Single-crystal X-ray diffraction study of cation distribution in MgAl<Subscript>2</Subscript>O<Subscript>4</Subscript>–MgFe<Subscript>2</Subscript>O<Subscript>4</Subscript> spinel solid solution     

A.?NakatsukaEmail author  H.?Ueno  N.?Nakayama  T.?Mizota  H.?Maekawa 《Physics and Chemistry of Minerals》2004,31(5):278-287

Synthesis experiments in the system MgAl₂O₄–MgFe₂O₄ [MgAl_2–xFe_xO₄ (0 x 2)] were carried out using a PbF₂ flux. The crystalline products synthesized in the compositional range of 0.6 <x 1.2 consisted of two spinel phases, whereas those synthesized in the compositional ranges of 0.0 x 0.6 and 1.2 < x 2.0 crystallized as single spinel phases. Structure refinements of the spinel single crystals, which grew in the ranges of 0.0 x 0.6 and 1.2 < x 2.0, show that the degree of randomness of cation distribution between A and B sites increases as x approaches the two-phase region. This means that the degree of the size mismatch among Mg²⁺, Fe³⁺ and Al³⁺occupying each equivalent mixing site increases as x approaches the two-phase region. Consequently, if the coexistence of two spinels observed in the intermediate compositions reveals the existence of a miscibility gap at low temperatures, this increase in the degree of the size mismatch among the three cations is suggested as a factor of energetic destabilization to form the miscibility gap.  相似文献   

Specific accumulation of persistent organochlorines in bluefin tuna collected from Japanese coastal waters     

Ueno D  Iwata H  Tanabe S  Ikeda K  Koyama J  Yamada H 《Marine pollution bulletin》2002,45(1-12):254-261

Concentrations of persistent organochlorines (OCs) such as PCBs, DDTs, chlordanes (CHLs), HCHs and HCB were determined in the liver of bluefin tuna (Thunnus thynnus) collected from Japanese coastal waters in order to elucidate accumulation profiles and to evaluate the suitability of this species as a biomonitor for pollution in the open sea ecosystem. Concentrations of PCBs, DDTs and CHLs in bluefin tuna increased significantly with body length (30–190 cm). HCHs and HCB residues were comparable among all the sampling regions, and the levels of these chemicals did not show correlation with body length. These results suggest significance of dietary uptake of PCBs, DDTs and CHLs compared to the intake via the gill. On the other hand, equilibrium partitioning with ambient water is a major determinant of the levels of HCHs and HCB in tuna. Body-length normalized values (BLNV) of PCBs, DDTs and CHLs concentrations in bluefin tuna were calculated using the linear regression equation obtained from the plot of concentrations and body length. BLNV of these chemicals on a lipid wt basis, which was adjusted for 100 cm body length, were indicative of the present state water pollution by PCBs, DDTs and CHLs. These results suggest that bluefin tuna is a suitable bioindicator for monitoring OCs contamination in the open sea ecosystem.  相似文献   

Carbon isotope chemostratigraphy of a Precambrian/Cambrian boundary section in the Three Gorge area, South China: Prominent global-scale isotope excursions just before the Cambrian Explosion     

Tomoko Ishikawa  Yuichiro Ueno  Tsuyoshi Komiya  Yusuke Sawaki  Jian Han  Degan Shu  Yong Li  Shigenori Maruyama  Naohiro Yoshida   《Gondwana Research》2008,14(1-2):193

