Enzymatic synthesis of methyl-galactoaldehyde     

Wang Qun  Yu Guangli 《中国海洋大学学报(英文版)》2002,1(2):145-147

Methyl-galactosides were oxidized at room temperature by galactose oxidase in a one-step reaction and afforded methyl-galactoaldehyde in excellent yield and high purity. The resulting galactoaldehyde as a useful intermediate can be directly used in glycopeptide synthesis.  相似文献   

A comparison of theoretical Sv emission line strengths with extreme ultraviolet observations of a sunspot     

F. P. Keenan  J. G. Doyle 《Solar physics》1990,128(2):345-351

Electron impact excitation rates for transitions in the S v ion, calculated with theR-matrix code, are used to derive the electron temperature sensitive emission line ratiosR ₁ =I(854.8 Å)/I(786.9 Å),R ₂ =I(852.2 Å)/I(786.9 Å),R ₃ =I(849.2 Å)/I(786.9 Å), andR ₄ =I(1199.1 Å)/I(786.9 Å), which are found to be significantly different from previous estimates. A comparison of the present results with observational data for a sunspot obtained with the Harvard S-055 spectrometer on boardSkylab reveals generally good agreement between theory and experiment, except in the case ofR ₁, which is probably due to blending in the 854.8 Å feature. The possible effects of Lyman continuum absorption on the observed line ratios is briefly discussed.  相似文献   

长江上游洪涝暴雨环流形势中期演变趋势分析     

郁淑华  骆红  芮良生 《成都信息工程学院学报》1990,(1)

本文通过对1980年以来长江上游10次洪涝过程的500hpa环流形势分析,并用车比雪夫多项式对500hpa高度场进行展开,研究了各类洪涝过程的中期演变特征,发现代表不同洪涝过程环流形势变化的不同的车氏系数值都有明显的特征变化,结合欧洲中心中期数值预告96小时500hpa高度场的车氏系数分析,可为洪涝暴雨的中期预报提供一种新的思路。  相似文献   

Evolution of Electric Currents Associated with Two M-Class Flares     

Baolin Tan  Haisheng Ji  Guangli Huang  Tuanhui Zhou  Qiwu Song  Yu Huang 《Solar physics》2006,239(1-2):137-148

Using one-minute cadence vector magnetograms from Big Bear Solar Observatory (BBSO), we analyze the temporal behavior of derived longitudinal electric currents associated with two flares on July 26, 2002. One of the events is an M1.0 flare which occurred in active region NOAA 10044, while the other is an M8.7 flare in the adjacent region 10039. Rapid changes of magnetic fields in the form of flux emergence are found to be associated with both of these events. However, the temporal behavior of electric currents are very different. For the M1.0 flare, the longitudinal electric current density drops rapidly near the flaring neutral line; while for the M8.7 flare, the current density rapidly increases, confirming the picture of the current-carrying flux emergence. We offer a possible explanation for such a difference: magnetic reconnection at different heights for the two events, near the photosphere for the M1.0 flare, and higher up for the M8.7 flare.  相似文献   

Simulations of multimode bolometric interferometers     

George Saklatvala  Michael P. Hobson  Stafford Withington 《Monthly notices of the Royal Astronomical Society》2006,367(3):1194-1200

We describe a procedure for the numerical modelling of astronomical interferometers, with particular relevance to far-infrared and submillimetre wavelengths. The scheme is based on identifying a set of modes that carry power from the sky to the detector. The procedure is extremely general, and can be used to model scalar or vector fields, in any state of coherence and polarization, the only limitation being that the propagation of a coherent field through the system be described by an integral transform, a constraint that is in practise always met.
We present simulations of ideal, multimode two-dimensional interferometers, and show that the modal theory reproduces the correct behaviour of both Michelson and Fizeau interferometers. We calculate simulated visibility data for a multimode bolometric Michelson interferometer, with a synthesized source, and produce a dirty map, recovering the original source with the usual artefacts associated with interferometers.  相似文献   

