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981.
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The presence of ultrahigh-energy (UHE) cosmic rays results in an increase in the degree of ionization in the post-recombination Universe, which stimulates the efficiency of the production of H2 molecules and the formation of the first stellar objects. As a result, the onset of the formation of the first stars is shifted to higher redshifts, and the masses of the first stellar systems decrease. As a consequence, a sufficient increase in the ionizing radiation providing the reionization of the Universe can occur. We discuss the possible observational manifestations of these effects and their dependence on the parameters of UHE cosmic rays. 相似文献
984.
V. I. Vinogradov G. A. Belenitskaya M. I. Bujakaite V. N. Kuleshov M. A. Minaeva B. G. Pokrovskii 《Lithology and Mineral Resources》2006,41(1):85-97
New isotope data on Lower Cambrian rocks of the Irkutsk amphitheater are reported in three communications. The first communication
is devoted to the sulfur isotopic composition, which is most sensitive to ostsedimentary geochemical transformations of sulfate
rocks in saliferous formations. It is shown that δ34S values in Bel’sk and Zhigalovo boreholes are within 22–35‰ The lowest values are close to the sulfur isotopic composition
of a halogenic basin, while the highest values are related to epigenetic sulfate reduction. This process was responsible for
the elimination of 100 m of anhydrites from the Lower Cambrian section. 相似文献
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E. M. Chamorro Pérez I. Daniel J.-C. Chervin P. Dumas J. D. Bass T. Inoue 《Physics and Chemistry of Minerals》2006,33(7):502-510
High-pressure synchrotron infrared (IR) absorption spectra were collected between 650 and 4,000 cm−1 at ambient temperature for hydrous Mg-ringwoodite (γ-Mg2SiO4) up to 30 GPa. The main feature in the OH− stretching region is an extremely broad band centred at 3,150 cm−1. The hydrogen bond is strong for most protons and the most probable site for protonation is the tetrahedral edge. With increasing pressure, this band shifts downward while decreasing its integrated intensity until disappearance at a pressure of 25 GPa. Only one band at 2,450 cm−1 and an absorption plateau persist with a maximum wavenumber of 3,800 cm−1. This behaviour is reversible upon pressure release. We interpret this as a second-order phase transition occurring in hydrated Mg-ringwoodite at high pressure (beyond ∼ 25 GPa). This result is compatible with the observation by Kleppe et al. (Phys Chem Miner 29:473–476, 2002a) who suggested the presence of Si–O–Si linkages and/or partial increase in the coordination of Si. Beyond the phase transition, the protons are delocalized and their environment on the ringwoodite structure is probably quite different from that at low pressure. Data obtained in situ at high pressures and temperatures are needed to better understand the effect of protonation on the structure and to better constrain this phase transition. 相似文献
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