Carbon isotope chemostratigraphy has been used for worldwide correlation of Precambrian/Cambrian (Pc/C) boundary sections, and has elucidated significant change of the carbon cycle during the rapid diversification of skeletal metazoa (i.e. the Cambrian Explosion). Nevertheless, the standard δ¹³C curve of the Early Cambrian has been poorly established mainly due to the lack of a continuous stratigraphic record. Here we report high-resolution δ¹³C chemostratigraphy of a drill core sample across the Pc/C boundary in the Three Gorge area, South China. This section extends from an uppermost Ediacaran dolostone (Dengying Fm.), through a lowermost Early Cambrian muddy limestone (Yanjiahe Fm.) to a middle Early Cambrian calcareous black shale (Shuijingtuo Fm.). As a result, we have identified two positive and two negative isotope excursions within this interval. Near the Pc/C boundary, the δ¹³C_carb increases moderately from 0 to + 2‰ (positive excursion 1: P1), and then drops dramatically down to − 7‰ (negative excursion 1: N1). Subsequently, the δ¹³C_carb increases continuously up to about + 5‰ at the upper part of the Nemakit–Daldynian stage. After this positive excursion, δ¹³C_carb sharply decreases down to about − 9‰ (N2) just below the basal Tommotian unconformity. These continuous patterns of the δ¹³C shift are irrespective of lithotype, suggesting a primary origin of the record. Moreover, the obtained δ¹³C profile, except for the sharp excursion N2, is comparable to records of other sections within and outside of the Yangtze Platform. Hence, we conclude that the general feature of our δ¹³C profile best represents the global change in seawater chemistry. The minimum δ¹³C of the N1 (− 7‰) is slightly lower than carbon input from the mantle, thus implying an enhanced flux of ¹³C-depleted carbon just across the Pc/C boundary. Hence, the ocean at that time probably became anoxic, which may have affected the survival of sessile or benthic Ediacaran biota. The subsequent δ¹³C rise up to + 5‰ (P2) indicates an increase of primary productivity or an enhanced rate of organic carbon burial, which should have resulted in lowering pCO₂ and following global cooling. This scenario accounts for the cause of the global-scale sea-level fall at the base of the Tommotian stage. The subsequent, very short-term, and exceptionally low δ¹³C (− 9‰) in N2 could have been associated with the release of methane from gas hydrates due to the sea-level fall. The inferred dramatic environmental changes (i.e., ocean anoxia, increasing productivity, global cooling and subsequent sea-level fall with methane release) appear to coincide with or occur just before the Cambrian Explosion. This may indicate synchronism between the environmental changes and rapid diversification of skeletal metazoa.  相似文献   

The X-ray spectrum and variability of the Seyfert 2 galaxy NGC 7172     

M. Guainazzi  G. Matt  L. A. Antonelli  F. Fiore  L. Piro  & S. Ueno 《Monthly notices of the Royal Astronomical Society》1998,298(3):824-830

We present evidence of flux variability, on both short (hours) and long (months) time-scales, of the Seyfert 2 galaxy NGC 7172. These results are based on the ASCA observation of NGC 7172 performed in 1996 May. The source was detected at a rather low flux level, about 3 times fainter than its usual state (including 1 yr before, when it was also observed by ASCA ).   The source also varied by about 30 per cent during the observation, confirming the presence of a type 1 nucleus in its centre. However, its spectrum appears to be flatter than the typical Seyfert 1 spectrum (in agreement with findings on other Seyfert 2s), posing problems for the unification model unless complex absorption is invoked.  相似文献   

A direct numerical approach to the Chandrasekhar'sH-functions for arbitrary characteristic functions     

Kiyoshi Kawabata  Takehiko Satoh  Sueo Ueno 《Astrophysics and Space Science》1991,182(2):249-260

The purpose of this paper is to present a numerical technique to directly compute the Chandrasekhar'sH ()-function for anisotropic scattering in terms of the roots of the characteristic equations as well as the quadrature points of a certain degreen employed to approximate the definite integral involved in the basic equation. The principal feature of the algorithm proposed here is a compact computer code to enumerate _n C _m combinations ofn distinct integers {1,...,n} takenm at a time. With these quantities available, the coefficients of the polynomial equation of the characteristics equation can be readily computed for any given characteristic function, so that a standard technique such as the Laguerre method can be applied to find all the roots.It is shown that the results obtained for some representativeH()-functions using the present technique with relatively low-order formula (e.g.,n=7) are sufficiently accurate for all practical purposes.  相似文献   

The 1957 great Aleutian earthquake     

Jean M. Johnson  Yuichiro Tanioka  Larry J. Ruff  Kenji Satake  Hiroo Kanamori  Lynn R. Sykes 《Pure and Applied Geophysics》1994,142(1):3-28

