 and 2-5 a, respectively. At the Minami-Ensei Knoll, which is characterized by black smokers, the total 210Pb(0.167 × 10~(-3)-2.5 × 10~(-3)_ Bq/kg) around the plumes is deficient relative to 226Ra but the total 210Po activities (1.83 × 10 ~(-3) - 2.83 × 10~(-3) Bq/kg) are in excess relative to 210Pb. The 210Po activities are higher than those in the East China Sea and the Okinawa Trough and excess 210Po has been found. The 210Pb/226Ra and 210Po/  相似文献   
96.
The concentration of dissolved rare earth elements (REE) were determined at 47 stations in the North Pacific surface waters. Combining with other previous data, we present the surface REE distribution in the North Pacific and discuss the controlling factors. The surface concentrations increase toward the high latitude and continental margin (e.g. [Nd] > 10 pmol kg−1) from the central North Pacific (e.g. [Nd] < 5 pmol kg−1). The North Pacific Deep Water-normalized REE patterns are varied, indicating that two or more factors contribute to the REE distribution. We examined four factors making the regional variation of surface REE concentrations mainly; a) particle scavenging, b) atmospheric dust input, c) vertical mixing and d) lateral transport from the coastal region. Flux calculations for Nd showed that the influence of atmospheric dust was less significant than the vertical input even in the western upwelling zone. Moreover, the longitudinal and latitudinal transitions of surface REE seem to reflect the lateral supply from the coastal areas. We constructed the diagram of surface Er/Lu and Er/Yb molar ratios in order to assess the origin and the input processes of the surface REE. Both molar ratios showed increasing trend toward PEW (Er/Lu (>10.5) and Er/Yb (>1.4)) from PSUW (Er/Lu (>7) and Er/Yb (>1.2)). The high Er/Lu and Er/Yb ratios in PEW indicate that the lateral supply of terrestrial materials from the coastal area is possibly the important factor in PEW, because only weathering and dissolution of rocks can explain such high Er/Lu and Er/Yb ratios to our knowledge.  相似文献   
97.
This is the first detailed study on the distribution of lead-210 in the Japan Sea water. The content of lead-210 ranged from 9.3±2.1 dph/l in the surface water to 3.4+-0.8 dph/l in the deep water—a quite low content as compared to that in the deep water of the North Pacific. Vertical profiles show that the content of lead-210 abruptly decreases below the seasonal thermocline (10–20 m in depth) and nearly uniform in the deep water. It is suggested that a significant amount of air-borne lead-210 deposited over the Japan Sea is transported along with the Tsushima Current to the open ocean. The budget of lead-210 is calculated by using a simple box-model and the mean residence time of lead-210 in the Japan Sea is estimated to be 15 yr.  相似文献   
98.
Major and trace element, and Sr-Nd isotope compositions were determined for Quaternary volcanic rocks from NE Sulawesi (the Sangihe are), Indonesia, in order to examine the origin of across-arc variation in lava and magma source chemistry. The arc is formed in an intraoceanic tectonic setting and is not associated with a backarc basin, thereby minimizing possible contributions from non-arc geochemical reservoirs. The geochemistry of these arc lavas is likely to provide essential information about the chemical characteristics of subduction components. All incompatible elements, except Pb, increase away from the volcancic front. Major element data for Mg-rich lavas together with available experimental data, suggest that primary magmas are produced at higher pressured by smaller degrees of partial melting beneath the backarc-side volcanoes. Rb/K and Ba/Pb are higher, and 87Sr/86Sr and 143Nd/144Nd are lower in backarc-side lavas. These variations may be attributed to generation of hydrous fluids in the downdragged hydrous peridotite layer at the base of the mantle wedge through the following reactions: decompositions of pargasitic amphibole to form phlogopite and breakdown of phlogopite to crystallize K-richterite, beneath the volcanic front and the backarc-side volcanoes, respectively.  相似文献   
99.