Thick and thin models of the evolution of carbon dioxide on Mars     

Curtis V. Manning  Christopher P. McKay 《Icarus》2006,180(1):38-59

We present results from a new simulation code that accounts for the evolution of the reservoirs of carbon dioxide on Mars, from its early years to the present. We establish a baseline model parameter set that produces results compatible with the present (i.e., Patm?6.5 mbar with permanent CO₂ ice cap) for a wide range of initial inventories. We find that the initial inventory of CO₂ broadly determines the evolutionary course of the reservoirs of CO₂. The reservoirs include the atmosphere, ice cap, adsorbed CO₂ in the regolith, and carbonate rocks. We track the evolution of the free inventory: the atmosphere, ice cap and regolith. Simulations begin at 4.53 Gyr before present with a rapid loss of free inventory to space in the early Noachian. Models that assume a relatively small initial inventory (?5 bar) have pronounced minima in the free inventory of CO₂ toward the end of the Noachian. Under baseline parameters, initial inventories below ∼4.5 bar result in a catastrophic loss of the free inventory to space. The current free inventory would be then determined by the balance between outgassing, sputtering losses and chemical weathering following the end of the late bombardment. We call these “thin” models. They generically predict small current free inventories in line with expectations of a small present CO₂ ice cap. For “thick” models, with initial inventories ?5 bar, a surplus of 300-700 mbar of free CO₂ remains during the late-Noachian. The histories of free inventory in time for thick models tend to converge within the last 3.5 Gyr toward a present with an ice cap plus atmospheric inventory of about 100 mbar. For thick models, the convergence is largely due to the effects of chemical weathering, which draws down higher free inventories more rapidly than the low. Thus, thick models have ?450 mbar carbonate reservoirs, while thin models have ?200 mbar. Though both thick and thin scenarios can reproduce the current atmospheric pressure, the thick models imply a relatively large current CO₂ ice cap and thin models, little or none. While the sublimation of a massive cap at a high obliquity would create a climate swing of greenhouse warming for thick models, under the thin model, mean temperatures and pressures would be essentially unaffected by increases in obliquity.  相似文献   

The Cosmology of Extra Dimensions and Varying Fundamental Constants     

Carlos J.A.P. Martins 《Astrophysics and Space Science》2003,283(4):439-444

I briefly present the Organizing Committee's and my own motivation for organizing this workshop, and I suggest a few key questions for which we will try to find possible answers in the coming days. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Constraints on a planetary origin for the gap in the protoplanetary disc of GM Aurigae   总被引：1，自引：0，他引：1  

W. K. M. Rice  Kenneth Wood  P. J. Armitage  B. A. Whitney  J. E. Bjorkman 《Monthly notices of the Royal Astronomical Society》2003,342(1):79-85

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Astrometric signatures of self-gravitating protoplanetary discs     

W. K. M. Rice  P. J. Armitage  M. R. Bate  I. A. Bonnell 《Monthly notices of the Royal Astronomical Society》2003,338(1):227-232

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Automated analysis of eclipsing binary light curves – II. Statistical analysis of OGLE LMC eclipsing binaries     

T. Mazeh  O. Tamuz  P. North 《Monthly notices of the Royal Astronomical Society》2006,367(4):1531-1542

In the first paper of this series, we presented EBAS – Eclipsing Binary Automated Solver, a new fully automated algorithm to analyse the light curves of eclipsing binaries, based on the ebop code. Here, we apply the new algorithm to the whole sample of 2580 binaries found in the Optical Gravitational Lensing Experiment (OGLE) Large Magellanic Cloud (LMC) photometric survey and derive the orbital elements for 1931 systems. To obtain the statistical properties of the short-period binaries of the LMC, we construct a well-defined subsample of 938 eclipsing binaries with main-sequence B-type primaries. Correcting for observational selection effects, we derive the distributions of the fractional radii of the two components and their sum, the brightness ratios and the periods of the short-period binaries. Somewhat surprisingly, the results are consistent with a flat distribution in log P between 2 and 10 d. We also estimate the total number of binaries in the LMC with the same characteristics, and not only the eclipsing binaries, to be about 5000. This figure leads us to suggest that  (0.7 ± 0.4)  per cent of the main-sequence B-type stars in the LMC are found in binaries with periods shorter than 10 d. This frequency is substantially smaller than the fraction of binaries found by small Galactic radial-velocity surveys of B stars. On the other hand, the binary frequency found by Hubble Space Telescope ( HST ) photometric searches within the late main-sequence stars of 47 Tuc is only slightly higher and still consistent with the frequency we deduced for the B stars in the LMC.  相似文献