The 9 March 1957 Aleutian earthquake has been estimated as the third largest earthquake this century and has the longest aftershock zone of any earthquake ever recorded—1200 km. However, due to a lack of high-quality seismic data, the actual source parameters for this earthquake have been poorly determined. We have examined all the available waveform data to determine the seismic moment, rupture area, and slip distribution. These data include body, surface and tsunami waves. Using body waves, we have estimated the duration of significant moment release as 4 min. From surface wave analysis, we have determined that significant moment release occurred only in the western half of the aftershock zone and that the best estimate for the seismic moment is 50–100×10²⁰ Nm. Using the tsunami waveforms, we estimated the source area of the 1957 tsunami by backward propagation. The tsunami source area is smaller than the aftershock zone and is about 850 km long. This does not include the Unalaska Island area in the eastern end of the aftershock zone, making this area a possible seismic gap and a possible site of a future large or great earthquake. We also inverted the tsunami waveforms for the slip distribution. Slip on the 1957 rupture zone was highest in the western half near the epicenter. Little slip occurred in the eastern half. The moment is estimated as 88×10²⁰ Nm, orM _w =8.6, making it the seventh largest earthquake during the period 1900 to 1993. We also compare the 1957 earthquake to the 1986 Andreanof Islands earthquake, which occurred within a segment of the 1957 rupture area. The 1986 earthquake represents a rerupturing of the major 1957 asperity.  相似文献   

Gender differences in agricultural productivity: evidence from maize farm households in southern Ethiopia     

Gebre  Girma Gezimu  Isoda  Hiroshi  Rahut  Dil Bahadur  Amekawa  Yuichiro  Nomura  Hisako 《GeoJournal》2021,86(2):843-864

GeoJournal - This study examines the impact of gender differences on maize productivity in Dawuro Zone, southern Ethiopia. Our study addressed the limitations of the previous studies in two ways....  相似文献   

Subsurface hydrographic structures and the temporal variations of Aleutian eddies     

Rui Saito  Ichiro Yasuda  Kosei Komatsu  Hiromu Ishiyama  Hiromichi Ueno  Hiroji Onishi  Takeshi Setou  Manabu Shimizu 《Ocean Dynamics》2016,66(5):605-621

  相似文献   

GAME-TIBET青藏高原云和降水综合观测概况及初步结果   总被引：13，自引：7，他引：6  

刘黎平  楚荣忠  宋新民  周筠君  冯锦明  陈成品  张彤  S.Shimizu  K.Ueno  T.Koike  H.Fujii  H.Yamada  Y.Aoi  T.Ueno  J.Horikomi  M.Kajikawa  R Shirooka  J.Teshima 《高原气象》1999,18(3):441-450

对中日合作青藏高原能量水分循环试验项目中云和降水的多普勒雷达观测使用的气象观测仪器和获取的资料等情况进行了总结,并给出了那曲地区水的日变化,不同 雨量计测量降水的对比分析,风速对测量降水影响,多普勒雷达资料的个例分析及云的数值模拟的等初步结果。  相似文献   

Snow accumulation in forests from ground and remote‐sensing data     

Angela Lundberg  Yuichiro Nakai  Hans Thunehed  Sven Halldin 《水文研究》2004,18(10):1941-1955

Winter‐forest processes affect global and local climates. The interception‐sublimation fraction (F) of snowfall in forests is a substantial part of the winter water budget (up to 40%). Climate, weather‐forecast and hydrological modellers incorporate increasingly realistic surface schemes into their models, and algorithms describing snow accumulation and snow‐interception sublimation are now finding their way into these schemes. Spatially variable data for calibration and verification of wintertime dynamics therefore are needed for such modelling schemes. The value of F was determined from snow courses in open and forested areas in Hokkaido, Japan. The value of F was related to species and canopy‐structure measures such as closure, sky‐view fraction (SVF) and leaf‐area index (LAI). Forest structure was deduced from fish‐eye photographs. The value of F showed a strong linear correlation to structure: F = 0·44 ? 0·6 × SVF for SVF < 0·72 and F = 0 for SVF > 0·72, and F = 0·11 LAI. These relationships seemed valid for evergreen conifers, larch trees, alder, birch and mixed deciduous stands. Forest snow accumulation (S_F) could be estimated from snowfall in open fields (S_o) and to LAI according to S_F = S_o (1 ? 0·11 LAI) as well as from SVF according to S_F = S_o (0·56 + 0·6 SVF) for SVF < 0·72. The value of S_F was equal to S_o for SVF values above 0·72. The value of sky‐view fraction was correlated to the normalized difference snow index (NDSI) using a Landsat‐TM image for observation plots exceeding 1 ha. Variables F and S_F were related to NDSI for these plots according to: F = ?0·37NDSI + 0·29 and S_F = S_o (0·81 + 0·37NDSI). These relationships are somewhat hypothetical because plot‐size limitation only allowed one sparse‐forest observation of NDSI to be used. There is, therefore, a need to confirm these relationships with further studies. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献