An absarokite from a phlogopite lherzolite source   总被引:1,自引:0,他引:1  
An absarokite (SiO2 47.72 wt %, K2O 3.41 wt %) occurs in the Katamata volcano, SW Japan. The rock carries phenocrysts of olivine, phlogopite, clinopyroxene, and hornblende. Chemical compositions of bulk rock (FeO*/ MgO 0.73) and minerals (Mg-rich olivine and phlogopite, Cr-rich chromite) suggest that the absarokite is not differentiated. Melting experiments at high pressures on the Katamata absarokite have been conducted. The completely anhydrous absarokite melt coexists with olivine, orthopyroxene, and clinopyroxene at 1310° C and 1.0 GPa. The melt with 3.29 wt % of H2O also coexists with the above three phases at 1230° C and 1.4 GPa; phlogopite appears at temperatures more than 80° C below the liquidus. On the other hand, the melt is not saturated with lherzolite minerals in the presence of 5.13 wt % of H2O and crystallizes olivine and phlogopite as liquidus phases; the stability limit of phlogopite is little affected at least by the present variation of H2O content in the absarokite melt. It is suggested that the absarokite magma was segregated from the upper mantle at 1170° C and 1.7 GPa leaving a phlogopite lherzolite as a residual material on the basis of the above experimental results and the petrographical observation that olivine and phlogopite crystallize at an earlier stage of crystallization sequence than clinopyroxene. The contribution of phlogopite at the stage of melting processes is also suggested by the geochemical characteristics that the absarokite is more enriched in Rb, K, and Ba and depleted in Ca and Na than a typical alkali olivine basalt from the same volcanic field.  相似文献   
100.
To carry out comparative geochemical investigation of refractory and reactive metals in different oceanic settings covering different θ-S characteristics, productivity, dissolved oxygen profiles, water and sediment discharge, etc., we have determined the vertical profiles of dissolved (<0.04 μm) Al, In and Ce, as well as 210Pb and 210Po in the eastern Indian Ocean (from 40°S in the Southern Ocean to 8°N in the Bay of Bengal) and the Southeast Asian Seas. In the Antarctic Circumpolar Region, the concentrations of these refractory metals are very low, presumably due to very low the atmospheric input and intensified scavenging. Resemblance in the vertical profiles of these metals is often seen in some other stations. However, there are also significant differences among their distributions, for example, in the magnitude of surface enrichment caused by the external input from eolian and fluvial-coastal sources. Comparison of Al distributions in surface waters with those of atmospherically derived 210Pb suggests the relative importance of eolian input over fluvial-coastal sources. Fluvial and coastal input appears to be insignificant for dissolved In, but may be important for Ce. The mean residence time of Al in the surface mixed layer was estimated to be ∼2 years which is similar to that of 210Pb.In the intermediate and deep waters, the concentrations of each element vary with depth and location. The range of variation is in the order of Al>Ce>In, depending upon particle reactivity. Although dissolved Al decreases along the water trajectory by particle scavenging, variations of dissolved In and Ce are relatively small which may be due to less scavenging for both elements. Compared with significantly high (>4 pM) dissolved Ce throughout the water column in the Bay of Bengal, dissolved Al concentration remains low, suggesting that it has higher affinity to particles and hence is scavenged by sinking particulate matter. This is consistent with the observation that the dissolved Al in the Antarctic Intermediate Water (AAIW) decreases from 4 to 6 nM in the 30°S Perth Basin to <0.7 nM in the 10°S West Australia Basin along its trajectory. Using the chlorofluorocarbons (CFCs) ventilation age of AAIW (Fine, 1993), the mean residence time of Al in the intermediate and deep waters in the eastern Indian Ocean is estimated to be <17 yr, approximately the same as that of 210Pb (10-15 yr). In the semiclosed basins of Southeast Asia, the distributions of Al, In and Ce are also very unique. In the South China Sea, there is a strong sediment source for dissolved In and Ce during the deepwater passage through the Luzon Strait.  相似文献   
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